Lead-zinc Mine Research Articles

Valorization of lead-zinc mine tailing waste through geopolymerization: Synthesis, mechanical, and microstructural properties

Lead-zinc mine tailing waste can have significant environmental impacts due to its potential for releasing toxic elements into the surroundings and contaminating local soil and water. This paper focuses on the valorization of lead-zinc mine tailing waste through geopolymerization, a sustainable process that can transform waste into useful building materials. Geopolymer matrixes with various mixtures of mine tailing (0−100 wt%), fly ash (0−100 wt%), and flue gas desulfurization (FGD) gypsum (0, 5, and 10 wt%) were synthesized using different activators such as sodium hydroxide (NaOH, 5, 10 M) and sodium silicate (waterglass, 0, 12.5 wt%). Visual inspection, unconfined compressive strength (UCS) testing, and microstructural analysis (e.g., X-ray diffractions, Fourier transforms infrared, and scanning electron microscopy) were employed for the physicochemical characterization of these geopolymers. The highest UCS value of 24.1 MPa was observed in a geopolymer specimen with 100 wt% fly ash and activated by 10 M NaOH and cured for 28 days. The blending of mine tailings would result in strength recession, e.g., the integrating of 25 wt% tailings showed a UCS of 12.3 MPa. The addition of 5 wt% gypsums can improve early strength development, particularly for matrixes with 50–75 wt% fly ash. But adding 10 wt% gypsums would lead to strength retrogression of the resulting geopolymers. The introduction of waterglass can also facilitate geopolymerization and improve strength development. However, the cointegrating of gypsum and waterglass can induce an antagonistic effect and lead to the collapse of the geopolymer specimens. The findings revealed that the strength and microstructural properties of geopolymer are determined by the matrix compositions, alkaline activators, etc. Effective regulation of these factors can produce geopolymer matrixes with high dimensional stability and UCS that well meet construction material standards. Overall, the study indicates that geopolymerization represents a viable and eco-friendly solution for valorizing lead-zinc mine tailing waste and gaining alternative building materials.

Heavy Metal Pollution and Health Risk Assessment in Karst Basin Around a Lead-Zinc Mine

Water quality is one of the most important environmental issues in the sustainable development of karst areas. To investigate heavy metal pollution and assess health risk in karst water basins around mines, 18 groups of water samples were collected from the river and groundwater in the Sidi River karst basin, and the concentrations of nine types of heavy metals(Cu, Pb, Zn, Cd, Mn, Fe, As, Cr, and Sr) were determined. Sample data were analyzed using principal component analysis, correlation analysis, water quality index, the Nemerow comprehensive pollution index, hazard quotient, and hazard index. The results showed that the Sidi River was slightly alkaline. The farther the river water samples were from the tailings reservoir, the lower were the concentrations of Cu, Pb, Zn, Cd, Mn, Fe, As, and Sr in the river water. Principal component and correlation analyses showed that heavy metals in the Sidi River karst basin mainly came from mine discharge(55.42%), carbonate weathering dissolution(21.41%), and human activities(14.72%). Eighty-two percent of the samples in the river and all the samples in the groundwater were excellent water. The Nemerow comprehensive pollution index in the river was 4.12 with strong pollution. All the hazard indices were below 1, and Pb, Zn, As, Cd, and Cr were potentially threatening metals in the Sidi River karst basin. The concentration of heavy metals changed significantly after entering the karst conduit, indicating that the unique properties of the karst aquifer affected the spatial variation of the heavy metal concentration. The results of this study can provide data reference for water resource prevention and human health protection in the Sidi River karst basin and similar karst basins.

