Volcanic Ash Layers Research Articles

Scour ponds from unusually large tsunamis on a beach-ridge plain in eastern Hokkaido, Japan

Scour ponds from unusually large tsunamis cut across the crest of a beach ridge in Kiritappu marsh, eastern Hokkaido. No fewer than ten of these ponds were imaged by photogrammetry as elongate topographic depressions as large as 5 m by 30 m. Sediments in these ponds are underlain by unconformities that were detected with ground-penetrating radar and observed directly in cores and a slice sample. Sediment deposits in the ponds contain peat and volcanic ash layers, the ages of which suggest that the scouring occurred during tsunamis generated by spatially extensive thrust ruptures along the southern Kuril trench, most recently during the early seventeenth century and its predecessor during the thirteenth–fourteenth century. Some of the ponds appear to have been formed during one tsunami and refreshed during later successors. This evidence of recurrent erosion suggests that the shoreline may retreat as part of earthquake-related cycles of coastal uplift and subsidence.

The coal-forming environment during mass extinction in the latest permian: Evidence from geochemistry of rare Earth elements

The C1 coal of Latest Permian during mass extinction in eastern Yunnan was studied to reveal the terrestrial paleoenvironment and influence of geological events on coal-formation during mass extinction. An analysis of Rare Earth Elements (REEs) was conducted on the C1 coal from the Yantang Mine of Xuanwei, eastern Yunnan Province, which was deposited during the latest Permian. A total of 24 samples from coals, partings, roofs and floors from the C1 coal were taken from the fresh face in the underground mine. The results of the REEs analysis indicated that the total REE content (∑REE) in the C1 coal varies from 23.99 μg/g to 267.94 μg/g, averaged 122.69 μg/g. The C1 coal is enriched in light REE (LREE) relative to heavy REE (HREE), signifying the fractionation between LREE and HREE. Most samples of the coal seam C1 are depleted in Eu in various degrees and slightly depleted in Ce, especially two partings in sub-seams B1 and B3 which show the significant negative Eu anomalies. The geochemical characteristics of REE reveal that the C1 coal was deposited in a weak oxidation environment; the sedimentary environment was turbulent during the middle-later stage of coal-forming process; the C1 coal was affected by the basalt clastic materials from the Khangdian Oldland and acidic synsedimentary volcanic ash in the coal-forming period. The geochemical characteristics of Tonsteins in C1 coal are similar to those of marine Permian-Triassic boundary (PTB) volcanic ash layers in South China, which are both derived from the felsic volcanism caused by the closure of the Paleo-Tethys at the southwestern margin of the South China. Furthermore, the C1 coal was also affected by the eruption of Siberian large igneous province (SLIP) in the early stage.

A synthesis of Carboniferous stratigraphy in Xinjiang, Northwest China with emphasis on regional and global correlations

The Carboniferous is the most widely distributed system in the pre-Mesozoic strata of Xinjiang, Northwest China, and they are exposed in structurally independent units within various tectonic settings across the southwest Central Asian Orogenic Belt and Tarim Craton in Northwest China. According to the lithofacies associations and biotic assemblages, the Carboniferous successions of Xinjiang can be divided into 18 stratal regions, and each of these stratal regions may be further separated into several subregions in terms of lithology, biota, and geochronologic data. The depositional succession of each region is described on the basis of the key section. The marine fossils such as foraminifers (fusulinids), brachiopods, corals, and conodonts, as well as nonmarine fossils such as plants and pollens are reviewed in this study. Combined with the geochronologic data from the volcanic rocks and ash layers, a refined scheme of the Carboniferous successions in different regions across Xinjiang, Northwest China is obtained. The detailed and newly established stratigraphic framework of the Carboniferous strata could be very helpful for the regional and global stratigraphic correlations. It can also offer a new and reliable chronostratigraphic foundation for the comprehensive understanding of the tectonic evolution and petroleum exploration in Central Asia.

