Large Orbital Angular Momentum Research Articles

Generation of ultrarelativistic vortex leptons with large orbital angular momenta

We put forward a novel method for generating ultrarelativistic vortex positrons and electrons with intrinsic orbital angular momenta (OAM) through nonlinear Breit-Wheeler (NBW) scattering of vortex γ photons. A complete angular momentum-resolved scattering theory has been formulated, introducing angular momenta of laser photons and vortex particles into the conventional NBW scattering framework. We find that vortex positron (electron) can be produced when the outgoing electron (positron) is generated along the collision axis. By unveiling the angular momentum transfer mechanism, we clarify that the OAM of the γ photon and the large angular momenta due to multiple laser photons are entirely transferred to the generated vortex leptons. Furthermore, the cone opening angle and superposition state of the vortex γ photon can be determined via the angular distribution of created pairs in NBW processes. Published by the American Physical Society 2024

Efficient approach for generating vortex sources with arbitrary orbital angular momentum in acoustic experiments

Abstract In theoretical research framework of acoustics or optics, how to provide stable and efficient experimental vortex sources with arbitrary orbital angular momentum (OAM) (especially with larger OAM) is a highly challenging research topic. Here, we propose and demonstrate the general principle of two different methods to generate vortex sources with arbitrary OAM, based on the point-sources array and acoustic metamaterials, respectively. Specifically, the general synthetic law is summarized from the analytical perspective behind generating two-dimensional vortex waves using different point sources with different phases, and the design flexibility of acoustic metamaterials is also utilized to provide an ideal solution for generating vortex sources with larger OAM. Besides, we qualitatively and quantitatively determine the OAM of generated vortex waves through simple formulas, and briefly discuss the applicability and stability of two different methods with complementary advantages. The principles of vortex sources generation revealed in this work provide direct theoretical support for the experimental exploration of interactions between multiphysics fields and complex media, with potential applications in vortex fields manipulation and OAM detection.

Perfect Zeeman Anisotropy in Rotationally Symmetric Quantum Dots with Strong Spin-Orbit Interaction.

In nanoscale structures with rotational symmetry, such as quantum rings, the orbital motion of electrons combined with a spin-orbit interaction can produce a very strong and anisotropic Zeeman effect. Since symmetry is sensitive to electric fields, ring-like geometries provide an opportunity to manipulate magnetic properties over an exceptionally wide range. In this work, we show that it is possible to form rotationally symmetric confinement potentials inside a semiconductor quantum dot, resulting in electron orbitals with large orbital angular momentum and strong spin-orbit interactions. We find complete suppression of Zeeman spin splitting for magnetic fields applied in the quantum dot plane, similar to the expected behavior of an ideal quantum ring. Spin splitting reappears as orbital interactions are activated with symmetry-breaking electric fields. For two valence electrons, representing a common basis for spin-qubits, we find that modulating the rotational symmetry may offer new prospects for realizing tunable protection and interaction of spin-orbital states.

Photonic Orbital Angular Momentum for quantum interplaying with atoms and entanglement

Photonic Orbital Angular Momentum (OAM) is becoming a pertinent quantum variable for atom-light interaction, in particular for non-linear interaction which leads to photon entanglement and OAM-entanglement. With two 4-levels atomic schemes, we show that Four Wave Mixing addressed by vortex beams leads to very different OAM-entanglement especially for large OAM values.

Photonic Orbital Angular Momentum for quantum interplaying with atoms and entanglement

Photonic Orbital Angular Momentum (OAM) is becoming a pertinent quantum variable for atom-light interaction, in particular for non-linear interaction which leads to photon entanglement and OAM-entanglement. With two 4-levels atomic schemes, we show that Four Wave Mixing addressed by vortex beams leads to very different OAM-entanglement especially for large OAM values.

A new dynamical mechanism of incomplete fusion in heavy-ion collisions

The incomplete fusion has been proved as the emission of the α particle from the very mass-asymmetric state the dinuclear system during its evolution to complete fusion which is hindered due to the increase in the intrinsic fusion barrier related with the large rotational energy. The results of the dinuclear system model have confirmed that the incomplete fusion in heavy-ion collisions occurs at a large orbital angular momentum (L>30ħ) when the sufficient part of the initial collision energy removes as centrifugal energy.

