Aerosol Concentration Levels Research Articles

Dust episodes in Hong Kong (South China) and their relationship with the Sharav and Mongolian cyclones and jet streams

The study presented in this paper analyses two dust episodes in Hong Kong, one occurring in March 2006 and the other on 22 March 2010. The latter is the worst dust episode on Hong Kong record. The focus is on the relationship between the dust episodes and the Sharav/Mongolian cyclones and jet streams. The 16 March 2006 episode is traceable to a continental-scale Saharan dust outbreak of 5–9 March 2006 caused by the cold front of an East Mediterranean Sharav cyclone arriving at north-west Africa on 5 March 2006. The eastward movement of the cyclone along the North African coast is clearly illustrated in the geopotential height contours. Simulations by the chemistry transport model GOCART provide a visible evidence of the transport as well as an estimate of contributions from the Sahara to the aerosol concentration levels in Hong Kong. The transport simulations suggest that the dust is injected to the polar jet north of the Caspian Sea, while it is transported eastward simultaneously by the more southerly subtropical jet. The major source of dust for Hong Kong is usually the Gobi desert. Despite the effect of remote sources, the 16 March 2006 dust episode was still mainly under the influence of the Mongolian cyclone cold fronts. In the recent episode of 22 March 2010, the influence of the Mongolian cyclone predominated as well. It appears that the concurrent influence of the Sharav and Mongolian cyclones on Hong Kong and East Asia is not a common occurrence. Besides transporting dusts from non-East Asian sources to Hong Kong and East Asia, the strong subtropical jet on 21 March 2010 (i.e. 1 day prior to the major dust episode) is believed to have strengthened an easterly monsoon surge to South China causing the transport of voluminous dusts to Taiwan and Hong Kong the following day.

Microbeam analysis of individual particles in indoor working environment

AbstractIn machine workshops and laboratories, specific materials and chemicals are processed and toxic aerosols may be released into air. For protection of the health of employees working in that environment, it is therefore important to gather knowledge about aerosol composition related to specific working activity and to monitor the aerosol concentration levels. An extensive study of this kind was performed in the machine workshop of Jožef Stefan Institute using a combination of time‐, particle size‐ and location‐resolved sampling. The majority of samples were analyzed by particle induced X‐ray emission (PIXE) and energy dispersive X‐ray spectrometry (EDX) techniques and the main results have been described in a separate paper. Here, we concentrate on presenting the results of individual particle analysis of an aerosol emission that is related to a short, unexpected episode related to the restoration of old furniture. Although the activity was identified by a strong correlation of elemental concentrations in a series of samples taken with a 2‐h time resolution, the single microparticle analysis of the cascade impactor samples taken over the longer time period offered an additional insight into the corresponding aerosol composition. The analysis of the aerosol size‐selected samples revealed strong pair correlations among concentration levels of Ba, Zn, S, Pb and Cl in a number of individual microparticles. The result is explained by the emission of Ba‐ and Pb‐rich aerosol particles in course of removal of the old white paint layers. The former particles appear to originate from white pigment called lithopone, which is a mixture of BaSO4 and ZnS, and the latter group seems to be related to Pattinson's white lead PbCl·OH. Although the individual particle analysis by itself is in principle capable of assigning the emission source, in this case, it was used as an excellent tool to enhance the quality of source characterization. Copyright © 2011 John Wiley & Sons, Ltd.

Dispersion of Legionella-containing aerosols from a biological treatment plant Norway

Legionella was detected in aeration ponds (biological treatment plant) at Borregaard Ind. Ltd., Norway, and in air samples harvested directly above these ponds. Since 2005, three outbreaks of legionellosis occurred within a 10 km radius from this plant. This work addresses the dispersion patterns of Legionella-containing particles by characterizing the aerosol plume emitted from these ponds (outbreak source) less than 500 meters using wind-tunnel measurements, CFD simulations, and real-life measurements. The most abundant particles directly over the ponds were less than 6 and more than 15 microm. The results showed that the aerosol plume remained narrow; 180 meters wide at 350 meters downwind of the ponds, and that 2 and 18 microm aerosols were mainly deposited in the vicinity of the ponds ( 150 - 200 meters). Furthermore, the maximum aerosol concentration level appeared 5-10 meters above ground level and the maximum concentration 500 meters downwind was approximately 2 per cent of the concentration level directly above the ponds. Our study demonstrates the strength of combining modeling with real-life aerosol analyses increasing the understanding of dispersion of airborne (pathogenic) microorganisms.

