Aims at keyhole instability and poor surface-quality in welding of aluminum alloy, a novel laser technology has been studied on welding of Al 6061. The novel laser beam consists of a ring part and a center part. Different power ratio of ring laser beam to center laser beam and different kind of laser beam welding experiments have been conducted, respectively. The keyhole stability and surface quality were analyzed by using a high-speed camera and a confocal sensor accordingly. Additionally, the energy absorption rate was studied by analyzing the penetration and fusion area of cross-section. Experimental results showed that the ring laser beam provided great stability on the center laser-induced keyhole in high-speed dual-mode ring/center laser welding of aluminum. The stability effects can be improved by increasing the ring power in dual-mode ring/center laser welding of aluminum alloy, and the stabilized effect would contribute to the high-surface quality on welding of aluminum alloy. Furthermore, the combination of ring laser and center laser (Gaussian laser) greatly improved the welding efficiency due to its synergistic effects on process status in the ARM laser welding process. This work provided a basic research to both scientist and engineer on the mechanism of ARM laser welding aluminum alloy.