Removal Of Lead Research Articles

Emulsion graft polymerization of glycidyl methacrylate onto bamboo fiber composites for efficient removal of lead ions from aqueous solutions

The emulsion graft polymerization process was used to synthesize a novel polyglycidyl methacrylate grafted silanized bamboo fiber composites. The grafting percentage was assessed by varying surfactant, initiator and monomer concentrations. The surface morphologies and thermal behavior of the biocomposites were analyzed using FTIR, SEM, XRD and TGA techniques. In batch adsorption studies, the effect of adsorption parameters like pH, adsorption time, adsorbent dose and solution temperature were examined on the adsorption efficiency of lead ions. The adsorption capacity of biosorbent composites was enhanced through conversion of epoxy group of Poly glycidyl methacrylate (PGMA) into sulfonic acid groups via sulfonation process. The sulfonic acid groups were incorporated into VMBF-g-PGMA by stirring the grafted sample in H2SO4 (98 %) for 2 h at 90 °C to obtain sulfonated grafted polymer (VMBF-g-PGMA-S). By increasing the concentration of monomers up to 5 %, the maximum grafting percentage (289 %) was achieved. The grafting % increases rapidly from 0.5 to 0.20 g initiator and at 0.20 g of initiator, the highest grafting yield was 512 %. The maximum Pb+2 adsorption capacity of adsorbent was 200 mg/g. The thermodynamic parameters for pb+2 adsorption revealed an exothermic and spontaneous nature of sorption process, and the entropy change showed that there are no substantial structural changes occurred in biosorbent material. The experimental results confirmed that sulfonated biosorbent composites are effective, economical, and promising adsorbent which could be used for removal of lead and other ions from aqueous solution.

Conversion of PET bottles into carbonaceous adsorbents for Pb(II) removal from aqueous solutions via KOH activation

In this study, we present a novel approach to repurpose waste Polyethylene terephthalate (PET), a prominent contributor to global plastic usage, for the synthesis of efficient adsorbents via facial pyrolysis. The as-synthesized adsorbents were applied for the removal of lead (Pb(II)) ions in aqueous solution. Controlled batch experiments at pH 5 with 0.075 g of adsorbent at room temperature (20 °C) were conducted to measure Pb(II) adsorption capacities (mg/g) and fitted on isotherm models (Langmuir, Freundlich, and Temkin) and kinetics models (Pseudo-First order, Pseudo-Second order, and Elovich). Thermodynamic experiments conducted at four different temperatures (293 K, 303 K, 313 K, and 323 K) provided enthalpy, entropy, and Gibbs free energy change parameters, explaining the Pb(II) adsorption behaviors on PET-based adsorbents. The activation process involving KOH, followed by carbonization, yielded adsorbents with exceptional surface areas, pore volumes, and elevated oxygen contents (up to 22.8 %). The best adsorbent exhibited superior performance, achieving a maximum adsorption capacity of 219.7 mg/g within a rapid equilibrium time of 15 min. The adsorption behavior adhered well to the Langmuir isotherm model (R2 = 0.999) and Pseudo-Second Order kinetics model (R2 = 0.999). Furthermore, C600K600 displayed outstanding reusability, with negligible efficiency reduction (<5 %) even after five consecutive cycles. These results underscore the successful conversion of PET waste into a low-cost and highly effective adsorbent, offering a promising solution for sustainable waste management.

Comprehensive analysis of substernal lead removal: experience from EV ICD Pilot, Pivotal, and Continued Access Studies.