Palynological Characteristics and Volcanic Ash from Sediments of Chistoye Lake, Northern Priokhotye

Chistoye Lake (59° 32' N, 151° 48' E) is located 10 km from the northern coast of Taui Bay (Okhotsk Sea) in the central part of a tectonic depression that has been infilled with Paleogene and Neogene deposits. The lake originated as the result of glacial activity during the latest Pleistocene (MIS2). A 550-cm-long lacustrine sediment core was raised from Chistoye Lake using a piston sampler. The core is dominated by silt with layers of peat and sand at its base. The silt includes two tephra layers at 360-364 cm and 77-80 cm. The tephra layers have different geochemical, magnetic, and mineralogical properties. Volcanic ash like the lower tephra in the Chistoye core has been found in other lacustrine sites from the Upper Kolyma, Upper Indigirka, and Northern Priokhotye regions. Radiocarbon dating of organic remains that bracket this second tephra, corresponding to the lower tephra in Chistoye Lake, indicates an age of 7 650 ± 50 years ago, which is comparable with the age of the Kurile Lake - Iliyinskaya caldera forming eruption in Kamchatka. The younger tephra also has been noted in cores from other lakes in Northern Priokhotye and dated to 2 745 ± 10 years ago. A distinctive feature of this Late Holocene tephra is its high magnetic susceptibility. Extrapolation of a sedimentation rate based on the tephra ages suggests that the Chistoye record is approximately 11 700 years old. Palynological analysis of the Chistoye Lake material showed that all samples contain pollen redeposited from Neogene sediments (Picea sect. Eupicea, Tsuga, Tilia, Corylus, Juglans, Ulmus). These taxa can be easily discounted as contaminant, but other pollen types (e. g., Pinus subgen. Haploxylon, Betula, Alnus, Cyperaceae, Poaceae) are more problematic for interpreting the paleovegetation, because they represent plants that were present during the Holocene and/or the Late Pleistocene and during the Neogene. Nonetheless, the changes in the percentages of Sphagnum spores suggest a gradual increase in effective moisture during the Younger Dryas and Holocene. A multiproxy study of the sediments from Chistoye Lake, in conjunction with their palynological characteristics, shows the importance of analyzing magnetic properties to help determine the presence of tephra in the sediments. Volcanic ash layers in the lake sediments from northeastern Siberia are reliable chronostratigraphic markers that can supplement radiocarbon dates and improve the regional understanding of climate and vegetation changes during the Holocene.

Clay mineralogy mediated by pH and chemical weathering intensity of Permian–Triassic boundary K-bentonites at Dongpan (Guangxi, South China)

Volcanic ash deposits of the Permian-Triassic (P-T) transition in South China, in addition to being associated with the Permian-Triassic boundary mass extinction, are useful marker beds for regional correlation of sedimentary strata. This study investigates the source(s) of P-T volcanic ash layers in South China by studying their clay mineralogy and geochemical characteristics in deep-marine facies at Dongpan. Mineralogically, the Dongpan deposits consist mainly of clay minerals and quartz, with small amounts of anatase and feldspar. C lay minerals in the volcanic ash layer are mainly composed of R1 mixed-layer illite/smectite (I/S) (56.2–74.8%), smectite (14–22.8%), kaolinite (5.4–27.3%) and illite (1.2–5.3%). The relatively high content of kaolinite and weak illitization of smectite at Dongpan differ from the features of clay-mineral assemblages in other contemporaneous deep-water facies. Our results indicate that strong chemical weathering in an acidic and oxidizing environment characterized by low K+/H+ ratios inhibited uptake of K+ in the interlayers of I/S clay minerals and, thus, illitization of smectite. We infer that weathering intensity rather than redox state was the primary influence on the rate of kaolinization of clay minerals in these deep-marine facies. The Dongpan section exhibits a uniform REE pattern, indicating a single and stable source of volcanic ash during the P-T transition. Trace-element and REE distribution patterns and mixed-layer I/S clay-mineral morphologies are consistent with the source of the volcanic ash at Dongpan being a nearby continent-margin volcanism.

Long-term change of the eruption activities of Sakurajima volcano, Japan, inferred from the fallout tephra deposits

Stratigraphic analysis of fallout tephra deposits in and around a volcano provides a framework for understanding the long-term temporal change in the volcano’s activities. Here, we reconstruct the evolution of the volcanic activities of Sakurajima volcano based on reconstructed tephra stratigraphy by original field surveys, compilations of geological and archeological data, and new 14C dating. We define three eruption stages of Stage 1 (30–24 ka), Stage 2 (12.8–4.8 ka), and Stage 3 (4.5 ka–present), based on a major hiatus and shifting of the volcanic centers. Stages 2 and 3 are further subdivided according to the predominant mode of volcanic activity. Revised distribution of tephra deposits indicates that a total of 14.5 km3 (5.8 km3 dense rock equivalent) of fallout tephra has erupted from Sakurajima. Among them, Stage 2a (13–8 ka) produced the largest volume of tephra fallout deposits, suggesting that Sakurajima peaked in magma discharge during Stage 2a (2.9 km3/kyr) and then decreased rapidly toward Stage 2b (8–4.8 ka; 0.07 km3/kyr). The eruption of large-volume tephra deposits in Stage 2a, followed by the development of a thick volcanic ash layer in Stage 2b, indicates the eruption style shifted from explosive pumice eruptions in Stage 2a to ash-producing Vulcanian activity in Stage 2b, with decreasing magma discharge rate. Thick volcanic ash deposits covered by several fallout tephra deposits during Stage 3 also reflect a shift in activity from repeated Vulcanian explosions with lava effusions in Stage 3a (4.5–1.6 ka) to predominantly pumice eruptions during the historical period (Stage 3b) with an increasing magma discharge rate. The case study of Sakurajima presented here demonstrates that the combined analysis of the distribution, stratigraphy, and age of pumice fall layers with the lava and pyroclastic cone deposits on the volcanic edifice is a powerful tool for deciphering the growth history of complex stratovolcanoes.