Occurrence Characteristics of Lead–Zinc Mine and Low-Flying Aeromagnetic Prospecting in a Forested Region of Yichun City

Understanding the characteristics of lead–zinc mine occurrences and mastering effective investigative techniques are paramount in modern ore prospecting. This research focuses on the forested region of Yichun city in China, with a specific emphasis on the strategic mineral resource of a lead–zinc mine. The study examines the distribution patterns of this mineral and employs advanced aeromagnetic exploration methods. Firstly, we analyzed the geological structure and features of the region by leveraging the latest high-precision aeromagnetic data collected using dynamic delta wing technology. This analysis was complemented by an assessment of the geological conditions of the research area, existing lead–zinc deposits, ground magnetic surveys, and verification studies. With the goal of establishing a meaningful correlation between aeromagnetic anomalies and lead–zinc deposits, we employed various potential field conversion techniques, including the reduction to the pole, vertical derivatives, upward continuation, and residual anomaly analysis techniques. Secondly, we investigated the metallogenic sites within this region and provided a comprehensive summary of the metallogenic circumstances and characteristics related to aeromagnetic prospecting. Thirdly, we employed human–computer interaction fitting inversion techniques to predict the potential for lead–zinc mine prospecting in areas exhibiting aeromagnetic anomalies. The study underscores the significance of high-amplitude and large-scale aeromagnetic anomalies in the study area. Furthermore, we examined the interplay between intrusive rocks, strata, and structural elements within the region to identify favorable conditions for lead–zinc mineralization. As a result of our analysis and discussions, a location was predicted where a lead–zinc mine may exist. The research methodology outlined in this article provides valuable insights for future lead–zinc mine exploration efforts in areas characterized by similar geological conditions.

Research on Strength Model of Cemented Tailings Deposit Body in Underground Tailings Reservoir

Due to the lack of clarity in the strength design of underground tailings reservoirs, it is imperative to investigate the interaction between the tailings deposit body (TDB) and surrounding rock. Taking the TDB as the subject of analysis, a differential equation for vertical stress on the TDB is proposed, considering the stresses from the hanging wall of the surrounding rock and physical and structural parameters of the TDB. Considering the similarity between the underground tailings reservoir and one-step subsequent filling, in situ data of the one-step subsequent filling body from a mine was utilized to compare calculated values of the theoretical model. The resulting theoretical prediction error was less than 10%, thus verifying the reliability of the proposed model. According to the theoretical model analysis, the height of the TDB exerts the most significant influence on vertical stress, while the width and length of the TDB have a negligible impact. Moreover, internal friction angle has a more pronounced effect on vertical stress than cohesion force. A case study for a lead–zinc mine in China is presented in this work. Through uniaxial compressive strength and triaxial shear experiments, the key mechanical parameters of TDB at different ratios of cement to tailings are obtained. According to the theoretical model proposed herein, the distribution law of vertical stress in the height direction of TDB is determined for various ratios of cement to tailings. The original technical scheme of the mine has been optimized by using uniaxial compressive strength greater than vertical stress as the evaluation index, achieving both storage safety and cost reduction goals.

Rhizosphere microbial characteristics of pioneer plant Oxyria sinensis Hemsl. in abandoned Pb-Zn mining area

Oxyria sinensis has the characteristics of drought resistance, barren resistance, pollution resistance and clonal reproduction, and has the potential to be developed as a restoration plant (pioneer plant) for vegetation restoration and heavy metal pollution control in mining wasteland. In this study, the rhizosphere microbial communities of the pioneer plant O. sinensis growing in a lead-zinc mine wasteland and the rhizosphere microbial communities of O. sinensis growing in adjacent non-mining areas were studied by field investigation. There were significant differences in the composition of microbial communities between the rhizosphere soil of O. sinensis and the bare soil. There were significant differences in the composition of soil microbial communities between the non-mining area control and the lead-zinc mine wasteland. Compared with the non-mining area control, the rhizosphere soil of O. sinensis in the lead-zinc mine wasteland had a unique microbial community. The dominant bacteria were Nitrospirae, Chloroflexi, Proteobacteria, Actinobacteria, Ascomycota and Kickxellomycota. Further gene function prediction showed that the metabolic pathway sequences related to heavy metal ion transport, heavy metal resistance and repair in the rhizosphere soil of O. sinensis were more abundant than those in the control. The dominant ecological functional groups of fungi in the rhizosphere soil of O. sinensis were saprophytic flora and pathological flora. Plenodomus, Surfurifusis, Sphingomonas, Filobasidium and Articulospora were enriched in the rhizosphere soil of O. sinensis in the abandoned land of lead-zinc mining area, and had high tolerance to heavy metals in the soil, indicating that O. sinensis can recruit heavy metal-tolerant microbial groups to promote its survival and adaptation in the abandoned land of the mining area.

