Latent Heat Research Articles

Variability of marine heatwaves’ characteristics and assessment of their potential drivers in the Baltic Sea over the last 42 years

This study examined Baltic Sea Marine Heatwaves (MHWs) using 42 years of satellite-derived sea surface temperature (SST) data. We found that MHWs in warmer months are more intense but shorter compared to MHWs in cooler months. Also, MHWs predominantly affect offshore areas in warmer months, whereas MHWs predominantly impacting coastal seas in cooler months, especially along the eastern coast. Our analysis of interannual variability revealed that, unlike in many other basins worldwide, Baltic MHWs tend to maintain a constant intensity, while their spatial extent has significantly increased over the last few decades. Shortwave radiation notably influences MHW intensity and spatial extent, with additional impacts from longwave radiation in cooler months and latent heat flux in warmer months. Northern Hemisphere teleconnections exhibit stronger correlations with MHWs in the Baltic Sea compared to global-scale climate oscillations, with the Eastern Atlantic pattern having a particularly significant effect on MHW variability in the region.

Design and multiperformance evaluation of the ternary azeotrope separation process via extractive distillation based on different extractants

Resource utilization and sustainable wastewater treatment have received widespread attention because of their efficient use of energy. In this study, an ethanol (EtOH)/ethyl tert-butyl ether/water ternary azeotropic system was used to explore the separation efficiency of various extractants. The relative volatility, toxicity, and process modeling of extractants were analyzed to provide a theoretical basis and practical guidance for screening the optimal extractant among nine commonly used extractants. Extractive distillation (ED) was optimized for six processes with a focus on total energy consumption (TEC) and total annual cost (TAC). The ED-EtOH process was the most economical, whereas the extractive ED-DMSO process had the lowest TEC. After heat integration (HI) treatment, the TAC and TEC of each process were reduced, among which HI-ED-EtOH and HI-ED-glycerol (GLY) had the best and lowest economy, respectively. Although high-boiling point and high latent heat extractants (such as GLY and EtOH) increase the heat demand and operating costs, their high latent heat characteristics can effectively recycle heat energy during the HI process. The optimal balance between economy and energy consumption was determined through multi objective optimization considering the physical and chemical properties, environmental impact, and adaptability of extractants.

Study on the Influence of Laser Power on the Heat–Flow Multi-Field Coupling of Laser Cladding Incoloy 926 on Stainless Steel Surface

In order to explore the influence of laser power on the evolution of molten pool and convective heat transfer of laser cladding Incoloy 926 on stainless steel surface, a three-dimensional thermal fluid multi-field coupled laser cladding numerical model was established in this paper. The variation of latent heat during solid-liquid phase transformation was treated by apparent heat capacity method. The change in the gas–liquid interface was tracked using the mesh growth method in real time. The instantaneous evolution of temperature field and velocity flow field of laser cladding Incoloy 926 on a stainless steel surface under different laser power was discussed. The solidification characteristic parameters of the cladding layer were calculated based on the temperature-time variation curves at different nodes. The mechanism of the impact of laser power on the microstructure of the cladding layer was revealed. The experiment of laser cladding Incoloy 926 on 316L surface was carried out under different laser power. Combined with the numerical simulation results, the effects of laser power on the geometrical morphology, microstructure and element distribution of the cladding layer were compared and analyzed. The results show that with the increase in laser power, the peak temperature and flow velocity of the molten pool surface both increase significantly. The thermal influence of the molten pool center on the edge is enhanced. The temperature gradient, solidification rate, and cooling rate increased gradually. The microstructure parameters (G/R) are relatively small when the laser power is 1000 W. In the experimental range, the dilution rate and wetting angle of the cladding layer both increase with the increase in laser power. When the laser power is 1000 W, the alloying elements of the cladding layer are more evenly distributed and the microstructure is finer. The experimental results are in good agreement with the simulation results.