Integration of high volume portable aerosol-to-hydrosol sampling and qPCR in monitoring bioaerosols

In this study, the integration of a high volume, portable aerosol-to-hydrosol sampling technique and quantitative polymerase chain reaction (qPCR) was investigated for bioaerosol monitoring by adapting the RCS High Flow to sample air with mineral-oil-strips. Bacillus subtilis var niger and Pseudomonas fluorescens were aerosolized and collected by the RCS High Flow loaded with mineral-oil-strips for 1, 2 and 5 min. In addition, the adapted aerosol-to-hydrosol sampler was also tested for sampling environmental bacterial aerosols in four different environments (a back yard, a student dorm, a dining hall, and a play ground). The performances of the RCS High Flow with mineral-oil-strips were compared with the use of agar strips under similar conditions in all experiments. Air samples collected by the RCS High Flow were cultured, and in addition those collected with mineral-oil-strips were also quantified using qPCR. When sampling B. subtilis var niger aerosols, the use of mineral-oil-strips was shown to report significantly higher culturable concentrations than those obtained by agar strips regardless of the sampling time tested (p-value = 0.04). In contrast, the differences between the two methods when sampling P. fluorescens aerosols were not statistically significant (p-value = 0.5). When coupled with qPCR, the RCS High Flow loaded with mineral-oil-strips obtained significantly higher bacterial aerosol concentrations than those detected by the culturing method. The sampling time was observed to have negligible effects on the efficiency of the technology developed here. When sampling in different environments, the use of mineral-oil-strip was observed to yield significantly higher, about 4-12 times, culturable bacterial aerosol concentration levels compared to the use of agar. This study demonstrated a high volume (100 L min⁻¹) portable aerosol-to-hydrosol sampling technique, holding broad promise in monitoring airborne biological threats when coupled with qPCR technology. Yet, caution should be taken in relating the bioaerosol concentrations to health risks as qPCR detects both culturable and non-culturable cells including inactivated ones.

Nano- and Micropowder Laser Multy Wavelengths Sensing and Aerodynamic Classification

Industrial aerodisperse flows were characterized by significant aerosol polydisperse and concentration level. Thus particle concentration and size distribution have the information about the corresponding technological process condition. The aerosol parameters studies in the different places of the aerodisperse flow allows us to fulfill the optimal monitoring method choosing of these parameters in real time for the cement production. The particle size spectrum transformation analysis in the aerodynamic qualifiers in the real industrial flow of the cement aerosol particles has shown the opportunity of the aerosol dispersive control in the real time by the spectral transparency at the number of the wavelengths method.

Personalized ventilation as a control measure for airborne transmissible disease spread.

The protective role of personalized ventilation (PV) against plausible airborne transmissible disease was investigated using cough droplets released from a 'coughing machine' simulating the human cough at different distances (1, 1.75 and 3 m) from the PV user. Particle image velocimetry was used to characterize and visualize the interaction between the cough-generated multiphase flow and PV-induced flow in the inhalation zone of the thermal breathing manikin. A dose-response model for unsteady imperfectly mixed environment was used to estimate the reduction in infection risk of two common diseases that can be transmitted by airborne mode. PV was able to both reduce the peak aerosol concentration levels and shorten the exposure time at all the examined injection distances. PV could reduce the infection risks of two diseases, influenza A and tuberculosis, by between 27 and 65 per cent. The protection offered by PV is less effective at a distance of 1.75 m than the other distances, as shown in the risk assessment results, as the PV-generated flow was blown off by the cough-generated flow for the longest time. Results of this study demonstrate the ability of desktop PV to mitigate the infection risk of airborne transmissible disease.

