Large Bubbles Research Articles

Computational fluid dynamics modeling of gas bubble separation efficiency in downhole separators and vertical / inclined annulus: An experimental validation and analysis

This study presents a comprehensive investigation into gas bubble separation efficiency in a vertical downhole separator using computational fluid dynamics (CFD) modeling, which is validated with experimental data. The research aims to provide detailed insights into the separation mechanisms and the factors affecting them, such as liquid velocity, gas bubble sizes, and positions. Using an Euler-Lagrange multiphase model, the behavior of individual gas bubbles within the liquid-gas mixture was simulated. The results demonstrate that separation efficiency decreases as the liquid flow rate increases. This reduction in efficiency occurs because the increased liquid flow rate drags more bubbles within the stream, making it harder for them to separate. The separation process is primarily driven by the buoyancy force acting on the bubbles and the velocity profile of the liquid flow. Smaller bubbles, which tend to be near the casing wall, separate more efficiently, while larger bubbles are predominantly located between the second and third quarters of the annulus space. The "quarters" refer to radial divisions from the casing wall to the tubing wall, with the first quarter closest to the casing wall and the fourth quarter closest to the tubing wall. The study introduces a nonlinear regression model based on the numerical results to predict liquid slug separation efficiency. This model, validated against experimental data, accurately predicts separation efficiency and offers a robust methodology for estimating the efficiency of gravity-driven gas-liquid separators. This methodology is crucial for refining separator design and improving the operational efficiency of downhole separation systems, which are vital for enhancing the performance of pumping systems in oil and gas wells. The contributions of this study include a deeper understanding of the downhole separation process, the development of a simplified model for assessing bubble separation efficiency, and the potential application of the proposed methodology to different gas-liquid separator designs and inclination angles, thereby informing the design and operation of downhole separation systems.

Fluid Dynamics Studies on Bottom Liquid Detachment from a Rising Bubble Crossing a Liquid–Liquid Interface

The detachment regimes and corresponding detachment height of lower liquid from a coated bubble during the bubble passage through an immiscible liquid–liquid interface were studied. High-speed imaging techniques were used to visualize the lower liquid detachment from a rising bubble near the interface. Analysis of industrial slag samples by a scanning electron microscope (SEM) was also carried out. The results indicate that the detachment height of lower liquid from a rising bubble showed a distinct correlation to penetration regimes. Bubble size and a fluid’s physical properties exerted a significant influence on the detachment height of the lower liquid. The detachment height for medium bubbles (Weber number: 4~4.5; Bond number: 2.5~7.5) varied significantly with increasing bubble size, which contributes to the lower liquid entrainment in the upper phase due, significantly, to the higher detachment height and large entrainment volume. The maximum detachment height for large bubbles is limited to approximately 100 mm due to the early detachment with the liquid column at the interface though large bubbles transporting a larger volume of lower liquid into the upper phase.

Migration characteristics of bubbles moving in gas–liquid countercurrent two-phase flow in an inclined pipe

While exploring and developing oil and gas, well kick and overflow accidents are inevitable. In such an accident, if the drilling bit is not at the bottom of the well, the drilling tool is blocked, or the reservoir contains toxic gases such as hydrogen sulfide, the traditional technique for well control is no longer suitable, and the bullheading method must be adopted to kill the well. However, during bullheading, the flow patterns of gas and liquid are intricate, making gas velocity hard to predict. To solve these problems, a set of visual simulation experimental device for directional well bullheading was built to find out the effects of wellbore inclination, liquid viscosity, gas and liquid velocities, and bubble size on bubble migration characteristics in gas–liquid countercurrent (gas flowing in opposite direction to the liquid). Prediction models of bubble distribution coefficient and rising velocity considering liquid viscosity, bubble size, and wellbore inclination angle were worked out. The experimental results show that small bubbles are mainly located in the center of the wellbore and large bubbles tend to approach the wellbore wall in gas–liquid countercurrent. Increasing wellbore inclination, viscosity, and the velocity of the liquid flowing against the bubbles results in a gradual decrease in Taylor bubble migration speed, which promotes the bubbles' pressing-back, as inhibiting the upward movement of large bubbles is essential for effective bullheading operations. The prediction models of distribution coefficient and bubble migration velocity have an error of less than 10% and 9. 78%, respectively.