Disentangling the Impacts of Environmental Factors on Evaporative Fraction Across Climate Regimes

AbstractEvaporative fraction (EF) is a useful measure for quantifying land surface energy partitioning processes and determining evaporative regimes; however, its influencing factors remain highly uncertain. Here, global data sets were compiled to disentangle the effects of environmental variables on EF variations along climate and land surface gradients. We found that (a) at annual timescales, ecosystem‐level EF could be expressed as a power law function of aridity index. The relationships of mean annual soil water content (SWC) and leaf area index (LAI) with mean annual EF resembled the traditional evaporative regime theory; (b) at daily timescales, the boosted regression tree method quantitatively revealed that the impacts of environmental variables (including meteorological variables) on EF showed equal importance, especially at humid sites, primarily due to the different response direction and magnitude of latent heat (LE) and sensible heat (H) fluxes to environmental changes. Particularly, the contrasting responses of LE (positive) and H (negative) to SWC, LAI, and relative humidity enhanced the positive effects of those influencing variables on EF; whereas, the correlations between EF and energy‐related factors (i.e., net radiation‐Rn and air temperature‐Ta) deteriorated as both LE and H showed positive response patterns to those variables; (c) meteorological factors were also found to have nonlinear effects on daily EF, further modified by climatic conditions. Rn near 150 W/m2 and Ta near 15°C appeared to be important energy‐partitioning thresholds at drier and humid sites, respectively. Moreover, changing interactions among environmental variables with climates were demonstrated to be important for better explaining EF variations.

Modeling Across Scales of Heavy Precipitation With a Global Variable‐Resolution Model: A Case Study of a Catastrophic Event in China

AbstractAn unprecedented heavy rainfall event in China (“21.7” extreme rainfall event) was simulated using the global variable‐resolution model (MPAS‐Atmosphere) across the scales (4, 8, 16 and 50 km). Although almost all experiments at different resolutions reproduce the spatiotemporal characteristics of precipitation, the simulated precipitation intensity from high to low is 16, 8, 50, and 4 km, with the 16 km simulation being closest to the observations. Precipitation magnitude is prominently influenced by the difference in simulated large‐scale circulation across a range of grid spacings. Further analysis revealed that the differences in latent heating across scales affect the geopotential height and wind field by altering temperature. The latent heating in 4 km simulation is the minimum while the 16 km simulation is maximum. More latent heating release leads to the low‐level pressure depression, amplifies the water vapor flux convergence, produces stronger upward motion and more clouds, and ultimately results in stronger precipitation. The sensitivity experiments for turning off latent heating tendencies during the event showed that the latent heat release has positive feedback on the “21.7” heavy rainfall event. This study highlights the importance of scale‐awareness of latent heat at different resolutions and suggests that the difference in simulated latent heat release during the event is the main reason for simulated different atmospheric circulation and precipitation across scales.

Optimization of the annular fin arrangement in phase change heat storage units based on response surface methodology

Latent heat thermal energy storage (LHTES) technology is of increasing industrial interest due to its advantages such as high heat storage density and near-constant temperature during the phase change process. However, the latent heat storage technology is impacted by the low thermal conductivity of the phase change material (PCM), leading to delays and heat loss in the heat transfer process within LHTES. This limitation reduces the efficiency of heat transfer and diminishes the performance of the heat storage unit. To address this issue, this paper employs numerical simulation and response surface methodology to investigate different types of annular fin phase change heat storage units, aiming to derive the optimal configuration for enhancing unit performance. Therefore, the effect of fin type and number on the melting and solidification process is analyzed in detail. The research results indicate that among the five different types of fins studied, the total time required for the unit to complete melting and solidification is the least with type “e” fins, only 51.78 h, demonstrating that type “e” fins have the best effect on improving unit performance. For type “e” fins, when the number of fins n is 15, it can most effectively shorten the melting and solidification time of the phase change heat storage unit, reducing it to only 47.81 h. In addition, the response surface methodology was utilized to derive the optimal fitting formulas for different types of annular fins and to validate these formulas, and the error between the validation analysis and the numerical simulations was within 5%, which confirms the reliability of the fitting formulas developed in this study. This approach facilitates the selection of various annular fin models for subsequent experimental and simulation studies, thereby reducing the time and cost associated with model selection.

