Large Electric Dipole Moment Research Articles

Electric Field Effects on Photoluminescence of CdSe Nanoparticles in a PMMA Film

External electric field effects on spectra and decay of photoluminescence (PL) as well as on absorption spectra were measured for CdSe nanoparticles in a poly(methyl methacrylate) (PMMA) film. Electrophotoluminescence (E-PL) spectra as well as electroabsorption spectra show a remarkable Stark shift which depends on the particle size, indicating a large electric dipole moment in the first exciton state. The E-PL spectra also show that PL of CdSe is quenched by application of electric fields, and the magnitude of the field-induced quenching becomes larger with increasing size. The PL decay profiles observed in the absence and presence of electric field show that the field-induced quenching of PL mainly originates from the field-induced decrease in population of the emitting state prepared through the relaxation from the photoexcited state.

Erratum: Large tau and tau neutrino electric dipole moments in models with vectorlike multiplets [Phys. Rev. D 81, 033007 (2010)

Erratum: Large tau and tau neutrino electric dipole moments in models with vectorlike multiplets [Phys. Rev. D 81, 033007 (2010)

Nitrobenzene anti-parallel dimer formation in non-polar solvents

We investigated the dielectric and depolarized Rayleigh scattering behaviors of nitrobenzene (NO2-Bz), which is a benzene mono-substituted with a planar molecular frame bearing the large electric dipole moment 4.0 D, in non-polar solvents solutions, such as tetrachloromethane and benzene, at up to 3 THz for the dielectric measurements and 8 THz for the scattering experiments at 20 °C. The dielectric relaxation strength of the system was substantially smaller than the proportionality to the concentration in a concentrated regime and showed a Kirkwood correlation factor markedly lower than unity; gK ∼ 0.65. This observation revealed that NO2-Bz has a tendency to form dimers, (NO2-Bz)2, in anti-parallel configurations for the dipole moment with increasing concentration of the two solvents. Both the dielectric and scattering data exhibited fast and slow Debye-type relaxation modes with the characteristic time constants ∼7 and ∼50 ps in a concentrated regime (∼15 and ∼30 ps in a dilute regime), respectively. The fast mode was simply attributed to the rotational motion of the (monomeric) NO2-Bz. However, the magnitude of the slow mode was proportional to the square of the concentration in the dilute regime; thus, the mode was assigned to the anti-parallel dimer, (NO2-Bz)2, dissociation process, and the slow relaxation time was attributed to the anti-parallel dimer lifetime. The concentration dependencies of both the dielectric and scattering data show that the NO2-Bz molecular processes are controlled through a chemical equilibrium between monomers and anti-parallel dimers, 2NO2-Bz ↔ (NO2-Bz)2, due to a strong dipole-dipole interaction between nitro groups.

Large electron electric dipole moment in minimal flavor violation framework with Majorana neutrinos

The latest data from the ACME Collaboration have put a stringent constraint on the electric dipole moment d_e of the electron. Nevertheless, the standard model (SM) prediction for d_e is many orders of magnitude below the new result, making this observable a powerful probe for physics beyond the SM. We carry out a model-independent study of d_e in the SM with right handed neutrinos and its extension with the neutrino seesaw mechanism under the framework of minimal flavor violation. We find that d_e crucially depends on whether neutrinos are Dirac or Majorana particles. In the Majorana case, d_e can reach its experimental bound, and it constrains the scale of minimal flavor violation to be above a few hundred GeV or more. We also explore extra CP-violating sources in the Yukawa couplings of the right-handed neutrinos. Such new sources can have important effects on d_e.

