Surface Layer Research Articles

A comparative study of worm-sludge treatment reed bed planted with Phragmites australis and Arundo donax in the Mediterranean region.

Sludge treatment reed bed planted (STRB) with Phragmites australis (P.australis) and Arundo donax (A.donax) was assessed in the presence of Eisenia fetida under control condition during the dry season. Worm-planted units were fed with mixed sewage sludge (dry and volatile solids of 29.44g DS.L-1 and 24.23g VS.L-1). Sludge loading rates (SLR) of 50, 60, and 70kg DS m-2year-1 were examined to assess dewatering efficiency. Surface layers in units with P.australis and A.donax achieved DS of 80 and 81% at a loading rate of 50kg DS m-2year-1, while their subsurface DS were 41 and 25%, respectively. Units with A.donax experienced plant loss when subjected to SLR exceeding 60kg DS m-2year-1. More than 10cm of residual sludge accumulated on the top of units after a 2-month final rest. Evapotranspiration was greater in the unit with P.australis (5.23mmday-1) compared to the unit with A.donax (4.24mmday-1) while both were fed with 70kg DS m-2year-1. Water loss contributions from residual sludge layer, drained water, and evapotranspiration were 3, 46, and 51%, respectively. Units with P.australis indicated 20% higher water loss compared to units with A.donax. Although the drained water quality improved over time, it did not meet standard limits. The residual sludge layer contained macro and micronutrients, and heavy metals with a significant elemental order of N > Ca > P > S > mg > K (N:P:K = 31:8:1), Fe > Na > B > Mn > Mo and Zn > Cr > Cu > Pb > Ni > Cd. Overall, STRB could be a sustainable alternative technology to conventional sewage sludge management techniques.

Crown Ethers with Different Cavity Diameters Inhibit Ion Migration and Passivate Defects toward Efficient and Stable Lead Halide Perovskite Solar Cells.

Organic-inorganic hybrid metal halide perovskite solar cells have been considered as one of the most promising next-generation photovoltaic technologies. Nevertheless, perovskite defects and Li+ ionic migration will seriously affect the power conversion efficiency and stability of the formal device. Herein, we designed two crown ether derivatives (PC12 and PC15) with different cavity diameters, which selectively bind to different metal cations. It is found that PC15 in perovskite precursor solution can actively regulate the nucleation and crystallization processes and passivate the uncoordinated Pb2+ ions, while PC12 at the interface between the perovskite layer and hole-transporting layer can effectively inhibit the migration of Li+ ions and reduce nonradiative recombination losses. Therefore, PC12 and PC15 can act as "lubricant" and defect passivators, as well as inhibitors of ion migration, when they are synergistically applied at the surface and bulk of perovskite layer. Consequently, the optimized device achieved a champion efficiency of 24.8% with significantly improved humidity, thermal, and light stability.

Membrane prewetting by condensates promotes tight-junction belt formation.

Biomolecular condensates enable cell compartmentalization by acting as membraneless organelles1. How cells control the interactions of condensates with other cellular structures such as membranes to drive morphological transitions remains poorly understood. We discovered that formation of a tight-junction belt, which is essential for sealing epithelial tissues, is driven by a wetting phenomenon that promotes the growth of a condensed ZO-1 layer2 around the apical membrane interface. Using temporal proximity proteomics in combination with imaging and thermodynamic theory, we found that the polarity protein PATJ mediates a transition of ZO-1 into a condensed surface layer that elongates around the apical interface. In line with the experimental observations, our theory of condensate growth shows that the speed of elongation depends on the binding affinity of ZO-1 to the apical interface and is constant. Here, using PATJ mutations, we show that ZO-1 interface binding is necessary and sufficient for tight-junction belt formation. Our results demonstrate how cells exploit the collective biophysical properties of protein condensates at membrane interfaces to shape mesoscale structures.

Laboratory-Simulated Photoirradiation Reveals Strong Resistance of Primary Macroplastics to Weathering.

