Laser Damage Research Articles

Laser pretreatment enhances the laser-induced damage threshold of MgAl2O4 transparent ceramics

The demand for transparent ceramics as essential optical components in high-energy laser systems is escalating. Given the continuous surge in laser output power, there is an urgent need to enhance their laser-induced damage threshold (LIDT). This research systematically investigates the influence of variables such as laser energy density, number of scan repetitions, and stepwise scanning on the LIDT of MgAl2O4 transparent ceramics by modulating the process parameters of laser pretreatment. Through this method, oxygen vacancy defects on the material surface were effectively minimized, achieving surface purification of transparent ceramics and reducing residual stress. Under a consistent laser energy density of 8.96 J/cm2, the transparent ceramics were subjected to 1 to 9 scanning passes. The LIDT showed a progressive increase with the number of scans, reaching a maximum value of 15.0 J/cm2 after seven scans, which corresponds to a 34% improvement compared to untreated samples. Additionally, laser pretreatment facilitated the expansion of the material's bandgap and increased transmittance in the 200-300 nm band, further substantiating the intimate relationship between the reduction of oxygen vacancy defects and the improvement of optical properties. The findings indicate that laser pretreatment, as an effective post-processing technique, can substantially augment its resistance to laser damage by optimizing the microstructure and surface characteristics of the material. Moreover, judicious control of laser energy density and number of scan repetitions is crucial for optimally improving LIDT. In conclusion, this study offers what we believe to be a new theoretical foundation and technical support for the performance optimization of transparent ceramics in high-power laser systems, underscoring the significant potential of laser pretreatment as an effective post-processing technology in enhancing material optical properties and durability.

The Effects of Defect Cluster CaK-SiP on the Structure and Laser Damage for KDP Crystals: A First-Principles Study

The Effects of Defect Cluster CaK-SiP on the Structure and Laser Damage for KDP Crystals: A First-Principles Study

Learned phase mask to protect camera under laser irradiation

The electro-optical imaging system works under focus conditions for clear imaging. However, under unexpected laser irradiation, the focused light with extremely high intensity can easily damage the imaging sensor, resulting in permanent degradation of its perceptual capabilities. With the escalating prevalence of compact high-performance lasers, safeguarding cameras from laser damage presents a formidable challenge. Here, we report an end-to-end method to construct the wavefront coding (WFC) imaging systems with simultaneous superior laser protection and imaging performance. In the optical coding part, we employ four types of phase mask parameterization methods: pixel-wise, concentric rings, linear combinations of Zernike bases, and odd-order polynomial bases, with parameters that are learnable. In the algorithm decoding part, a method combined of deconvolution module and residual-Unet is proposed to furthest restore the phase-mask-induced image blurring. The optical and algorithm parts are jointly optimized within the end-to-end framework to determine the performance boundary. The governing rule of the laser protection capability versus imaging quality is revealed by tuning the optimization loss function, and the system database is established for various working conditions. Numerical simulations and experimental validations both demonstrate that the proposed laser-protection WFC imaging system can reduce the peak single-pixel laser power by 99.4% while maintaining high-quality imaging with peak signal-to-noise ratio more than 22 dB. This work pioneers what we believe to be a new path for the design of laser protection imaging systems, with promising applications in security and autonomous driving.

Regulations of oxygen-silicon ratio and microstructure to enhance laser damage resistance of fused silica via oxygen ion implantation

Regulations of oxygen-silicon ratio and microstructure to enhance laser damage resistance of fused silica via oxygen ion implantation

Magnetoplasmonic Triblock Nanorods for Collective Linear Dichroism.

Polarized light detection is crucial for advancements in optical imaging, positioning, and obstacle avoidance systems. While optical nanomaterials sensitive to polarization are well-established, the ability to align these materials remains a significant challenge. Here, we introduce Au-Fe3O4-Au triblock nanorods as a novel solution. Synthesized via a space-confined seeded growth method, these magnetoplasmonic nanocomposites uniquely combine the strong polarization capabilities of Au nanorods with the magnetic alignment properties of Fe3O4 nanorods. This architecture results in exceptional collective linear dichroism, achieving a polarization ratio of approximately 14 at the device level. Our nanorods exhibit high detection sensitivity and laser damage resistance, positioning them as a promising platform for developing advanced optical devices.

