Laser Fluence Research Articles

Ultrafast optical pumping induced polarity and chirality reversal of Néel skyrmions in amorphous GdFeCo ferrimagnet

The development of next-generation data storage devices relies on the efficient control of topological spin textures at ultrafast timescales with minimal energy consumption. Here, we theoretically investigate the switching of the magnetic skyrmion in ferrimagnetic GdFeCo utilizing the helicity-independent all-optical switching (HI-AOS) driven by femtosecond laser pulses. Our study demonstrates the switching of Néel skyrmion between the two degenerate skyrmion ground states having opposite polarity and chirality. A systematic study was done by varying the laser fluence, and we found that single-shot skyrmion switching is observed for a range of fluence values, where optically induced magnetization switching is observed. The present study proves that HI-AOS is a potential mechanism for switching magnetic skyrmion at ultrafast timescales. Our results offer significant insight into implementing optical writing skyrmion-based memory devices.

From Farm to Fork: Enhancing Agricultural and Food Safety Monitoring with Laser-Engineered Graphene Sensors

In the critical fields of precision agriculture and food safety, the demand for accurate and sensitive monitoring tools for fertilizers, pesticides, and food-borne pathogens cannot be overstated. Our collaborative research with commercial entities seeks to overcome the challenges faced by current electrochemical ion-selective, enzymatic, and immunosensors, which often fall short in selectivity, stability, and sensitivity, particularly under field conditions. We showcase the tunable properties of Laser-Induced Graphene (LIG) – such as surface wettability, roughness/area, and electrical conductivity – and their instrumental role in enhancing the commercial viability of these sensor technologies.We demonstrate the conversion of hydrophilic Laser-Induced Graphene (LIG) to a near-superhydrophobic state using an innovative dual-laser process in ambient conditions. This method intricately sculpts the surface into micro and nanoscale structures reminiscent of a lotus leaf, resulting in nearly superhydrophobic characteristics. By modifying the laser's power, speed, and fluence, we can also fine-tune the electroactive surface area and electrical conductivity, significantly impacting sensor functionality. For solid contact ion-selective electrodes (SC-ISEs), enhancing the LIG surface with high hydrophobicity prevents water layer accumulation at the ion-selective membrane and electrode interface. This design expels water from within the membrane, fosters stronger membrane-electrode adhesion, and consequently, diminishes signal interference. Such improvements are instrumental in boosting the sensor's accuracy and extending its operational lifespan. In contrast, a hydrophilic LIG with a large surface area enhances catalytic efficiency and allows more biorecognition agents to adhere to its surface, thereby amplifying the sensitivity of enzymatic pesticide sensors. Lastly, a flat, hydrophilic LIG surface ensures an even distribution of antibodies, which enhances the performance of sensors detecting foodborne pathogens.These modifications to LIG and the resulting sensors have substantial commercial potential. We have developed ions sensors for nitrate, ammonium, potassium, calcium, and magnesium have demonstrated near-Nernstian sensitivities, extensive sensing ranges across four orders of magnitude, and the ability to detect concentrations as low as 1 ppm in soil and water samples. These sensors are currently being integrated into commercial soil moisture and temperature probes for monitoring in farm fields. The pesticide sensing capability of the sensor can reach an extremely low picomolar detect limit for organophosphates, the nanomolar regime for neonicotinoids, and micromolar regime for glyphosate in surface waters. These sensors are currently being interfaced with LIG-based mist/fog harvesting devices to monitor pesticide and spray drift in farm fields. Finally, the LIG-based Salmonella sensors are capable of monitoring bacteria such as Salmonella to about 10 CFU/mL in actual food matrices such as chicken broth without the need for sample preconcentration or costly lab analyses.This research forges innovative avenues in agriculture and food safety monitoring, laying the groundwork for mass production of efficient and economical sensors. We believe this technology will revolutionize field monitoring, significantly advancing sustainable agriculture and improving public health safety. Figure 1