Position dependence of the standing-wave radiation pressure quadrupole projection on a sphere applied to drop shape.

There have been decades of interest in using the ultrasonic radiation pressure of standing waves to deform nearly spherical objects. An analytical approach sometimes associated with the present author involves approximating projections of the radiation pressure on spheres small in comparison with the wavelength and calculating the response to that projection. In 1981, for small fluid spheres, some terms in the quadrupole projection were published along with the dependence on the size and location of the sphere. An associated application was the flattening of levitated drops in air which are attracted toward velocity antinodes of a standing wave having horizontal equiphase surfaces. In subsequent applications of those results, the predicted analytical dependence on the location of the drop is frequently neglected. For the case of small weakly deformed drops in air in normal gravity, that omission is shown to result in an overestimation of the deformation and of the magnitude of the quadrupole radiation pressure projection. The present discussion simplifies the early results when applied to oblate drops and illustrates the consequence of including the position dependence on the modified small deformation. For large trapped oblate bubbles in water (also reviewed), the shape and location depend on the size.

Modeling and scaling of cavitation compliance in Venturi

Understanding cavitation compliance in Venturi is important for research on system oscillations in fluid machinery, which describes the responsiveness of the cavity size to alternating inflow parameters. To consider both Venturi geometries and inflow conditions in evaluating the cavitation compliance, the cavitation region is modeled as a large vapor bubble, based on the experimental characteristics of the attached cavity characterizing the cavity size. Steady-state numerical solutions of cavity sizes show the influencing trends by geometrical and inflow parameters consistent with experiments. According to the analytical solution approximating the numerical solution, effective cavitation number σe and effective length ratio L̃* are defined to unify these influencing parameters. Based on the causes of cavitation pressure drops at the throat indicated by σe, cavitation compliance can be categorized into two regimes. Regime I features a smaller σe, and the dynamic pressure dominates in the pressure drops, theoretically resulting in L̃*∝σe−9. Regime II features a larger σe, and the bend-flow inertia and dynamic pressure are comparable, resulting in L̃*∝σe−2 in contrast. The power-law predictions of cavitation compliance are validated by experiments and literature.

Effect of Ni addition and bath temperature on electroless Cu microstructure in microvia preparation for HDI substrate

In this work, we investigated the microstructure evolution of electroless copper (Cu) deposition under different nickel (Ni) additions and reaction temperatures. It was found that the grain structure of electroless Cu is significantly influenced by the addition of Ni due to its inhibitory effect on Cu self-diffusion, while bath temperature had no impact on the electroless Cu grain growth. Additionally. nanovoids were observed in the electroless layer, primarily at the interface between the Cu trace and electroless layer, which is caused by the attachment of hydrogen bubbles during the electroless Cu reaction. These nanovoids do not affect the epitaxial grain growth in the microvia structure as observed through transmission electron microscopy (TEM). The nanovoids in the electroless Cu under different deposition conditions were also investigated through TEM images with the assistance of ImageJ. We found that the dimension of nanovoids initially increases with the reaction rate, as a result of the higher deposition rate introducing large hydrogen bubbles. However, as the reaction rate further increases, the size of the nanovoids stabilizes because larger hydrogen bubbles more easily escape the surface. This work may offer insights into potential approaches to enhance the quality of electroless Cu deposition for microvia preparation.