The extravascular implantable cardioverter-defibrillator (EV ICD) has been shown to be safe and effective for patients at risk of sudden cardiac death, but little is known about EV ICD lead removal in humans. This analysis aimed to characterize the EV ICD lead removal experience thus far. This was a retrospective analysis of lead removals from the EV ICD Pilot, Pivotal, and Continued Access Studies. Patients with a successful EV ICD implant who underwent lead removal were included. The main objective was lead removal success. Ancillary objectives included characterizing technique used, procedure complications, and reimplantation status. An EV ICD system was successfully implanted in 347 patients across the 3 studies (25.9% female; 53.4 ± 13.3 years; left ventricular ejection fraction: 39.7 ± 15.9). Of these patients, 29 (8.4%) underwent lead removal with a mean lead dwell time of 12.6 ± 14.3 months (0.2-58.4). The main reason for lead removal was lead dislodgement (n = 9, 31.0%). Lead removal was successful in 27/29 (93.1%) cases [100% (19/19) success rate <1 year and 80% (8/10) success rate >1 year post-implant]. Simple traction was used in 22/26 (84.6%) and extraction tools in 4/26 (15.4%) successful cases where technique was known. No complications were reported for any of the removal procedures. All 11 EV ICD reimplant attempts were successful. Complete removal of the EV ICD lead was successful in 93.1% of cases, and simple traction was sufficient in most instances. Based on these results, lead removal from the substernal space was safe and achievable up to 3 years post-implant.

Valorization of fava, lentil, pea, and soya husks as sustainable adsorbents for lead removal from contaminated water: characterization, adsorption kinetics, and isotherms

Valorization of fava, lentil, pea, and soya husks as sustainable adsorbents for lead removal from contaminated water: characterization, adsorption kinetics, and isotherms

Natural deep eutectic solvent-functionalized multiwall carbon nanotubes for lead removal from wastewater

In this study, two natural deep eutectic solvents (NADESs) were prepared from natural hydrogen bond donors (HBDs) based on sugar, namely fructose and sucrose, alongside H2O, and choline chloride as a hydrogen bond acceptor (HBA). The prepared NADESs were used as functionalizing agents with multiwall carbon nanotubes (MWCNTs), and the functionalized MWCNTs were used as adsorbents of Pb(II) lead ions from aqueous solution. The analyses demonstrated that MWCNTs functionalized with sucrose-based NADES to have more sub-stems and functional groups than the MWCNTs functionalized with fructose-based NADES, providing more possible sites for Pb(II) adsorption. The time dependence of Pb(II) adsorption onto these novel adsorbents was found to be better described by a pseudo-second-order kinetic model. Additionally, the Langmuir model better fits the adsorption data due to its higher coefficient of determination. Finally, the operating conditions (pH, adsorbent concentration, and contact time) were optimized using the Box-Behnken model, which demonstrated pH to exert greater influence on the adsorption process than the other studied factors. To the best of our knowledge, this study is the first to apply NADESs as emerging functionalizing agents for carbon nanomaterials in the removal of heavy metals from synthetic wastewater.

Simultaneous removal of malachite green and lead from water by consortium dry-biomasses of Bacillus licheniformis AG3 and Bacillus cereus M116

Synthetic textile dye malachite green (MG) and heavy metals present in industrial wastewater are hazardous to the ecosystem. Bioremediation of dyes and heavy metals using dry-biomasses has advantages over chemical methods. This study screened an acclimatized, heavy metal-resistant, and dye-degrading Gram positive Bacillus licheniformis AG3 strain from the textile wastewater near Kolkata, West Bengal. The EDXRF analysis of this colored wastewater effluent showed 36.33 mg/L lead, significantly higher than the WHO recommendation. Previously, Bag et al. showed bioremediation of synthetic dyes using dry-biomass of Bacillus cereus M116 from an aqueous solution (Bag et al. Arch Microbiol 203(7):3811–3823, 2021). Here, a consortium of dry-biomasses of B.licheniformis AG3 and B. cereus M116 strains (1:1 w/w ratio) was prepared for the simultaneous removal of lead and MG from wastewater. Statistical optimization determines that the pH, initial concentration of contaminants, and dry-biomass concentrations are critical for bioremediation under batch procedures. Further, optimization using the response surface methodology showed that 0.01% consortium dry-biomasses eliminated a maximum of 99.35% MG and 96.01% lead (II) within 6 h. SEM–EDS and FTIR confirmed a strong surface biosorption. Furthermore, a fixed-bed biofilter column of the consortium dry-biomasses was prepared, which was able to remove 98.1% MG and 98.5% lead at the 0.5–1 mL/min flow rate. Together, this study developed a biofilter with a consortium dry biomasses of B. licheniformis AG3 and B. cereus M116 for the simultaneous removal of MG and lead from wastewater.