(Invited) Laser-Induced Graphene for Improved Electrochemical Biosensors

Laser-induced graphene (LIG) has emerged as a promising technique for fabricating porous graphene electrodes for many applications, including biosensors and medical devices. However, improving electrochemical properties of LIG hinges on not only understanding the kinetics and energetics governing the physicochemical process of lasing, but also the tunability of surface chemistry and morphology of the produced LIG. This talk reveals the spatiotemporal laser control for achieving different LIG morphology and atomic structures with demonstrations of seamless transitions between conductive networked LIG structures and insulating fibrous LIG morphologies. The effect of laser fluence and multi-pass lasing on LIG morphology and properties will be shown. In addition, molecular engineering of the polymer substrate is explored for controlling the chemical and physical properties of the produced LIG. Finally, the electrochemical detection of neurotransmitters in the nanomolar range will be demonstrated. Our results show that heteroatom doping of graphene is possible by including sulfur or fluorine atoms into the backbone of the polyimide synthesized by two-step polycondensation. Accordingly, both the surface hydrophobicity and sensing sensitivity are shown to depend on the heteroatom-doping content. Taken together, our work paves the way for scalable fabrication of functional graphene-based electrodes and coatings on polymers for flexible and wearable electronics, as well as implantable devices, such as neural probes.

Effective electronic properties and coupling for two-temperature model-molecular dynamics simulation of ultrafast laser ablation of nickel

ABSTRACT The accuracy of hybrid two temperature model-molecular dynamics (TTM-MD) simulations in predicting the ultrafast laser ablation phenomena in metals is influenced by the functional definition of subsystem properties and electronic-lattice coupling. In this work, laser ablation of nickel is simulated using hybrid TTM-MD with empirical and density function theory (DFT) derived electronic and coupling parameter sets. The investigation revealed that the empirically derived temperature-dependent parameterisation of electronic specific heat, thermal conductivity, and coupling factor enhanced the fidelity of electron–phonon nonequilibrium dynamics when used in conjunction with simple optical absorption models, aligning closely with prior experimental observations for nickel specimens. The TTM-MD setup is then coupled utilising two widely used coupling techniques – the temperature difference scaled and Langevin thermostat. It is found that the former exhibits increased tensile stress due to artificial enhancement of the collision cascade owing to deterministic nature of the coupling force. While the probabilistic nature of the Langevin thermostat offers more accurate predictions of the ablation threshold/yield. Under these conditions, the TTM-MD scheme is tested for a range of absorbed laser fluence, with ablation threshold, and the onset of phase explosion is determined as 115 and 270 mJ/cm2, respectively for a 1 picosecond (ps-) laser pulse.

Ultrasound-assisted laser therapy for selective removal of melanoma cells.

The current study explores the potential of ultrasound-assisted laser therapy (USaLT) to selectively destroy melanoma cells. The technology was tested on an ex vivo melanoma model, which was established by growing melanoma cells in chicken breast tissue. Ultrasound-only and laser-only treatments were used as control groups. USaLT was able to effectively destroy melanoma cells and selectively remove 66.41% of melanoma cells in the ex vivo tumor model when an ultrasound peak negative pressure of 2MPa was concurrently applied with a laser fluence of 28mJ/cm2 at 532nm optical wavelength for 5min. The therapeutic efficiency was further improved with the use of a higher laser fluence, and the treatment depth was improved to 3.5mm with the use of 1,064nm laser light at a fluence of 150mJ/cm2. None of the laser-only and ultrasound-only treatments were able to remove any melanoma cells. The treatment outcome was validated with histological analyses and photoacoustic imaging. This study opens the possibility of USaLT for melanoma that is currently treated by laser therapy, but at a much lower laser fluence level, hence improving the safety potential of laser therapy.