Provenance changes for mineral matter in the latest Permian coals from western Guizhou, southwestern China, relative to tectonic and volcanic activity in the Emeishan Large Igneous Province and Paleo-Tethys region

Recent studies have found that the provenance for water-transported sediments in some coal seams in the Late Permian and Early Triassic sequences from SW China have changed from mafic rocks of Emeishan Large Igneous Province (ELIP) to intermediate-felsic and alkaline igneous rocks from the ELIP and Paleo-Tethys convergent margins. However, the mechanism of provenance changes for mineral matter in the late Permian coals from SW China remains unclear. This paper uses the detailed mineralogical and geochemical characteristics of the latest Permian coal-bearing strata from the Huopu coal deposit in SW China to identify the potential detrital provenances of mineral matter.The mineralogy of the Huopu coals is dominated by kaolinite, quartz, and calcite. Fracture-filling kaolinite, calcite, quartz, anatase, as well as closely coexisting fracture-filling kaolinite, quartz, and chamosite, were possibly formed by multiple-stage solution injections. The Al2O3/TiO2 values, REY distribution patterns (REY, rare earth elements and Y), as well as Nb/Yb vs. Al2O3/TiO2 and Zr/TiO2 vs. Al2O3/TiO2 diagrams all indicate that the roof and floor sediments of the coal seam were sourced mostly from the ELIP high-Ti basalts. In contrast, the inorganic matter of the coals was derived from the Kangdian tops exposing (1) the Proterozoic meta-granitic complex; (2) the ELIP’s volcanic complex including, in addition to basalts, alkaline and intermediate-felsic lavas and small intrusions; and (3) volcanic ashes from the Paleo-Tethys convergent margins. The latest Permian sedimentation in the Huopu coal deposit is suggested to have been controlled by tectonic activity along the Xiaojiang Fault that separates the inner ELIP from the Western Yangtze Cratonic Basin (WYCB). This activity is characterized by repeated uplifts of the inner ELIP associated with some downward movements in the WYCB and vice versa. The ELIP uplift and WYCB subsidence may have led to intensive erosion of the ELIP basalts and marine transgression producing the clastic sediments, while the ELIP’s downward movement associated with some WYCB uplift may have promoted peat deposition and erosion of the Kangdian tops exposing both the ELIP intermediate-felsic volcanic rocks and the older meta-granitic complexes. Both sedimentation regimes were evidently accompanied by volcanic activity on the Paleo-Tethys convergent margins, but preservation of the volcanic ash layers was possible only during more quiescent peat-accumulation periods. The reduced detrital supply in these periods would result in a higher proportion of the intermediate-felsic pyroclastic debris disseminated in the coals.

Orbital-scale cyclicity and organic matter production in a Permian shallow mixed carbonate-siliciclastic system: Paraná Basin, Brazil

