Saturated fluorocarbons (SFCs) of the form CnF(2n+2) are chosen for their optical properties (high transparency in the near UV, adapted refractive index and low chromatic dispersion over wavelength ranges of interest) for use as Cherenkov radiators. The COMPASS and LHCb experiments currently use C4F10 and CF4 gas radiators. SFCs have high Global Warming Potentials (GWPs), however (in the range 5000–9000). There is thus an impetus to reduce their use and wastage through leaks in existing installations.Newer fluids of the form CnF2nO, including the 3M NOVEC® range, can offer similar optical performance to SFCs of the same order, n, but with GWPs equivalent to CO2. These GWPs are, however, geometry-specific: closed molecular rings having an oxygen atom as a link can have GWPs as high as those of SFCs, and should be avoided.While the optical constraints of RICH detectors can motivate a “special case” argument to retain the use of preferred SFCs, legislation and external market forces will limit their future availability, leaving “holes” in the CnFx spectrum that might not be filled by NOVEC equivalents. This situation might require the blending of low molar concentrations of heritage-stock higher-order SFCs and NOVEC vapours with transparent light gases such as nitrogen, and is the subject of this paper.While continuous optical measurement of refractive index in dynamically changing gas mixtures is very demanding, the monitoring of sound velocity has been historically shown to provide simple, reliable and continuous real time mixture information. Indeed the speed of sound is, in itself, a monitor of the speed of light and the Cherenkov threshold in a gas radiator.This ultrasonic (“sonar”) technique was first used for controlling the real-time blending C5F12 with N2 in the SLD CRID at the SLAC linear collider. The technique could become important again in future operation to meet the optical and low GWP constraints of future Cherenkov gas radiators. Some examples are explored in this paper.
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