Leaching Of Rare Earth Elements Research Articles

Optimization of a Rare Earth and Aluminum Leaching Process from Weathered Crust Elution-Deposited Rare Earth Ore with Surfactant CTAB

Ammonium sulfate is typically employed as a leaching agent in the in situ leaching of weathered crust elution-deposited rare earth ore. However, it is associated with challenges such as low efficiency in mass transfer for rare earth (RE) leaching, high usage of the leaching agent, and prolonged leaching duration. To address the issues mentioned above, the surfactant cetyltrimethyl ammonium bromide (CTAB) was compounded with 2% ammonium sulfate to form a leaching agent in this paper. The effects of CTAB concentration, temperature, pH, and leaching agent flow rate on the rare earth (RE) and aluminum (Al) leaching mass transfer process from RE ore were investigated using chromatographic plate theory. The results revealed that CTAB addition improved the RE mass transfer process while moderately inhibiting the Al mass transfer efficiency. Increasing the temperature and pH of the leaching solution led to higher theoretical plate numbers for RE and Al leaching, lowered theoretical plate height (HETP), and enhanced leaching mass transfer efficiency. However, under high temperature and alkaline conditions, the mass transfer efficiency begins to decrease, indicating that high temperature and alkaline conditions are not conducive to the synergistic enhancement of RE and Al leaching by CTAB. Considering that clay minerals have good pH buffering properties, adjusting the pH of the leaching solution during rare earth ore leaching operations was deemed unnecessary. The optimal mass transfer conditions for leaching RE and Al were identified as 2% ammonium sulfate concentration, 0.00103 mol/L CTAB concentration, pH range of 5.2–5.5 for the leaching solution, 0.6 mL/min leaching solution flow rate, and room temperature. The rare earth leaching mass transfer effect could be enhanced during summer operations.

Utilizing Deep Eutectic Solvents in the Recycle, Recovery, Purification and Miscellaneous Uses of Rare Earth Elements.

The boosted interest in using rare earth elements (REEs) in modern technologies has also increased the necessity of their recovery from various sources, including raw materials and wastes. Though hydrometallurgy plays a key role in these recovery processes, some drawbacks (apparent or not) of these processes (including the use of aggressive mineral acids, harmful extractants, and diluents, etc.) have led to the development of an environmental friendship subclass named solvometallurgy, in which non-aqueous solvents substituted to the aqueous media of the hydrometallurgical processing. Together with ionic liquids (ILs), the non-aqueous solvents chosen for these usages are the chemicals known as deep eutectic solvents (DEEs). The utilization of DEEs included the leaching of REEs from the different sources containing them and also in the separation-purification steps necessary for yielding these elements, normally oxides or salts, in the most purified form. This work reviewed the most recent literature (2023 year) about using deep eutectic solvents to recover REEs from various sources and coupling these two (DESs and REEs) to derive compounds to be used in other fields.

The impact of apatite on sulfuric acid baking of a monazite concentrate and the benefit of goethite addition on rare earth leaching

Sulfuric acid baking of monazite ((Ce,La,Th)PO4) bearing ores is one of the major processes used in commercial production of rare earth elements. In hydrothermal vein type rare earth deposits, apatite is often found together with monazite. Rare earth enriched fluorapatite ores may also contain significant amounts of rare earths hosted in monazite. An understanding of the effect of apatite on the sulfuric acid baking of monazite is therefore important for the development of effective sulfuric acid based treatment methods for such ores. In this work, the addition of a natural hydroxyapatite (Ca5(PO4)3(OH)) sample to a monazite acid bake followed by acid leach was investigated using a combination of chemical analyses, SEM-EDS, XRD and TG-DSC. Hydroxyapatite addition significantly decreased the dissolution of rare earth elements from monazite in the leach after baking at temperatures above 300 °C. For a bake temperature of 500 °C, the rare earth dissolution in the leach dropped from 80% for monazite alone, to 30% for a 1:1 (w/w) addition of hydroxyapatite. This decrease in rare earth leaching was attributed to the formation of an insoluble thorium and rare earth bearing polyphosphate. The rare earth elements were incorporated into this polyphosphate phase in preference to calcium. At 800 °C, monazite was re-formed, causing a further reduction in rare earth extraction, while simultaneous formation of calcium pyrophosphate (Ca2P2O7) led to an increase in calcium and phosphorus dissolution. The detrimental effect of apatite could be partially overcome by the addition of goethite. Addition of goethite to the acid bake of a monazite/apatite mixture at 500 °C improved the total rare earth dissolution from 29% to 85% in the subsequent leach. Results also demonstrated that the order of reactivity, in terms of formation of polyphosphates is Fe > REE > Ca.