Insights into the environmental benefits of using apple pomace for biosorption of lead from contaminated water

The apple processing industry generates large quantities of organic waste, presenting a major source of organic contamination. Consequently, finding an effective solution for valorizing this waste has become a pressing issue. This study aims to address two key concerns: (i) solving an agricultural problem by efficiently using agri-food residue, and (ii) removing lead, an extremely toxic element, from contaminated waters to mitigate environmental pollution. Two biosorbents were tested: raw apple waste (RA), obtained from a mixture of apple varieties, and the same material after extracting valuable bioactive and reusable components, extracted apple (EA). The study evaluated the influence of pH, initial biosorbent mass, adsorption kinetics, and equilibrium isotherms. The results are very promising, showing a lead removal efficiency of 82 % for RA and 100 % for EA at a low initial concentration of the solution of 20 mg Pb2⁺/L and an optimal pH of 5 ± 0.5. The Langmuir model predicted a maximum adsorption capacity of 44.6 mg/g for RA and 48.6 mg/g for EA. These findings demonstrate that apple waste, even after selective extraction of valuable bioactive components, can be effectively used for environmental remediation on a practical scale.

Removal of lead and cadmium from aqueous solution by using cashew gum polysaccharide (Arabinogalactan) - Acrylamide hydrogel

There is an increasing need for clean water for human health and the environment, so the removal of toxic metals from wastewater with low-cost adsorbents plays an essential role. In this research, the synthesis of cashew gum (CG) polysaccharide (arabinogalactan)-acrylamide (Am) (CG-AM) hydrogel was carried out with three independent variables: Hydration ratio (ml/g), amount of monomer (acrylamide, Am) (g) and concentration of crosslinker (methylene-bisacrylamide, MBA) (%) by radical polymerisation. The removal efficiency of Pb2+ and Cd2+ from the stock solution of lead nitrate and cadmium sulphate by adsorption technique was also studied by optimisation using BBD of RSM. Furthermore, the functional and structural properties of all types of hydrogels were analysed by characterisation with FTIR, (XRD), (SEM) with EDS and swelling capacity analysis. An optimum hydrogel yield of 4.527 g was obtained at a hydration ratio of 10 ml/g, monomer amount of 2.5 g and crosslinker concentration of 3% w/v of one gram of extracted arabinogalactan. For Pb2+ removal, 86.985 % removal efficiency was obtained at a hydration ratio of 25 ml/g, monomer amount of 1g and crosslinker concentration of 1%, while for Cd2+ removal, 18.875 % removal efficiency was obtained at a hydration ratio of 10 ml/g, monomer amount of 4g and crosslinker concentration of 2%. (CG-AM)H Pb2+ had the highest swelling capacity of 11.072 g H2O/g polymer hydrogel but (CG-AM)H had the lowest of 5.322 g H2O/g polymer hydrogel due to crosslinking capacity. The FTIR result, the (CG-AM)H Pb2+ showed a significant peak of C-O stretching of the S-glycosidic bond of hydrogel to absorb the Pb2+ ions. From XRD and SEM results, (CG-AM)H Pb2+ showed an amorphous nature of hygroscopic properties and a three-dimensional network structure with open pores.