Thermal performance of multifunctional louver window integrated phase change material and spherical louver

The integration of phase change material (PCM) into glazed envelope is an effective measure to enhance its thermal inertia and reduce energy consumption. However, the inefficient utilization of latent heat stored in double-glazed unit filled with PCM (PCMW) in winter and overheating in summer restricts the adoption of PCM in cold regions. Therefore, this work proposed a multifunctional new phase-change louver window integrating PCM and spherical louvers, and numerically investigated its thermal behaviour in summer and winter seasons. The effects of different melting temperatures and ventilation mechanisms on the thermal performance and energy efficiency of phase change louvers were analyzed. The results show that the new phase-change louver window can significantly improve the thermal comfort and energy efficiency of the window. In winter, insulated PCM louver window has the best performance, reducing heating energy consumption by 2618.56kJ/(m2·d) compared to hollow window, with energy saving of 54.03 %, whereas in summer, reflective PCM louver window performed best, reducing cooling energy consumption by 3584.47 kJ/(m2·d) compared to hollow window, with an energy saving rate of 37.08 %. The analysis of various melting temperatures shows that the melting temperature of RT14 is the most suitable in the annual basis, and the introduction of ventilating mechanism for ventilated reflective PCM louvers window can significantly enhance the performance of the window.

Phase-Field Simulation and Dendrite Evolution Analysis of Solidification Process for Cu-W Alloy Contact Materials under Arc Ablation

Cu-W alloys are widely used in high-voltage circuit breaker contacts due to their high resistance to arc ablation, but few studies have analyzed the microstructure of Cu-W alloys under arc ablation. This study applied a phase-field model based on the phase-field model developed by Karma and co-workers to the evolution of dendrite growth in the solidification process of Cu-W alloy under arc ablation. The process of columnar dendrite evolution during solidification was simulated, and the effect of the supercooling degree and anisotropic strength on the morphology of the dendrites during solidification was analyzed. The results show that the solid–liquid interface becomes unstable with the release of latent heat, and competitive growth between dendrites occurs with a large amount of solute discharge. In addition, when the supercooling degree is 289 K, the interface is located at a lower height of only 15 μm, and the growth rate is slow. At high anisotropy, the side branches of the dendrites are more fully developed and tertiary dendritic arms appear, leading to a decrease in the alloy’s relative density and poorer ablation resistance. In contrast, the main dendrites are more developed under high supercooling, which improves the density and ablation resistance of the material. The results in this paper may provide a novel way to study the microstructure evolution and material property changes in Cu-W alloys under the high temperature of the arc for high-voltage circuit breaker contacts.

Unveiling the Pivotal Influence of Sea Spray Heat Fluxes on Hurricane Rapid Intensification

Abstract Predicting rapid hurricane intensification remains a challenge, partially due to neglected factors like sea spray-mediated heat flux. To shed light on the specific roles of spray-mediated sensible and latent heat fluxes, we conducted sensitivity experiments with heat flux parameterizations. Our results demonstrate that the inclusion and variation of the spray-mediated sensible heat significantly reduce model errors when compared against dropsonde data. These findings uniquely quantify the pivotal role of spray-mediated sensible heat flux in accurately predicting hurricane rapid intensification compared to previous studies. Without sea spray processes, ocean-coupled model simulations could not reproduce the steep intensification rate observed in multi-case studies of four high-impact hurricanes. This study also highlights that dropsonde data, as well as directly observed flux, is useful in minimizing uncertainty in the flux parameterization used for hurricane simulations. In this paper, we show how spray-mediated heat flux affects hurricane energetics through turbulent heat exchange and subsequent humid air inflow through primary and secondary circulations. Our findings provide new insights into the transformative role of sea spray in turbulent heat exchange that drives rapid hurricane intensification.

Experimental Study on Heat Recovery in a CaO/Ca(OH)2-Based Mechanical Fluidized Bed Thermochemical Energy Storage Reactor

Long-term storage of seasonally available solar energy and its provision to balance heating energy demand can contribute significantly to the sustainable use of energy resources. Thermochemical energy storage is a suitable process for this purpose, offering the possibility of loss-free long-term energy storing and heat supply. In order to develop suitable technical solutions for the use of this technology, novel reactor concepts and scientific questions regarding material and technology development are being investigated. In this publication, the energy storage process of a long-term energy storage system based on a ploughshare reactor is experimentally investigated under various technically relevant operating conditions. One specific aspect of this technology is related to the release of water vapour during the charging process. Therefore, this work focusses, in particular, on the possibility of technically utilizing the latent heat of the released water vapour in the range of 45 °C to 80 °C, which covers the operating requirements of common heating systems in households. The experiments have shown that the dehydration process enables the separation of two heat fluxes: the chemically bound energy for long-term storage and the physically (sensible and latent) stored energy for short-term applications. However, the limitation of gas transport was also identified as the most important influencing parameter for optimising the performance of the process.