Mixed deposition in shallow seas is highly sensitive to climate variations and sea-level changes, which are the primary controls of high-frequency cycles in the stratigraphic record. The widespread Lower Permian mixed carbonate-siliciclastic succession of the Paraná Basin is composed of rhythmic organic-rich shale interbedded with dolostone. The strata are organized into several orders of magnitude of superimposed asymmetrical and symmetrical facies stacking patterns that developed in a broad epeiric sea, which extended over 106 km2 of Permian Gondwanan land. Detailed sedimentological and stratal stacking analysis allow the hierarchical organization to be identified in large-scale, medium-scale, small-scale, and elementary stacking patterns. The high-frequency depositional cycles compose four 3rd-order sequences. They comprise gray to black shale, marls, and peloidal to micritic dolostone. Due to the shallow water setting, the minimal available accommodation is responsible for the reduced cycle thickness and the overall mixed succession. The rhythmic deposits host highly productive hydrocarbon source rocks. Two widespread, thicker intervals of bituminous shale that develop during 3rd-order sequence transgression events are highly organic-rich oil shale (27 wt%). In addition, thin black shale laminae, which are interbedded with dolostone in high-frequency stacking patterns, are also rich in organic carbon (2–8 wt%). The alternation of high carbonate content and organic matter production was controlled by wet‒dry seasons and was related to total solar radiation maxima and minima. The total solar radiation maxima are translated into elevated carbonate precipitation due to shallower and hypersaline conditions. Total solar radiation minima induce freshwater discharge in shallow and hypersaline environments during wet stages, resulting in water column stratification. The occurrence of kerogen types III and IV, a high gammacerane index, variable Pr/Ph ratios, and C35 homohopane indices indicate this condition. In addition, the input of nutrient-rich terrigenous sediments favor algal blooms, enhancing anoxia in the bottom water, which is responsible for the organic-rich shale facies, as indicated by kerogen types I and II, high hydrogen index values, high C27/C29 sterane ratios, and higher β-carotane values. Based on the hierarchical organization and previous U–Pb SHRIMP zircon ages of volcanic ash layers, it is possible to correlate the observed succession with the global sea-level curve. A time span of 8.0 Ma is assessed for the Irati Sea, with an average of 2.7 Ma for the large-scale cycles. Furthermore, the high-frequency patterns that are compatible with the precession and eccentricity of the short (±100 ka) and major (±400 ka) periodicities of the Earth's orbit are estimated to be 26.6 ka, 135.5 ka, and 400 ka. The high-frequency cycles of organic-rich shales and carbonate that are deposited over thousands of years under long-term sea-level changes and are correlated along the basin suggest climatic control driven by the Earth's orbital perturbation, which is possible in the Milankovitch frequency band.

Natural glass alteration under a hyperalkaline condition for about 4000years.

Silicate glasses are durable materials in our daily life, but corrosion rate accelerates under alkaline aqueous environment. Such situation has raised concerns, for example, in nuclear waste disposal where vitrified wastes encounter to alkaline leachate from surrounding concrete materials. Here we report volcanic glass example surviving with a hyperalkaline groundwater (pH > 11) and high flow rate for about 4000 years. The tiny glass fragments were extracted from the volcanic ash layer sandwiched between ultramafic sediments using microanalytical techniques. Sharp elemental distributions at the glass surface, where amorphous-like smectite precursors and crystalline smectites coexist, suggest the corrosion by an interface-coupled dissolution–precipitation mechanism rather than inter-diffusion. The corrosion rate was maintained at, the minimum, 2.5 orders of magnitude less than the rate observed for fresh glass, even in the presence of Fe and Mg that might have consumed Si through the silicate precipitation.

An astronomically calibrated 40Ar/39Ar age for the North Atlantic Z2 Ash: Implications for the Greenland ice core timescale

Timescales based on counted annual ice layers underpin the interpretation of late Quaternary rapid climatic oscillations recorded in the Greenland ice cores and their correlation to tropical and Antarctic climate archives. An inherent problem in the annual counted ice layer dating method is the large accumulated age uncertainties for the older part of the Greenland ice core timescale due to so called uncertain annual ice layers. Annual ice layers become thinner with depth due to increased compaction. Thus, the occurrence of uncertain annual layers becomes more frequent, such that by a depth of ∼2150 m (43 ka) in the NGRIP ice core the accumulated uncertainty on the age is > 2%. Radio-isotopic age determination of interbedded volcanic ash layers can provide independent verification of the Greenland counted annual ice layer ages along with the possibility of improved precision for the older part of this important timescale. Here we report an astronomically calibrated Ar40/Ar39 age of 56.14 ± 0.44 ka (2σ) for the widespread North Atlantic Z2 ash forming Icelandic Thórsmörk peralkaline rhyolitic eruption. The Z2 ash is found at a depth of 2359.45 m in the NGRIP ice core and has an annual layer counted age of 55.38 ± 2.37 ka (2σ, b2k). Our radio-isotopic age for the Z2 eruption is > 5 times more precise than the one based on counted annual ice layers and when referenced relative to b2k indicates that the oldest part of the GICC05 timescale is systematically too young by approximately 740 years. We use our Z2 eruption age to calculate refined astronomically calibrated ages for Greenland Interstadials (GI) 11 to 17 which results in reducing the age uncertainties on the majority of these events from the millennial to the centennial level. Our refined ages for GI 11–17 generally show good agreement with the NALPS U–Th stalagmite record that covers this same interval and together these high-precision radio-isotopic timescales provide firmer constraints for testing for synchronicity, or leads and lags between different geographical parts of the late Pleistocene climate system.

