LiF Thermoluminescence Research Articles

The effect of cooling rate on the precision of measurement of glow peak 5 in the thermoluminescence of LiF:Mg,Ti (TLD-100).

The effect of natural rapid cooling and oven slow cooling on the precision of thermoluminescence measurements of LiF:Mg,Ti is investigated. Three separate series of measurements resulted in average precisions of 5.1 and 5.0%, respectively. However, the highest precision of 1.7% (1SD) was achieved for an oven-cooled material.

Dose and secondary cancer-risk estimation of patients undergoing high dose rate intracavitary gynaecological brachytherapy

Dose and secondary cancer risk of the breast and thyroid during high dose rate (HDR) brachytherapy for 100 gynaecological cancer patients have been estimated. The organ doses were measured using LiF thermoluminescence dosimeters LiF (TLD-100). Patient demographic data (i.e. age and body mass index (BMI)) were also collected and analyzed. Statistical significance (p-value = 0.04; 0.01; 0.01) was observed for the correlation between age and breast dose; body mass index (BMI) and breast dose as well as BMI and thyroid dose. The average breast dose for cervical, vaginal and endometrial cancers were 7.44, 8.03 and 10.72 mGy, respectively. The average thyroid dose for cervical, vaginal and endometrial cancers were 2.32, 2.95 and 3.02 mGy, respectively. Excess absolute risk of the breast increased with attainable age and excess relative risk of the thyroid decreased with age at exposure. It is recommended to intensify post-treatment follow-ups and optimize the doses to the breast and thyroid.

MEASUREMENT OF ENTRANCE SKIN DOSE AND ABSORBED DOSE TO DIFFERENT ORGANS IN DUAL-ENERGY X-RAY ABSORPTIOMETRY SCANS USING THERMOLUMINESCENCE DOSIMETRY.

Thermoluminescence dosimetry is considered as an effective method in estimating the absorbed doses to organs in different imaging modalities. The present study focuses on dosimetry in dual-energy X-ray absorptiometry scans, for patients, and phantoms in various imaging centres. The cubical LiF (Mg, Ti) thermoluminescence dosemeters were inserted inside the holes of the Rando phantom slabs, to measure the absorbed dose to different organs in the whole body and lumbar scans. According to the results the maximum entrance skin dose was found to be 202.06μGy for Hologic discovery W, which uses the fan beam scanning mode. The Norland XR-800 device took the scans with a much lower dose, as it uses the pencil beam for scanning the patients. The results of the study show that the radiation beam type, patient thickness, imaging technique and scan time may affect the radiation dose received by patient.

Exposure Doses to Technologists Working in 7 PET/CT Departments.

Objective:The aim of this study was to measure occupational exposure doses of technologists who dispense and inject radiopharmaceuticals in 7 positron emission tomography/computed tomography (PET/CT) departments. This was done with the goal to help improving protective designs in PET departments and/or establishing national protection standards.Method:Common LiF thermoluminescence dosimeters (TLDs) were placed on the chest and necklace of the technologists to monitor whole-body and thyroid doses, respectively. Ring TLDs were also worn on both index fingers to measure individual hand doses. All TLDs were assembled and measured once every 3 months for a total of 12 months. Additionally, we measured and compared the dose of TLDs attached to both the inside and the outside of the technologist’s lead coat.Results:Technologists received relatively high exposures, which accounted for 64% to 94% of the collective dose in their respective departments. Their thyroid doses ranged from 1.2 to 1.7 mSv/a; some technologists’ hand doses exceeded 500 mSv/a. Use of a lead coat reduced the average dose by 8%.Conclusion:Technologists working in PET/CT departments were the main population exposed to radiation. This work underscores the need for enhanced protective measures for these workers to better reduce their exposure, particularly for their hands.