Crystal growth, linear optical, thermal, mechanical and third-order nonlinear optical properties of 1,3-diphenyl prop‑2-en-1-one single crystals

This work brings out the viability of the chalcone derivative (E)-1,3-diphenyl-2-propen-1-one (DPP) for industrial applications in nonlinear optical technology and device fabrication, through investigations on its crystal structure and nonlinear optical properties. The unit cell features of the DPP single crystals grown by slow evaporation solution growth method have been determined and hkl values indexed. The optical transparency of DPP in the near infrared and visible range is found to be admirable and an optical bandgap of 3.42 eV is revealed in the UV–Vis-NIR analysis. The work hardening coefficient (n) of DPP, determined as 2 from Vickers microhardness measurement, shows the moderate mechanical strength of the crystal. The Laser Damage Threshold value of 3.9 GW/cm2 sheds light on the high tolerance of DPP to optical damage and suggests its suitability in device fabrication. The potential of DPP crystal in nonlinear optical applications is suggested from its superior value of 1.16×10−7 esu for third order susceptibility and appealing values of other nonlinear optical parameters.

Time-Dependent Resistance of Sol–Gel HfO2 Films to In Situ High-Temperature Laser Damage

Laser damage in films under long-term high-temperature conditions is a significant concern for advancing laser applications. This study focused on HfO2 films prepared using the sol–gel method with HfCl4 as a precursor. It examined the effects of temperature on various properties of the films, including their optical properties, microstructure, surface morphology, absorption, and laser-induced damage threshold (LIDT). The prepared film demonstrated desirable characteristics at the high temperature of 423 K, such as high transmittance, low absorption, and high LIDT. As the duration of its high-temperature exposure increased, the LIDT of the films gradually decreased. An intriguing finding was that the film’s LIDT exhibited an exponential decay pattern with prolonged heating time. This observation could be attributed to the power-law increase in defects on both the internal and surface areas of the film as the duration of high-temperature exposure lengthened. Moreover, even after a 15-day heating period at 423 K, the film maintained an LIDT of 12.9 J/cm2, indicating its potential applicability in practical high-temperature environments. This study provided a general pattern and a universal formula for understanding the laser damage of sol–gel films at high temperatures over time. Furthermore, it opened possibilities for future developments of laser films suitable for extreme environments.

Crystallographic and Optical Spectroscopic Study of Metal–Organic 2D Polymeric Crystals of Silver(I)– and Zinc(II)–Squarates

Metal–organic framework materials, as innovative functional materials for nonlinear optical technologies, feature linear and nonlinear optical responses, such as a laser damage threshold, outstanding mechanical properties, thermal stability, and optical transparency. Their non-centrosymmetric crystal structure induces a higher-order nonlinear optical response, which guarantees technological applications. ZnII– and AgI–squarate complexes are attractive templates for these purposes due to their good crystal growth, optical transparency, high thermal stability, etc. However, the space group type of the catena-((μ2-squarato)-tetra-aqua-zinc(II)) complex ([Zn(C4O4)(H2O)4]) is debatable, (1) showing centro- and non-centrosymmetric monoclinic C2/c and Cc phases. The same is valid for the catena-((μ3-squarato)-(μ2-aqua)-silver(I)) complex (Ag2C4O4), (2) exhibiting, so far, only a C2/c phase. This study is the first to report new crystallographic data on (1) and (2) re-determined at different temperatures (293(2) and 300(2)K) and the non-centrosymmetric Cc phase of (2), having different numbers of molecules per unit cell compared with the C2/c phase. There are high-resolution crystallographic measurements of single crystals, experimental electronic absorption, and vibrational spectroscopic data, together with ultra-high-resolution mass spectrometric ones. The experimental results are supported for theoretical optical and nonlinear optical properties obtained via high-accuracy static computational methods and molecular dynamics, using density functional theory as well as chemometrics.

Bismorpholin-4-ium tetrabromo-cadmium metal-organic single crystal delivering Crystal structure, physicochemical properties and Characterizations for Optoelectronic Applications

