The effects of laser shock forming (LSF) on material microstructure evolution and its electrochemical corrosion behaviour were investigated. Results show that high-density dislocations and stacking faults are formed on the laser-irradiated surface layer of parts. The laser-irradiated surface of the parts subjected to two-shot LSF exhibited better corrosion resistance, with a 2-fold decrease in the passive current density, 3.5-fold increase in the charge resistance, and ∼12-fold thicker passive film compared with the undeformed sheet. The formation of nano-grains, compressive residual stresses, and a dense Cu2O oxidation film during LSF contributed to the improved corrosion resistance of the LSF-fabricated copper parts.