Comparison of optical absorption and thermoluminescence in LiF:Mg, TI (TLD-100) following irradiation by high energy protons and 90Sr/90Y beta rays

The optical absorption (OA) energy spectrum and thermoluminescence (TL) glow curve characteristics of LiF:Mg, Ti (TLD-100) samples following 90Sr/90Y beta ray irradiation and high energy proton irradiation are compared for the first time. The beta ray irradiations were carried at room temperature at a dose rate in LiF of approximately 0.13 Gy min−1. Proton irradiations were carried out at energies of 20 MeV, 40 MeV and 58 MeV with initial stopping powers of 5.5, 3.2 and 2.3 keV μm−1 respectively. Proton escaping the TL detectors had average energies 55.9, 37.1, 14.4 MeV and the corresponding stopping power in LiF 2.43, 3.36, 7.19 keV μm−1 respectively. All proton irradiations were carried out at a dose of 1124 Gy in LiF and the beta irradiations at a dose of 970 Gy in LIF. The OA spectra were deconvoluted with Gaussian Peak Shapes using a commercial “Peak-Fit” non-linear curve fitting program from Jandel Scientific. The Gaussian bands are characterized by the two parameters of band energy and width. The glow curves were deconvoluted using the Ben Gurion University mixed-order kinetics program. In the analysis first-order kinetics glow peak shapes were employed. The major difference between the two spectra is in the optical density of the F band at 5.08 eV; 0.17 compared to an average value of 0.33 following beta and proton irradiation respectively. The relative intensity, protons to betas, of the other OA bands are remarkably similar within the experimental errors and indicate that the traps associated with these OA bands are not created by the irradiation. It is demonstrated that proton irradiation of LiF:Mg, Ti (TLD-100) creates F centers with 75% greater efficiency than 90Sr/90Y beta particles. This finding lends further support to the conclusion that track structure theory is unable to accurately predict proton relative efficiencies in LiF:Mg, Ti The results are also interpreted in the framework the spatially correlated trapping center/luminescent center model for composite peak 5 in LiF:Mg,Ti.

A TLD-Microdosimeter for aerospace usage: Results relevant to airline pilots undertook long-haul intercontinental flights during March–May 2017

During high altitude long haul flights pilots, cabin crew and passengers are exposed to enhanced level of radiation originating from cosmic ray showers (CRS), produced via the interaction of very high-energy (~GeV) primary protons with the air molecules in Earth's atmosphere. The CRS are composed of energetic particles of diverse species, i.e. neutrons, protons, electrons, muons, pions and photons. Furthermore, the magnitude of aircrew radiation exposure depends on flight altitude and duration, geographical location (latitude), geomagnetic conditions and solar activity (modulation) status. In 1990 the International Commission on Radiological Protection (ICRP) classified airline crewmembers as “radiation workers”. A miniature passive microdosimeter (LiBe-14) based on LiF (TLD700) and Beryllium Oxide (BeO) thermoluminescence dosimeter chips emulating a large volume gas-filled Tissue Equivalent Proportional Counter (TEPC) was developed by one of the authors (BM). The LiBe-14 was deployed to assess the integrated ambient dose equivalent of two commercial pilots on long haul intercontinental flights during March–May 2017. The accumulated dose equivalents of 1st (38 y, Female, 148 total block hours) and 2nd (29 y, Male, 149 total block hours) pilots were evaluated to be 565 μSv ± 105 μSv and 738 μSv ± 137 μSv, respectively. The results agreed well within ±20% of simulated data evaluated using the well-known EPCARD (European Program Package for the Calculation of Aviation Route Doses) aviation dosimetry code. The implementation of LiBe-14 Microdosimeter in routine long haul, high-altitude commercial flights for the estimation of dose equivalent, average LET and quality factor relevant to impinging cosmic radiation is recommended.

A machine learning approach to glow curve analysis

We present a first study of using artificial neural networks to estimate the fading time and irradiation dose using glow curve data from LiF thermoluminescent (TL) dosemeters. The resulting uncertainties in the inference process are compared to those obtained in previous studies without machine learning algorithms. The current study is based on measurement and simulated data using an effective model of the kinetic parameters. We show that the resulting uncertainties of the estimated quantities can be significantly reduced with the machine learning algorithm applied: fading times of up to 30 days can be predicted with an uncertainty of up to 10%, irradiation doses larger than 1 mSv can be estimated with an uncertainty of up to 10% for batch-calibrated dosemeters.