Effect of pretreatment methods on the selective leaching of rare earth elements from NdFeB permanent magnets using deep eutectic solvents

In this study, deep eutectic solvents (DESs) were employed as environmentally friendly alternatives of inorganic acid to selectively leach REEs from waste NdFeB magnets. Three DESs were tested, effective for light REE leaching, and preliminary experiments were conducted to study the selective leaching of REEs, using synthetic materials, Nd2O3, Fe, Fe3O4, and Fe2O3. The findings suggest that neodymium and iron should exist as Nd2O3 and Fe2O3, respectively, for selective leaching. To enhance the selective leaching of the NdFeB magnet, three pretreatment methods were applied: oxidative roasting, NaOH digestion, and NaOH digestion-oxidative roasting. During the oxidative roasting, NdFeO3 was formed, and it hindered REE leaching, achieving the highest REE leaching efficiency of 22.5% in the guanidine hydrochloride (GUC)-lactic acid (LA) DES. To counteract NdFeO3 formation, the NaOH digestion was introduced, yielding Nd(OH)3 and Fe3O4. These were then converted to Nd2O3 and Fe2O3 through oxidative roasting. With the NaOH-digested product, selective REE leaching was achieved solely with the ethylene glycol (EG)-maleic acid (MA) DES, while it was feasible in all three DESs with the NaOH digestion-oxidative roasting. The EG-MA DES displayed the highest selectivity, with a leaching efficiency of 97.3% Nd and 0.8% Fe. Additionally, the solvent could be reused at least twice, and the leaching efficiencies of 97% for Nd and 0.7% for Fe were maintained. This selective leaching technique benefits from using environmentally friendly solvents compared to the traditional inorganic acid leaching and demonstrates high REE selectivity and solvent reusability, suggesting a novel method for REE recovery via DESs.

Rare Earth Extraction from Phosphogypsum by Aspergillus niger Culture Broth.

The extraction of rare earth elements (REEs) from phosphogypsum (PG) is of great significance for the effective utilization of rare earth resources and enhancing the resource value of PG waste residues. This study used Aspergillus niger (A. niger) fungal culture filtrate as a leaching agent to investigate the behavior of extracting REEs from PG through direct and indirect contact methods. According to the ICP-MS results, direct leaching at a temperature of 30 °C, shaking speed of 150 rpm, and a solid-liquid ratio of 2:1, achieved an extraction rate of 74% for REEs, with the main elements being yttrium (Y), lanthanum (La), cerium (Ce), and neodymium (Nd). Under the same conditions, the extraction rate of REEs from phosphogypsum using an A. niger culture filtrate was 63.3% higher than that using the simulated organic acid-mixed solution prepared with the main organic acid components in the A. niger leachate. Moreover, the morphological changes observed in A. niger before and after leaching further suggest the direct involvement of A. niger's metabolic process in the extraction of REEs. When compared to using organic acids, A. niger culture filtrate exhibits higher leaching efficiency for extracting REEs from PG. Additionally, using A. niger culture filtrate is a more environmentally friendly method with the potential for industrial-scale applications than using inorganic acids for the leaching of REEs from PG.

Rare earth element systematics of chimney anhydrite from seafloor hydrothermal vents

