During the Leonid meteor shower on 18 November 1999, the five spectrographic imagers onboard the Midcourse Space Experiment (MSX) satellite recorded the first complete meteor spectra from 110 to 860 nm. The observation occurred at 00:23:36.2 UT, at which time the satellite was pointed at a tangent altitude of 100 km over 37.2°N and 78.2°E. The spectrograph slits were oriented approximately parallel to the horizon at a tangent altitude of 100 km, and the meteor passed approximately perpendicular through the slits’ fields of view. All five spectrographic imagers observed the passage of a bright object ( m v < −2.8 at 100 km) and each recorded several frames of data. In the visible, common meteor emissions were observed from iron, sodium, and oxygen. However, the ultraviolet spectrum displayed a wealth of more intense features, some of which actually caused saturation in the spectrographs. The most intense features appeared between 220 and 300 nm and are attributed to neutral and singly ionized iron and ionized magnesium. Some unknown emissions, possibly from an unidentified molecular species such as iron oxide, appear between 180 and 220 nm. In the far ultraviolet from 110 to 130 nm, oxygen and nitrogen features appear in the spectrum, with some features from ionized iron and magnesium. In particular, the FUV spectrum showed an intense emission from hydrogen Lyman alpha and a much weaker emission from what appeared to be neutral carbon. The atmospheric emissions can be associated with the heating within the meteor shock, while the metallic emissions originate from the fireball of the meteor proper. The ultraviolet emissions were much stronger than those in the visible and near-infrared parts of the spectrum. The energy of emissions in the ultraviolet (110 < λ < 337 nm) exceeded the energy of the visible (337 < λ < 650 nm) by a factor of at least 5.