Kinetic simulation of dose-rate effects in the irradiation stage of LiF:Mg,Ti (TLD-100): A model based on hole release via V3-Vk transformation – Implications to TL efficiency

The possibility of undiscovered dose-rate effects in the thermoluminescence (TL) of LiF:Mg,Ti (TLD-100) remains an open question. Previous experimental investigations are inconclusive and have been recently criticized. Earlier kinetic calculations have predicted the likelihood of dose-rate effects mainly based on competition between excitation and trapping rates. In this study we discuss the possibility of dose rate effects due to the likely dependence on dose-rate of V3 creation (a two hole center) and transformation to VK one hole centers via electron capture. Kinetic simulations demonstrate that such a dependence can lead to significant changes in the concentrations of the luminescent centers (LCs) following irradiation and consequently to expected changes in the TL response associated with these LCs. The simulations also predict changes in the concentration of the hole-only and electron-hole configurations of the spatially correlated trapping center-luminescent center giving rise to peaks 4 and 5a respectively in the glow curve of TLD-100. The results further emphasize the importance of highly controlled experimental studies.

OSL in NaCl vs. TL in LiF for absorbed dose measurements and radiation quality assessment in the photon energy range 20 keV to 1.3 MeV

The aim of this study was to determine the photon energy dependence of absorbed dose measurements, in a comparison of optically stimulated luminescence (OSL) in NaCl with thermoluminescence (TL) in LiF:Mg,Cu,P. The comparisons were made at exposure to ionizing radiation in the photon energy range 20 keV to 1.3 MeV. Specially designed dosemeter kits containing both NaCl and LiF were used under i) laboratory conditions using defined radiation fields, ii) laboratory conditions using sealed point sources mimicking unintentional exposures, and iii) field conditions in areas in Japan that were affected by the Fukushima Daiichi nuclear disaster in 2011. The dosemeter kits used in Japan showed that absorbed doses as low as 100 μGy can be assessed from the OSL signal in NaCl. The ratio of the dosemeter readings using OSL in NaCl and TL in LiF increases after irradiation at lower photon energies (less than a few hundred keV) as determined under laboratory conditions. Compensating for this energy dependence of the absorbed dose determinations obtained from OSL in NaCl would thus require an energy-dependent conversion factor for photon energies below 600 keV. On the other hand, the difference in the photon energy dependence between NaCl and LiF may be used to assess the mean effective energy of the photon field. The signal ratios between NaCl and LiF after exposure to radiation in the Fukushima Dashii contaminated areas in Japan, 1.67 ± 0.26 (2013) and 1.63 ± 0.32 (2015), indicate that the mean photon energy in this area was 300–400 keV during the years of the survey.

REVIEW OF DOSE-RATE EFFECTS IN THE THERMOLUMINESCENCE OF Lif:mg,ti (HARSHAW).

The literature describing the experimental investigations of possible dose-rate effects in the thermoluminescence (TL) of LiF:Mg,Ti (Harshaw) is reviewed. The total lack of glow curve analysis, coupled with inclusion of all or part of the high temperature TL and absence of parallel measurements of possible dose-rate effects in the irradiation stage severely limit the scientific and technical level of the experiments. In addition, the experimental procedures are far from sufficient to warrant any conclusion concerning the presence or absence of dose-rate effects in the TL of LiF:Mg,Ti. This decision is contrary to the widely held belief that there are no dose-rate effects in the TL of LiF:Mg,Ti. In addition, the literature on dose-rate effects in the optical absorption (irradiation stage) of LiF is reviewed and is found contradictory. No dose-rate studies have been carried out on optical absorption in LiF:Mg,Ti. Kinetic simulations demonstrating the possibility, even likelihood, of dose-rate effects are also reviewed. Dose-rate effects are shown to be likely due to competition between excitation and recombination in the irradiation stage. Some other possible mechanisms involving multiple charge carrier trapping are suggested. Further definitive experiments are sorely needed, but the interested researcher should beware, it is not an easy task.

Kinetic modeling of thermoluminescence, optical absorption and bleaching in LiF:Mg,Ti

In this paper we describe some aspects of our recent work which treats via kinetic simulations the experimentally observed linear/supralinear/saturating dose response of the thermoluminescence, optical absorption and behavior of optical bleaching at various photon energies in irradiated LiF:Mg,Ti (TLD-100) system in a physically realistic scenario. The results of the simulations are in good agreement with the experimental observations and this can be considered as a validation of the details of the proposed models.