Comparative studies of sulphide chemistry have been conducted over the past few decades to characterise seafloor hydrothermal mineralisation, but few studies have been carried out on sulphate minerals. Here we report on a systematic study of the S isotopic composition and rare earth element (REE) chemistry of chimney anhydrite from various types of seafloor hydrothermal vent fields in the Central Indian Ridge, North Fiji Basin, and Tonga intra-oceanic arc. Our results show that sulphate δ34S values of anhydrite cluster around that of seawater sulphate, indicating a significant role for fluid–seawater mixing during anhydrite precipitation. However, some anhydrite has δ34S values lower than that of seawater. This likely reflects sulphate derived from magmatic SO2 disproportionation. Chondrite-normalised REE patterns of the anhydrite are not uniform on the scale of individual grains and/or between each type of hydrothermal vent field. The REE compositions of the anhydrite do not have a clear relationship with the REE compositions of the primary host rocks with which the hydrothermal fluids interacted. This indicates that the REEs are not sensitive indicators of the host rock compositions, even though the host rocks are the dominant source of REEs in the seafloor hydrothermal fluids. In contrast, anhydrite REE concentrations and Eu anomalies are correlated with δ34S values and the redox state of the hydrothermal fluids, respectively. We suggest that relatively REE-enriched anhydrite is formed by efficient leaching of REEs from host rocks by acidic magmatic fluids (i.e., a low pH), whereas a low redox potential of the hydrothermal fluids is the most important factor controlling Eu mobility. The original concentrations of REEs supplied to the hydrothermal fluids can also be modified by fluid boiling and fluid–seawater mixing. The former produces light REE-depleted anhydrite because the availability of chloride ligands decreases in low-density vapor-dominated boiled fluids. In situ geochemical analysis of anhydrite on the intra-grain scale shows that high degrees of fluid–seawater mixing contribute to the relatively low REE concentrations and positive Eu anomalies. As such, our results indicate that the REE systematics of anhydrite are mainly controlled by the combined effects of fluid conditions (i.e., redox state, pH, and Cl concentrations) and sub-seafloor geochemical processes (i.e., magmatic input, fluid boiling, and seawater mixing) rather than the nature of the source materials. In situ analysis of anhydrite grains is a useful tool for constraining variable hydrothermal mineralisation conditions during chimney growth, which cannot be solely inferred from geochemical studies of sulphide minerals, particularly in inactive and relict systems where the hydrothermal fluids cannot be sampled.

Characterization and acid leaching of rare earth elements in coal gangue using pretreatment of selective grinding, tailings discarding and alkali roasting

Characterization and acid leaching of rare earth elements in coal gangue using pretreatment of selective grinding, tailings discarding and alkali roasting

Effect of Calcination Atmosphere on the Acid Leaching Recovery of Rare Earth Elements in Coal-Byproducts

ABSTRACT Thermal treatment of coal byproducts has been shown to improve leaching characteristics of rare earth elements (REEs) in bituminous coal sources due to its influence on the associated minerals. This study investigated the impact of the calcination atmosphere on REE leaching behavior in different density fractions of Baker and Fire Clay seam coarse refuse sources using a thermogravimetric analyzer to create an oxidizing or reducing atmosphere at a desired temperature for 2 h. The effect on leaching characteristics was evaluated using 1.2 M sulfuric acid at 75°C for 5 h at 1% w/v solid concentration. Rare earth element (REE) recovery for the 2.2 specific gravity (SG) sink fraction improved by approximately 15 absolute percentage points at 1000°C relative to the 600°C calcined sample in an inert atmosphere and equilibrated within 10 min from the start of the test. Contrarily, thermal treatment at 1000°C under oxidizing atmosphere significantly reduced the REE recovery due to sintering of the clays, which limited access to the RE minerals for leaching. In general, thermal treatment of heavier fractions in both atmospheres significantly improved the light REE (LREE) recovery while the increase in heavy REE (HREE) recovery was relatively less. As common clay minerals in the coal sources, kaolinite and illite samples were tested under the same conditions and using a digital scanning calorimeter. The findings confirmed that the improvement observed in REE leaching through thermal treatment at 600°C was due to decarbonization for the lighter density fractions and dehydroxylation of clays.

Use of Plackett–Burman Statistical Design to Study Factors Acting on the Nitric Acid Leaching of Rare Earth Elements from Moroccan Phosphogypsum

This work is an attempt to understand and optimize the rare earth elements leaching from Moroccan phosphogypsum using a nitric acid solution. The Plackett–Burman statistical design was used to identify the statistically significant factors responsible for the optimum leaching conditions. With this purpose, the following seven variables were studied: nitric acid concentration (X1), solid‐to‐liquid ratio (X2), temperature (X3), leaching time (X4), stirring speed (X5), drying (X6), and particle size (X7). Given that the leaching recovery of rare earth elements is limited by the quantity of dissolved phosphogypsum, we examined two simultaneous responses, namely, the leaching efficiency of rare earth elements YREEs and the leaching efficiency of calcium YCa (dissolution rate of phosphogypsum). The predicted values of the two fitted models were in good agreement with the experimental values by a coefficient of determination (R2) equal to 98.6% and 96.50%, respectively. In the model of YREEs, only the effect of drying was found to be statistically insignificant with a p‐value greater than 0.05. Nitric acid concentration, solid‐to‐liquid ratio, and temperature are the only variables having a statistically significant effect in the model of YCa. At a dissolution rate of phosphogypsum equal to 30.13%, the leaching efficiency of rare earth elements from our sample has reached a maximum of 87.55%. The optimal experimental conditions are a nitric acid concentration of 3.3 M, a solid‐to‐liquid ratio of 1/9, a temperature of 75°C, a leaching time of 20 min, a stirring speed of 200 rpm, and d ≤ 100 µm as a particle size.