Heavy metals biosorption in unary, binary, and ternary systems onto bacteria in a moving bed biofilm reactor

Toxic and heavy metals cause direct and indirect damage to the environment and ultimately to humans. This study involved the isolation of indigenous bacteria from heavy metal-contaminated environments that have the ability to bioabsorb heavy metals such as cadmium, nickel, and lead. The bioabsorption process was optimized by varying parameters such as temperature, metal concentration, number of bacteria, pH, and more. The bacterial isolates were investigated in terms of morphology, biochemistry, and phylogeny, with 12 strains chosen in the initial stage and one strain chosen in the final stage. It should be remembered that the metal uptake capacity of all isolates was approximately calculated. A box and reactor were designed to house these optimized microorganisms. Based on biochemical, morphological, and molecular results, the isolated strain was found to be closely related to the Bacillus genus. In the first five steps of testing, the ideal pH for removing lead alone, lead with cadmium, lead with nickel, and lead ternary (with cadmium and nickel) by Bacillus bacteria was found to be 7, 6, 5.5, and 6.5, respectively. The absorption efficiencies for single lead (unary), lead together with nickel, cadmium (binary), and ternary (lead with cadmium and nickel) were found to be 0.36, 0.25, 0.22, and 0.21 mmol/g, respectively. The ideal temperature for lead removal was around 30 °C. The adsorption isotherm for each lead metal in different states was found to be similar to the Langmuir isotherm, indicating that the surface absorption process is a single-layer process. The kinetics of the process follow the second-order kinetic model. The amount of Bacillus bacteria biomass obtained during this process was approximately 1.5 g per liter.

Characteristics of Removal of Lead, Cadmium and Chromium from Soil Using Biosorbent and Biochar

The study proposed the use of aspen wood sawdust and biochar derived from this sawdust for the removal of Pb(II), Cd(II), and Cr(VI) ions from soil in systems containing single metals as well as a mixture of all the studied metals. The effectiveness of the applied sorbents was compared with the sorptive properties of activated carbon. The results showed that all the tested materials reduced the metal content in the soil, and the obtained biochar was able to sorb lead, cadmium, and chromium ions in both studied systems. The influence of the type of sorbent, its dose, process duration, and the impact of metal on the removal efficiency and sorption capacity was analyzed. A statistical analysis of the obtained results was also conducted, determining the influence of process parameters on the removal capabilities of metal ions. The highest Pb, Cd and Cr ion removal efficiencies were obtained in a 36-day process at a sorbent dose of 10%. Aspen sawdust, biochar and activated carbon removed 46%, 50% and 71% of Pb(II), 35%, 43% and 53% of Cd(II) and 15%, 27% and 38% of Cr(VI), respectively. In turn, the highest sorption capacity values were achieved in a 36-day process at a sorbent dose of 2%, obtaining results of 20.2 mg/g, 22.3 mg/g and 23.2 mg/g of Pb(II), 5.1 mg/g, 7.9 mg/g and 11.7 mg/g of Cd(II) and 3.8 mg/g, 5.8 mg/g and 8.5 mg/g of Cr(VI), respectively. It was found that both raw aspen wood sawdust and biochar derived from this wood are effective in removing toxic metal ions from soil, which presents a potential solution to their presence in the natural environment.

Simultaneous removal of lead(II) and cadmium(II) from acidic wastewater by Fe-modified sludge biochar

In natural environments, heavy metal water pollution often involves simultaneous presence of various heavy metal ions (HMs), posing significant challenges for their removal. In this study, Fe-modified sludge biochar was synthesized via the co-precipitation method, and the effects of various environmental factors on simultaneously removing lead(II) and cadmium(II) by Fe@SBC were investigated. Batch adsorption experiments showed that Fe@SBC has a higher removal capacities for Pb(II) than for Cd(II) in both single or binary solutions. Increasing solution pH promoted the HMs removal on Fe@SBC. Coexisting divalent cations (Mg2+ and Ca2+) exhibited stronger inhibitory effects on HMs removal by Fe@SBC than monovalent cations (K+ and Na+). The presence of humic acid (HA) did not affect Pb(II) removal on Fe@SBC in either single or binary systems. In single systems, increasing HA concentration enhanced Cd(II) removing on Fe@SBC, while in binary systems, increasing HA concentrations inhibited the Cd(II) removal on Fe@SBC. The sorption of Pb(II) and Cd(II) on Fe@SBC followed the pseudo-second-order kinetic model and the Langmuir model. The removal mechanisms involved electrostatic interactions, complexation with O-containing group, and mineral dissolution-precipitation. After three regenerations, the adsorption capacity of Fe@SBC for Pb(II) and Cd(II) decreased by approximately 5–10 %. In summary, this environmentally friendly composite material has great potential for simultaneously remediating of Pb(II) and Cd(II).

