Yarn-shaped energy-storage devices (YSEs), including supercapacitors and batteries, are becoming promising energy-supply units with decent mechanical flexibility to be integrated into e-textiles, in various shapes and locations with the possibility of hiding among regular textile yarns without being noticed or detected. However, a robust YSE configuration, which can provide long-term and reliable power output after rigorous weaving/knitting processes and upon all kinds of end-use scenarios, is yet to be established. Most YSEs today still suffer from performance decay and short-circuiting risks, primarily due to structural failures of active materials involved. Moreover, a prominent length-dependent output has been observed in many YSE samples, which exhibit a plateaued capacitance/capacity at extended yarn lengths. In this talk, we will give an overview of existing issues of the state-of-the-art YSEs, and their possible solutions or mitigation strategies. In detail, we will discuss the incorporation of separator threads in a twisted YSE, to withstand repetitive mechanical deformations. A detailed mathematical model for YSEs will also be discussed to clarify the length dependence of their performances. REFERENCES He, X. Zhang, J. Song, F. Zhao, W. Gao*, Modeling of yarn-shaped supercapacitors – Unraveling its length dependent output, Journal of Power Sources, 2024, 595, 234067He, J. Song, J. Liao, F. Zhao, W. Gao*, Separator Threads in Yarn-Shaped Supercapacitors to Avoid Short-Circuiting Upon Length, npj Flexible Electronics , 2022, 6, article number 19.He, N.; King, C.; Xie, Q.; Zhao, F.; Gao, W.* A Multidirectional Forearm Electromagnetic Generator Designed via Numerical Simulations. Actuators,2023, 12 (6), 225.Wang, Y.; Shim, E.; He, N.; Pourdeyhimi, B.; Gao, W.* Modeling the Triboelectric Behaviors of Elastomeric Nonwoven Fabrics. Adv. Mater. 2022, 34 (2), 2106429.Subjalearndee, N. He, H. Cheng, P. Teastchabut, P. Eiamlamai, P. Limthongkul, V. Instasanta, W. Gao*, X. Zhang*, Gamma (ɣ)-MnO2/rGO Fibered Cathode Fabrication from Wet Spinning and Dip Coating Techniques for Cable-Shaped Zn-Ion Batteries, Adv. Fiber. Mater. , 2022, 1-18.Mainka, W. Gao, N. He, J. Dillet, O. Lottin, A General Equipvalent Electrical Cuicuit Model for the Characterization of MXene/graphene oxide hybrid-fiber supercapacitors by electrochemical impedance spectroscopy-Impace of fiber length, Electrochimica Acta , 2022, 404, 139740N. He, J. Liao, F. Zhao, W. Gao*, Dual-Core Supercapacitor Yarns: An Enhanced Performance Consistency and Linear Power Density, ACS Appl. Mater. Interfaces , 2020, 12, 15211-25219. ACKNOWLEDGMENT This work has been financially supported by 1) United States Army Research Office under the contract number W911NF19C0074 and W911NF18C0086; 2) Intelligence Advanced Research Projects Activity (IARPA) under the SMART ePANTS program. Figure 1
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