The photodegradation of macroplastics in the marine environment remains poorly understood. Here, we investigated the weathering of commercially available plastics (tabs 1.3 × 4.4 × 0.16 cm), including high-density polyethylene, low-density polyethylene, polypropylene, polystyrene, and polycarbonate, in seawater under laboratory-simulated ultraviolet A radiation for 3-9 months, equivalent to 25-75 years of natural sunlight exposure without considering other confounding factors. After the exposure, the physical integrity and thermal stability of the tabs remained relatively intact, suggesting that the bulk polymer chains were not severely altered despite strong irradiation, likely due to their low specific surface area. In contrast, the surface layer (∼1 μm) of the tabs was highly oxidized and eroded after 9 months of accelerated weathering. Several antioxidant additives were identified in the plastics through low temperature pyrolysis coupled with gas chromatography/mass spectrometry (Pyr-GC/MS) analysis. The Pyr-GC/MS results also revealed many new oxygen-containing compounds formed during photodegradation, and these compounds indicated the dominance of chain scission reactions during weathering. These findings highlight the strong resistance of industrial macroplastics to weathering, emphasizing the need for a broader range of plastics with varying properties and sizes to accurately estimate plastic degradation in the marine environment.

Distribution and risk assessment of nutrients and heavy metals from sediments in the world-class water transfer projects

South-to-North Water Diversion Project, a globally renowned engineering feat, aims to address water supply issues. The sediments within reservoirs play a pivotal role in natural ecosystems, not only as habitats for diverse biota but also as repositories of heavy metals, organic matter, and other contaminants. These sediments serve as a critical interface between sediment and water bodies. This comprehensive analysis focused on the spatial patterns of nutrients, organic matter, and heavy metals in the surface layer and profiles of reservoirs, exploring their interconnectedness. Leveraging the integrated pollution index, organic pollution index, potential ecological risk index, and geo-accumulation index, an ecological risk assessment was performed. The key findings are as follows: (i) Along the Middle Route of the South-to-North Diversion Project, the nutrient and organic matter contents in sediments tends to rise with distance from the Danjiangkou Reservoir, with the TN and TC contents increasing by 2.35- and 3.05-fold, respectively. (ii) As the sediment depth increases, the carbon, nitrogen, phosphorus, and organic matter contents exhibit varying degrees of decline, with average decreases of 62.38%, 67.47%, 17.56%, and 41.83% for TN, TC, TP, and OM, respectively. (iii) Among the eight heavy metals, only manganese (Mn) and zinc (Zn) in the Yahekou Reservoir showed moderate pollution levels, according to the geo-accumulation index. The Mn content within the surface sediments of the six reservoirs ranges from 550 to 1837 mg/kg (average, 1019.5 ± 548.3 mg/kg), whereas the Zn content ranges from 89 to 360 mg/kg (average, 156.5 ± 101.6 mg/kg). (vi) Total phosphorus (TP) and total nitrogen (TN) emerged as the primary pollutants in surface sediments. Comprehensive nitrogen and phosphorus pollution assessment revealed that the surface sediment of Danjiangkou Reservoir is mildly polluted, while Baiguishan and Jiangang Reservoirs are moderately polluted, and the rest are heavily contaminated. For the Yahekou and Chaohe Reservoirs, the average pollutant content indicates moderate pollution, while the remaining reservoirs show mild pollution levels.Graphical