For the development of nonlinear optical (NLO) materials, compositions of cadmium chloride (CC) and Morpholinium bromide (MB) molecules were utilized to form metal-organic materials. Morpholinium bromide was incorporated with cadmium metal to have electron charge transfer by constructing acentric structures that take advantage of strong third-order nonlinear optical properties. Bis Morpholinium cadmium bromide (BMCB) crystals were synthesized by a slow evaporation method (SEST). The BMCB crystal belongs to monoclinic P21/c space group with four molecules in the unit cell (a=6.7607(4) Å, b=16.5811(2) Å, c=14.9744(2) Å, β=94.136(3) ° and Z=4). The grown BMCB crystal phase purity and crystallinity were further investigated using powder X-ray diffraction (PXRD) analysis. Using Fourier transform infrared (FTIR) spectroscopy, the functional groups and their vibrational states were evaluated. From the results obtained from UV-vis-NIR spectral analysis, it is clear that the title compound is transparent in the visible range with the lower cut-off wavelength of 254 nm. The TG-DTA measurement has been used to evaluate thermal stability. Microhardness measurements were carried out to evaluate the mechanical stability of the grown crystal. The third-order nonlinear optical (NLO) characteristics were studied using Z-scan technique. The grown crystal exhibits outstanding third-order NLO response and wide laser damage threshold (LDT), which are crucial characteristics for developing practical NLO devices. The findings consequently open a novel path for the logical design of enormous, thermally stable and NLO-active metal-organic complexes for NLO applications.

Optimizing strategy of bifacial TOPCon solar cells with front-side local passivation contact realized by numerical simulation

The tunnelling oxide passivation contact (TOPCon) solar cells have been impressive in the global photovoltaic (PV) market originating from their high efficiency and stability. However, it exhibits significant recombination losses due to its boron diffusion, laser damage and metal-semiconductor contact on front side. The bifacial TOPCon structure demonstrates massive potential in the improvement of passivation and contact performance with the premise that it can solve the parasitic absorption of polycrystalline silicon (poly-Si). In this study, the localized poly finger structure with excellent optics and passivation performance is designed in the front side of bifacial solar cells to compare with traditional TOPCon and full-area poly passivation devices. The theoretical efficiency and detailed power loss analysis in our simulation reveal that suppressing the recombination of FSF (front surface field) and the contact area is the crucial strategy to improve device performance, with optimized efficiency of 26.62 % and FF of 85.16 %. These results indicate that the route of BJ (back junction) structure containing localized selective contact and full coverage high-quality passivation holds potential in realizing both high Jsc and Voc for FBC (front and back contact) solar cells, featuring great instructive significance for future industrialization of PV production.

Extending mid-infrared wavelength to 6.84 μm in oxide nonlinear optical crystal via birefringence dispersion management.

Extending lasing wavelengths to the mid-infrared (MIR) spectrum is vital for both civilian and military applications; however, it remains challenging when employing oxide nonlinear optical crystals. In this study, we report the generation of MIR nanosecond pulses via difference frequency generation (DFG) with a near-IR pump using a newly designed langasite (LGS) crystal, La3(Nb0.6Ta0.4)0.5Ga5.5O14 (LGNT0.4), which incorporates birefringence dispersion management techniques with La3Ga5.5Nb0.5O14 (LGN) as a template. Due to the improved effective nonlinear coefficients and the maintained IR cutoff relative to LGN, the tunable DFG laser in LGNT0.4 extended from 4.24 to 6.84 μm, delivering a maximum pulse energy of 16.3 μJ at 5.02 μm. To the best of our knowledge, this is the first known oxide material capable of generating tunable nanosecond pulsed lasers beyond 6 μm at μJ-level energies, demonstrating promising potential for high-intensity MIR laser systems owing to its high laser damage threshold.

Quasi-in-situ characterization and laser damage investigation of flaws in silica antireflection coatings

Quasi-in-situ characterization and laser damage investigation of flaws in silica antireflection coatings

Rapid screening of fibrous plaster ceilings health status using a laser Doppler vibrometer

The pressing necessity to determine a fast, efficient and rigorous approach to assess the health status of fibrous plaster ceilings across the UK motivated the research presented in this paper. Health monitoring techniques commonly used in the civil engineering sector are generally based on the measurement of the dynamic response of structures, such as buildings or bridges, using sensors (mainly accelerometers). This approach can certainly be adopted for suspended ceiling damage identification studies as well; however, the use of sensors directly connected to the ceiling might be prohibitive and time consuming and, therefore, more suitable for permanent monitoring systems. In this regard, in this study we explore the use of the laser Doppler vibrometer for the rapid screening of fibrous plaster ceilings health status. First, rigorous detailed studies have been conducted in the laboratory to assess damage using an ad hoc manufactured fibrous plaster panel using different sources of excitation in conjunction with the laser vibrometer. Damage indicators for the fibrous plaster ceiling have been introduced and validated through the laboratory experiments. Finally, the proposed approach based on laser vibrometer measurements and damage indicators has been applied to the Institution of Civil Engineers library ceiling in London, UK.