Blue in green: forestation turns blue water green, mitigating heat at the expense of water availability

Abstract In order to meet a stringent carbon budget, shared socioeconomic pathways (SSPs) aligned with the Paris Agreement typically require substantial land-use changes (LUC), such as large-scale forestation and bioenergy crop plantations. What if such a low-emission, intense-LUC scenario actually materialized? This paper quantifies the biophysical effects of LUC under SSP1-2.6 using an ensemble of regional climate simulations over Europe. We find that LUC projected over the 21st century, primarily broadleaf-tree forestation at the expense of grasslands, reduce summertime heat extremes significantly over large swaths of continental Europe. In fact, cooling from LUC trumps warming by greenhouse gas (GHG) emissions, resulting in milder heat extremes by 2100 for about half of the European population. Forestation brings heat relief by shifting the partition of turbulent energy fluxes away from sensible and towards latent heat fluxes. Impacts on the water cycle are then assessed. Forestation enhances precipitation recycling over continental Europe, but not enough to match the boost of evapotranspiration (green water flux). Run-off (blue water flux) is reduced as a consequence. Some regions experience severe drying in response. In other words, forestation turns blue water green, bringing heat relief but compromising water availability in some already-dry regions.

The Application of Pinch Technology to a Novel Closed-Loop Spray Drying System with a Condenser and Reheater.

Spray drying is an energy-intensive process in industrial use, making energy recovery a critical focus for improving overall efficiency. This study investigates the potential of integrating heat-recovery systems, including an innovative air reheater, into a closed-loop spray-drying unit to maximise energy savings. Through detailed pinch analysis, the system achieved a very low approach temperature, averaging 3.48 K, which is significantly lower than that of conventional open-loop systems. The study quantifies the energy-recovery potential by demonstrating that the integration of heat-recovery components can reduce the external heating demand by up to 30%. This not only enhances heat-transfer efficiency but also lowers operational costs and reduces the system's environmental impact. The results suggest that closed-loop systems with air reheaters offer a scalable solution for improving energy efficiency across different industrial applications. The research highlights a new paradigm: focusing on latent energy within the system rather than adjusting individual operational variables.

Controllable heat release of supercooled Erythritol-based phase change materials for long-term thermal energy storage

Transeasonal heat storage in organic phase change materials (PCMs) present a promising solution to the intermittent nature of renewable energy. However, PCMs are prone to spontaneous crystallization during storage, leading to the loss of stored latent heat in low-temperature environments. In this study, we incorporated tetrasodium ethylenediaminetetraacetic acid (EDTA-4Na) and superabsorbent polymer (SAP) to erythritol (ERY), referred to as EES-PCMs, to overcome these challenges and achieve more controllable and stable thermal energy storage. The incorporation of EDTA-4Na and SAP into ERY significantly improves the supercooling stability and phase change enthalpy. The optimal ratio (EES-PCMs-2) of phase change enthalpy reaches an impressive 286.62 J/g, with stable performance maintained for 120 days at room temperature. The EES-PCMs-2 exhibits exceptional thermal cycling stability, retaining its properties even after 100 cycles. A novel air-triggered crystallization method is demonstrated, enabling a temperature increase from room temperature to 48.21 °C in 320 s after being exposed to air for long-term storage. This innovative approach effectively overcomes the limitations of traditional triggering mechanisms, providing a straightforward and efficient method for thermal management. The high thermal storage capacity, stability, and controlled exothermic properties of EES-PCMs position them as promising candidates for applications in seasonal solar thermal energy storage.