Humidity impact on the aerosol effect in warm cumulus clouds

The effects of aerosols on clouds are recognized as among the most important factors affecting climate change yet these effects are poorly understood due to the complexity of cloud processes and the strong influence of other environmental conditions. A numerical cloud model is used here to study the combined influence of aerosol concentration and upper level humidity conditions on moderate‐sized, coastal, convective clouds. We show that these variables are strongly linked in their effects on clouds and suggest a microphysical variable space in which their influence can be distinguished.

Size distribution and emission rate measurement of fine and ultrafine particle from indoor human activities

Human indoor activities generate airborne particles which contribute to the increase of aerosol concentration levels in the home. The particle size distribution emission rate was measured for 18 different activities (burning candle or incense, cooking, spray use, computer printing and household cleaning). The particle emission rate was calculated from concentration measurements with a DMS500 (CAMBUSTION) in an experimental chamber (2.36 ± 0.05 m 3). The results showed that ultrafine particles are emitted during these activities and the lowest number distribution mode was 6 nm for one of the burning candles. All the cooking activities had similar emissions with a mode between 20 and 40 nm. The measured size distributions were represented in a database by the sum of 1, 2 or 3 lognormal distributions. The measured total emission rate ranged between 0.06 × 10 10 and 13.10 × 10 10 s −1 and the highest emission rate was measured for the self cleaning oven program (pyrolysis).

PM10 and PM2.5 Levels in the Eastern Mediterranean (Akrotiri Research Station, Crete, Greece)

Particulate matter measurements (PM10, PM2.5) using a beta radiation attenuation monitor were performed at the Akrotiri research station (May 2003–March 2006) on the island of Crete (Greece). The mean PM10 concentration during the measuring period (05/02/03–03/09/04) was equal to 35.0 ± 17.7 μg/m3 whereas the mean PM2.5 concentration (03/10/04–04/02/06) was equal to 25.4 ± 16.5 μg/m3. The aerosol concentration at the Akrotiri station shows a large variability during the year. Mean concentrations of particulate matter undergo a seasonal change characterised by higher concentrations during summer [PM10, 38.7 ± 10.8 μg/m3 (2003); PM2.5, 27.9 ± 8.7 μg/m3 (2004) and 27.8 ± 9.7 μg/m3 (2005)] and lower concentrations during winter [PM10, 28.7 ± 22.5 μg/m3 (2003/2004); PM2.5, 21.0 ± 13.0 μg/m3 (2004/2005) and 21.4 ± 21.9 μg/m3 (2005/2006)]. Comparative measurements of the PM10 concentration between the beta radiation attenuation monitor, a standardized low volume gravimetric reference sampler and a low volume sequential particulate sampler showed that PM10 concentrations measured by the beta radiation attenuation monitor were higher than values given by the gravimetric samplers (mean ratio 1.17 ± 0.11 and 1.21 ± 0.08, respectively). Statistical and back trajectory analysis showed that elevated PM concentrations (PM10, 93.8 ± 49.1 μg/m3; PM2.5: 102.9 ± 59.9 μg/m3) are associated to desert dust events. In addition regional transport contributes significantly to the aerosol concentration levels whereas low aerosol concentrations were observed during storm episodes.

Pan‐Arctic enhancements of light absorbing aerosol concentrations due to North American boreal forest fires during summer 2004

