Laser machining of ceramics at the green state offers a low-cost route to the near-net fabrication of ceramics. A matrix of laser machining (i.e., laser cutting and scanning) parameters were tested on 5 mm-thick green bodies of magnesium oxide (MgO) using a CO2 laser with a maximum power capacity of 130 W. The input parameters were feed rate and power; we scanned the feed rate of 3–14 mm/s and power of 23–31 W for laser cutting, and 10–60 mm/s and 16–27 W for laser scanning. The quality of the laser-cut and -scanned surfaces was tracked through SEM. Thermal damage along the laser path was assessed to optimize laser cutting. High laser power and/or long dwell time resulted in partial sintering. At both cutting and scanning operations, low feed rates induced thermal damage, while high feed rates provided better edge retention and surface smoothness. However, very high feed rates failed to generate complete cuts and through-holes due to insufficient transfer of the excitation energy. Various combinations of the feed rate and power produced completely cut 5 mm cubes with smooth surfaces via laser cutting in a single pass. The most energy-efficient combination of 12 mm/s and 28 W rendered the highest surface quality with minimum thermal damage. This parameterization set provides a practical roadmap for choosing process parameters for the laser machining of MgO at the green state.
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