Bacterial reduction and temperature increase of titanium dental implant models treated with a 445 nm diode laser: an in vitro study

In this in vitro study, the use of a 445 nm diode laser was investigated for the decontamination of titanium dental implants. Different irradiation protocols and the effect of repetitive laser irradiation on temperature increase and decontamination efficacy were evaluated on titanium implant models. An automated setup was developed to realize a scanning procedure for a full surface irradiation to recapitulate a clinical treatment. Three irradiation parameter sets A (continuous wave, power 0.8 W, duty cycle (DC) 100%, and 5 s), B (pulsed mode, DC 50%, power 1.0 W, and 10 s), and C (pulsed mode, DC 10%, power 3.0 W, and 20 s) were used to treat the rods for up to ten consecutive scans. The resulting temperature increase was measured by a thermal imaging camera and the decontamination efficacy of the procedures was evaluated against Escherichia coli and Staphylococcus aureus, and correlated with the applied laser fluence. An implant’s temperature increase of 10 °C was set as the limit accepted in literature to avoid thermal damage to the surrounding tissue in vivo. Repeated irradiation of the specimens resulted in a steady increase in temperature. Parameter sets A and B caused a temperature increase of 11.27 ± 0.81 °C and 9.90 ± 0.37 °C after five consecutive laser scans, respectively, while parameter set C resulted in a temperature increase of only 8.20 ± 0.53 °C after ten surface scans. The microbiological study showed that all irradiation parameter sets achieved a complete bacterial reduction (99.9999% or 6-log10) after ten consecutive scans, however only parameter set C did not exceed the temperature threshold. A 445 nm diode laser can be used to decontaminate dental titanium rods, and repeated laser irradiation of the contaminated areas increases the antimicrobial effect of the treatment; however, the correct choice of parameters is needed to provide adequate laser fluence while preventing an implant’s temperature increase that could cause damage to the surrounding tissue.

Gold nanoparticle-mediated nanosecond laser-induced polystyrene carbonization with luminescent products

A highly soluble Au(I) gold precursor is used to produce a nanocomposite material consisting of a polystyrene matrix and gold nanoparticles. Irradiation of such a material with nanosecond laser pulses at the plasmon resonance wavelength leads to the formation of black spots containing luminescent products of carbonization. HR TEM analysis and Raman spectroscopy confirm disordered carbon. A simple model, based on laser heating of a nanoparticle to a temperature of more than 2000 K and stabilization of this temperature by the endothermic process of polystyrene carbonization, fits well with the dependence of the luminescent signal increment on the laser fluence.

Improving energy harvesting through femtosecond laser surface modification of PVDF/ZnS composite nanofibrous nanogenerators for electronic applications

Surface modification in ceramic/polymer composites holds paramount importance for electronic devices applications. Laser is a versatile and flexible device for modifying the surface characteristics of various materials. Here, we propose a novel approach to enhance the energy harvesting efficiency of polyvinylidene fluoride (PVDF) and zinc sulfide (ZnS) composite nanofibrous membranes through femtosecond laser surface modification. The electrospinning technique is used to produce nanofibers with a high β-phase content in a single step. The PVDF membrane was further enriched with ZnS nanoparticles to enhance the β-phase content. The membranes were systematically investigated using scanning electron microscopy (SEM), transmission electron microscopy (TEM), Electron Energy Loss spectroscopy (EELS), and Fourier-transform infrared spectroscopy (FTIR) to characterize their morphological and chemical properties. Femtosecond laser was employed to induce controlled surface modifications, resulting in hierarchical microstructures and surface functionalization. The results showed patterned tracks on the fiber surface while preserving its inherent nature. To validate its utility as an energy harvesting device, the membrane's capability was assessed by measuring the open circuit voltage. The results revealing average output voltages for nanogenerators treated with laser fluences of 0.5 J/cm2, 0.7 J/cm2, and 0.9 J/cm2 are 15.6 V, 25 V, and 17 V, respectively. The maximum output voltage is observed for a laser fluence of 0.7 J/cm2, attributed to the deeper structure created, increasing the surface area of contact and deformation in the structure. This work offers promising avenues for enhancing energy harvesting efficiency and expanding the scope of electronic devices such as sensors and actuators.