Cold Recycling Technology for Airfield Pavement Rehabilitation Practices

Cold recycling technology has recently achieved significant success in highway maintenance and construction applications. In this study, the potential of incorporating emulsion-based cold recycled layers into airfield pavement design is explored. The permanent deformation resistance of cold recycled (CR) mixtures was characterized under various stress states and loading conditions to provide a realistic representation of the loads induced by aircraft tires on typical airfield pavement structures. Finite element modeling simulations of several airfield structures incorporating a CR layer were leveraged to derive the triaxial stress states induced by the moving load of various aircraft tires on the CR layer. A mix design was developed using a common approach. The simulated stress states were then projected and applied to the developed mix design in triaxial compression repeated load permanent deformation experiments. The influence of time and temperature dependence of the material on permanent deformation was also studied. The experiment highlighted the sensitivity of the mixture to tire pressure, surface layer thickness, vehicle speed, and temperature. The results indicate that the selection of cold recycling applications for airfield pavement should account for the unique site-specific conditions and the structural composition of the pavement where the CR layer will be incorporated. The evident viscoplastic characteristics in CR mixtures in the triaxial repeated load experiments highlighted the importance of considering them in the structural design of the CR layer.

About Height of the Surface Air Layer by Sodar Data

Average empirical estimations of the surface air layer height in Moscow have been received by the data of long-term acoustic remote sensing of the atmosphere using MODOS Doppler sodar of METEK (Germany) production. Based on the assumption that the average conditions are close to neutral stratification, this height, as the top of the quasi-linear section of the average long-term wind velocity profile in semi-logarithmic coordinates, is 40–60 m. The wind rotation height, i. e. the height of intersection of day and night wind profiles is on average 95 meters per year. The roughness length in conditions of loose but high urban development in vicinity of Moscow State University in Moscow is 5 m. According to the criterion of the constant wind direction in the surface air layer, its height appears in the average monthly wind direction profiles over the “dead zone” of the sodar (40 m) in approximately one case out of three and usually amounts to 60 m, less often 80 or 100 m. In the rest cases, it is apparently masked by “dead zone”. The average height of the surface layer according to this approach is probably a little less than 50 m, which is close to the estimate obtained from the logarithmic distribution of wind velocity with height in this layer. The daily course of the surface air layer height is noted by the largest values in the afternoon (80–100 m in summer under conditions of prevailing unstable stratification and 60–80 m in winter) and the smallest ones (less than 40 m) in the late evening and at night in summer and from evening to noon in winter.

Assessing horticulture-based land management impacts on carbon dynamics and soil quality

The present study was carried during 2020 and 2021 at School of Agricultural Sciences and Rural Development (Nagaland University), Medziphema, Nagaland to study the effects of different horticulture-based land use systems on carbon stock, soil fertility and soil biological health in acidic hill soils of Nagaland. Average values of bulk density of the soils were 1.20 and 1.21 g/cm3 in surface and sub-surface soils, respectively irrespective of type of orchards. The maximum and minimum carbon stock was recorded in pineapple [Ananas comosus (L.) Merr.] (46.77 and 43.38 mg/ha) and citrus (Citrus spp.) (33.07 and 32.42 mg/ha) orchard soils. Soil microbial biomass carbon in pineapple (270.13 and 244.23 µg/g) and citrus orchard soils (165.64 and 152.49 µg/g) was recorded in surface and sub-surface layers, respectively. Banana (Musa spp.) orchard soils had greater values of dehydrogenase activity (15.26 and 9.83 µg TPF/g/h). Soils of banana orchard also recorded highest acid phosphatase activity (176.0 and 165.5 µg PNP/g/h), which was at par with mango (Mangifera indica L.) orchard soils (175 and 166 µg PNP/g/h). Minimum acid phosphatase activity (162.0 and 150.0 µg PNP/g/h) was recorded in citrus orchard soils. Maximum earthworm population density was recorded in banana orchard (12–20 number/m2) and minimum (4–12 number/m2) in citrus orchards.

Quantum-Confined Tunable Ferromagnetism on the Surface of a Van der Waals Antiferromagnet NaCrTe2.