Structure, Magnetic and Magnetocaloric Properties of Attempted P Substitutions in LaFe<sub>11.5</sub>Si<sub>1.5</sub> Giant Magnetocaloric Material

Recent theoretical and experimental studies suggested that P can enter the structure of La(Fe,Si)13 alloys and lead to a significant enhancement of the isothermal entropy change, one of the two main quantities characterizing the magnetocaloric effect. Here, we report a systematic study of P for Si substitutions in La(Fe,Si)13 alloys. Eight LaFe11.5Si1.5-xPx polycrystalline bulk samples with 0 ≤ x ≤ 0.2 were prepared by arc-melting followed by heat treatment. Powder x-ray diffraction and SEM/EDX analyses show that the α-Fe secondary phase progressively increases with the increase in P substitutions and that a La-rich LaP secondary phase appears. We therefore found that P does not actually enter the main La(Fe,Si)13 phase. Magnetization and DSC measurements confirm this interpretation as the Curie temperatures of La(Fe,Si,P)13 alloys are nearly insensitive to P for Si substitutions and the latent heat of the first-order ferromagnetic transition decreases with the increase in nominal P substitutions. Our work put into questions former reports of the literature on P addition in La(Fe,Si)13 and highlights the particularly complex synthesis of these alloys.

Revisiting the connection between variations in the Tsushima Warm Current and winter rainfall along the coast of Japan

AbstractEnhanced autumn transport via the Tsushima Warm Current (TWC) has been reported to increase winter rainfall along Japan’s northern coast. However, observations reveal a significantly weakened correlation after 2006. Although enhanced transport via the Eastern channel of the Tsushima Strait affects rainfall by enhancing latent heat flux along Japan’s northern coast, the role of oceanic flows in varying sea-surface temperatures has weakened since 2006. Stronger northwesterly winds co-occur with enhanced surface heat loss that overwhelms the impact of the TWC. Our findings imply that atmospheric conditions should be considered when using TWC transport as a precursor for winter rainfall.

A novel heat recovery VRF system: Principle and cooling performance analysis

Faced with an increasingly severe energy problem and increased demand for indoor comfort, heat recovery VRF systems have demonstrated remarkable potential for energy conservation. However, traditional heat recovery VRF systems need more suboptimal energy efficiency in terms of cooling and dehumidification and fail to guarantee precise temperature and humidity control in specific environments. In this study, a novel heat recovery VRF system that can achieve highly efficient cooling while ensuring precise humidity control is proposed. It can realize four primary operation modes by changing the function of indoor heat exchangers. The results showed that the optimal volume ratio of the two compressor cylinders was 1.4, which was used as the design parameter for the system. Compared to the single-evaporation temperature system, the proposed double-evaporation temperature system has better energy efficiency and dehumidification capacity in the cooling mode. The cooling coefficient of performance (COP) can be increased by 3.18 %–6.05 %, the compressor energy consumption can be reduced by 3.07 %–7.03 %, and the moisture extraction rate and latent heat ratio of the system can be increased by 5.6 %–33.3 %.

Electrochemistry of Phase-Change Materials in Thermal Energy Storage Systems: A Critical Review of Green Transitions in Built Environments

This article reviews recent research on phase-change materials (PCMs) used in thermal energy storage systems with the aim of enhancing their performance. The study explores various methods to improve heat transfer in PCMs, such as microencapsulation, infill materials, fins and nanofluids. Additionally, it evaluates techniques to boost heat transfer in latent heat thermal energy storage (LHTES) systems and investigates ways to increase thermal conductivity using porous and low-density materials. PCMs store thermal energy, making them suitable for use in solar energy systems when solar energy is not available. The need for eco-friendly alternatives to conventional heating and cooling in global construction and the significant energy consumption of buildings has driven research on this topic. As such, this study additionally examines current advancements in free cooling systems with latent heat storage to identify the key factors affecting their effectiveness. The findings show that using PCMs for overnight cooling maintains the room temperature within the comfort zone and reduces the cooling loads in various climates. Using machine learning methods, this study also compares recent advancements in the use of PCMs in various solar energy systems, including solar thermal power plants, solar air purifiers, solar water heaters and solar appliances. Results derived feature key factors crucial for the optimal selection of PCMs and the challenges associated with sustainable green transitions in built environments. HIGHLIGHTS This review provides an in-depth examination of PCM thermal energy storage systems. This study investigates the use of fillers, nanofluids, and nanoparticles for enhanced heat transfer. Analytical methods for boosting the PCM thermal conductivity are briefly outlined. Geometric design and thermal conductivity enhancement affect the Latent Heat Thermal Energy Storage (LHTES). The assessment also evaluates advanced free-cooling systems using the LHTES. PCMs help to store heat energy in solar systems and bridge supply gaps. GRAPHICAL ABSTRACT