Polycrystalline T- and H-Nb2O5 Thin Films Prepared by Pulsed Laser Deposition: Impact of Laser Fluence

Polycrystalline T- and H-Nb2O5 Thin Films Prepared by Pulsed Laser Deposition: Impact of Laser Fluence

Fabrication of high-performance nanostructured CsPbI3/Si perovskite photodetector by pulsed laser deposition: Challenges and prospects

The inorganic perovskite CsPbI3 is a promising material for optoelectronic applications like photodetectors and solar cells due to its suitable bandgap and excellent properties. In this work, nanostructured CsPbI3 thin films were deposited on glass and silicon substrates by pulsed laser deposition (PLD) at laser fluences ranging from 5.7 to 10 J/cm2. Systematic characterization revealed that increasing the laser fluence significantly enhances the crystallinity, phase purity, optical emission intensity, charge carrier concentration (up to 1.38 × 1012 cm−3), and mobility (up to 164.7 cm2/Vs) of the CsPbI3 films. An optimal laser fluence of 10 J/cm2 resulted in large, elongated grains over 280 nm, tightly packed films with minimal defects, and a suitable bandgap of 1.83 eV CsPbI3/Si heterojunction photodetectors were fabricated, with the device made at 8.5 J/cm2 exhibiting maximum responsivity of 8 A/W at 600 nm, detectivity exceeding 1014 Jones, external quantum efficiency up to 17.5 × 102 %, and a high ON/OFF ratio of 225 under illumination. The photodetector performance was strongly correlated with the optimized structural order, morphology, and optoelectronic quality achieved by careful control of the laser fluence during PLD. This work highlights PLD as an effective technique for realizing high-quality CsPbI3 films with tailored properties for advanced photodetection and photovoltaic applications.

Laser-Induced Interference to Infrared Detector Using Continuous Wave and Short-Pulse Lasers.

The response of a DPbS3200 infrared detector irradiated by a nanosecond pulsed laser and CW laser has been investigated to study laser-induced interference. A laser interference experiment system was constructed to measure the time-varying response signal. A nanosecond pulsed laser and a CW laser of 10 Hz were used, with a 1064 nm wavelength and a millimeter-scale irradiation spot diameter. Firstly, the characteristics of transient interference signals induced by pulsed lasers were analyzed. Then, the characteristics of response signal interference by both CW laser and pulsed laser irradiation were further investigated. The results showed that the pulsed laser only produced transient interference. However, the CW laser led to a significant amplitude reduction of the response signal, which could continuously interfere in the operating time. For transient interferences, the amplitude of the interference signal increased linearly with the laser fluence. The relation between the pulse repetition rate of the incident laser and the operating frequency of the detector determined the numbers of transient interference signals in one response period; for the interference induced by both the CW laser and pulsed laser, CW laser interference played a leading role when CW laser power density increased to 4.1 W/cm2 or more. As the CW laser fluence reached 6.1 W/cm2, the PbS infrared detector was no longer able to detect any signal, which caused temporary blindness. In the end, a probit model was used to determine the interference threshold.

Analysis method of point defects evolution in fused silica under multi-pulse nanosecond laser irradiation.