Synthesis, thermoluminescence, defect center and dosimetric characteristics of LiF:Mg,Cu,P,Si phosphor

LiF:Mg,Cu,P,Si (MCPS), a new tissue equivalent phosphor, was synthesized by solid state method. Powder x-ray diffraction and scanning electron microscope were employed to determine the structural features. The dosimetric characteristics, electron spin resonance (ESR) and defect centers of this newly prepared phosphor were investigated. The MCPS phosphor is highly sensitive when compared with LiF:Mg,Ti and LiF:Mg,Cu,P (MCP), with the TL sensitivity being 35 times and 1.3 times higher respectively. The dosimetric peak occurs at 220°C with a well defined glow curve structure similar to MCP. MCPS phosphor shows a linear dose response till 10Gy. The minimum detectable dose has been found to be 8μGy. The thermal stability of the phosphor could be enhanced by 20°C from 240°C to 260°C when compared to MCP. Defect centers formed in the phosphor by gamma irradiation have been studied by ESR to identify the centers associated with the TL process in this phosphor. Thermal annealing experiments reveal the presence of several defect centers. Center I which shows an isotropic g factor of 2.0233 has been found to relate with the TL peaks at 160°C, 220°C and 265°C. Centers II and III are characterized by isotropic g values of 2.0096 and 2.0019 respectively and are attributed to F centers.

Whole-body dose and energy measurements in radiotherapy by a combination of LiF:Mg,Cu,P and LiF:Mg,Ti

PurposeLong-term survivors of cancer who were treated with radiotherapy are at risk of a radiation-induced tumor. Hence, it is important to model the out-of-field dose resulting from a cancer treatment. These models have to be verified with measurements, due to the small size, the high sensitivity to ionizing radiation and the tissue-equivalent composition, LiF thermoluminescence dosimeters (TLD) are well-suited for out-of-field dose measurements. However, the photon energy variation of the stray dose leads to systematic dose errors caused by the variation in response with radiation energy of the TLDs. We present a dosimeter which automatically corrects for the energy variation of the measured photons by combining LiF:Mg,Ti (TLD100) and LiF:Mg,Cu,P (TLD100H) chips. MethodsThe response with radiation energy of TLD100 and TLD100H compared to 60Co was taken from the literature. For the measurement, a TLD100H was placed on top of a TLD100 chip. The dose ratio between the TLD100 and TLD100H, combined with the ratio of the response curves was used to determine the mean energy. With the energy, the individual correction factors for TLD100 and TLD100H could be found. The accuracy in determining the in- and out-of-field dose for a nominal beam energy of 6MV using the double-TLD unit was evaluated by an end-to-end measurement. Furthermore, published Monte Carlo (M.C.) simulations of the mean photon energy for brachytherapy sources, stray radiation of a treatment machine and cone beam CT (CBCT) were compared to the measured mean energies. Finally, the photon energy distribution in an Alderson phantom was measured for different treatment techniques applied with a linear accelerator. Additionally, a treatment plan was measured with a cobalt machine combined with an MRI. ResultsFor external radiotherapy, the presented double-TLD unit showed a relative type A uncertainty in doses of −1%±2% at the two standard deviation level compared to an ionization chamber. The type A uncertainty in dose was in agreement with the theoretically calculated type B uncertainty. The measured energies for brachytherapy sources, stray radiation of a treatment machine and CBCT imaging were in agreement with M.C. simulations. A shift in energy with increasing distance to the isocenter was noticed for the various treatment plans measured with the Alderson phantom. The calculated type B uncertainties in energy were in line with the experimentally evaluated type A uncertainties. ConclusionThe double-TLD unit is able to predict the photon energy of scatter radiation in external radiotherapy, X-ray imagine and brachytherapy sources. For external radiotherapy, the individual energy correction factors enabled a more accurate dose determination compared to conventional TLD measurements.

Radiation damage and sensitization effects on thermoluminescence of LiF:Mg,Ti (TLD-700)