Endophytic Fungus Talaromyces sp. MR1 Promotes the Growth and Cadmium Uptake of Arabidopsis thaliana L. Under Cadmium Stress.

Endophytes play essential roles in plant growth under metal(loid)s stress. An endophytic fungus strain MR1 was isolated from the roots of Miscanthus floridulus collected from a lead-zinc mining area (Huayuan, China), which could produce indole-3-acetic acid and have Cadmium (Cd) tolerance. Further 18S rRNA sequencing analysis showed that it was highly similar (99.83%) to Talaromyces pinophilus. In pot experiments, we explored the effects of strain MR1 on the growth and Cd uptake of a wide-type Arabidopsis thaliana under low (LC) and high (HC) Cd concentrations. The results showed that MR1 effectively increased the dry weight of aboveground and underground tissues by 25.95-107.21% in both LC and HC groups. Due to MR1 inoculation, the Cd content in the underground tissues was significantly (p < 0.05) decreased by 39.28% under low Cd concentration, while it was significantly (p < 0.05) increased by 28.28% under high Cd concentration. Besides, MR1 inoculations significantly (p < 0.05) increased the total content of removed Cd (17.080μg) and BCF (0.064) by 129.77% and 153.95% under high Cd concentration. Therefore, we speculated that MR1 might be selected as the effective microbial agent to increase crop yield and control Cd content in the crop in light Cd-contaminated soil. Besides, MR1 could potentially enhance the phytoremediation efficiency of extremely Cd-contaminated soil.

Multi-devices field magnetic susceptibility: ‘3D’ spatialization of metallic contamination in soils and reverse correlation in carbonated context (Jebel Ressas, Tunisia)

Soil contamination linked to abandoned lead–zinc mining wastes represents a serious environmental hazard of worldwide concern, raising the need for cost-effective tools to spatialize the contaminated area and assess the risks. In worldwide industrial environments, positive correlation between magnetic susceptibility and heavy metal soil contamination is often reported and used for fast preliminary site assessments. In this study, we report monitoring of an olive grove, situated below one of the abandoned tailings dump of the former Jebel Ressas Pb–Zn mining site (Tunisia), with three different commercial susceptibilimeters (Terraplus KT10, Bartington MS2D and Geonics EM38 induction device). Integration depths of above-mentioned susceptibilimeters vary from 3 to 150 cm. Similar broad-scale magnetic susceptibility maps for the three devices emphasize the effect of topography and runoff transfer as the main mechanisms for tailings material dispersion. Very low susceptibilities (~ 10 × 10–5 SI) characterize the contaminants magnetic signal, while uncontaminated soils susceptibilities are one order of magnitude higher (100–150 × 10–5 SI). This unique case of reverse correlation between magnetic susceptibilities and contamination (Pb, Zn, Cd) trace efficiently the degree of contamination and is substantiated by further mineralogical and magnetic properties analyses showing the predominance of iron amorphous oxyhydroxides in the dump, while (titano)maghemite is the main natural magnetic carriers in the uncontaminated soils in this specific carbonated context. The Geonics EM 38, with a proper calibration procedure, reveals a performant tool increasing the depth of investigation and when combined with shallower susceptibilimeter, opens perspectives for qualitative 3D spatialization of metallic contamination.