The surface of three-dimensional materials provides an ideal and versatile platform to explore quantum-confined physics. Here, we systematically investigate the electronic structure of Na-intercalated CrTe2, a van der Waals antiferromagnet, using angle-resolved photoemission spectroscopy and ab initio calculations. The measured band structure deviates from the calculation of bulk NaCrTe2 but agrees with that of ferromagnetic monolayer CrTe2. Consistently, we observe unexpected exchange splitting of the band dispersions, persisting well above the Néel temperature of bulk NaCrTe2. We argue that NaCrTe2 features a quantum-confined 2D ferromagnetic state in the topmost surface layer due to strong ferromagnetic correlation in the CrTe2 layer. Moreover, the exchange splitting and the critical temperature can be controlled by surface doping of alkali-metal atoms, suggesting the feasibility of tuning the surface ferromagnetism. Our work not only presents a simple platform for exploring tunable 2D ferromagnetism but also provides important insights into the quantum-confined low-dimensional magnetic states.

Adsorption of Bichromate and Arsenate Anions by a Sorbent Based on Bentonite Clay Modified with Polyhydroxocations of Iron and Aluminum by the “Co-Precipitation” Method

The physicochemical properties of natural bentonite and its sorbents were studied. It has been established the modification of natural bentonites using polyhydroxoxides of iron (III) (mod.1_Fe_5-c) and aluminum (III) (mod.1_Al_5-c) by the “co-precipitation” method led to changes in their chemical composition, structure, and sorption properties. It was shown that modified sorbents based on natural bentonite are finely porous (nanostructured) objects with a predominance of pores of 1.5–8.0 nm in size. The modification of bentonite with iron (III) and aluminum compounds by the “co-precipitation” method also leads to an increase in the sorption capacity of the obtained sorbents with respect to bichromate and arsenate anions. A kinetic analysis showed that, at the initial stage, the sorption process was controlled by an external diffusion factor, that is, the diffusion of the sorbent from the solution to the liquid film on the surface of the sorbent. The sorption process then began to proceed in a mixed diffusion mode when it limited both the external diffusion factor and the intra-diffusion factor (diffusion of the sorbent to the active centers through the system of pores and capillaries). To clarify the contribution of the chemical stage to the rate of adsorption of bichromate and arsenate anions by the sorbents under study, kinetic curves were processed using equations of chemical kinetics (pseudo-first-order, pseudo-second-order, and Elovich models). It was found that the adsorption of the studied anions by the modified sorbents based on natural bentonite was best described by a pseudo-second-order kinetic model. The high value of the correlation coefficient for the Elovich model (R2 > 0.9) allows us to conclude that there are structural disorders in the porous system of the studied sorbents, and their surfaces can be considered heterogeneous. Considering that heterogeneous processes occur on the surface of the sorbent, it is natural that all surface properties (structure, chemical composition of the surface layer, etc.) play an important role in anion adsorption.

Strategic tillage of no-till decreased surface and subsurface losses of dissolved phosphorus.

Enrichment of soluble P on the surface layer of long-term no-till (NT) soils, and consequent increase in dissolved P losses, is a concern for which occasional plowing has been suggested as a remedy. We measured the effect of such strategic tillage (ST) on surface and subsurface P losses from 0.5-ha field plots on clay soil for 4years. Two NT plots had discharged threefold dissolved molybdate-reactive P (DRP) losses compared to annually plowed soil conventional tillage (CT). ST by plowing to 20-cm depth was applied on one of the NT plots, whereas the other remained under NT. ST done in July was sown with canola (Brassica napus ssp. oleifera) to establish plant cover before winter. Summed 4-year DRP loss from ST treatment was 60% lower compared to NT (0.78vs. 1.96kg ha-1), accompanied with 11% higher particulate P (PP) loss (4.39vs. 3.97kg ha-1). CT plots produced slightly lower DRP losses (0.53-0.76kg ha-1) than ST, but higher PP losses (6.02-7.96kg ha-1). Bioavailable P (BAP) losses from ST were lower than from the other treatments if >7% of PP turns bioavailable. After ST, soil P stratification first vanished, but started to develop again when NT was resumed. Occasional tillage of NT soils mitigates DRP losses over several years, and it was at the study site the preferred mitigation option in reducing BAP losses.

