Concentrated latex is an intermediate rubber product in Thailand. It is an important industry that generates income for the country and Its southern region. The main products of the latex factory were concentrated latex and skim blocks. The industrial waste from the concentrated latex factory is called latex sediment. It appears to be a white mixed light-yellow sludge or a dark brown color, contains magnesium compounds, and phosphorus is an important element. Therefore, finding appropriate measures for rubber production and environmentally friendly industrial waste management is important. Therefore, this study investigates the pyrolysis of latex sediment as an alternative to industrial waste management. Pyrolysis of 100 g of latex sediment was performed at 300 °C, 500 °C, and 700 °C. From the experiment, it was found that the properties of the liquid product from the pyrolysis process at 500 °C were alkaline, with a pH of 9.45. However, acetic acid was the highest amount of organic substance in the liquid product. Substances in the amine and amide groups were also observed, a base result for the liquid product exhibiting an alkaline value. The pH is an important factor in the decomposition of organic substances under anaerobic conditions. Therefore, a 1 wt% liquid product was used in a volume of 13.5 mL, which is the most appropriate amount because it uses the least amount of liquid product to adjust the alkalinity of the skim latex serum before entering the anaerobic fermentation system. Pyrolysis is an environmentally friendly option for managing factory latex sediments for sustainable production and creating a good image for the organization.