Intercomparison of sensible and latent heat flux measurements from combined eddy covariance, energy balance, and Bowen ratio methods above a grassland prairie

We present a comparison of four different methods of measuring sensible (H) and latent (LE) heat fluxes for a year over a mixed grass prairie ecosystem in the Nebraska SandHills [eddy covariance (EC), energy balance/Bowen ratio (EBBR), residual energy (RES), modified Bowen ratio (MBR) methods]. Additionally, we developed a set of quality control criteria for each method and present a simplification to the traditional EBBR setup. Using EC as reference, all methods yielded similar estimates of yearly H (regression slopes (m) ~ 2% from unity; HEC > HEBBR, HRES, and HMBR). For yearly LE, EBBR and RES yielded similar estimates with EC (m ~ 2% from unity; LEEC < LEEBBR and LERES), while a larger bias was found from MBR (m ~ 8% from unity; LEEC > LEMBR). At shorter time scales (~ hourly), moderate scatter was found about linear regression fits for H between EBBR and EC (R2 = 0.81), with smaller scatter between RES and MBR, and EC (R2 = 0.91). For LE, smaller scatter was also measured between EC, and EBBR and RES (R2 = 0.89 and 0.87, respectively), with the larger scatter between EC and MBR (R2 = 0.65). This suggests methods other than EC may be well suited to longer-term applications (≥ yearly), but have larger uncertainty on individual measurements.

Numerical investigation of heat and moisture migration in clayey and sandy soils, exploring seasonal fluctuations

Geothermal energy is widely known as a sustainable and eco-friendly energy source. For its applications, assessing the hydrothermal soil behaviour is crucial. However, the installation of ground geothermal systems at shallow depths makes them sensitive to atmospheric conditions, which affect the temperature field and the thermal balance. This paper presents the results of a numerical study investigating the hydrothermal behaviour of unsaturated soils (clay and sand), considering the meteorological variations at the ground surface. The atmospheric-soil interactions, including solar radiation, sensible heat flux, and latent heat flux, are essential for quantifying the energy balance and the hydro-thermal transfer processes taking place at the ground surface. By analysing these components, we can gain a comprehensive understanding of how energy is distributed and transferred to the soil. A numerical study was carried out using a finite element method (FEM) to assess the hydrothermal behaviour of unsaturated soils. The analysis of the obtained results from the model simulation reveals that variations in soil types have an impact on the distribution of heat and moisture migration, with both time and depth. Moreover, it appears that clayey soils show the highest efficiency in geothermal energy transfer. This research offers crucial insights into the optimization of both the design and implementation of geothermal systems.

Highly inhomogeneous interactions between background climate and urban warming across typical local climate zones in heatwave and non-heatwave days

Abstract Urban heat island (UHI) in conjunction with heatwave (HW) leads to exacerbation of thermal stress in urban areas. Prior research on UHI and HW has predominantly concentrated on examining the thermal conditions at the surface and near-surface, with few investigations extending to the radiative and dynamical interactions of UHI and HW, particularly with a focus on the inhomogeneities across local climate zones (LCZs). Here, we analyse the temperature disparity between HW and non-HW conditions across LCZs in the Sydney area by quantifying the contributions of individual radiative and dynamical processes using the coupled surface-atmosphere climate feedback-response analysis method (CFRAM). Three moist HW events in 2017, 2019, and 2020 are simulated using the Weather Research and Forecasting (WRF) model coupled with the Single-Layer Urban Canopy Model (SLUCM). It is found that the maximum surface and 900-hPa temperature difference between HW and non-HW days may reach up to 10 K, with the increased net solar radiation during HWs being comparable to the typical level of anthropogenic heat flux in urban areas. It is also found that the reduction of clouds, the presence of vapor, and the increase of sensible heat contribute to the warming effect to various degrees, with the contribution of clouds being the most dominant. Conversely, the generation of dry convection and the increase of latent heat flux lead to cooling effects, with the latter being more dominant and capable of causing up to 10 K surface temperature difference between LCZ1 (compact high-rise) and LCZ9 (sparsely built). The differences in the contributions of climate feedback processes across different LCZs become more evident during more severe and humid HWs. These findings underscore the necessity of implementing local climate zone-tailored heat mitigation strategies.