Effect of thermal oxidation on helium implanted pure iron

The impact of thermal oxidation on Helium (He) implanted pure iron (Fe) was investigated to experimentally evaluate how thermal oxidation influences the diffusion and distribution of He within the material. In case of the sample with the lowest dose (2 × 1017 ions/cm2), the thinnest oxide layer was observed compared to the non-implanted pure Fe. It is due to He nano bubbles implanted in the material, which hinder the diffusion of Fe ions necessary for forming the oxide layer. For the medium dose sample (5 × 1017 ions/cm2), the oxide layer was slightly thicker than that of the lowest dose, however it had more porous structure due to the numerous nano He bubbles. In addition, a large bubble region around 150–200 nm depth was generated. The highest dose sample (1 × 1018 ions/cm2) was observed that the escape of He was accelerated by the large amount of nano He bubbles from within the metal, forming a porous Fe matrix on the top surface and an oxide layer that is very porous but thicker than those of lower doses.

Effect of electric field on bubble dynamics in channel flow boiling using lattice Boltzmann method

The application of an electric field in flow boiling has been proven to effectively enhance heat transfer and reduce pressure drop instability. This study aims to elucidate the mechanism of the impact of electric fields on flow boiling bubble dynamics through the pseudo-potential lattice Boltzmann method (LBM). The interplay between the externally imposed electric field incoming velocity in different gravity conditions examined. These factors can regulate flow boiling heat transfer in horizontal channel. The results demonstrate a competitive relationship between electric field and gravity and between incoming velocity and gravity. Therefore, under higher gravity condition, an electric field is less effective to enhance flow boiling heat transfer than in low gravity condition and vice versa. Additionally, there exists a synergistic relationship between incoming velocity and the electric field that mitigates their competition. Moreover, when considering multipoint nucleation processes, applying an electric field can attenuates bubble–bubble interactions and inhibit large bubble formation so as to accelerates bubble condensation in supercooled flows and enhance boiling heat transfer. This work provides comprehensive physical insights into the mechanism of electric field to enhance the heat transfer in flow boiling, which is instructive for the development of electrohydrodynamic technique in flow boiling enhancement.

Large Energy Bubble Solutions for Supercritical Fractional Schrödinger Equation with Double Potentials

Large Energy Bubble Solutions for Supercritical Fractional Schrödinger Equation with Double Potentials

Performance Evaluation of UOWC Systems from an Empirical Channel Model Approach for Air Bubble-Induced Scattering.

Underwater optical wireless communication (UOWC) systems provide the potential to establish secure high-data-rate communication links in underwater environments. The uniqueness of oceanic impairments, such as absorption, scattering, oceanic turbulence, and air bubbles demands accurate statistical channel models based on empirical measurements for the development of UOWC systems adapted to different types of water and link conditions. Recently, generalized Gamma and a mixture of two generalized Gamma probability density functions (PDF) were proposed to describe the statistical behavior of small and large air bubbles, respectively, when considering several levels of particle-induced scattering. In this paper, we derive novel closed-form analytic expressions to compute the bit error rate (BER) and outage performance using both proposed PDFs for various scattering conditions. Furthermore, simple asymptotic expressions are obtained to determine the diversity order of each scenario. Monte Carlo simulation results verify the obtained theoretical expressions. Our results also reveal that UOWC systems present lower BER and outage performance under more turbid water cases with respect to the tap water case due to the higher diversity order and despite the significant increases in pathloss at short link distances. Particle-induced scattering provides an inherent mechanism of turbid waters to mitigate air bubble-induced fluctuations and light blockages.