Circular use of fine-grained tailings to underground mine wind walls

Mining activities tend to generate various waste including tailings, waste water and waste rock. Efficient management and disposal of these waste materials are critical to minimize their environmental impact and ensure the sustainable operation of mining activities. A huge number of tailings are produced all around the world each year. Generally, part of the tailings is used for underground backfilling and another part is discharged to the tailings dam. The former can provide underground support while the latter tends to cause some environmental problems because the tailings are generally mixed with some chemicals. Regarding this, enhancing the circular use of tailings is crucial to guarantee the sustainable mining engineering. In this study, the feasibility of using fine-grained tailings to make non-burning hollow bricks for underground windbreaks is investigated. A two-stage experiment was implemented where the first stage experiment indicated the threshold of water content, the ratio of cement and tailings and the ratio of fine-grained and rod-mill tailings. In addition, it can be indicated that the addition of polyethylene fibers would increase the compressive strength of hollow bricks in some extent. The second-stage experiment was conducted with no rod-mill tailing added and it can be found that when the ratio of cement and tailings is equal or higher than 1:6, fiber content is more significant in improving brick strength but when this value is lower, the ratio of cement is more important than fiber factors. When the ratio of cement and fine-grained tailings is 1:8 with 0.5 g/kg and 12 mm polypropylene fiber added, the hollow brick is capable of achieving strength of 1.4 MPa for 28 days curation with the price of 0.50 RMB/block. This proportioning scheme is the least expensive while meeting the strength of the windbreak wall for the Fan Kou lead–zinc mine. Finally, it can be indicated that the usage of fine-grained tailings to make underground windbreak wall is feasible and thus provide a new scenario to circular usage of tailings. In addition, other proportioning schemes proposed in this study perhaps can meet more engineering requirements so as to provide more alternatives for circular use of tailings.

Occurrence of Heavy Metals in Soil and Selected Edible Plants in the Vicinity of Major Lead-Zinc Mining Sites in Ebonyi State, Nigeria

Occurrence of Heavy Metals in Soil and Selected Edible Plants in the Vicinity of Major Lead-Zinc Mining Sites in Ebonyi State, Nigeria

Dve britanske misije u rudniku Trepča: prilozi za razumevanje politike Velike Britanije prema Jugoslaviji 1944–1945. godine

The paper explores two British missions in Serbia between December 1944 and June 1945, unknown until now. The purpose of both missions was to protect British interests by surveying the state of the Trepča mining complex in Kosovo and Metohija once the war operations were over. A majority stake in the Trepča lead-zinc mines was held by the British company Trepca Mines Limited owned by a mining magnate, Sir Alfred Chester Beatty. The two missions unveiled not only the importance of Trepča for the war effort of the Allies (as the need for lead ore had increased), but also the manner in which the new communist authorities in the Democratic Federative Yugoslavia treated the foreign capital in the country. The documents used in the paper are kept by the U.K. National Archives (TNA) in London.

Study on Correlations between Tailings Particle Size Distribution and Rheological Properties of Filling Slurries

The influence of the mass concentration and particle size distribution on rheological parameters and slump was investigated by analyzing the mixture of overflow tailings (OT) and classified tailings (CT). The correlation between the rheological parameters, slump and characteristic value of the tailings particle diameter was discussed. Finally, the ratio parameters of a mixed tailings filling slurry were optimized using a lead–zinc mine in Guangdong, China as the engineering background. The results showed a quadratic decrease in the slump of the tailings slurry as the mass concentration increased, while the slump decreased with a decreasing particle size. With the increase in the mass concentration, the yield stress of the tailings slurry follows a quadratic function, while the plastic viscosity exhibits linear growth. The influence of tailings fine particles on the sensitivity of the yield stress and plastic viscosity to the mass concentration is reduced as their content increases. The yield stress and plastic viscosity of the tailings slurry exhibit a quadratic function decrease and linear growth as the slump increases. The slump of the tailings slurry is related to the particle size characteristic value and the mass concentration of the slurry. The correlation coefficient between the yield stress and the aggregate characteristic particle size increases most obviously at d10~d50, and the increase in the characteristic particle size will enhance the correlation between the yield stress and particle gradation. The correlation coefficient between the plastic viscosity and aggregate particle gradation parameters exhibits an initial increase followed by stabilization with an increasing characteristic particle size, with the most significant increase observed at d10~d50.

Pb speciation and elemental distribution in leeks by micro X-ray fluorescence and X-ray absorption near-edge structure.