Reducing rare earth loss by adding acetic acid in the aluminum removal process of rare earth leaching solution

The ionic-type rare earth ore, abundant in medium and heavy rare earth elements, is a strategic mineral resource. The removal of aluminum from ionic rare earth leaching solution results in over 8% loss of rare earths. Preliminary research has found that adding acetic acid (HAc) during aluminum removal process can effectively reduce the loss of rare earth elements. In this paper, through the calculation of the species distribution in the La2(SO4)3-Al2(SO4)3-HAc-H2O system, it is found that HAc forms an AlOH-Ac+ complex with aluminum ions, with a proportion of up to 70%, which will increase the initial precipitation pH of aluminum hydroxide. Furthermore, HAc and lanthanum form a LaAc2+ complex, and the proportion can reach more than 20%. Moreover, the zeta potential, FT-IR, and XPS tests of aluminum hydroxide, obtained by neutralization precipitation, revealed that the complexation of HAc and aluminum can reduce the precipitation rate of aluminum hydroxide, so that its particle size increases, the specific surface area decreases, and the van der Waals force adsorption sites are reduced. HAc can be chemically adsorbed on aluminum hydroxide, thereby increasing the zeta potential of aluminum hydroxide and ultimately reducing its electrostatic adsorption effect on rare earths. Additionally, the complexation of HAc and rare earth elements can reduce the local supersaturation of rare earth hydroxides and decline the coprecipitation of rare earth elements. Finally, under a precipitation endpoint pH of 5.2, HAc concentration of 0.006 mol/L, aluminum concentration of 0.2 g/L, rare earth concentration of 0.8 g/L, magnesium ion concentration of 0.5 g/L and magnesium oxide slurry concentration of 0.45 mol/L, the aluminum removal efficiency obtained with rare earth leaching solution reached 98.47%, and the rare earth loss efficiency was 2.62%. Compared with the control, the rare earth loss efficiency was reduced by 5.59%. This paper provides guidance for the efficient and green development of ionic-type rare earth ore.

Preparation of phosphorylated conjugated microporous organic polymers and extraction of low-concentration rare earth elements

Aiming at the extraction and recovery of rare earth elements (REEs) in low-concentration rare earth leaching tailings, a kind of phosphorylated conjugated microporous organic polymer (P-CMP) was prepared and applied to adsorb rare earth ions (Nd3+, Dy3+, Y3+). The structure of P-CMP was characterized by FT-IR. SEM and EDS were utilized to illustrate the surface morphology and element distribution of P-CMP, respectively.The adsorption mechanism of P-CMP was determined by XPS. The effects of pH, ion concentration and adsorption time on adsorption capacity were investigated. The isotherm of the rare earth adsorption process was fitted by Langmuir and Freundlich models, and the kinetics was fitted by Pseudo-firstorder and Pseudo-second-order. The results show that P-CMP is an amorphous microporous material, which has strong interaction with Nd3+ (30.18 mg/g), Dy3+ (37.84 mg/g) and Y3+ (22.01 mg/g), and the synergistic effect of amino and phosphate groups provides good selectivity (S.F.(Nd3+/Men+) = 5*103~5*104). The PCMP selectively adsorbs rare earth ions in the actual system and cycles 8 times.

Scalable and Consolidated Microbial Platform for Rare Earth Element Leaching and Recovery from Waste Sources.