Influence of cavity geometry on the bubble dynamics of nucleate pool boiling

Nucleate pool boiling is known for its exceptional heat transfer coefficients, with the use of cavities further improving bubble nucleation and heat transfer rate. To promote this heat transfer enhancement technique, a thorough understanding of the influence of cavity geometry on single bubble dynamics is required. The influence of depth and radius of cylindrical and conical cavities on the bubble dynamics of nucleate pool boiling of R1234yf were numerically investigated. The cavity radius was varied between 50 and 400 μm and the cavity depth between 100 and 1000 μm at a fixed heat flux of 28 kW/m2. It was found that the maximum equivalent diameter prior to departure was constant for cavities with radii smaller than 120 μm, while it increased linearly when increasing the cavity radius further. Cylindrical cavities exhibited high stability regardless of cavity radius or depth whereas conical cavities showed a decrease in vapor retention with increasing cavity angle. During the necking phase, the bubble interface became pinned at the cavity edge, depending on conical cavity angle, implying that smaller radii allowed for enhanced surface rewetting. Conical cavities could be considered as cylindrical cavities when the cavity angle was less than a quarter of the interface contact angle. When translating the single cavity findings to cavity array design, cylindrical cavities were recommended as they allowed for stable bubble behavior. For increased nucleation zones and rewetting, a sub-critical radius was recommended. Wider cavities were recommended for high superheat conditions as larger bubbles could enhance bubble growth.

Effect of liquid elasticity on transient cavitation bubbles in the tube

We investigate the effect of liquid elasticity on the transient cavitation bubbles confined in a tube both experimentally and theoretically. In experiments, the tube-arrest apparatus is used to generate cavitation bubbles near the tube bottom with various polyethylene oxide solutions. Our experiments show that bubble dynamics, particularly the maximum bubble length, are significantly influenced by liquid elasticity. We establish a double oscillator model for the liquid column to explain the experimental results and predict the bubble dynamics over a broader range. Finally, we propose that the reciprocal of the cavitation number Ca2 and prR/k determine the regimes of the liquid column separation, where pr is the reference pressure, R is tube radius, and k is the “stiffness coefficient” of the liquid column. Our work provides a quantitative scaling of the dynamics of large cylindrical cavitation bubbles in viscoelastic liquids during the transient process.

Coating powder beds with liquids and foams based on viscous formulations using a twin screw mixer: A continuous process study

Coating with viscous formulations has been essential in numerous industries as it can be a means for providing functionalization, additional properties, as well as other benefits. However, there have been scarce studies that have investigated and proposed methodologies in literature. Continuous coating of powders with viscous liquids poses as a promising technology, which has been mentioned in some studies, but has not yet been thoroughly investigated. This paper employs the use of image processing and analysis, in combination with statistical analysis of particles to evaluate the effectiveness of foams and liquids as a means of coating powder beds. Two different sizes of twin screw mixers that are working in continuous operation are employed, and a new continuous foaming device is fabricated and used for the experiments of coating. The effect of materials and process parameters (as for example rotational speed, and flowrate) on the quality of coating are investigated. Image analysis is used to assess the coating quality. The results clearly showcase the potential of using twin screw mixers for coating purposes and not only for mixing. The hypothesis that using large bubble foams to improve the coating of viscous liquids on particles is proven correct, as they provide higher quality coatings compared to their equivalent liquids, when used in the twin screw mixer. Surprisingly, using a larger scale twin screw mixer, does not show a substantial effect on the mixing, regarding quality, however there is still a requirement for mix optimization for achieving scale-up of this process. These results provide a new pathway for coating powders with viscous formulations in industrial applications, requiring less energy and effort in this process, and can pave the way towards introducing more sustainable industrial methodologies for coating.

Numerical simulation study on opening blood–brain barrier by ultrasonic cavitation

Experimental studies have shown that ultrasonic cavitation can reversibly open the blood–brain barrier (BBB) to assist drug delivery. Nevertheless, the majority of the present study focused on experimental aspects of BBB opening. In this study, we developed a three-bubble-liquid-solid model to investigate the dynamic behavior of multiple bubbles within the blood vessels, and elucidate the physical mechanism of drug molecules through endothelial cells under ultrasonic cavitation excitation. The results showed that the large bubbles have a significant inhibitory effect on the movement of small bubbles, and the vibration morphology of intravascular microbubbles was affected by the acoustic parameters, microbubble size, and the distance between the microbubbles. The ultrasonic cavitation can significantly enhance the unidirectional flux of drug molecules, and the unidirectional flux growth rate of the wall can reach more than 5 %. Microjets and shock waves emitted from microbubbles generate different stress distribution patterns on the vascular wall, which in turn affects the pore size of the vessel wall and the permeability of drug molecules. The vibration morphology of microbubbles is related to the concentration, arrangement and scale of microbubbles, and the drug permeation impact can be enhanced by optimizing bubble size and acoustic parameters. The results offer an extensive depiction of the factors influencing the blood–brain barrier opening through ultrasonic cavitation, and the model may provide a potential technique to actively regulate the penetration capacity of drugs through endothelial layer of the neurovascular system by regulating BBB opening.