Although no optically visible damage is produced in the fused silica under laser irradiation below its laser-induced damage threshold (LIDT), defect proliferation may occur due to the evolution of its internal atomic structure. The escalation in defect content leads to heightened absorption, and resulting in the degradation of the optical performance of the optics. In recent decades, there have been a lot of experimental studies on laser-induced damage and laser conditioning, but there is still a great lack of in-depth understanding and theoretical analysis of the evolution process of point defects in fused silica. In this study, the emphasis is on the evolution of point defects and fatigue damage in fused silica under multi-pulse nanosecond laser irradiation. To address this, a point-defect evolution model is developed, and the coupled evolution law of temperature and defect during laser irradiation is derived by integrating it with a numerical model. The results demonstrate that the model effectively predicts the defect evolution of fused silica under laser irradiation and facilitates the prediction of fatigue damage. It is revealed that the rate of defect evolution in fused silica is more influenced by temperature than stress, and a temperature threshold can be used to judge the condition of damage occurrence. Furthermore, through an analysis of the effect of laser fluence on defect relaxation rate, a defect relaxation method employing variable laser fluence was proposed. This study provides a reliable theoretical analysis method for understanding the fatigue damage induced by multi-pulse laser irradiation in fused silica and offers a new perspective for the annealing treatment of point defects in fused silica.

Novel imidacloprid nanoribbons prepared by laser fragmentation/exfoliation in liquid media

The preparation of Imidacloprid (IMC) Nanoribbons by laser induced simultaneous fragmentation and exfoliation of micrometer sized IMC powders suspended in water is reported. Samples were prepared varying both the laser fluence and quantity of IMC powder. The prepared nanostructures were characterized by transmission electron microscopy (TEM), Raman spectroscopy and X-Ray Photoelectron Spectroscopy (XPS). TEM characterization showed that nearly spherical nanoparticles were obtained at the lowest fluence whereas at the highest fluence, IMC nanoribbons (IMCNR) with widths from 500 to 1000 nm and thickness of few atomic layers were obtained. Raman Spectroscopy showed the vibrational features of imidacloprid revealing that this organic molecule was preserved after laser irradiation. The XPS characterization confirms and supports the Raman results revealing that the nanoribbons were formed by the IMC organic molecule. The toxicity evaluation showed that IMCNR caused a more accelerated mortality of Drosophila melanogaster than the same dose of IMC.

Colloidal Titanium Nitride Nanoparticles by Laser Ablation in Solvents for Plasmonic Applications.

Titanium nitride (TiN) is a candidate material for several plasmonic applications, and pulsed laser ablation in liquids (PLAL) represents a rapid, scalable, and environmentally friendly approach for the large-scale production of nanomaterials with customized properties. In this work, the nanosecond PLAL process is developed, and we provide a concise understanding of the process parameters, such as the solvent and the laser fluence and pulse wavelength, to the size and structure of the produced TiN nanoparticles (NPs). TiN films of a 0.6 μm thickness developed by direct-current (DC) magnetron sputtering were used as the ablation targets. All laser process parameters lead to the fabrication of spherical NPs, while the laser pulse fluence was used to control the NPs' size. High laser pulse fluence values result in larger TiN NPs (diameter around 42 nm for 5 mJ and 25 nm for 1 mJ), as measured from scanning electron microscopy (SEM). On the other hand, the wavelength of the laser pulse does not affect the mean size of the TiN NPs (24, 26, and 25 nm for 355, 532, and 1064 nm wavelengths, respectively). However, the wavelength plays a vital role in the quality of the produced TiN NPs. Shorter wavelengths result in NPs with fewer defects, as indicated by Raman spectra and XPS analysis. The solvent type also significantly affects the size of the NPs. In aqueous solutions, strong oxidation of the NPs is evident, while organic solvents such as acetone, carbides, and oxides cover the TiN NPs.

Fiber Laser Writing of Highly Sensitive Nickel Nanoparticle-Incorporated Graphene Strain Sensors.

Unlocking new dimensions in wearable sensor technology, this research highlights ultrasensitive stretchable strain sensors fabricated with the customized laser-induced graphene (LIG) decorated with uniformly distributed nickel nanoparticles with a fiber laser writing process. The nickel nanoparticle-incorporated LIG (Ni-NPs@LIG) strain sensors fabricated by a simple all-laser-based method utilize a commercial fiber laser. The Ni-NPs@LIG sensors showcase an impressive gauge factor, reaching up to 248 for strain values below 5%, demonstrating a sensitivity increase of up to 430% compared to the pure LIG sensors. Moreover, these sensors offer adjustable strain sensitivity based on laser fluence. The key advancement of this study lies in the direct laser writing of highly porous nickel-graphene nanostructures with adjustable properties, making them applicable across a broad range of applications. As an application demonstration, the strain sensors were employed to assess the small deformation of a pouch battery or track the large deformation of a balloon surface.