Vegetables are crucial to a human diet as they supply the body with essential vitamins, minerals, etc. Heavy metals that accumulate in plants consequently enter the food chain and endanger people's health. Studying the spatial distribution and chemical forms of elements in plant/vegetable tissues is vital to comprehending the potential interactions between elements and detoxification mechanisms. In this study, leek plants and soil from vegetable gardens near lead-zinc mines were collected and cultivated with 500 mg L-1 PbNO3 solutions for three weeks. Micro X-ray fluorescence was used to map the distribution of Pb and other chemical elements in leek roots, and X-ray absorption near-edge spectroscopy was used to assess the Pb speciation in leek roots and leaves. These findings demonstrated that Pb, Cu, Mn, Cr, Ti and Fe were detected in the outer rings of the root's cross section, and high-intensity points were observed in the epidermis. Zn, K and Ca, on the other hand, were distributed throughout the root's cross section. Leek root and leaf contained significant quantities of lead phosphate and basic lead carbonate at more than 80%, followed by lead sulfide (19%) and lead stearate (11.1%). The capacity of leek roots to convert ambient lead into precipitated lead and fix it on the root epidermis and other inner surfaces is a key mechanism for reducing the toxic effects of Pb.

Effect of dry-wet cycles on the strength and deformation of the red-bed rockfill material in western Yunnan

Introduction: The shear strength deterioration of red-bed rockfill under the dry-wet cycle is the key factor affecting the slope stability of accumulation body. Studying the strength deterioration law and deterioration mechanism of red-bed rockfill can provide theoretical support for slope stability control.Methods: Through the disintegration resistance test of argillaceous siltstone rockfill in Lanping lead-zinc Mine, the disintegration characteristics of red-bed soft rock were studied. The effects of the number of dry-wet cycles on the cohesion, internal friction angle, shear dilation rate and shear modulus of the red-bed rockfill were investigated by using a dry-wet cycle shear tester to conduct shear tests on the reduced scale graded soil material, and the strength deterioration mechanism of the soils was revealed from the perspective of meso-structure.Results: The results showed that argillaceous siltstone was rich in clay minerals and produces strong disintegration when exposed to water. The disintegration process could be divided into three stages: massive disintegration stage, transitional stage and stabilization stage. With the accumulation of dry-wet cycles, the shear dilation rate and shear modulus of the argillaceous siltstone rockfill gradually decrease, and the shear failure developed gradually from strain hardening to shear plastic flow, and the characteristic of weak stress softening occurred. After eight dry-wet cycles, the cohesion and internal friction angle of argillaceous siltstone rockfill materials decreased by 89.87% and 18.94%, respectively, indicating a higher effect on the cohesion than on the internal friction angle.Discussion: The thickening of the bound water between the fine particles on the shear surface, the weakening of the coarse particle attachment, and the increase in the number of directionally arranged fine particles were the main reasons for the continuous deterioration of the soil strength.

Pollution Level, Ecological Risk Assessment and Vertical Distribution Pattern Analysis of Heavy Metals in the Tailings Dam of an Abandon Lead–Zinc Mine

Tailings dams in mining areas frequently experience the phenomenon of haphazard dumping and stacking of a large amount of tailings waste. Under the influence of surface runoff and groundwater infiltration, heavy metals from tailings waste can migrate to the surrounding areas and underground soil, resulting in extensive heavy metal pollution. To analyze the pollution level and ecological risk of heavy metals in an abandoned lead–zinc mine tailings dam, this study first employed X-ray fluorescence analysis to determine the vertical distribution patterns of heavy metals with depth. Then, the pollution levels of heavy metals were analyzed based on the Nemerow comprehensive pollution index and geoaccumulation index. Subsequently, the ecological risk of heavy metal pollution was further assessed using the potential ecological risk (PER) index. Finally, the sources and potential hazards of heavy metal pollution were investigated. The results reveal that (1) heavy metal pollutants are identified as lead (Pb), zinc (Zn), copper (Cu) and arsenic (As), displaying enrichment at the interface layer between the reclaimed zone and tailings layer with the highest concentrations; (2) the pollution degrees in each zone follow the order of interface layer &gt; tailings layer &gt; deep zone &gt; reclaimed zone, and the pollution levels for the four heavy metals in decreasing order are Pb &gt; Zn &gt; As &gt; Cu; (3) after considering the toxic effects of heavy metals, the potential ecological risk in each zone remains consistent with the ranking of pollution levels, and the contribution of the four heavy metals to PER changes to Pb &gt; As &gt; Zn &gt; Cu, corresponding average Eri values of 913.928, 416.900, 96.462 and 47.998, respectively; (4) ecological risk of heavy metals originates from lead–zinc ore extraction, and heavy metal pollution poses potential risks to public water security and surrounding ecological resources.