The radiation damage effects and enhancement the thermoluminescence (TL) efficiency of LiF:Mg,Ti (TLD-700)dosimeters via sensitization method were discussed. Attempts to eliminate the effects of damage and sensitization were made using different types of annealing processes. The results showed that after irradiating the dosimeters with dose>250Gy of 60Co gamma source, damage effects were observed. The sensitivity of the total area under the curve was decreased by a factor of ∼0.5 after irradiation at a pre-test dose of 2kGy. However, the effects of radiation damage on each glow-peak are different. The glow-peak 2 was the only peak that was not affected by the high-dose irradiation. It has been shown that the degree of the radiation damage effect is related to the maximum dose-response function, f(D)max of the glow-peak. In general, significant radiation damage effects were observed for the glow-peaks of high f(D)max. Post-irradiation anneal at 280°C for 30 min causes dramatic effects on the shape of the glow-curve and as well as on the sensitivity of the dosimeters. An increasing by a factor of ∼35 in the sensitivity of the total area under the curve was observed at a pre-test dose of 2kGy. Improving the sensitivity of peak 7 by a factor of∼22 was the dominant factor in increasing the sensitivity of the dosimeters. On the other hand, an increasing by factors of ∼2.5 and ∼4 was found for peaks 2 and 5 respectively. On the other hand, a decreasing by a factor ∼0.5 was observed for peaks 3 and 4. At pre-test dose levels >250Gy, a very strange and high intensity tail was observed in the high-temperature region of the glow-curves. The readout anneal was not enough to remove this tail. While, the furnace anneal could eliminate the sensitization effects but not the radiation damage effects on the sensitivity of the dosimeters.

Out-of-field in vivo dosimetry using TLD in SABR for primary kidney cancer involving mixed photon fields

PurposeTo assess out-of-field dose using three different variants of LiF thermoluminescence dosimeters (TLD) for ten patients who underwent stereotactic ablative body radiotherapy (SABR) for primary renal cell carcinoma (RCC) and compare with treatment planning system (TPS) dose calculations. Methods and materialsThermoluminescent dosimeter (TLD) measurements were conducted at 20, 30, 40 and 50cm from isocentre on ten patients undergoing SABR for primary RCC. Three types of high-sensitivity LiF:Mg,Cu,P TLD material with different 6Li/7Li isotope ratios were used. Patient plans were calculated using Eclipse Anisotropic Analytical Algorithm (AAA) for clinical evaluation and recalculated using Pencil Beam Convolution (PBC) algorithm for comparison. ResultsBoth AAA and PBC showed diminished accuracy for photon doses at increasing distance out-of-field. At 50cm, measured photon dose was 0.3cGy normalised to a 10Gy prescription on average with only small variation across all patients. This is likely due to the leakage component of the out-of-field dose. The 6Li-enriched TLD materials showed increased signal attributable to additional neutron contribution. ConclusionLiF:Mg,Cu,P TLD containing 6Li is sensitive enough to measure out-of-field dose 50cm from isocentre however will over-estimate the photon component of out-of-field dose in high energy treatments due to the presence of thermal neutrons. 7Li enriched materials which are insensitive to neutrons are therefore required for accurate photon dosimetry. Neutron signal has been shown here to increase with MUs and is higher for patients treated using certain non coplanar beam arrangements. Further work is required to convert this additional neutron signal to dose.

Study of the effect of optical bleaching at selected photon energies on the optical absorption and thermoluminescence of LiF: Mg, Ti (TLD-100)

A new interpretation of the optical absorption energy spectrum of LiF:Mg,Ti (TLD-100) is presented in which the 4.0 eV band is composed of two-sub-bands at 3.84 eV and 4.3 eV. The new interpretation is of central importance in the understanding of the geminate recombination mechanisms giving rise to glow peak 4 and composite glow peak 5 in the thermoluminescence (TL) of TLD-100. Photon bleaches at energies of 3.6 eV and 4.2 eV on samples of gamma irradiated TLD-100 were carried out in order to investigate the correlation of the 4.3 eV absorption band with the electron-hole configuration giving rise to glow peak 5a and the 3.84 eV absorption band with the e-only configuration giving rise to glow peak 5. The increase in peak 4 (correlated with the hole-only configuration) induced by the 4.2 eV bleach is enhanced by 90% over the increase induced by the 3.6 eV bleach. The decrease in peaks 5a and 5 induced by the 4.2 eV bleach are enhanced by 400% and 50% respectively over the 3.6 eV bleach. The results are consistent with the suggested structures giving rise to the 4.3 eV and 3.84 eV bands observed in the optical absorption energy spectrum.