Nanosecond pulsed laser irradiation of titanium in acetone: The effects of coating film structures on the hydrogen absorption properties

Pulsed laser irradiation was performed on titanium in acetone and then the hydrogen storage properties were investigated under a hydrogen atmosphere. TiOxCy films were formed by the irradiation of Ti powders with a fluence of 0.36 J cm−2. The irradiation increased the hydrogen absorption temperatures. Thus, the TiOxCy films showed a specific kind of hydrogen barrier effect. Irradiation with a fluence of 0.36 J cm−2 was performed to coat the Ti plate. Although the TiOxCy films formed on the surface, the amount of hydrogen absorption increased compared with the non-irradiated plate because of the change in surface chemical bonding states and high porosity of the films due to the irradiation. The phases generated by irradiation were controlled by the laser fluence. With a low fluence of 0.17 J cm−2, TiO2 films were formed instead of TiOxCy films, and these dense films showed better hydrogen barrier effects than the non-irradiated plate.

High-strength and impermeable sapphire/aluminum joints fabricated by ultrafast laser microwelding: Microstructures and joining mechanism

In this work, robust joints of sapphire and aluminum were successfully achieved by direct ultrafast laser transmission microwelding. Effects of laser parameters on the microstructures and mechanical properties were comprehensively studied. The welding process highly depended on the laser ablated metal nanoparticles within the heterojunction, as well as the thermal accumulation under multiple laser pulses irradiation. It showed that lack of fusion at the sapphire/aluminum interface can occur due to the incomplete melting of ablated nanoparticles at low laser fluence (<0.48 J/cm2). While serious cavities and cracks inside the brittle sapphire were formed with the intensified stress concentration after melting-solidification process at excessive laser fluence (>0.64 J/cm2). A nearly defect-free joint was obtained with max. shear strength of 128.1 ± 8.2 MPa at room temperature, when the laser fluence was 0.56 J/cm2. The high shear strength can be attributed to the tortuous interface with wide elemental transition layer. Meanwhile, the welded sapphire/aluminum joints exhibited high reliability under extreme service temperatures, which the shear strength can reach 159.8 ± 8.96 MPa at −50 °C and 80.6 ± 11.1 MPa at 200 °C. The sealing tests also showed the excellent impermeability of laser welded sapphire/aluminum structure, confirming the micro-crack free joint formation. This work demonstrates the feasibility of using ultrafast laser to achieve high-quality sapphire/aluminum joint, which is promising in heat-dissipation substrate manufacturing in power semiconductor devices.

Modeling and simulation of laser-ignited Al-PTFE reactive material in vacuum

Despite extensive investigations elucidating the initial response behavior of aluminized polytetrafluoroethylene (Al-PTFE) under atmospheric pressure, research on their response in lean-oxygen environments pertinent to propulsion and explosion scenarios is still lacking. This paper theoretically analyzes the multi-physical processes of laser-ignited Al-PTFE, identifying the initial response, main chemical reaction paths, and gas-phase product flow mechanisms. A dynamic reaction model of Al-PTFE considering material moving front, chemical reactions, gas-phase product dynamics, and variations in thermophysical properties, was developed. The robust coupling scheme in the model addresses nonlinear equations and fluid-solid coupling boundary conditions. Validation was achieved by comparing the ablation depth and plume number density field calculated by the model with the experimental results in the literature. The model reveals a positive correlation between laser fluence and both temperature growth rate and ablation depth of Al-PTFE, with the effects mainly observed in the full width at half maximum (FWHM) of the pulsed laser due to the thermal decomposition of the PTFE matrix. Simulations of the equilibrium constants and molar fractions of 19 components in the Al-PTFE ablation plume within the temperature range of 2000 K to 30,000 K at 0.001 Pa indicate that the equilibrium constants for dissociative reactions exceed those for ionization reactions, primarily in the early plume formation stages. Analysis of kinetic parameters and ambient pressure effects shows that during laser ablation, the maximum temperature of the plume initially appears near the ablation surface, shifting to the front, where the maximum velocity is always located. An elliptical shock wave forms due to adiabatic expansion of the plume, creating a cavity inside the plume. Lower ambient pressure increases plume expansion velocity, temperature, and size.