Phytoremediation strategies for heavy metal-contaminated soil by selecting native plants near mining areas in Inner Mongolia.

Phytoremediation technology, as an eco-friendly and cost-effective approach, is widely used to restore soil contaminated by heavy metal(loid)s. However, the adaptability and absorption capacity of plants to multiple elements are the crucial factors affecting the application of phytoremediation in mining areas. In this study, dominant native plant species and their paired soils were collected near a lead-zinc mine in Inner Mongolia, to assess the ecological risk of heavy metal(loid)s and phytoremediation potential. The results showed that Cd and As were the dominant soil pollutants, with levels of 90.91% and 100%, respectively, exceeding the risk intervention values for soil contamination of agricultural land. The rates of Pb, Cu, and Zn exceeding the risk screening values were 69.70%, 60.61%, and 96.97%, respectively. Extremely high ecological risk of heavy metal(loid)s was observed in this area. The ability of native plants accumulating heavy metals varied among species. The bioconcentration factor (BCF) varied from 0.14 to 2.59 for Cd, 0.02 to 0.45 for As, 0.06 to 0.76 for Pb, 0.05 to 2.69 for Cr, 0.15 to 1.00 for Cu, and 0.22 to 4.10 for Zn. Chinese Cinquefoil Herb (Potentilla chinensis Ser.) showed the potential to accumulate multiple toxic elements based on the biomass, shoot content, translocation factor (TF), BCF, and metal extraction rate (MER), while, other species showed the potential to accumulate single toxic element: goosefoot (Chenopodium album L.), Lespedeza daurica (Laxm.) Schindl. and peashrubs (Caragana korshinskii Kom.), Herba Artemisiae Scopariae (Artemisia capillaris Thunb.), alfalfa (Medicago sativa L.), and Moldavian Dragonhead (Dracocephalum moldavica L.) for Cd, As, Cr, Cu, and Zn, respectively. Furthermore, wild leek (Allium ramosum L.), cogongrass (Imperata cylindrica (L.) Beauv.), fringed sagebrush (Artemisia frigida Willd.), and field bindweed (Convolvulus arvensis L.) were selected for phytostabilization of specific elements, considering the heavy metal contents in the roots and low TF values. This study provides a reference for selecting appropriate species for the remediation of heavy metal-contaminated soils in certain mining areas.

Investigating metal pollution in the food chain surrounding a lead-zinc mine (Northwestern Iran); an evaluation of health risks to humans and animals.

The current study aims to evaluate the health risk of heavy metals for humans and animals in the Angouran mining complex (northwest of Iran). Twenty-five plant species and their corresponding soils (natural soils) were collected along with mine tailings samples. The carcinogenic and non-carcinogenic risks of heavy metals (Zn, Pb, Cd, Cr, and Co) for humans using the hazard quotient (HQ) and hazard index (HI) were evaluated. Moreover, the health risk caused by forage feeding to grazing ruminants (cow and sheep) and the risk associated with animal products consumption by humans in the soil-plant-animal transfer system were assessed. The value of HI in natural soils (rangeland use) was less than one (HI < 1), while regarding tailings, the HQ via oral ingestion and the HI were greater than one (HI & HQ > 1). The range of total carcinogenesis risk in natural soils exceeded the target risk (Risk < 10-6) and for tailings, it showed the probability of cancer risk, 1 person per 3636 populations, which is much higher than the acceptable or tolerable range (10-4 < Risk < 10-6). Regarding the animal health risk, the content of Pb and Cd in most of the animal organs was higher than the control values. In turn, dietary exposure to Pb and Cd is worrying for residents due to exceeding the provisional tolerable weekly intake (PTWI). This comprehensive study suggests the necessity of risk assessment of mining sites in Iran and immediate control measures to diminish pollutants.