A Study of Copper and Lead Removal from Synthetic Leachate by Photocatalysis

A Study of Copper and Lead Removal from Synthetic Leachate by Photocatalysis

Clinoptilolite- and glauconite-based sorbents for lead removal from natural waters

The aim of the research is to determine the effect of heat treatment and microwave irradiation on the sorption properties of a natural clinoptilolite and glauconite to Pb2+ ions. To improve the sorption capacity the samples were heat treated at 550 °C for 3 hours or microwaved at 790 W for 30 minutes. The XRD and XRF analysis present the content of investigated samples and prove the increase in the sorption capacity after treatment. After contact with Pb, its content in the natural clinoptilolite increased to 2.66%, and in the thermally treated – to 6.035%. The PbO content in natural glauconite increased to 3.9%, but after microwaving it reached 5.2% of the total sample weight. Heat treatment is useful for improving the sorption capacity of clinoptilolite, and microwave irradiation can significantly increase the adsorption capacity of glauconite.

Adsorption of Pb(II) from aqueous environment on artificially synthesized mordenite and its biochar composite

Biochar was used to enrobe artificially synthesized mordenite by co-pyrolysis, and the performance of the composite in removing lead from dilute solutions was compared with that of the mordenite alone. The optimal parameters for the hydrothermal synthesis of mordenite were as follows: crystallization temperature of 180℃, crystallization time of 4 days, pH value of 11, and aging time of 24 h. The optimal mass ratio of mordenite to biochar was 20:1, and the pyrolysis temperature was 500℃. Adsorption equilibrium was reached within 3 h, yielding a total average lead removal of 78.9 % for mordenite alone and 98.6 % for the composite. Pseudo-second-order kinetics and Langmuir isotherms adequately described the data. The predicted maximum adsorption capacities were 156.6 mg/g for the mordenite alone and 283.4 mg/g for the composite. When the initial concentration of Pb(Ⅱ) was 80 mg/L, the optimum doses were determined to be 6–7 g/L for the mordenite and 5–6 g/L for the composite. At pH less than 7, mordenite removed up to 80 % of the lead and the composite removed between 90 % and 100 %. Coexisting ions had little effect on mordenite, but K(I), Ca(II), and Mg(II) could significantly increase the adsorption efficiency by up to 5.7 % for the composite. Furthermore, tannic acid and fulvic acid showed a promoting effect. Adsorption mechanisms were proposed based on the characterization results of the materials before and after adsorption, batch experiments, and density functional theory calculations. Specifically, mordenite adsorption was found to be based primarily on electrostatic attraction, surface complexation and ion exchange. Adsorption by the composite also involved π-electronic interaction and coprecipitation. In general, the composite exhibited better adsorption performance than mordenite alone.