Theoretical characterization and design of highly efficient iridium (III) complexes bearing guanidinate ancillary ligand

A density functional theory/time-depended density functional theory was used to investigate the synthesized guanidinate-based iridium(III) complex [(ppy)2Ir{(NiPr)2C(NPh2)}] (1) and two designed derivatives (2 and 3) to determine the influences of different cyclometalated ligands on photophysical properties. Except the conventional discussions on geometric relaxations, absorption and emission properties, many relevant parameters, including spin-orbital coupling (SOC) matrix elements, zero-field-splitting parameters, radiative rate constants (kr) and so on were quantitatively evaluated. The results reveal that the replacement of the pyridine ring in the 2-phenylpyridine ligand with different diazole rings cannot only enlarge the frontier molecular orbital energy gaps, resulting in a blue-shift of the absorption spectra for 2 and 3, but also enhance the absorption intensity of 3 in the lower-energy region. Furthermore, it is intriguing to note that the photoluminescence quantum efficiency (ΦPL) of 3 is significantly higher than that of 1. This can be explained by its large SOC value<T1|HSO|Sn>(n=3–4) and large transition electric dipole moment (μS3), which could significantly contribute to a larger kr. Besides, compared with 1, the higher emitting energy (ET1) and smaller <S0|HSO|T1>2 value for 3 may lead to a smaller non-radiative decay rate. Additionally, the detailed results also indicate that compared to 1 with pyridine ring, 3 with imidazole ring performs a better hole injection ability. Therefore, the designed complex 3 can be expected as a promising candidate for highly efficient guanidinate-based phosphorescence emitter for OLEDs applications.

Size effect and stability of polarized fluid phases

The existence of a ferroelectric fluid phase for systems of 1000-2000 dipolar hard or soft spheres is well established by numerical simulations. Theoretical approaches proposed to determine the stability of such a phase are either in qualitative agreement with the simulation results or disagree with them. Experimental results for systems of molecules or particles with large electric or magnetic dipole moments are also inconclusive. As a contribution to the question of existence and stability of a fluid ferroelectric phase this simulation work considers system sizes of the order of 10000 particles, thus an order of magnitude larger than those used in previous studies. It shows that although ferroelectricity is not affected by an increase of system size, different spatial arrangements of the dipolar hard spheres in such a phase are possible whose free energies seem to differ only marginally.

Atom control and gravity measurements using Rydberg positronium

We consider some of the obstacles that will have to be overcome in order to perform a direct measurement of the gravitational free-fall of positronium atoms. Foremost among these are the production of positronium atoms in a cryogenic environment, efficient excitation of these atoms to suitably long-lived Rydberg states, and their subsequent control via the interaction of their large electric dipole moments with inhomogeneous electric fields. Recent developments in all of these areas can be directly applied to a positronium free-fall gravity measurement, making such an endeavour both timely and feasible.

Scanning tunneling microscopy of fluorinated fullerene molecules on silicon surfaces

Scanning tunneling microscopy (STM) under ultra-high vacuum conditions is used to study the initial stages of adsorption of C60F18 and C60F36 fluorofullerene molecules on Si(111)-7 x 7 and Si(100)-2 x 1 surfaces. Spatially resolved STM images of individual molecules and ab initio calculations show that the fluorofullerene molecules interact with an Si surface, with the F atoms oriented toward the surface. The large electric dipole moment of the molecules induces strong polarization on the surface, but the charge transfer is weak. The presence of C60F36 isomers with different symmetry—T, C3, and C1—is revealed in STM images for the first time.

Prospects for ultracold polar and magnetic chromium–closed-shell-atom molecules

The properties of the electronic ground state of the polar and paramagnetic chromium--closed-shell-atom molecules have been investigated. State-of-the-art \textit{ab initio} techniques have been applied to compute the potential energy curves for the chromium--alkaline-earth-metal-atom, CrX (X = Be, Mg, Ca, Sr, Ba), and chromium--ytterbium, CrYb, molecules in the Born-Oppenheimer approximation for the $X^7\Sigma^+$ high-spin electronic ground state. The spin restricted open-shell coupled cluster method restricted to single, double, and noniterative triple excitations, RCCSD(T), was employed and the scalar relativistic effects within Douglas-Kroll-Hess Hamiltonian or energy-consistent pseudopotentials were included. The permanent electric dipole moments and static electric dipole polarizabilities were computed. The leading long-range coefficients describing the dispersion interaction between atoms at large interatomic distances, $C_6$, are also reported. Molecules under investigation are an example of species possessing both large magnetic and electric dipole moments making them potentially interesting candidates for ultracold many-body physics studies.