Chemical methods for the extraction and refinement of technologically critical rare earth elements (REEs) are energy-intensive, hazardous, and environmentally destructive. Current biobased extraction systems rely on extremophilic organisms and generate many of the same detrimental effects as chemical methodologies. The mesophilic methylotrophic bacterium Methylobacterium extorquens AM1 was previously shown to grow using electronic waste by naturally acquiring REEs to power methanol metabolism. Here we show that growth using electronic waste as a sole REE source is scalable up to 10 L with consistent metal yields without the use of harsh acids or high temperatures. The addition of organic acids increases REE leaching in a nonspecific manner. REE-specific bioleaching can be engineered through the overproduction of REE-binding ligands (called lanthanophores) and pyrroloquinoline quinone. REE bioaccumulation increases with the leachate concentration and is highly specific. REEs are stored intracellularly in polyphosphate granules, and genetic engineering to eliminate exopolyphosphatase activity increases metal accumulation, confirming the link between phosphate metabolism and biological REE use. Finally, we report the innate ability of M. extorquens to grow using other complex REE sources, including pulverized smartphones, demonstrating the flexibility and potential for use as a recovery platform for these critical metals.

Intelligent leaching rare earth elements from waste fluorescent lamps.

Rare earth elements (REEs), one of the global key strategic resources, are widely applied in electronic information and national defense, etc. The sharply increasing demand for REEs leads to their overexploitation and environmental pollution. Recycling REEs from their second resources such as waste fluorescent lamps (WFLs) is a win-win strategy for REEs resource utilization and environmental production. Pyrometallurgy pretreatment combined with acid leaching is proven as an efficient approach to recycling REEs from WFLs. Unfortunately, due to the uncontrollable components of wastes, many trials were required to obtain the optimal parameters, leading to a high cost of recovery and new environmental risks. This study applied machine learning (ML) to build models for assisting the leaching of six REEs (Tb, Y, Eu, La, and Gd) from WFLs, only needing the measurement of particle size and composition of the waste feed. The feature importance analysis of 40 input features demonstrated that the particle size, Mg, Al, Fe, Sr, Ca, Ba, and Sb content in the waste feed, the pyrometallurgical and leaching parameters have important effects on REEs leaching. Furthermore, their influence rules on different REEs leaching were revealed. Finally, some verification experiments were also conducted to demonstrate the reliability and practicality of the model. This study can quickly get the optimal parameters and leaching efficiency for REEs without extensive optimization experiments, which significantly reduces the recovery cost and environmental risks. Our work carves a path for the intelligent recycling of strategic REEs from waste.

Strengthening rare earth and inhibiting aluminum leaching in magnesium salt-acetic acid compound system from ion-adsorption type rare earth ore

The leaching process of rare earth (RE) from ion-adsorption type rare earth ore (IATREO) using ammonium salt or magnesium salt as leaching agents presents challenges to inefficient leaching of RE elements and simultaneous leaching of ion-exchangeable phase aluminum (Al). This paper introduced acetic acid (HAc) into the leaching process of IATREO, to enhance the leaching of RE elements and inhibit the leaching of ion-exchangeable phase Al. The results show that RE elements and HAc mainly existed in the form of REAc2+, with a relative proportion of approximately 15 %. The presence of the HAc-Ac- conjugate acid-base pair provided a buffer capacity. In the MgSO4-HAc compound system, column leaching was controlled by internal diffusion, and the supplementation of HAc decreased the activation energy of the RE leaching reaction to 7.11 kJ/mol while increasing the leaching rate. Besides, the HAc-Ac- buffer system increased the pH of the leaching process and promoted the hydrolysis of ion-exchangeable phase Al, thereby inhibiting its leaching. Single-factor experiments indicated that under the optimal conditions, the leaching efficiency of RE elements reached 98.40 %, while the leaching efficiency of Al was 66.61 %. Compared with the ammonium and magnesium salts leaching systems, the leaching efficiency of RE elements increased by more than 6 %, while the leaching efficiency of Al was reduced by 23.33 %. This paper plays an important role in promoting the efficient and green extraction of IATREO.

Extraction of Rare Earth Elements from Brown Coals of the Sergeevskoe Deposit (Amur Region) According to Experimental Data

A series of experiments on the leaching of rare earth elements (REEs) from Miocene brown coals of the Sergeevskoe deposit with water and alkaline and acid solutions was carried out. Using a set of methods (ICP MS, XRD analysis, heavy concentrate analysis, SEM EDS, and IR spectrometry), it was revealed that acid leaching was the most effective: 72–99% of REEs was extracted with a 1 M solution of hydrochloric acid in 24–48 h. This fact indicates that most of the REEs in the brown coals of the Sergeevskoe deposit were associatedwith the organic matrix in the form of complexes with the carboxyl groups of humic and fulvic acids. The high percentage of REE extraction indicates the possibility of using coals from the Sergeevskoe deposit as an easily enriched source of REEs.