Geochemical distributions of natural radionuclides in surface soils and sediments impacted by lead-zinc mining activity

This study investigated the distribution features of uranium-238 (238U), radium-226 (226Ra), thorium-232 (232Th), and potassium-40 (40K) and evaluated the associated environmental radiological hazards of the topsoil and river sediments in the Jinding lead-zinc (Pb-Zn) mine catchment from Southwest China. The activity concentrations of 238U, 226Ra, 232Th, and 40K ranged from 24.0 ± 2.29–60.3 ± 5.26 Bq.kg-1, from 32.5 ± 3.95–69.8 ± 3.39 Bq.kg-1, from 15.3 ± 2.24–58.3 ± 4.92 Bq.kg-1, and from 203 ± 10.2–1140 ± 27.4 Bq.kg-1, respectively. The highest activity concentrations for all these radionuclides were primarily found in the mining areas and decreased with increasing distance from the mining sites. The radiological hazard indices, including radium equivalent activity, absorbed gamma dose rate in the air, outdoor annual effective dose equivalent, annual gonadal dose equivalent, and excess lifetime cancer, revealed that the highest values were observed in the mining area and downstream, specifically in the vicinity of the ore body. These elevated values exceeded the global mean value but remained below the threshold value, suggesting that routine protection measures for Pb-Zn miners during production activities are sufficient. The correlation analysis and cluster analysis revealed strong associations between radionuclides such as 238U, 226Ra, and 232Th, indicating a common source of these radionuclides. The activity ratios of 226Ra/238U, 226Ra/232Th, and 238U/40K varied with distance, suggesting the influence of geological processes and lithological composition on their transport and accumulation. In the mining catchment areas, the variations in these activity ratios increased indicated the impact of limestone material dilution on the levels of 232Th, 40K, and 238U in the upstream region. Moreover, the presence of sulfide minerals in the mining soils contributed to the enrichment of 226Ra and the removal of 238U caused those activity ratios decreased in the mining areas. Therefore, in the Jinding PbZn deposit, the patterns of mining activities and surface runoff processes in the catchment area favored the accumulation of 232Th and 226Ra over 40K and 238U. This study provides the first case study on the geochemical distributions of natural radionuclides in a typical Mississippi Valley-type PbZn mining area and offers fundamental information on radionuclide migration and baseline radiometric data for PbZn deposits worldwide.

Evaluation of excavation method on point load strength of rocks with poor geological conditions in a deep metal mine

In the field of deep mining engineering, it poses a challenge to promptly determine the mechanical properties of rocks under poor geological conditions through in-situ tests. However, the indirect determination of uniaxial compressive strength (UCS) of rocks can be achieved through the point load strength index (PLSI) test on irregular samples. In the present study, laboratory uniaxial compressive and field PLSI tests were carried out on irregular ore and rock blocks extracted through mechanical mining methods from a stope at a lead–zinc mine in Yunnan Province, China, with a depth of approximately 1000 m. The effects of mechanical excavation and drilling-blasting methods on the PLSI of rocks and ores are compared. It is found that there are significant differences in the point load strength indexes obtained by different excavation methods, and the Is(50) obtained after the mechanical excavation method approximates the actual value of ore and surrounding rocks. Two correction methods were utilized to obtain the point load strength indexes Is(50)-1 and Is(50)-2 of irregular rock samples. The correlation factors (k) linking Is(50) to UCS and Brazilian splitting strength are derived based on testing results. The findings indicate that using the conversion factor (k) recommended by ISRM to predict the UCS of rocks may significantly underestimate the actual strength of rocks in intricate mining environments. This study can serve as a benchmark for analogous deep mining projects.

