Based on drill hole sampling and sedimentary rock dating by palynology, the present research focuses on the palynostratigraphic events established in the key geological section of Guedelhinha–Lançadoiras–Algaré located in the Portuguese Neves–Corvo mine region, Iberian Pyrite Belt. The age data allow detailing the lithostratigraphic sequence and further understanding the complex structural setting, representing an important contribution to the geological knowledge of this sector located to the immediate WNW of the Neves–Corvo VMS deposit. The combination of the studied events allows the reconstruction of the Devonian-Carboniferous sedimentation and paleoenvironments along the Iberian Pyrite Belt. Several stratigraphic hiatuses identified in the Neves–Corvo region by the palynological record are confirmed, mainly occurring from the mid Frasnian to mid Famennian, from the early and mid Strunian, and from the early to late Tournaisian, which were mainly coincident with the worldwide extinction events, in particular during Frasnian–Famennian and Late Devonian times. Extensional tectonics and related gravitational faults, local uplift mechanisms and intense volcanic activity could also explain the lack of palynological data and sedimentary hiatus. In this research, the importance of the late Strunian times in the Iberian Pyrite Belt (Miospore Biozone LN of the Neves Formation) is highlighted, confirming the contemporaneity of felsic volcanism, hydrothermalism, sulphide mineralization precipitation and black shale anoxic sedimentation.