Damage mechanism and bending properties degradation of aviation composite honeycomb sandwich structures under laser irradiation

Damage mechanism and bending properties degradation of aviation composite honeycomb sandwich structures are studied under different laser conditions in this paper. Firstly, the damage test of composite honeycomb sandwich structures is conducted. Temperature field and ablation process during laser irradiation are analyzed. Damage morphology and mechanism are verified. Secondly, the influence of laser damage on the bending properties of composite honeycomb panels is studied. Progressive damage process and failure mechanism of honeycomb structures during loading are explored by digital image correlation (DIC) and strain trend. The results show that the temperature at the center point of front surface reaches more than 2000 °C within 1 s under the laser irradiation, while the temperature of back surface exhibits hysteresis. The ablation hole is funnel-shaped and has severe delamination. In the heat affected zone (HAZ), resin matrix has been basically sublimated and oxidized, leaving only carbon fiber bundles and some residual carbon. The honeycomb core in this area has been completely carbonized and deformed. During bending process, the honeycomb core breaks firstly, and strain appears peak at both crack ends, leading the crack extend along both sides. The ultimate load of damaged specimen is 2.35kN, which has a 42.26 % drop compared to that of healthy specimen 4.07kN. Bending properties of specimen are significantly degraded by laser damage.

Study on the effects caused by defect LaK in KH2PO4 crystal

Based on first-principles calculations, we have investigated the effects of different charged states of LaK on the defect formation energies (DFE), lattice distortions, electronic structures, and optical properties of paraelectric phase (PE-KDP) and ferroelectrical phase (FE-KDP) crystals. Our calculations indicate that LaK·· is readily formed in both crystal structures, and the degree of H–O bond distortion is more pronounced in PE-KDP. This could explain the formation of small growth mounds on the surface of La-doped crystals observed in the experiments, as well as the large decrease in the hardness of La-doped crystals. Furthermore, the band gap value of La-doped crystals is smaller than that of perfect crystals. This can be attributed to the fact that the 5d orbitals of La affect the 2p orbitals of O located in the conduction band minimum (CBM), resulting in a splitting of the energy levels and the formation of a defective energy level that enters the forbidden band. The optical spectra have been obtained considering the electron-phonon coupling. Large stokes redshift and nonradiative jump will lower the crystal laser damage threshold. The La-doped PE-KDP has an absorption band at 3.03 eV (409 nm) in good agreement with the experimentally observed absorption band at 390 nm.

Unified modeling of photothermal and photochemical damage.

Correlating damage outcomes to a retinal laser exposure is critical for diagnosis and choosing appropriate treatment modalities. Therefore, it is important to understand the causal relationships between laser parameters, such as wavelength, power density, and length of exposure, and any resulting injury. Differentiating photothermal from photochemical processes in an in vitro retinal model using cultured retinal pigment epithelial cells would be a first step in achieving this goal. The first-order rate constant of Arrhenius has been used for decades to approximate cellular thermal damage. A modification of this equation, called the damage integral (Ω), has been used extensively to predict the accumulation of laser damage from photothermal inactivation of critical cellular proteins. Damage from photochemical processes is less well studied and most models have not been verified because they require quantification of one or more uncharacterized chemical species. Additionally, few reports on photochemical damage report temperature history, measured or simulated. We used simulated threshold temperatures from a previous in vitro study to distinguish between photothermal and photochemical processes. Assuming purely photochemical processes also inactivate critical cellular proteins, we report the use of a photothermal Ω and a photochemical Ω that work in tandem to indicate overall damage accumulation. The combined damage integral (ΩCDI) applies a mathematical switch designed to describe photochemical damage relative to wavelength and rate of photon delivery. Although only tested in an in vitro model, this approach may transition to predict damage at the mammalian retina.