Prediction of crude oil physical properties based on molecular compositional modeling approach

AbstractIn this study, the Structural Units‐Bonding Matrix will be introduced into the crude oil characteristics analysis, specifically engineered to depict the molecular intricacies of petroleum substances. This methodology synergizes the bonding matrix with structural units, assigning the bonding matrix to the foundational layer, while the structural units adorn the surface layer. Through meticulous analysis of crude oil data, this study identified the core and branched molecular constituents of crude oil, facilitating the digital articulation of these molecules. Leveraging this foundational work, this study developed composition models for five quintessential types of crude oil, enabling the precise prognostication of their macroscopic physical properties. Further, by evaluating the viscosity‐temperature characteristics of these selected crude oils, this study established a predictive model for the viscosity–temperature relationship of crude oils, grounded in the quantitative structure–property relationship method. This approach not only augments this study understanding of crude oil molecular composition but also enhances the predictive accuracy of their physical properties, heralding a significant advancement in the field of petroleum molecular science.

On Low-Velocity Impact Response and Compression after Impact of Hybrid Woven Composite Laminates

This paper aims to study the low-velocity impact (LVI) response and compression after impact (CAI) performance of carbon/aramid hybrid woven composite laminates employed in marine structures subjected to different energy impacts. The study includes a detailed analysis of the typical LVI responses of hybrid woven composite laminates subjected to the impact with three different energies, as well as a comparative analysis of cracks and internal delamination damage within impact craters. Additionally, the influence of different impact energies on the residual compressive strength of hybrid woven composite laminate is investigated through CAI tests and a comparative analysis of internal delamination damage is also conducted. The results indicate that as the impact energy increases, the impact load and CAI strength show a decreasing trend, while impact displacement and impact dent show an increasing trend. The low-velocity impact tests revealed a range of failure modes observed in the hybrid woven composite laminates. Depending on the specific combination of fiber materials and their orientations, the laminates exhibited different failure mechanisms. Buckling failures were observed in the uppermost composite layers of laminates with intermediate modulus systems. In contrast, laminates with higher modulus systems showed early damage in the form of delamination within the top surface layers.

Investigation of Gamma-Induced Changes to Screening Currents and AC Losses in Mono- Versus Multi-filamentary REBCO Coated Conductors Using DC and AC Magnetometry

AbstractREBCO (rare-earth barium copper oxide) coated conductor tapes are a highly attractive option for magnet materials in future tokamak fusion power plants. However, the threat of intense neutron and gamma radiation, together with AC losses during magnet coil ramping, has raised concerns around magnet coil lifetimes. Irradiation-induced changes to flux creep rate has been identified as a key performance-limiting factor in REBCO tapes at low temperatures and high fields post-irradiation with gamma rays; spontaneous flux creep contributes to hysteretic AC loss in REBCO cables under applied AC fields. Knowing that multi-filamentary tapes are under consideration for tokamaks as an AC loss mitigation, magnetic measurements and gamma irradiation experiments are presented here on striated and mono-filamentary YBCO tapes to investigate the differences in post-irradiation screening currents and AC losses. Reduction in AC losses improved magnetisation critical current density (Jc) retention after 1 MGy in the multi- relative to the mono-filamentary samples. After the 5 MGy dose, striations then made the multi-filamentary tape more susceptible to Jc degradation because of the thinner individual filament width. Scanning transmission electron microscopy analysis on an analogous GdYBCO mono-filamentary tape did not indicate the introduction of nm-scale amorphisation to the active GdYBCO layer after gamma irradiation. A potential theoretical explanation for the underlying mechanism altering the flux-pinning landscape across the REBCO layer surface in gamma-irradiated tapes is discussed. This work concluded that gamma effects on screening current capability should be considered in future tokamak REBCO tape qualification studies.