How do ultralong-range homonuclear Rydberg molecules get their permanent dipole moments?

Cold and ultracold Rydberg atoms are in considerable vogue for their ability to creating strong interactions, stemming from their exaggerated and readily tunable properties. Ultralong-range Rydberg molecules have been predicted to form from the interaction of ultracold Rydberg atoms with ground-state atoms and polar molecules. In this work, we discuss and demonstrate how such molecules, which are homonuclear, form substantially large permanent electric dipole moments. A corollary benefit of such strong hybridisation is the realisation of high angular momentum degenerate Rydberg molecules (so-called trilobite molecules) with standard photoassociation techniques.

Cooling molecules the optoelectric way

In a newly implemented technique, the complex rotational and vibrational motions of molecules are not a hindrance but a help.

Excitation of He atoms by 10–30 keV He+ impact

The anticrossing spectra of the helium line λ(1s4l–1s2p 3P) = 447.2 nm were measured for 10–30 keV He+–He collisions. The theoretical intensity functions were calculated taking into account cascade processes, the inhomogeneity of the axial electric field in the collision volume and the density distribution of the target He atoms. Comparing the theoretical intensities with the measured ones, the post-collisional states of He atoms were determined. The results indicate that for this projectile-energy range, the electronic charge distributions of the excited-atom states change from almost symmetric to strongly asymmetric ones with large electric dipole moments. This result suggests that for projectile energies of 20–30 keV, Paul-trap promotion becomes the main excitation mechanism.

Dynamical Processes in Rydberg-Stark Deceleration and Trapping of Atoms and Molecules

The interaction between inhomogeneous electric fields and the large electric dipole moments of atoms and molecules in Rydberg states of high principal quantum number can be used to efficiently accelerate and decelerate atoms and molecules in the gas phase. We describe here how hydrogen atoms and molecules initially moving with velocities of ∼600 m/s in supersonic beams can be decelerated to zero velocity and loaded into electric traps. The long observation times that are made possible by the electrostatic trapping enables one to study slow relaxation processes. Experiments are presented in which we have observed photoionization processes and transitions between Rydberg states induced by blackbody radiation at temperatures between 10 K and 300 K on a time scale of several milliseconds. Comparison of these processes in Rydberg states of H and H(2) suggests the importance, in H(2), of collisional processes and of the process of blackbody-radiation-induced predissociation.

Experimental consequences of predicted charge rigidity of superconductors

The theory of hole superconductivity predicts that in superconductors the charged superfluid is about a million times more rigid than the normal electron fluid. We point out that this physics should give rise to large changes in the bulk and surface plasmon dispersion relations of metals entering the superconducting state, that have not yet been experimentally detected and would be in stark contradiction with the expected behavior within conventional BCS-London theory. We also propose that this explains the puzzling experimental observations of Avramenko et al. [1] on electron sound propagation in superconductors and the puzzling experiments of de Heer et al. [2] detecting large electric dipole moments in small metal clusters, as well as the Tao effect [3] on aggregation of superconducting microparticles in an electric field. Associated with the enhanced charge rigidity is a large increase in the electric screening length of superconductors at low temperatures that has not yet been experimentally detected. The physical origin of the enhanced charge rigidity and its relation to other aspects of the theory of hole superconductivity is discussed.

Search for electric dipole moments at storage rings

Permanent electric dipole moments (EDMs) violate parity and time-reversal symmetry. Within the Standard Model (SM) they are many orders of magnitude below present experimental sensitivity. Many extensions of the SM predict much larger EDMs, which are therefore an excellent probe for the existence of “new physics”. Until recently it was believed that only electrically neutral systems could be used for sensitive searches of EDMs. With the introduction of a novel experimental method, high precision for charged systems will be within reach as well. The features of this method and its possibilities are discussed.