Effect of dopants’ concentration on high-dose high-temperature thermoluminescence of LiF:Mg,Cu,P detectors: Mg and Cu influence

In search of origin and mechanism of the high-dose high-temperature TL emission with presence of the peak ‘B’ about thirty batches of LiF:Mg,Cu,P detectors with different dopants' concentration were produced and comprehensive studies of their high-dose TL features have been performed. Within each step of the research, these characteristics were compared with the high-dose TL properties of the typical MCP-N detectors' batch highly exposed simultaneously with the detectors from batches of varying dopants concentration. We determined the effect of concentration of specific dopants on the TL peak ‘B’. It was found that both magnesium and copper are necessary to obtain high-dose TL signal, however, the important for high-dose TL features seems to be also concentration of phosphorus. In the framework of this study we present results of magnesium and copper concentration changes to the TL signal after high-doses of electron radiation.

Activation of hip prostheses in high energy radiotherapy and resultant dose to nearby tissue.

High energy radiotherapy can produce contaminant neutrons through the photonuclear effect. Patients receiving external beam radiation therapy to the pelvis may have high‐density hip prostheses. Metallic materials such as those in hip prostheses, often have high cross‐sections for neutron interaction. In this study, Thackray (UK) prosthetic hips have been irradiated by 18 MV radiotherapy beams to evaluate the additional dose to patients from the activation products. Hips were irradiated in‐ and out‐of field at various distances from the beam isocenter to assess activation caused in‐field by photo‐activation, and neutron activation which occurs both in and out‐of‐field. NaI(Tl) scintillator detectors were used to measure the subsequent gamma‐ray emissions and their half‐lives. High sensitivity Mg, Cu, P doped LiF thermoluminescence dosimeter chips (TLD‐100H) were used to measure the subsequent dose at the surface of a prosthesis over the 12 h following an in‐field irradiation of 10,000 MU to a hip prosthesis located at the beam isocenter in a water phantom. 53Fe, 56Mn, and 52V were identified within the hip following irradiation by radiotherapy beams. The dose measured at the surface of a prosthesis following irradiation in a water phantom was 0.20 mGy over 12 h. The dose at the surface of prostheses irradiated to 200 MU was below the limit of detection (0.05 mGy) of the TLD100H. Prosthetic hips are activated by incident photons and neutrons in high energy radiotherapy, however, the dose resulting from activation is very small.

The effect of optical bleaching at selected photon energies on the thermoluminescence of LiF:Mg,Ti

A new interpretation of the optical absorption energy spectrum of LiF:Mg,Ti (TLD-100) is presented in which the 4.0 eV band is composed of two-sub-bands at 3.8 eV and 4.3 eV. The new interpretation is of central importance in the understanding of the geminate recombination mechanisms giving rise to composite glow peak 5 in the thermoluminescence (TL) of TLD-100. Photon bleaches at energies of 3.6 eV and 4.3 eV on samples of gamma irradiated TLD-100 were carried out in order to investigate the correlation of the 4.3 eV absorption band with the electron-hole configuration giving rise to glow peak 5a and the 3.8 eV absorption band with the e-only configuration giving rise to glow peak 5. The 4.3 eV bleach decreases peak 5a dramatically and increases peak 4 (a hole-only configuration). No such effect is observed following the 3.6 eV bleach. The results strongly support the suggested structures giving rise to the 4.3 eV and 3.8 eV bands observed in the optical absorption energy spectrum.

Preparation, thermoluminescence and photoluminescence properties of LiF:Mg,Cu,B phosphor

This paper presents the thermoluminescence (TL), TL emission and photoluminescence (PL) properties of LiF:Mg,Cu,B (MCB) phosphor synthesized by a solid state method. The structural and morphological property was characterized by X-ray Diffraction technique and high resolution scanning electron microscope. The intensity of main dosimetric peak in MCB phosphor increases with increase in boron concentration and reaches maximum at 1.92 mol% and then decreases. Its main dosimetric peak appears at 218°C with the linear heating rate of 2°C/s. MCB phosphor is 12 times more sensitive than LiF:Mg,Ti and about 1.9 times less sensitive than LiF:Mg,Cu,P phosphor. A noteworthy feature is that this phosphor exhibits a linear TL dose response up to 100Gy and then it becomes sublinear. MCB exhibits a residual signal of about 1.1%, which is very much lower compared to GR-200P. The TL emission spectra was recorded at various temperatures and analyzed. PL study shows the formation of various color centers like F2 and F3+ center in the irradiated phosphor. By combining TL emission and PL study the mechanism for observation of TL has been proposed.