Effect of Volcanic Activity on Hydrocarbon-Forming Organisms in Organic-Rich Shale: A Case Study of Dalong Formation in Northwestern Sichuan Basin, China

Hydrocarbon-generating material determines the elemental composition and hydrocarbon-generating potential of kerogens in a source rock, and it is the key material basis to control the hydrocarbon-generating capacity of the source rock. Previous studies have shown that many intervals of high-quality source rocks generally contain a varying number of volcanic ash layers. The impact of these volcanic ash layers on the development of high-quality source rocks has attracted extensive attention. However, these studies mainly focused on the development of hydrocarbon-forming organisms and the preservation of organic matters but rarely dealt with the differential development of hydrocarbon-forming organisms between multiple volcanic ash layers. The Permian Dalong Formation in the northwestern Sichuan Basin, China, is a set of high-quality source rocks with multiple volcanic sedimentary layers. To understand the differential development of hydrocarbon-forming organisms between volcanic ash layers, with the Dalong Formation in the Longfeng quarry section, Guangyuan, the Sichuan Basin as an example, this study analyzes the types of hydrocarbon-generating materials of high-quality source rocks of the Dalong Formation and the reasons why volcanic activities affected the growth of hydrocarbon-forming organisms and explores the impact of volcanic activities on the development of different types of hydrocarbon-forming organisms. The results show that the TOC of the Longfeng quarry section is 0.05%–15.46%, with an average of 4.76%, and the average TOC of the Dalong Formation is as high as 5.16%, which belongs to high-quality source rocks. The hydrocarbon-forming organism association in the Dalong Formation source rocks is mainly composed of floating algae and benthic algae and vertically divided into three parts: a few radiolarians and trace fossils occasionally in the lower part; a large number of radiolarians, calcium spheres, and algal debris in the middle part; and mainly foraminifera and gastropods in the upper part. There are 36 volcanic ash layers in the Dalong Formation of the study area. In the process of volcanic activity, the “fertilization” effect of volcanic ash made the nutrient elements in the volcanic ash enter water, increasing the number of hydrocarbon-forming organisms, causing the differential development of various hydrocarbon-forming organisms, and promoting the formation of reducing water to support the preservation of organic matters. The development of hydrocarbon-forming organisms is controlled by the changes of element types and abundances caused by magmatic properties. The time interval of volcanic activities also has an important impact on the development of hydrocarbon-forming organisms.

Reexamination of Eruptive Activity of Akanfuji in the Me-Akan Volcano, Eastern Hokkaido, Japan

Eruption history of Akanfuji in the Me-akan volcano, eastern Hokkaido, has been examined by comparing multiple natural outcrops. In a previous study, at least 17 layers of scoria fall deposits were recognized. To obtain more detailed geological information and reexamine the eruptive activity of Akanfuji, we conducted trench surveys. At each survey site, the scoria fall deposits from Akanfuji are layered with a total thickness of several tens of centimeters to 1 m. A light brown volcanic ash layer is deposited just under the lowest layer of Akanfuji, and the fresh glass in the light brown volcanic ash shows the glass composition of the volcanic ash that erupted at Tarumai volcano 2500 BP. In addition, volcanic ash ejected from Ponmachineshiri of the Me-akan volcano is deposited on top of the newest deposits in the Akanfuji series with a thin soil layer in between. The volcanic ash ejected from Ponmachineshiri contains patches of volcanic ash from the Mashu volcano that erupted 1000 years ago. Therefore, Akanfuji was active from about 2500 to 1000 years ago. Akanfuji ejected scoria fall deposits at least 17 times (Akf-1 to Akf-17), and assuming that it erupted an average number of times during the activity period, it would be once every 90 years. The eruption rate was estimated to be 0.12 km3 DRE/ka.