Application of Guar Gum Treatment of Basalt Residual-Soil Shallow Slope in Early Ecological Restoration

This paper found that environmentally friendly guar gum biopolymers are helpful for stopping the erosion of basalt residual-soil shallow slopes, while also improving the problems of poor stability, difficult growth of early vegetation, and weak initial resistance to the rainfall scouring of these slopes under extreme climatic conditions. Then, to illustrate the effects of the guar gum treatment, laboratory tests have been conducted, including a soil strength test, water retention and water absorption tests, a disintegration test, and a simulated rainfall erosion test, and the pattern of its effect on vegetation growth has been explored. The results indicate that as the content of guar gum increases, both the cohesion and angle of internal friction exhibit a trend of first increasing and then decreasing; the angle of internal friction varies within a range of 21° to 26°. The evaporation rate, water absorption rate, and disintegration rate of this guar gum-treated soil were significantly reduced, while the cracking of the surface layer was significantly improved. The disintegration rate of the soil is only about 2%, as the guar gum content is greater than 1%. Moreover, there is no sign indicating that vegetation germination was affected by the guar gum, meaning that it maintains a favorable environment for vegetation to grow. Guar gum-cured slopes were significantly protected under heavy rainfall washout conditions, with a 94.85% reduction in total soil loss from the slope surface compared to untreated slopes. Since the pores of soil are filled with guar gum hydrogel, the erosion resistance of soil is greatly enhanced. The results of this study will provide a scientific basis for engineering the protection of shallow slopes of basalt residual soils.

GIS- and Multivariate-Based Approaches for Assessing Potential Environmental Hazards in Some Areas of Southwestern Saudi Arabia

Soil contamination is a major issue that endangers the ecology in most countries. Total concentrations of As, Cd, Co, Cr, Cu, Mn, Ni, Pb, VFe, and Zn were determined by analyzing soil samples from 32 surface soil samples in southwest Saudi Arabia, including certain areas of Al-Baha. Kriging techniques were used to create maps of the distribution of metal. To assess the levels of soil contamination in the research area, principal component analysis (PCA), contamination factors (CF), and pollution load index were used. The results show the stable model gave the best fit to the As and Zn semivariograms. The circular model fits the Cd, Co, and Ni semivariograms the best, while the exponential model fits the Cr, V, and Fe semivariograms the best. For Ni and Pb, respectively, spherical and Gaussian models are fitted. The findings demonstrated two clusters containing different soil heavy metal concentrations. According to the data, there were two different pollution levels in the research region: 36.58% of it is strongly contaminated, while 63.41% of it has a moderate level of contamination (with average levels of these metals 5.28 ± 5.83, 0.81 ± 0.19, 18.65 ± 6.22, 45.15 ± 23.25, 60.55 ± 23.74, 972.30 ± 223.50, 33.45 ± 14.11, 10.05 ± 5.13, 84.15 ± 30.72, 97.40 ± 30.05, and 43,245.00 ± 8942.95 mg kg−1 for As, Cd, Co, Cr, Cu, Mn, Ni, Pb, V, Fe, and Zn, respectively). The research area’s poor management practices are reflected in the current results, which raised the concentration of harmful elements in the soil’s surface layers. Ultimately, the outcomes of pollution concentration and spatial distribution maps could aid in informing decision-makers when creating suitable heavy metal mitigation strategies.

Long-term trends of pH, alkalinity, and hydrogen ion concentration in an upwelling-dominated coastal ecosystem: Ría de Vigo, NW Spain