Geochemical behavior and source analysis of rare earth elements in intensive agriculture soils through high-resolution sampling

Rare Earth Elements (REEs) are crucial for a low-carbon economy but overuse pollutes ecosystems. Studying their behavior and source in agricultural soils provides vital insights for soil management. To address this, we collected an extensive dataset comprising 2901 topsoil and 733 subsoil samples from an agriculturally dominant region in eastern China, characterized by uniform parent material. This comprehensive dataset enabled a thorough examination of the geochemical behavior and sources of REEs in the region. Our findings revealed the feasibility of utilizing La, Ce, and Y to predict ΣREE, LREE, HREE, and LREE/HREE ratios, thereby enhancing the REEs database for eastern China. The average ΣREE concentration in the study area measured 193.0 μg/g, with LREEs constituting 89 % of this total, representing a slight enrichment relative to the Upper Continental Crust. Notably, the electron-donating ability of Ce exhibited a correlation with Mn, indicating its potential as an indicator of redox reactions. The results obtained through structural equation modeling and random forest analysis identified Al, Ti, and K as the most influential environmental factors affecting ΣREE concentrations. Additionally, the indirect impact of K on ΣREE through pH was established. The strong correlation observed between major elements and Heavy Rare Earth Elements (HREEs) shed light on the mechanisms responsible for the notable fractionation of REEs in topsoil. Furthermore, our investigation underscored the substantial influence of pedogenetic processes on the enrichment and leaching of REEs. Source analysis pinpointed significant contributors to REEs, including fertilizers, pesticides, domestic wastewater, coal fly ash, and the native soil parent material. In conclusion, our study emphasizes the pressing need for judicious control of anthropogenic REE inputs. This step is pivotal not only for ensuring the sustainable utilization of soil but also for ultimately safeguarding ecosystems and environmental quality.

Solidification treatment of rare earth tailings by a renewable biological cementation method

Rare earth mineral is a kind of polymetallic co-associated mineral, in addition to containing iron, rare earth, niobium, and a certain amount of thorium and uranium. The tailings after wet leaching of rare earth are both a kind of hazardous waste and a kind of potential strategic resource. Therefore, the treatment and disposal of rare earth tailings should not only achieve the purpose of risk control, but also cannot affect the subsequent reuse. Microbially induced calcium carbonate precipitation (MICP) as an environmentally friendly biological cementation technique, it can solidify the tailings and stabilize the polluting elements. The valuable elements in the tailings can be further recovered after the sample solidified by MICP is decomposed by acid. In this study, a strain of urease-producing bacteria (K-1) with excellent performance was screened by dilution culture method from rare earth tailings. Through physiological and biochemical analysis and 16 s rDNA analysis, the strain K-1 belonged to the genus Lysinibacillus. In the mold, strain K-1 was used to induce the formation of calcium carbonate for cementing rare earth tailings, the strength of the cured body after cementation can reach 1.73 MPa after 28 d. There was a significant reduction in the leaching of heavy metals and radionuclides in the cured body. The results obtained from the scanning electron microscopy (SEM) and X-ray diffraction (XRD) indicated that strain K-1 induced a large amount of calcium carbonate, whose crystal forms are vaterite and calcite. The calcium carbonates cemented the rare earth tailings together for tighter texture and reduced porosity. The X-ray fluorescence (XRF) analysis of the rare earth tailings before and after solidification and after acid decomposition showed that the loss of rare earth elements in rare earth tailings after MICP treatment was small. Moreover, the cured body was relatively easy to dissociate, which facilitated the recovery and reuse of potential valuable elements in the tailings. This study provides technical support for the long-term storage of rare earth tailings and the sustainable development of the rare earth industry.