Global tephra studies: role and importance of the international tephra research group “Commission on Tephrochronology” in its first 60 years

Abstract. Tephrochronology is a correlational and age-equivalent dating method whereby practitioners characterize, map, and date tephra (or volcanic ash) layers and use them stratigraphically as connecting and dating tools in the geosciences (including volcanology) and in studies of past environments and archaeology. Modern tephra studies per se began around 100 years ago (in the 1920s), but the first collective of tephrochronologists with a common purpose and nascent global outlook was not formed until 7 September 1961 in Warsaw, Poland. On that date, the inaugural “Commission on Tephrochronology” (COT) was ratified under the aegis of the International Union for Quaternary Research (INQUA). The formation of COT is attributable largely to the leadership of Kunio Kobayashi of Japan, the commission's president for its first 12 years. We were motivated to record and evaluate the function and importance of COT because tephrochronology continues to grow globally and its heritage needs to be understood, appreciated, and preserved. In addition, studies on cryptotephras, which are fine-grained glass-shard and/or crystal concentrations preserved in sediments or soils but insufficiently numerous to be visible as a layer to the naked eye, have also expanded dramatically in recent times. Therefore, in this article, we review the role and impacts of COT under the umbrella of INQUA for 53 of the last 60 years or under IAVCEI (International Association of Volcanology and Chemistry of the Earth's Interior) for 7 of the last 60 years, including since 2019. The commission also functioned under other names (abbreviated as COTS, CEV, ICCT, COTAV, SCOTAV, and INTAV; see Table 2 for definitions). As well as identifying key persons of influence, we describe the development of the commission, its leaders, and its activities, which include organizing nine specialist tephra field meetings in seven different countries. Members of the commission have participated in numerous other conferences (including specialist tephra sessions) or workshops of regional to international scale, and they have played leading roles in international projects such as INTIMATE (INTegrating Ice-core, MArine and TErrestrial records) and SMART (Synchronising Marine And ice-core Records using Tephrochronology). As well as strongly supporting early-career researchers including graduate students, the commission has generated 10 tephra-themed journal volumes and two books. It has published numerous other articles including field guidebooks, reports, and specialist internet documents/sites. Although its fortunes have ebbed as well as flowed, the commission began to prosper after 1987 when key changes in leadership occurred. COT has blossomed further, especially in the past decade or so, as an entire new cohort of specialists, including many engaged in cryptotephra studies, has emerged alongside new geoanalytical and dating techniques or protocols to become a vibrant global group today. We name 29 elected officers who have been involved with COT since 1961 as well as 15 honorary life members. After reviewing the aims of the commission, we conclude by evaluating its legacies and by documenting current and future work.

The influence of Late Ordovician volcanism on the marine environment based on high-resolution mercury data from South China

AbstractVolcanic ash interbeds in the Late Ordovician strata in South China record highfrequency volcanic activity. To assess the impact of these volcanic events on the climate and marine biological evolutionary crisis during the Late Ordovician Mass Extinction (LOME), we present high-resolution measurements of mercury (Hg) concentrations and organic carbon isotope ratios (δ13Corg) in an Ordovician–Silurian sedimentary succession (Muchanggou section). The results show that high-frequency volcanic ash layers and Hg enrichments developed synchronously in the Katian graptolite P. pacificus (Lower Subzone) and T. typicus biozones and are coupled with a negative shift of ~1‰ in δ13Corg, which reflects the perturbation of the surface carbon and mercury cycles by intense volcanic activity. Based on volcanic Hg fluxes, it is estimated that more than 1.1 × 1013 tons of CO2 were emitted by the Katian volcanic activities in South China, which interrupted the growth of the polar ice sheet and the rapid cooling of tropical oceans in the mid-Boda event. As volcanism weakened, increased weathering led to the growth of the polar ice sheet and cooling in the Hirnantian. Both regional and global biodiversity declined rapidly with the end of volcanism, which suggests that the marine ecological crisis was related to a series of disruptions in biogeochemical cycles in the post-volcanic period.

The body of the Bellingshausen Ice Dome as a biogeochemical space

The investigation of glacial sediments has not received a lot of attention, but the processes in place on the surface of glaciers are quite interesting and multidirectional. In this article, we focused on glacial sediments material sampled from the surface of the Bellingshausen Ice Dome (King George Island, South Shetland Islands, Antarctica). These sediments have different genesis: material from cryoconite holes, denuded layers of volcanic ash, flushed ash and soils and soil-like bodies formed in the glacial zone. Chemical analysis of the samples showed that the bulk composition of sediments is as follows: SiO2 > Fe2O3 > Al2O3 > SO3 > CaO > MgO > Na2O > TiO2 > K2O > P2O5 > MnO (with SiO2 content 50–55%, Fe2O3 – 17–23%, Al2O3 – 6–12%). The loss on ignition was maximum (10–11%) for samples taken at the top of the dome. Calculation of geochemical indexes showed that the mineral part of the samples is a product of erosion and sedimentation processes and is less chemically weathered in the lower part of the ice dome. The weathering type is fersiallitic. The maximum content of organogenic compounds (Total organic carbon – up to 5%, ammonium nitrogen – up to 116 mg/kg and mobile potassium – up to 373 mg/kg) also recorded at the top of the glacial dome; this may be associated with microbiological activity in cryoconite holes and the penetration of organic material from bird fauna. The low content of organogenic compounds on the slopes is caused by the processes of their washout with melt water. The content of trace metals Zn, Ni, and Pb found at higher elevations and distribution of Cu and Cd have more a local character associated with tourism activities and anthropogenic influence from year-round scientific stations. Thus, a number of multidirectional processes take place in the glacial sediments on the Bellingshausen Ice Dome, these are not simple denuded layers of ancient volcanic ash. The glacier cover can be considered as a “living” biogeochemical shell, accumulating products of microbiological and anthropogenic activity, products of erosion and sedimentation and organic matter of ornithogenic origin.