Effects of multi-heavy metal composite pollution on microorganisms around a lead-zinc mine in typical karst areas, southwest China

Heavy metal pollution poses a serious hazard to the soil bacterial community. The purpose of this study is to understand the characteristics of soil heavy metal pollution in lead-zinc mines in karst areas and the response of Pb, Zn, Cd, and As-induced composite pollution to soil microorganisms. This paper selected soil samples from the lead-zinc mining area of Xiangrong Mining Co., Ltd., Puding County, Guizhou Province, China. The soil in the mining area is contaminated by multiple heavy metals such as Pb, Zn, Cd and As. The average levels of Pb, Zn, Cd and As in the Pb-Zn mining soil were 14.5, 7.8, 5.5 and 4.4 times higher than the soil background in this area, respectively. Bacterial community structures and functions were analyzed using 16 S rRNA high-throughput sequencing technology and the PICRUSt method. A total of 19 bacterial phyla, 34 classes and 76 orders were detected in the tested soil. At the phylum level, the Proteobacteria are the dominant flora of the soil in the tailings reservoir area of the lead-zinc mine, respectively GWK1 (49.64%), GWK2 (81.89%), GWK3 (95.16%); and for the surrounding farmland soil, the Proteobacteria, Actinobacteriota, Acidobacteriota, Chloroflexi and Firmicutes are the most abundant in five bacterial groups. RDA analyses revealed that the heavy metal pollution of the lead-zinc mining area has a significant impact on the diversity of soil microorganisms. As the distance from the mining area increased, the heavy metal comprehensive pollution and potential risk value decreased, and the bacterial diversity increased. Additionally, various types of heavy metals have different effects on bacterial communities, and soil heavy metal content will also change the bacterial community structure. Proteobacteria positively related to Pb, Cd, and Zn, therefore, Proteobacteria were highly resistant to heavy metals. PICRUSt analysis suggested that heavy metals significantly affect the metabolic function of microorganisms. Microorganisms might generate resistance and enable themselves to survive by increasing the transport of metal ions and excreting metal ions. These results can be used as a basis for the microbial remediation of heavy metal-contaminated farmland in mining areas.

Source Analysis of Soil Heavy Metals in Agricultural Land Around the Mining Area Based on APCS-MLR Receptor Model and Geostatistical Method

In order to identify the source of heavy metals in the soil around a mining area and provide effective suggestions for the prevention and control of regional soil pollution, 118 topsoil samples (0-20 cm) were collected in the northern part of Wuli Township, Qianjiang District, Chongqing. The heavy metal (Cd, Hg, Pb, As, Cr, Cu, Zn, and Ni) contents in the soil and soil pH were analyzed, and the spatial distribution and sources of heavy metals in the soil were studied using the geostatistical method and APCS-MLR receptor model. The results showed that the content of heavy metals in the soil was significantly higher than the background value in Chongqing; there was obvious surface accumulation; and Hg, Pb, Cd, As, and Zn showed strong variation. The proportions of soil Cd, Hg, Pb, As, and Zn exceeding the risk screening values were 47.11%, 6.61%, 4.96%, 5.79%, and 7.44%, respectively, and the proportions of soil Cd, Hg, Pb, and As exceeding the risk control values were 0.83%, 4.13%, 0.83%, and 0.83%; thus, the problem of excessive heavy metals in the soil was significant. Soil Cd, As, Cr, Cu, and Ni were mainly affected by soil parent materials, and their contribution rates to the total soil elements were 77.65%, 68.55%, 71.98%, 90.83%, and 82.19%, respectively. Soil Hg, Pb, and Zn were mainly affected by the mining of mercury mines and lead-zinc mines, with the contribution rates of 86.59%, 88.06%, and 91.34%, respectively. In addition, agricultural activities also affected soil Cd and As contents. It is recommended to strengthen the safety monitoring of agricultural products and agricultural inputs, plant varieties with a low accumulation of heavy metals, reduce the use of livestock manure, and grow non-edible agricultural products in areas that exceed the control value of heavy metal pollution risk.