Electrified Nano-Gaps Under AC Field: A Molecular Dynamics Study

Solid-Liquid Interfaces (SLIs) hold immense significance in various areas such as materials science, chemistry, physics, biology and medicine [1]. Many studies aim to decipher the molecular details of SLIs through analytical, computational or experimental methods [2]-[3], each optimized for different aspects of SLIs. Analytical methods are mainly based on the mean field approximation and work best for dilute solutions. Computational methods are bound by their maximum accessible time and length scales, while the limitation of experimental approach tend to lie in minimum values accessible of these scales. The concomitant deployment of both the approaches is a powerful tool in studying SLIs.In the current study both the computational and experimental tools are employed to study the interface of silica with aqueous saline solutions under electric fields. Molecular Dynamics (MD) simulation are utilized to investigate the relative response of the ions and waters exposed to an external AC field in a nanoscale silica-elecrolyte-gold system. Complementary experimental measurements are conducted with atomic force microscopy (AFM) which measures the dielectric force exerted on the nanoscale AFM probe. The impact of external factors such as salt concentration, AC voltage frequency and the system size is systematically investigated.Simulations reveal both the transient and stable response of water and ions as the main component of the system to the AC field. In the transient response, the water electric dipole increases monotonically with the voltage at the first cycle while it takes longer for ions to react to the field, limited by their diffusion time. When the ionic response becomes large enough to screen the field, the dipole moment of water molecules decreases and lead the phase of the applied field. The lag in the ionic response is owing to the time required for the ionic diffusion, while the lead in the water response is due to ionic lag.To obtain the stable response through MD simulation, Fourier transform was deployed with the results showing that electric dipole of ions and water have a periodic behavior with a frequency similar to the AC field and waters in lead and ions in lag. The dipole-voltage plots for ions and waters depicted an energy transfer between water and ions in each cycle. Decreasing the frequency to 10MHz, no energy exchange was observed concomitant to the removal of water lead. Besides, in the frequency range of 100MHz-200MHz in which the water phase lead reaches its maximum value, there is also a maximum in the energy exchange. Thus, there is a direct relation between the water-ion energy exchange and lead in the water response.The stable response is affected by various factors including the separation distance between the surfaces, the ionic concentration and the AC frequency. The MD observations of a decrease in the water lead and ionic lag with reducing the electrolyte gap could explain AFM measurements where the dielectric force appears to decrease for small gaps, a counter-intuitive result if bulk electrolyte properties are assumed. The simulation results also show that the sum of the electric dipole of water and ions is always in phase with the applied voltage implying that the field is totally screened by the combination of both of them. To provide the same amount of screening in larger separation distance the electric dipole of ions has to increase to counteract its larger lag which is observed in the ionic dipole values. As the ionic dipole despite water molecules are caused by translational entropy, larger ionic dipole translates to larger forces which is observed in the AFM experiments.[1] Taketoshi et al. Japanese Journal of Applied Physics (2021).[2] T. Fukuma and R. Garcia, ACS nano (2018).[3] J.M. Andanson and A. Baiker, Chemical Society Reviews (2010).

Removal of Lead and Nitrate from Simulated Lead- and Nitrate-Containing Wastewater via Hydroxide Precipitation

Removal of Lead and Nitrate from Simulated Lead- and Nitrate-Containing Wastewater via Hydroxide Precipitation

Removal of lead and cadmium ions from water using primary-secondary amine modified magnetic microbeads: Equilibrium, kinetic, and thermodynamic studies

This study developed novel magnetic microbeads based on trimethoxysilylpropylethylenediamine (TSD) as a primary-secondary amine source through a one-pot process. The process involves coating magnetic iron oxide nanoparticles (MNPs) with primary-secondary amine (TSD), followed by cross-linking with alginate (Alg). The ternary magnetic microbeads (Alg@MTSD) were used to remove Pb2+ and Cd2+ ions from aqueous media. The nanocomposite was characterized using various techniques, including Fourier-transform infrared spectroscopy (FTIR), energy-dispersive X-ray spectroscopy (EDX), scanning electron microscopy (SEM), and vibrating sample magnetometry (VSM). Adsorption experiments were conducted under optimal conditions, and isothermal models, including Langmuir and Freundlich, as well as kinetic models, were applied to evaluate the experimental data. The findings indicated that the Langmuir model best fit the adsorption data for Pb2+ and Cd2+ ions, with R2 > 0.99. The maximum adsorption capacities were 68 mg·g−1 for Pb2+ and 51 mg·g−1 for Cd2+. Kinetic studies showed that the adsorption process followed the pseudo-second-order model. Thermodynamic analysis suggested that the adsorption mechanism was physisorption.

Removal of leads broken during extraction: A comparison of different approaches and tools.

