Timely identification of the aging stage of the transformer can effectively ensure the safe operation of the transformer and prevent the aging fault of the transformer. This work proposes the aging diagnosis of transformer using the Raman spectroscopic recurrence plot combined with learning vector quantization (LVQ) neural network. Oil-paper insulation samples at different aging stages are obtained by accelerated thermal aging tests. Acquisition of Raman spectra of insulating oil is from 800 to 3000 cm <sup xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">−1</sup> and converts to the Raman spectroscopic recurrence plot. The gray-level cooccurrence matrix (GLCM) is used to extract the characteristic information of the Raman spectroscopic recurrence plot. The optimal number of neurons in competitive layer of LVQ neural network is determined by the experimental method. A transformer aging diagnosis model based on the Raman spectroscopic recurrence plot is established. The results show that the diagnostic accuracy of the proposed diagnostic model reached 95%. The Raman spectroscopic recurrence plot has more abundant aging “fingerprint” characteristic information and the proposed diagnostic method shows potential for monitoring oil-paper insulation.