Firefighters are usually exposed to high temperatures, smoke and other hazards from the environment when carrying out fire fighting and rescue. Fire fighting clothes are special protective clothes used to protect firefighters from high temperature and fire damage. PPS fabrics can meet the basic requirements of fire service coatings. According to the standard requirements of a pair of firefighters’ chemical protective clothing, this topic further coats the surface of PPS fabric to achieve a certain chemical penetration resistance, and does basic research on the application of PPS fibers in the outer layer of chemical protective clothing. It can be used to make exterior material of Fire Fighting Protective clothing. Fabric density affects the warp and weft tear properties, but due to the limited fabric density in this design, the density does not affect much. In addition, it has been found that reducing the latitude and longitude density difference can increase the latitudinal tear strength value. The possibility of multi-stage airbag cushioning type pressure-proof protective clothing captured in actual fire-fighting and rescue work is analyzed, which provides a certain guarantee for the safety of fire-fighters during fire-fighting and rescue operations.