Depositional age models in lacustrine systems from zircon and carbonate U‐Pb geochronology

AbstractThe Yacoraite Formation (Salta rift, Argentina) consists of Maastrichtian–Danian lacustrine carbonate and siliciclastic deposits with interbedded volcanic ash layers, organized in four third‐order stratigraphic sequences. It offers the exceptional opportunity to jointly apply in situ zircon and carbonate U‐Pb geochronology that resulted in two distinct depositional age depth models. Ages of the youngest zircon population from ash layers were linearly interpolated to derive a zircon depositional age depth model. A carbonate depositional age depth model was instead obtained from dated carbonate phases including microbialites, ooids, oncoids of calcitic and dolomitic mineralogy as well as early lacustrine calcite cements. Mean ages were defined from different carbonate phases belonging to the same layer and then linearly interpolated. Sedimentation rates were calculated from both depth models between pairs of dated samples and used to estimate the age of sequence boundaries, as well as the duration of the four stratigraphic sequences. The zircon and carbonate depositional age depth models agree with biostratigraphic constraints and exhibit excellent consistency. The onset and end of sedimentation were estimated at 68.2 ± 0.9 Ma and 62.3 ± 0.6 Ma (duration ca 5.7 Ma) via zircon geochronology and at 67.9 ± 1.7 Ma and 61.9 ± 1.3 Ma (duration ca 6.0 Ma) via carbonate geochronology. Results from this study show that with suitable samples and a newly implemented working strategy, in situ U‐Pb dating of depositional and early diagenetic carbonates represent a valuable chronostratigraphic tool for estimating sedimentation rate and duration in poorly time‐framed depositional systems.

The role of organic matter diversity on the Re-Os systematics of organic-rich sedimentary units: Insights into the controls of isochron age determinations from the lacustrine Green River Formation

The range of 187Re/188Os values measured from samples of five organic-rich lacustrine mudstones units in the Eocene Green River Formation in the easternmost Uinta Basin covaries with organic matter diversity driven by changing water column conditions. A set of samples from the Douglas Creek Member has the highest pristane/phytane ratio and lowest β-carotane/n-C30 ratio compared to overlying units, indicating deposition in an oxic-anoxic environment with low salinity that would have allowed for the accumulation of a diverse assemblage of aquatic organisms. These samples define the broadest 187Re/188Os range of 1504. In contrast, samples from the R6 and Mahogany zones possess lower pristane/phytane ratios and higher β-carotane/n-C30 ratios indicating deposition in a more restricted lacustrine environment with elevated salinities and alkalinities that would have limited aquatic organic matter diversity. The R6 and Mahogany zones have the narrowest range of 187Re/188Os values measured in this study of 254.9 and 154.6, respectively. As noted by previous workers, these results suggest that organic matter diversity plays a primary role in determining the range of 187Re/188Os ratios in a sample set, and in turn the uncertainty of Re-Os age determinations from organic-rich sedimentary rocks.The Re-Os data from the R3 zone and R6 zone yield ages of 49.7 ± 3.4 Ma and 42.0 ± 18 Ma, respectively, which are statistically indistinguishable based on 2σ uncertainty from three previously reported Re-Os age determinations and those provided by 40Ar/39Ar geochronology of interbedded volcanic ash beds. Although the age uncertainty is high, these findings further highlight the importance of Re-Os geochronology in lacustrine basins, particularly those with thick mudstone successions that lack volcanic ash layers, reliable biostratigraphy, or magnetostratigraphic control. In these cases, even ages with large uncertainties can be useful to constrain burial history and thermal history models.Together, the initial 187Os/188Os ratios of five sets of samples analyzed from the Uinta Basin define the largest Os isotope stratigraphic record from any lacustrine basin compiled to date and record a shift from a value of 1.40 to 1.48 between the R3 and R4 zones in the lower part of the Parachute Creek Member. This small shift may signify a change in the chemical weathering products that entered the lake preserved 20 to 50 m above the contact between the Douglas Creek and the lower Parachute Creek members during a period when the basin transitioned from a shallow lake with mostly open hydrology to an alkaline lake with more frequent basin restrictions.

