Abstract We introduce a systematic method to produce left-invariant, non-Ricci-flat Einstein metrics of indefinite signature on nice nilpotent Lie groups. On a nice nilpotent Lie group, we give a simple algebraic characterization of non-Ricci-flat left-invariant Einstein metrics in both the class of metrics for which the nice basis is orthogonal and a more general class associated to order two permutations of the nice basis. We obtain classifications in dimension 8 and, under the assumption that the root matrix is surjective, dimension 9; moreover, we prove that Einstein nilpotent Lie groups of nonzero scalar curvature exist in every dimension ≥ 8 {\geq 8} .