Influence of the Glycidyl Azide Polymer on the Energy Release of Aluminum Sub-Micron Particles under Ultrafast Heating Rates Stimulated by Electric Explosion and Solid Laser

Glycidyl azide polymer (GAP)-coated sub-micron aluminum (sub-mAl@GAP) particles exhibit higher heat release than their uncoated counterparts under low heating rates. However, their application in explosives has been hindered due to a lack of understanding of their energy release characteristics under heating rates of detonation levels. To address this problem, the energy release performances of sub-mAl@GAP particles under ultrafast heating rates stimulated by an electric explosion of wire and high-energy laser were studied. The results showed that the reaction of sub-mAl@GAP particles was more violent than that of an uncoated counterpart under an electric explosion stimulus. Additionally, the reaction time of the former was 0.4 ms shorter than that of the latter. In addition, the propagations of shock waves of the sub-mAl@GAP and sub-mAl were analyzed. The propagation distances of shock waves of the sub-mAl@GAP were all longer than those of sub-mAl under laser fluences of 0.5 J/cm2, 1.2 J/cm2, and 2.4 J/cm2. The distance difference gradually increased with the decrease in the laser fluence. Under a laser fluence of 0.5 J/cm2, the velocity and distance differences of the sub-mAl@GAP and sub-mAl were both the largest due to the energy contribution from the GAP. In conclusion, the fast decomposition rate of the GAP and its energy contribution would benefit the energy release of sub-mAl under ultrafast heating rates.

A comparative study of laser fluence effect on surface modification and hardness profile of austempered ductile iron

The impact of laser transformation hardening (LSH) and Laser surface melting (LSM) on an austempered ductile iron (ADI) alloy was investigated. Various laser fluences (J mm−2) were irradiated on the ADI specimens, obtained by different beam powers and scanning speeds to reach the optimum parameters to attain a surface with a good combination of high hardness and deep hardened depth, together with obtaining minimal distortion and crack-free surface. ADI surfaces were treated by means of high-power Nd:YAG laser in continuous wave mode. A detailed investigation of the obtained microstructure was characterized via optical and scanning electron microscopy attached to an EDX analyzer as well as X-ray diffraction analysis. Such a wide laser fluence range has a considerable effect on the achieved microstructure. A process parameter map was established which indicated that three different laser treatments were induced under such values of laser fluences: a laser transformation hardening, a partial laser melting, and a complete laser melting. The results revealed that to produce a hardened microstructure, specimens have to be operated within a very small range of laser fluence from 9.6 up to 29 J mm−2, achieving surface hardness values around 900 HV0.1 and depths of approximately 184–700 μm, respectively. Meanwhile, partial melting of the treated layer took place at a medium energy density range from 37 to 112 J mm−2, by a further increase in laser fluence (120–360 J mm−2), complete melting occurred which resulted in a deeper treated layer that reached 3.5 mm with an increase in microhardness value to almost 1100 HV0.1 at 360 J mm−2. The obtained microstructure in case of low laser fluence consisted of an austenite dendritic structure with undissolved graphite nodules, however, at medium and high laser fluence, the microstructure contains large cementite plates, iron-silicon carbides, a small area of ledeburite structure, and some retained austenite. The quantitative amounts of such phases directly depend on the applied laser fluence. Such phases were identified by means of EDX analysis.