Can the Symmetric Fermi and eROSITA Bubbles Be Produced by Tilted Jets?

The Fermi Gamma-Ray Space Telescope reveals two large bubbles in the Galaxy, extending nearly symmetrically ∼50° above and below the Galactic center (GC). Previous simulations of bubble formation invoking active galactic nucleus (AGN) jets have assumed that the jets are vertical to the Galactic disk; however, in general, the jet orientation does not necessarily correlate with the rotational axis of the Galactic disk. Using three-dimensional special relativistic hydrodynamic simulations including cosmic rays (CRs) and thermal gas, we show that the dense clumpy gas within the Galactic disk disrupts jet collimation (“failed jets” hereafter), which causes the failed jets to form hot bubbles. Subsequent buoyancy in the stratified atmosphere renders them vertical to form the symmetric Fermi and eROSITA bubbles (collectively, Galactic bubbles). We find that (1) despite the relativistic jets emanating from the GC at various angles ≤45° with respect to the rotational axis of the Galaxy, the Galactic bubbles nonetheless appear aligned with the axis; (2) the edge of the eROSITA bubbles corresponds to a forward shock driven by the hot bubbles; (3) followed by the forward shock is a tangling contact discontinuity corresponding to the edge of the Fermi bubbles; (4) assuming a leptonic model we find that the observed gamma-ray bubbles and microwave haze can be reproduced with a best-fit CR power-law spectral index of 2.4; The agreements between the simulated and the observed multiwavelength features suggest that forming the Galactic bubbles by oblique AGN failed jets is a plausible scenario.

Scaling-Free Cathodes: Enabling Electrochemical Extraction of High-Purity Nano-CaCO3 and -Mg(OH)2 in Seawater.

For electrochemical application in seawater or brine, continuous scaling on cathodes will form insulation layers, making it nearly impossible to run an electrochemical reaction continuously. Herein, we report our discovery that a cathode consisting of conical nanobundle arrays with hydrophobic surfaces exhibits a unique scaling-free function. The hydrophobic surfaces will be covered with microbubbles created by electrolytic water splitting, which limits scale crystals from standing only on nanotips of conical nanobundles, and the bursting of large bubbles formed by the accumulation of microbubbles will cause a violent disturbance, removing scale crystals automatically from nanotips. Benefiting from the scaling-free properties of the cathode, high-purity nano-CaCO3 (98.9%) and nano-Mg(OH)2 (99.5%) were extracted from seawater. This novel scaling-free cathode is expected to eliminate the inherent limitations of electrochemical technology and open up a new route to seawater mining.

Anterior Chamber Air Bubble Dynamics With Decreases in Atmospheric Pressure.

To evaluate the effect of decreasing barometric pressure on intracameral bubble size and intraocular pressure (IOP) in eyes with varying air fills in the anterior chamber. A total of 36 human donor eyes received 30%, 50%, or 90% anterior chamber air fill. The eyes were subjected to decreases in atmospheric pressure down to 750 hPa, equal to 2400 m in altitude, and were repeatedly imaged using anterior segment OCT while IOP was measured continuously. Eyes with 30% air fill initially showed moderate increases in IOP yet rising to an average of 30.83 mm Hg at 850 hPa (mimicking 1400 m altitude) and 42.08 mm Hg at 750 hPa. Eyes with larger air bubbles showed more acute increases in IOP with increases to an average of 47.25 mm Hg in eyes with 50% air fill at 850 hPa and 63.33 mm Hg at 750 hPa. In eyes with 90% air fill in the anterior chamber, IOP readings with an average of 113.42 mm Hg were observed already at 850 hPa, at which point additional pressure reduction was not performed. While severe increases in IOP were observed with decreased atmospheric pressure in eyes with large air bubbles in the anterior chamber, small and moderately sized bubbles seem to allow for travel over modest changes in altitude.

