Hypogene karst caves, formed independently of surface processes, have garnered increasing attention in recent decades, revealing a wider distribution than previously assumed. While most studies have relied on morphological observations, this research combines morphological and geochemical approaches to present new insights from the Obir caves in the Northern Karawank Mountains, Austria. These caverns, discovered during mining activities, lack natural entrances and developed along a prominent master horizon about 500 m above the current spring level. Notably, large shafts within the caves originate in narrow fissures and terminate blindly at the top, also suggesting a phreatic regime during their formation, with some areas being modified by vadose waters later on. A comprehensive study of drill cores indicates a stable isotope halo in the first few centimeters of the wall rock, characterized by significantly depleted δ13C and moderately depleted δ18O values compared to the pristine limestone, accompanied by bleaching of the host rock. This geochemical evidence of wall rock alteration is only present where the original phreatic solutional morphology is preserved and absent where vadose waters resulted in rugged cave wall surfaces.Considering the lack of evidence for the involvement of sulfuric acid or thermal waters, the formation of the Obir caves is attributed to carbonic acid speleogenesis. This interpretation is supported by the observed strong C isotope shift in the wall rock and the presence of CO2-bearing springs both north and south of the Periadriatic Fault. In contrast to previous studies of carbonic acid speleogenesis suggesting large-scale upwelling of aggressive waters, we propose an alternative mechanism: the injection of carbon dioxide gas into limestone situated in the phreatic zone. These injections likely occurred along subvertical tectonic fissures, triggered by the tectonic transpression of the Northern Karawank Mountains during the middle Miocene. Subsequent tectonic uplift and the incision of valleys led to a drop in the groundwater table, widespread collapse of larger cave rooms and localized vadose overprint.This study highlights the strength of combining mega- to the microscale cave morphological observations with systematic geochemical analyses of wall rock alteration in identifying caves formed by carbonic acid speleogenesis.
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