Optimisation of ultrasound-assisted alkali-acid leaching of rare earth elements from run-of-mine and discard coal using the response surface methodology

This paper presents the results of an ultrasonic-assisted alkali-acid leaching process for concurrently recovering rare earth elements (REEs) and coal from South African run-of-mine (RMC) and discard (DC) coal. The response surface methodology (RSM) was used during the alkali leaching of DC to evaluate and optimise the process parameters. REE recovery increased while ash content decreased with increasing alkali leaching parameters (temperature, 20 °C-80 °C; concentration, 20%-40%; time, 30–120 min; and ultrasound frequency, 20–40 kHz). The optimal parameters achieved for DC were also used to pre-treat RMC. Pre-treatment of DC with the caustic solution at optimised conditions increased REE concentrations in RMC from 225.3 to 270.4 ppm and in DC from 245.5 to 301.5 ppm, respectively. Leaching of the alkalised samples with 7.5% hydrochloric acid (HCl) at 50 °C for 30 min, led to a TREE recovery of 88.8% and 79.6% from RMC and DC, respectively. The ash content in the samples was reduced in RMC from 50.9% to 36% and in DC from 68.3% to 59.3%. RMC proved to be a suitable source for the simultaneous extraction of the REEs and clean coal. Whereas, DC seemed to be a more viable secondary source of REEs only due to its higher TREE content and comparative REE recovery. This study demonstrated that coal used can be a valuable source of critical REEs that can be recovered effectively.

Leaching kinetics and permeability of polyethyleneimine added ammonium sulfate on weathered crust elution-deposited rare earth ores

At present, in-situ leaching of weathered crust elution-deposited rare earth ores (WCE-DREOs) encounter with problems such as long leaching cycles, slow infiltration rate and low product purity. In order to solve the above problems, the conventional leaching agent ammonium sulfate ((NH4)2SO4) was compounded with polymeric surfactant polyethyleneimine (PEI) to form a composite leaching agent. The effects of leaching temperature, PEI concentration, flow rate and pH on leaching kinetics and permeability of rare earths (RE) and aluminum (Al) in orebody were studied. It is found that with temperature increasing, the time required to reach leaching equilibrium for both RE and Al is shortened, the apparent activation energies of RE and Al are 14.79 and 13.45 kJ/mol, respectively, and the leaching processes are in accordance with the outer diffusion control. When the concentrations of (NH4)2SO4 and PEI in the composite leaching agent are 2.0 wt% and 0.4 wt%, the time required to reach leaching equilibrium for RE and Al is about 50% shorter than that using (NH4)2SO4 alone, and the leaching efficiencies of RE are slightly higher than that of Al. Properly increasing the temperature and flow rate of the composite leaching agent can improve the leaching efficiencies of RE and Al, but pH has neglected effects on the leaching efficiencies of RE. At PEI concentrations below 0.4 wt%, the addition of PEI promotes the leaching of RE and Al. In column leaching studies of the WCE-DREO, the addition of 0.4 wt% PEI to the traditional leaching agent (NH4)2SO4 has no impact on the leaching efficiencies of RE. However, it can significantly increase the infiltration rate of WCE-DREO, shortening the leaching time per 10 mL effluent from about 30 min for (NH4)2SO4 leaching system to 20 min for the composite leaching system. The leaching time is shortened by one-third, and the leaching cost is reduced, which can provide theoretical guidance for the development and commercial implementation of novel composite leaching agent for WCE-DREO.

A Critical Review of the Enhanced Recovery of Rare Earth Elements from Phosphogypsum.

The increasing demand for rare earth elements (REEs), especially from new and innovative technology, has strained their supply, which makes the exploration of new REE sources necessary, for example, the recovery of REEs from phsophogypsum (PG). PG is a byproduct during the wet production of phosphoric acid, which is an attractive secondary resource for REEs due to a large amount of REEs locked in them. In most cases, REEs contained in PG are mainly encapsulated in the gypsum crystal, leading to a low leaching efficiency. Therefore, it is particularly important to use various methods to enhance the leaching of REEs from PG. In this review, we summarized and classified various enhanced leaching methods for the recovery of REEs from PG, and the advantages and disadvantages of different methods were compared. A joint method of recrystallization and RIL may be a promising enhanced leaching approach for the recovery of REEs from PG. Recrystallization could achieve both the complete REE release and simultaneous preparation of industrial materials with high value added, such as high-strength α-hemihydrate gypsum by phase transformation of PG, and the RIL technology could adsorb the releasing REEs and realize their efficient extraction. Such a combination appears to show significant advantages because of high REE recovery, as well as high value-added product preparation at low cost.