Extraction of a broken lead fragment (BLF) has received scant attention in the literature. Retrospective analysis was to compare the effectiveness of different approaches and tools used for BLF removal during 127 procedures. A superior approach was the most popular (75.6%), femoral (15.7%) and combined (8.7%) approaches were the least common. Of 127 BLFs 78 (61.4%) were removed in their entirety and BLF length was significantly reduced to less than 4 cm in 21 (16.5%) or lead tip in 12 (9.4%) cases. The best results were achieved when BLFs were longer (>4 cm) (62/93 66.7% of longer BLFs), either in the case of BLFs free-floating in vascular bed including pulmonary circulation (68.4% of them) but not in cases of short BLFs (20.0% of short BLFs). Complete procedural success was achieved in 57.5% of procedures, the lead tip retained in the heart wall in 12 cases (9.4%) and short BLFs were found in 26.0%, whereas BLFs >4 cm were left in place in four cases (3.1%) of procedures only. There was no relationship between approach in lead remnant removal and long-term mortality. (1) Effectiveness of fractured lead removal is satisfactory: entire BLFs were removed in 61.4% (total procedural success-57.5%, was lower because five major complications occurred) and BLF length was significantly reduced in 26.0%. (2) Among the broken leads, leads with a long stay in the patient (16.3 years on average), passive leads (97.6%) and pacemaker leads 92.1% are significantly more common, but not ICD leads (only 7.9% of lead fractures) compared to TLE without lead fractures. (3) Broken lead removal (superior approach) using a CS access sheath as a "subclavian workstation" for continuation of dilatation with conventional tools deserves attention. (4) Lead fracture management should become an integral part of training in transvenous lead extraction.

Adsorption Study for the Removal of Cadmium and Lead from Synthetic Storm Water Using Fired Clay

Adsorption Study for the Removal of Cadmium and Lead from Synthetic Storm Water Using Fired Clay

A novel approach for the modification of eggshell powder and its application for lead and methylene blue removal

Water pollution is one of the major concerns due to rapid industrialization and urbanization. Wastewater treatment has been an area of great interest for the researchers and among many technologies developed for water treatment, adsorption is the most preferred due to its efficiency and ability of been economical method. In this research, eggshell powder (ESP) is converted into modified eggshell powder (MESP) through chemical and thermal treatment (at 550 °C for 2 h) to use it as an adsorbent to remediate Pb2+ and Methylene blue (MB) from water, then it is transferred into modified eggshell powder magnetic composite (MESPMC) with iron coating to resolve the separation challenges and to boost the MESP's adsorption efficiency. FTIR analysis identified the functional groups of ESP, MESP, and MESPMC. XRD analysis reveals a hexagonal crystal structure of calcite in MESP and a combination of the hexagonal crystal structure of calcite and the cubic crystal structure of iron in MESPMC. The Scherrer equation is used to determine the average crystallite sizes of MESP and MESPMC, which are 22.59 nm and 12.15 nm, respectively. The SEM image shows the irregular shape of the MESP and MESPMC particles, as well as the active coating layer in MESPMC. EDX analysis reveals that Ca (20.92 %), O (56.83 %), and Fe (41.03 %), O (48.83 %) are the most abundant elements in MESP and MESPMC respectively. TGA analysis points out that MESPMC outperforms MESP in terms of thermal stability between 600 and 750 °C. MESP and MESPMC were found to be very efficient adsorbent for lead and methylene blue in aqueous medium. At 40 mg/mL adsorbent dosage, ESP, MESP, and MESPMC had the highest yields of Pb2+ removal, with 46.996 %, 99.27 %, and 99.78 % respectively at 200 rpm for 60 min with 25 °C. Furthermore, at the 0.5 mg/mL adsorbent dosage, ESP, MESP, and MESPMC have the maximum removal efficiency of methylene blue, with 47.19 %, 90.1 %, and 92 %, respectively at 200 rpm for 30 min with 25 °C. In both cases, the removal efficiency of MESPMC is slightly higher than that of MESP and much higher than that of ESP. Additionally, the results confirm that MESP and MESPMC are potential environment-friendly bio sources to remediate heavy metal (Pb2+) and methylene blue dye from water.