Physicochemical properties of 2-amino-5-methylpyridinium 3-carboxy-4-hydroxybenzenesulfonate single crystal: An efficient material for optoelectronic applications

A novel third-order organic nonlinear optical (NLO) material with promising excellent properties in the crucial NLO application. For the first time high NLO active 2-amino-5-methylpyridinium 5-sulfosalicylic acid (2A5MP3C4H) has been rationally designed and single crystals have been grown by the slow evaporation solution growth technique (SEST). X-ray diffraction analysis revealed that 2A5MP3C4H belongs to the category of triclinic system and has a Centro symmetric space group of P1. Remarkably, the grown crystal exhibits competitive and even superior physical properties including high thermal stability and wider transparency than the standard NLO single crystal. The morphology of the as-grown 2A5MP3C4H crystal was equivalent to the theoretically produced morphology. Fourier transform infrared spectroscopy (FTIR) was used to investigate the molecular vibrations of 2A5MP3C4H. The optical characteristics of 2A5MP3C4H recorded optical transmittance spectrum reveals that the 2A5MP3C4H crystal possesses good optical transparency in the range between ultraviolet (UV) and near-infrared (NIR) regions. Intriguingly, the short cut-off edge of the grown crystal is found to be about 345 nm which is more favourable for developing modern photonic and optoelectronic devices application. The Laser Damage Threshold (LDT), were investigated to understand its effectiveness to be utilized in the area of optoelectronics and photonics. The thermal and mechanical stability of 2A5MP3C4H was tested using Thermo gravimetric Differential Thermal Analysis (TG-DTA) and Vickers hardness test. The third-order nonlinear optical properties of 2A5MP3C4H single crystals were analyzed, which involves studying the absorption coefficient and refractive index behaviour using a continuous wave laser. Additionally, the grown crystal exhibits outstanding third-order NLO response and wide LDT, which are crucial characteristics for developing practical NLO devices. There are various 2-amino-5-methylpyridine (2A5MP) derivative single crystals available in the literature. However 2A5MP3C4H crystal has not been reported earlier. So, we have carried out our researcher on this new novel crystal. Our findings consequently open a novel path for the logical design of enormous, thermally stable and NLO-active organic complexes for true NLO applications.

Improvement of Laser Damage Resistance of Fused Silica Using Oxygen-Aided Reactive Ion Etching

Reactive ion etching (RIE) with fluorocarbon plasma is a facile method to tracelessly remove the subsurface damage layer of fused silica but has the drawback of unsatisfactory improvement in laser damage resistance due to the induction of secondary defects. This work proposes to incorporate O2 into the CHF3/Ar feedstock of RIE to suppress the formation of secondary defects during the etching process. Experimental results confirm that both the chemical structural defects, such as oxygen-deficient center (ODC) and non-bridging oxygen hole center (NBOHC) defects, and the impurity element defects, such as fluorine, are significantly reduced with this method. Laser-induced damage resistance is consequently greatly improved, with the 0% probability damage threshold increasing by 121% compared to the originally polished sample and by 41% compared to the sample treated with conventional RIE.

Growth of laser damage in fused silica and CaF2 under 263 nm laser irradiation

Growth of laser damage in fused silica and CaF2 under 263 nm laser irradiation

Optical, Mechanical and Dielectric Characterization of 5-(3,4,5-Trimethoxybenzyl) Pyrimidine-2,4-Diamine (Trimethoprim- An Antibiotic Drug) Single Crystal

Objectives: To evaluate the optical properties of the trimethoprim (TMP) single crystal. Methods: 5-(3, 4, 5- trimethoxybenzyl) pyrimidine-2-4-diamine known as trimethoprim (TMP), a single crystal is a well-known antibiotic drug, was grown by the slow evaporation method. Findings: The TMP unit cell parameters were confirmed by single crystal X-ray diffraction. Functional groups of TMP crystal was confirmed by Fourier transform infrared spectral analysis. The optical spectrum shows the wide transparency window of TMP which is the prerequisite for NLO material. The band gap is calculated as 4.10 eV from Tauc’s plot. The various optical constants like extinction coefficient, refractive index and reflectance were calculated from the transmittance spectrum data. The optical and electrical parameters like optical conductivity, electrical conductivity and susceptibility of the single crystal of TMP were determined from the UV spectrum. The fluorescence spectrum shows the presence of a sharp intense peak at 690 nm indicates red emission and a weak peak observed at 480 nm indicates blue emission. The Vickers hardness study shows the grown crystal belongs to the soft type single crystal with Meyer’s index (n) of 2. The yield strength of the crystal was calculated. Dielectric constant and dielectric loss are measured as a function of frequency. The laser damage threshold of the TMP crystal was measured using an Nd: YAG laser with a wavelength of 1064 nm. Novelty: The various studies show that the TMP crystal possesses excellent optical properties and can be used for opto-electronics device fabrication. Keywords: Unit cell, Transmittance, Emission, Hardness, Dielectric constant and loss