How reliable is µXRF core scanning at detecting tephra layers in sedimentary records? A case study using the Lake Suigetsu archive (central Japan)

AbstractHere, we evaluate the ability of micro X‐ray fluorescence (µXRF) core scanning to identify non‐visible volcanic ash (cryptotephra) layers in sedimentary records. Its suitability is assessed using the annually resolved lacustrine sediments of Lake Suigetsu (Japan) for which there is high‐resolution ITRAX µXRF core scanning data, and a detailed crypto‐tephrostratigraphy (formerly established via density separation techniques). The studied core sections contain 10 visible and 30 cryptotephra markers that span a range of glass concentrations (from 1000 to >20 000 shards per gram of dried sediment) and compositions (basalts, trachy‐andesites, phonolites, trachytes and rhyolites), thus providing an ideal case study. The ITRAX core scanner produced recognisable µXRF elemental responses for the visible ash layers, including those just 1 mm thick. However, just 10% of the cryptotephra layers could be unequivocally identified. Although this study demonstrates that µXRF core scanning should not be used as an independent method within a similar geological setting, we show it can provide a powerful tool alongside traditional techniques. Where detected, µXRF profiles can verify and refine cryptotephra positions (here to a sub‐millimetre resolution), and help establish reworking signatures. These insights create possibilities for ultra‐precise synchronisation of records, improved chronological modelling and help generate more complete eruption histories.

Loss tangent estimation from ground-penetrating radar data using Ricker wavelet centroid-frequency shift analysis

A novel method to estimate the loss tangent using ground-penetrating radar (GPR) data and assuming a Ricker wavelet as the transmitted radar signal is presented. This method proposes a new relation between centroid frequency and loss tangent, which allows retrieval of the loss tangent of a material through a probabilistic inversion approach. The reliability of the results is carefully evaluated by performing an uncertainty analysis that accounts for the white Gaussian noise affecting the radar data. The method is validated in low- and high-loss scenarios, using synthetic data generated by a well-established finite-difference time-domain model (gprMax). The simulations are performed assuming a dipping sharp reflector separating two materials with different electric properties. The loss tangent values retrieved using the centroid-frequency method are compared, for different levels of noise, with those estimated using the maximum frequency method. The results find that the centroid-frequency method is, in general, more precise when the noise level is high, and it is more accurate in a high-loss environment. Finally, the new approach is applied to real GPR data collected with 500 MHz and 1 GHz antennas on a volcanic ash deposit on Mount Etna (Italy), using the signal reflected from a sloping interface separating two distinct volcanic ash layers.

Recovery after volcanic ash deposition: vegetation effects on soil organic carbon, soil structure and infiltration rates

Background and purposeVolcanic eruptions of pyroclastic tephra, including the ash-sized fraction (< 2 mm; referred to as volcanic ash), have negative direct impacts on soil quality. The intensity (deposit thickness, particle-size distribution) and frequency (return period) of tephra deposition influence soil formation. Vulnerability and subsequent recovery (resilience) of the plant-soil system depend on land-uses (vegetation and management). Few previous studies covered the whole deposition-recovery cycle. We investigated the volcanic ash deposition effects on soil properties and their recovery across land-uses on a densely populated volcanic slope.MethodsWe measured the canopy cover and volcanic ash thickness six years after the 2014 Mt. Kelud eruption in four land-use systems: remnant (degraded) forests, complex agroforestry, simple agroforestry, and annual crops. Each system was monitored in three landscape replicates (total 12 plots). For the soil recovery study, we measured litter thickness, soil texture, Corg, soil C stocks, aggregate stability, porosity, and soil infiltration in three different observation periods (pre-eruption, three, and six years after eruption).ResultsPost-eruption volcanic ash thickness varied between land-use systems and was influenced by the plots slope position rather than canopy cover. The average soil texture and porosity did not vary significantly between the periods. Surface volcanic ash and soil layers initially had low aggregate stability and limited soil infiltration, demonstrating hydrophobicity. While Corg slowly increased from low levels in the fresh volcanic ash, surface litter layer, aggregate stability, and soil infiltration quickly recovered.ConclusionsDifferent land-use management resulted in different recovery trajectories of soil physical properties and function over the medium to long term after volcanic ash deposition.