The present study focuses on the Ría de Vigo (NW Spain), a coastal embayment influenced by the Canary Current Upwelling System, which is among the world’s significant Eastern Boundary Upwelling Ecosystems. The research assesses historical changes in the marine carbonate system by generating 25-year weekly time series at six stations . Assessing ocean acidification in the region is complex due to diverse factors influencing coastal carbon dynamics, making predictions more challenging. To capture the specific dynamics in Ría de Vigo, ensembles of Neural Networks were applied. These networks were trained with a data set obtained in several oceanographic cruises, in order to retrieve pH, hydrogen ion concentration and alkalinity, achieving a root mean square error of 0.0272 pH units, 0.588 nmol kg-1\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\\hbox {kg}^{-1}$$\\end{document}, and 10.6 μ\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\\upmu$$\\end{document}mol kg-1\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\\hbox {kg}^{-1}$$\\end{document}, respectively. Subsequently, time series of the selected variables were generated, applying data of predictors measured at the aforementioned stations . An increase in normalized alkalinity was observed for all stations, except in the surface layer at the innermost location. A decrease in pH and an increase in hydrogen ion concentration were observed for all points, with trends that exceed reported rates of ocean acidification in the open ocean.

Experimental Study of Soil Compaction with Proctor Standard Test Equipment

Soil is the surface layer of the earth which consists of minerals, organic materials, air, living things. Clay soil is one type of soil that is important in determining the bearing capacity of subgrade required for construction. The bearing capacity of the soil is obtained by compacting it, using the TS-365 Automatic Standard Proctor. Soil compaction is the process of removing air from the pores of the soil, and is effective for improving soil properties in order to increase the density (density) of the soil so that shear strength increases, soil settlement decreases, and soil permeability decreases. The standard proctor test uses 5 separate soil samples weighing 2 kg, with a mixture of 16%, 19%, 22%, 25% and 28% air respectively. The test results show that the soil obtained from the Pojok sub-district area. Mojoroto, East Java obtained the results of soil compaction data using a standard proctor test, it was obtained that the optimum dry volume weight of the soil was 1,630 gr/cm3 and the optimum water content was 32%. So that the results of soil testing in the laboratory can be used as a reference for controlling soil compaction in construction.

Synthesizing vulnerability indices within a diverse lithological context: Corollaries for groundwater quality assurance and surface layer corrosiveness of Lokoja Geomaterials, Nigeria

ABSTRACT This study provides prototypical evaluation of groundwater vulnerability to contamination and soil corrosivity in Lokoja region, central Nigeria. By combining the aquifer vulnerability index, integrated electrical conductivity, groundwater confinement overlying strata depth to water table (GOD), and electrical anisotropy coefficient (λ) derived from lithological composition, resistivity, and layer thickness; the study identifies substantial vulnerabilities in the groundwater resources. Findings indicate that over 70% of the region is moderately to very highly vulnerable to groundwater pollution, especially in the eastern and southern parts, highlighting the need for tailored groundwater management strategies in highly vulnerable areas, covering 40% of the region. Corrosion potential varies spatially, with 80% of the upper layer being minimally corrosive and around 45% of the lower moisture-rich layer showing moderate to significant corrosiveness, emphasizing risks in central and northern zones associated with lithological compositions and moisture content. These accentuate the necessity of rigorous monitoring programs and strict land use regulations to protect aquifers and infrastructure. This research underscores the value of proactive management for safeguarding groundwater resources, providing an invaluable framework for decision-making and resource allocation to tackle contamination and corrosion risks. Importantly, the research addresses a significant research gap in a region with limited scientific exploration.

Enhanced Surface Determination beyond Photoemission via Auger Photoelectron Coincidence Spectroscopy.

The study of surface properties at the nanoscale plays a crucial role in material science applications. This paper demonstrates the capabilities of Auger PhotoElectron Coincidence Spectroscopy (APECS) to obtain data with varying surface sensitivities from a single measurement. This makes it possible to extract the spectrum from the outermost surface layer even when faced with strongly overlapping surface and bulk spectral features, which we demonstrate by accurately extracting the surface component in Au 4f photoemission. Leveraging high energy resolution, transmission efficiency, tunable photon energy, and remarkable surface sensitivity of the APECS setup, we propose that optimal experimental conditions can be tailored to determine surface spectra accurately for a diverse range of materials. This opens new avenues for advancing our understanding of nanoscale surface phenomena across various material systems.