Terahertz vibrational properties of water nanoclusters relevant to biology

Water nanoclusters are shown from first-principles calculations to possess unique terahertz-frequency vibrational modes in the 1-6THz range, corresponding to O-O-O "bending," "squashing," and "twisting" "surface" distortions of the clusters. The cluster molecular-orbital LUMOs are huge Rydberg-like "S," "P," "D," and "F" orbitals that accept an extra electron via optical excitation, ionization, or electron donation from interacting biomolecules. Dynamic Jahn-Teller coupling of these "hydrated-electron" orbitals to the THz vibrations promotes such water clusters as vibronically active "structured water" essential to biomolecular function such as protein folding. In biological microtubules, confined water-cluster THz vibrations may induce their "quantum coherence" communicated by Jahn-Teller phonons via coupling of the THz electromagnetic field to the water clusters' large electric dipole moments.

SUSY CP problem in gauge mediation model

SUSY CP problem in the gauge mediation supersymmetry breaking model is reconsidered. We pay particular attention to two sources of CP violating phases whose effects were not seriously studied before; one is the effect of the breaking of the GUT relation among the gaugino masses due to the field responsible for the GUT symmetry breaking, and the other is the supergravity effect on the supersymmetry breaking parameters, in particular, on the bi-linear supersymmetry breaking Higgs mass term. We show that both of them can induce too large electric dipole moments of electron, neutron, and so on, to be consistent with the experimental bounds.

Search for EDMs using Storage Rings

Permanent electric dipole moments (EDMs) violate parity and time-reversal symmetry. Within the Standard Model (SM), they require CP violation and are many orders of magnitude below present experimental sensitivity. Many extensions of the SM predict much larger EDMs, which are therefore an excellent probe for the existence of new physics. Until recently it was believed that only electrically neutral systems could be used for sensitive searches of EDMs. With the introduction of a novel experimental method, high precision for charged systems will be within reach as well. The features of this method and its possibilities and status are discussed.

Piezoelectric poly-g-benzyl-L-glutamate polymethyl methacrylate composite disks fabricated using molds.

Poly-g-benzyl-L-glutamety Polymethyl methacrylate (PBLG-PMMA) composite polymer, a new piezoelectric transduction material, was invented by Yu et al. In this study a method is developed to fabricate a disk using detachable molding. Unlike film-type piezoelectric polymers such as the polyvinylidenefluoride (PVDF), this new material can be used to form a body of various shapes and sizes such as conventional piezoelectric ceramics. The piezoelectric characteristics mainly come from the state of alignment of polygamma-benzyl alpha, L-glutamate molecules (PBLG), which have large electric dipole moment. The PBLG can be melted with methyl methacrylate by heating, and mixture with applying electric field can be polymerized as a piezoelectric PBLG-PMMA composite in the mold. The fabricated specimens have the dimensions of 20 mm in diameter and 3 mm in height. The piezoelectric coefficient (d33) depends on the concentration of PBLG. Measured values were 0.45 and 1.9 pC/N with concentrations of 10 and 30 wt %, respectively. Even though these values are lower than PVDF, PBLG-PMMA could be applied as a transduction material in various shapes of acoustic transducers because the results suggest that increasing the intensity of electric field and the PBLG concentration may improve the piezoelectricity. Moreover, it is also a great potential to consider new matrix materials instead of PMMA. [Work supported by Grant No. ADD-UD080004DD.]

Large muon electric dipole moment from flavor?

We study the prospects and opportunities of a large muon electric dipole moment (EDM) of the order (10^{-24} - 10^{-22}) ecm. We investigate how natural such a value is within the general minimal supersymmetric extension of the Standard Model with CP violation from lepton flavor violation in view of the experimental constraints. In models with hybrid gauge-gravity mediated supersymmetry breaking a large muon EDM is indicative for the structure of flavor breaking at the Planck scale, and points towards a high messenger scale.