During summer of 2004, about 2.7 million hectare of boreal forest burned in Alaska, the largest annual area burned on record, and another 3.1 million hectare burned in Canada. This study explores the impact of emissions from these fires on light absorbing aerosol concentration levels, aerosol optical depths (AOD), and albedo at the Arctic stations Barrow (Alaska), Alert (Canada), Summit (Greenland), and Zeppelin/Ny Ålesund on Spitsbergen (Norway). The Lagrangian particle dispersion model FLEXPART was run backward from these sites to identify periods that were influenced by forest fire pollution plumes. It is shown that the fires led to enhanced values of particle light absorption coefficients (σap) at all of these sites. Barrow, about 1000 km away from the fires, was affected by several fire pollution plumes, one leading to spectacularly high 3‐hour mean σap values of up to 32 Mm−1, more than the highest values measured in Arctic Haze. AOD measurements for a wavelength of 500 nm saturated but were estimated at above 4–5 units, unprecedented in the station records. Fire plumes were transported through the atmospheric column over Summit continuously for 2 months, during which all measured AOD values were enhanced, with maxima up to 0.4–0.5 units. Equivalent black carbon concentrations at the surface at Summit were up to 600 ng m−3 during two major episodes, and Alert saw at least one event with enhanced σap values. FLEXPART results show that Zeppelin was located in a relatively unaffected part of the Arctic. Nevertheless, there was a 4‐day period with daily mean σap > 0.3 Mm−1, the strongest episode of the summer half year, and enhanced AOD values. Elevated concentrations of the highly source‐specific compound levoglucosan positively confirmed that biomass burning was the source of the aerosols at Zeppelin. In summary, this paper shows that boreal forest fires can lead to elevated concentrations of light absorbing aerosols throughout the entire Arctic. Enhanced AOD values suggest a substantial impact of these plumes on radiation transmission in the Arctic atmosphere. During the passage of the largest fire plume, a pronounced drop of the albedo of the snow was observed at Summit. We suggest that this is due to the deposition of light absorbing particles on the snow, with further potentially important consequences for the Arctic radiation budget.

Atmospheric aerosol concentration level and chemical characteristics of water-soluble ionic species in wintertime in Beijing, China.

Total suspended particulate (TSP) samples were collected during wintertime from November 24, 1998 to February 12, 1999 in Beijing. Ionic species including Cl-, NO3(-), SO4(2-), Na+, NH4(+), K+, Mg2+ and Ca2+ were determined by Ion Chromatography (IC). The sum average concentration of all the determined ions accounted for 18.9% of the TSP concentration, and SO4(2-) appeared the dominant ion with an average concentration of 30.84 microg m(-3); the sum mass concentration of SO4(2-), NO3(-), Ca2+ and NH4(+) accounted for about 83.2% of all the eight ions measured. The study indicated that the chemical form of sulfate and ammonium varies with TSP concentration levels. During heavy pollution periods, the average TSP concentration was 0.66 mg m(-3), and the NH4(+)/SO4(2-) molar ratio was low (0.58). It indicated that sulfate may present as CaSO4 and (NH4)2SO4 x CaSO4 x 2H2O. When TSP concentration (average 0.186 mg m(-3)) was relatively low, the NH4(+)/SO4(2-) molar ratio was 1.94, close to the theoretical ratio of 2 of (NH4)2SO4. Under this condition (NH4)2SO4 is expected to exist as the major form of sulfate. When the TSP concentration level was medium (average 0.35 mg m(-3)), the NH4+/SO4(2-) molar ratio appeared an average value (1.27), (NH4)2SO4, (NH4)2SO4 x CaSO4 x 2H2O and CaSO4 are expected to be present in those aerosol particles. Meteorological conditions including wind speed and wind direction were related to the TSP concentration level.

Photometer response determination based on aerosol physical characteristics.

Aerosol photometers often are calibrated against field measurements of total or respirable aerosol concentrations. However, the response of these instruments to a particular aerosol concentration level will change if there is a change in aerosol size distribution. To determine a predictable correction factor that relates photometer to gravimetric measurements of an aerosol, the authors performed an analysis of photometer response relative to particle size distribution, density, and refractive index. A series of trials was performed at different concentration levels using both Arizona road dust and ground corn dust. The correction factor was calculated from a knowledge of the instrument response pattern relative to particle size, as well as the ratios of actual dust density and refractive index relative to that of the dust used to calibrate the instruments. Results demonstrated that the calculated correction factors were within 10% of a correction factor predicted from the slope of a linear regression relating gravimetric measurements to the average of photometer readings taken during the sample period.