Fate of Nanobubbles Generated from CO2–Hydrate Dissociation: Coexistence with Nanodroplets—A Combined Investigation from Experiment and Molecular Dynamics Simulations

The evolution of CO2 nanobubbles generated by gas–hydrate dissociation is comprehensively studied in this research, employing a synergistic approach that combines laboratory experiments and molecular dynamics simulations. The results show that a higher concentration of nanobubbles can be observed in the early stages of hydrate dissociation, while smaller, thus‐generated, nanobubbles are less stable and prefer to amalgamate into larger bubbles through coalescence or Ostwald ripening. From the high Laplace pressure inside some nanobubbles as well as their higher local densities, they may transform into nanodroplets by densification fluctuations. Thus, the dynamic coexistence of nanobubbles and ‐droplets is confirmed from both experimental and simulation measurements. The number and size of the nanobubbles in the system affects the interaction between water molecules and their movements so that the water molecules diffuse faster upon this condition. The water–water interactions become more pronounced in the presence of nanobubbles and the hydrogen bond network is better preserved in the bulk. This study provides new insights into the microscale mechanisms of gas–hydrate dissociation and highlights the complex interactions between nanobubbles/ ‐droplets, and the aqueous environment after CO2–hydrate dissociation.

Novel concept for 3D-printed, baffled micro-fluidized beds for the regulation of bubble behavior and the suppression of solid back-mixing: Experiments and simulations

In Micro-Fluidized Beds (MFBs), large bubbles (or slugs) and strong solid back-mixing might hinder good mixing, heat and mass transfer, while reducing conversion rates, and limiting selectivity in certain gas–solid reactions. In this study, a series of novel baffled MFBs were produced using 3D-printing. The influence of the number and position of baffles on the regulation of bubble performance and solid back-mixing in MFBs was investigated through fluidization experiments and Two-Fluid Model (TFM) simulations. The results show that the introduction of baffles effectively suppress slug formation and expand the bubbling regime. Baffles placed at mid-height disrupt fully developed slugs more effectively than those at the bottom. Increasing the number of baffles enhances bubble-breaking efficiency. Numerical simulations suggest that baffles positioned in the lower portion of the bed are more effective for the inhibition of global solid back-mixing. This study shed new light on the design and optimization of baffled MFBs.

Bubble Induced Mixing In A Bubble Column With Counter-Current Liquid Flow

Bubble columns have been widely investigated over the last few decades, concentrating on the bubble parameters, and gas/liquid motion. However, mixing and often the resulting interaction between chemical reaction and hydrodynamics in the column are rarely analysed. For this reason, experiments with Laser Induced Fluorescence (LIF) applying Sulforhodamine G as fluorescent dye, and shadow imaging were performed in a square laboratory-scale counter-current flow bubble column at 21 different flow conditions and three different dye inlet positions. In these experiments the mixing efficiency was investigated by varying the bubble size, the gas and the liquid flow rates, to obtain the necessary data for a further understanding of mixing processes in bubbly flows. The strong influence of the bubble presence, their size and the counter-current liquid flow rate on mixing in the column is obvious from these results. Bubble induced mixing leads to a good homogenisation inside the column, compared to a flow without bubbles. Also, the larger the bubbles the higher the bubble induced upward velocity, which leads to a better mixing. The highest counter-current liquid flow rate led to a more concentrated dye jet, which was less dispersed than at lower liquid flow rates, while the moderate counter-current liquid flow rate (11.1 l· min-1) has been found optimal for mixing in the investigated cases. The combination of large bubbles generated with the 3.6 mm capillaries, and a moderate counter-current liquid flow rate led to the best mixing performance in the bubble column.