The contamination of water with a myriad of pollutants has become an increasingly global issue in recent decades due to the widespread expansion of industrialization, which has tremendously propagated the development of large-scale industries and increased metallurgic production. Water contamination is anticipated to increase at least two-fold over the next 20 years. In this talk, a new design of an integrated electrode is introduced for the photo-electrochemical purification of water from a wastewater treatment plant. A nanoporous TiO2 structure, directly grown on a Ti substrate by anodization, and a RuO2-IrO2-based electrode was utilized as the photocatalyst and the electrocatalyst, respectively. Photocatalytic and electrocatalytic activities were synergistically combined to achieve an integrated and highly catalytically active electrode. Our experimental results have shown that the efficient enablement of photocatalytic and electrocatalytic activities within a single integrated electrode may be achieved via the new design. The applicability of this integrated electrode system was also tested in a pilot plant at a local water treatment facility. The pilot plant testing results revealed that much more efficient removal of organic waste was accomplished using the integrated electrode system as compared to only photocatalyst or electrocatalyst. The synergistic effect of the integrated bi-functional electrodes will be discussed.
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