Diesel Exhaust Aerosol: Review of Occupational Exposure

Abstract The U.S. Bureau of Mines and others have conducted a number of occupational exposure surveys since the publication of the International Agency for Research on Cancer report of 1989, which labeled diesel exhaust as a probable human carcinogen. These surveys have assessed diesel exhaust exposure using measurements of diesel aerosol and/or specific polycyclic aromatic hydrocarbons as indicators of exposure. This article reviews present diesel emission standards, available diesel exhaust aerosol measurement techniques, and the results of the occupational exposure surveys. In the surveys, diesel aerosol was emphasized because it is a major component of diesel exhaust, is suspected to contribute to the health hazard, and is readily measurable. Three primary aerosol measurement techniques were used: respirable combustible dust, size-selective sampling, and measurement of the elemental carbon fraction. Occupations surveyed included mine workers, railroad workers, forklift operators, fire fighters, and truck drivers. The studies found mean diesel aerosol concentration levels in the range of 0.004 to 1.74 mg/m3. The highest aerosol exposures were in confined spaces such as mines where heavy diesel equipment is used. Polycyclic aromatic hydrocarbons typically are found at very low concentration levels and are not unique to diesel exhaust.

Comparing the calculated and measured aerosol concentrations and depositions around a metallurgical plant

The aerosol concentration and deposition around a metallurgical plant have been analysed. Measurements were carried out continuously over 14 months in order to obtain reliable data on the emissions, the local meteorological conditions and the ambient aerosol concentration and deposition levels. A bi-Gaussian dispersion model with source depletion has been used for the simulation of the aerosol concentration and deposition. The accuracy of the calculated short-term concentrations was better than 40 % while for the average depositions it was better than 60%. The dominating role of the fugitive compared with stack emissions was emphasized and the inevitable inaccuracies in the simulation of these sources were demonstrated. The fall-out velocity for the ISO deposit gauge was experimentally determined and interpreted with respect to the sampling conditions. Air concentrations were shown to be not very sensitive to the deposition velocity and plume rise up to the maximum sampling distance 4 km.

The Behavior of Constant Rate Aerosol Reactors

An aerosol reactor is a gaseous system in which fine particles are formed by chemical reaction in either a batch or flow process. The particle sizes of interest range from less than 10 Å (molecular clusters) to 10μm. Such reactors may be operated to study the aerosol formation process, as in a smog reactor, or to generate a product such as a pigment or a catalytic aerosol. Aerosol reactors can be characterized by three temporal or spatial zones or regions of operation for batch and flow reactors, respectively. In zone I, chemical reaction results in the formation of condensable molecular products which nucleate and form very high concentrations of small particles. The number density depends on the concentration of preexisting aerosol. Zone II is a transition region in which the aerosol number concentration levels off as a result of hetergeneous condensation by the stable aerosol. In zone III coagulation becomes sufficiently rapid to reduce the particle number concentration. There may be a zone IV in which agglomerates form. Chemical reaction may continue to generate condensable material throughout the various zones. This paper deals with reactors in which aerosol material is generated at a constant rate. Design parameters of interest are the particle size distribution, number density, surface area, and mass loadings. For ideal systems composed of spherical coalescing particles, these can be predicted theoretically for certain limiting cases. However, the irregular agglomerates which may form in zone IV are more difficult to characterize theoretically.

Stratospheric Aerosol Measurements with Implications for Global Climate

In this paper we present measurement results obtained in New Mexico with bistatic optical probing of the atmosphere using a searchlight beam. The data yield vertical profiles of the aerosol attenuation coefficient. Because they approximate proportionality to aerosol concentration, these profiles provide information concerning the aerosol layer structure and its parameters. During a 9-day period in October and November 1970, a series of forty-one such profiles was obtained which includes altitudes 12-25 km, selected for study because of the relatively high aerosol content of this stratospheric region and its relation to global climate. The mean stratospheric aerosol distribution for this period is double layered with maxima at 15.6 km and 19.3 km. An early phase of volcanic dust incursion is examined. A chronology of stratospheric aerosol concentration levels is developed based on measurements with the same instrumentation at the same sites since February 1963. The chronology shows that the particulate background level of a nonvolcanic, nonpolluted stratosphere is represented by an aerosol optical thickness Tau(p)(O.55 micro) = 2.0 x 10(-2). A calculation with this background level is included, which indicates feasibility of a laser-satellite method for acquiring data related to global climate. The Appendix introduces an original method of numerical integration (used in the calculations), which is suited to radiative transfer studies.