Observation of Asymmetric Oxidation Catalysis with B20 Chiral Crystals**

AbstractThe study of heterogeneous reactions for enantiomeric processes based on inorganic crystals has been resurgent in recent years. However, the question remains how homochirality develops in nature and chemical reactions. Here, the successful growth of B20 group PdGa single crystals with different chiral lattices enabled us to achieve enantioselective recognition of 3,4‐dihydroxyphenylalanine (DOPA) based on a new mechanism, namely orbital angular momentum (OAM) polarization. The orbital textures of PdGa crystals indicate large OAM polarization near the Fermi level and carrying opposite signs. A positive or negative magnetization in the [111] direction is expected depending on the chiral lattice of PdGa crystals. Due to this, the adsorption energies of PdGa crystals and DOPA molecules differ depending on how well the O‐2p orbital of DOPA pairs with the Pd‐4d orbital of PdGa. The results provide one possible explanation for how chirality arises in nature by providing an enantioselective route with pure inorganic crystals.

Observation of Asymmetric Oxidation Catalysis with B20 Chiral Crystals.

The study of heterogeneous reactions for enantiomeric processes based on inorganic crystals has been resurgent in recent years. However, the question remains how homochirality develops in nature and chemical reactions. Here, the successful growth of B20 group PdGa single crystals with different chiral lattices enabled us to achieve enantioselective recognition of 3,4-dihydroxyphenylalanine (DOPA) based on a new mechanism, namely orbital angular momentum (OAM) polarization. The orbital textures of PdGa crystals indicate large OAM polarization near the Fermi level and carrying opposite signs. A positive or negative magnetization in the [111] direction is expected depending on the chiral lattice of PdGa crystals. Due to this, the adsorption energies of PdGa crystals and DOPA molecules differ depending on how well the O-2p orbital of DOPA pairs with the Pd-4d orbital of PdGa. The results provide one possible explanation for how chirality arises in nature by providing an enantioselective route with pure inorganic crystals.

Generation of bright collimated vortex γ -ray via laser driven cone-fan target

We use numerical simulations to demonstrate that a source of bright collimated vortex γ-ray with large orbital angular momentum and small divergence can be achieved by irradiating an intense circularly polarized laser on a cone-fan target. In the all-optical setup, electron beam of energy with hundreds of MeV and also vortex laser pulse are formed. A considerable fraction of angular momentum of laser is converted to electron beam and furthermore to final vortex γ-ray, which are roughly 27.8% and 3%, respectively. The conversion efficiency of energy from laser to them is around 41% and 3.8%. Moreover, comparative simulations for different inner sizes of the cone reveal that there exists an optimal size making the highest angular momentum of γ-ray photons. For simulations with different laser modes, the circularly polarized laser is more appropriate rather than the Laguerre–Gaussian one to generate vortex γ-ray.

Twisted Magnon Frequency Comb and Penrose Superradiance.

Quantization effects of the nonlinear magnon-vortex interaction in ferromagnetic nanodisks are studied. We show that the circular geometry twists the spin-wave fields with spiral phase dislocations carrying quantized orbital angular momentum (OAM). Meanwhile, the confluence and splitting scattering of twisted magnons off the gyrating vortex core (VC) generates a frequency comb consisting of discrete and equally spaced spectral lines, dubbed as twisted magnon frequency comb (TMFC). It is found that the mode spacing of the TMFC is equal to the gyration frequency of the VC and the OAM quantum numbers between adjacent spectral lines differ by one. By applying a magnetic field perpendicular to the plane of a thick nanodisk, we observe a magnonic Penrose superradiance inside the cone vortex state, which mimics the amplification of particles scattered from a rotating black hole. It is demonstrated that the higher-order modes of TMFC are significantly amplified while the lower-order ones are trapped within the VC gyrating orbit which manifests as the ergoregion. These results suggest a promising way to generate twisted magnons with large OAM and to drastically improve the flatness of the magnon comb.

Bright γ-ray source with large orbital angular momentum from the laser near-critical-plasma interaction

We propose a new laser-plasma-based method to generate bright γ-rays carrying large orbital angular momentum by interacting a circularly polarized Laguerre–Gaussian laser pulse with a near-critical hydrogen plasma confined in an over-dense solid tube. In the first stage of the interaction, it is found via fully relativistic three-dimensional particle-in-cell simulations that high-energy helical electron beams with large orbital angular momentum are generated. In the second stage, this electron beam interacts with the laser pulse reflected from the plasma disc behind the solid tube, and helical γ beams are generated with the same topological structure as the electron beams. The results show that the electrons receive angular momentum from the drive laser, which can be further transferred to the γ photons during the interaction. The γ beam orbital angular momentum is strongly dependent on the laser topological charge l and laser intensity a 0, which scales as . A short (duration of 5 fs) isolated helical γ beam with an angular momentum of −3.3 × 10−14 kg m2 s−1 is generated using the Laguerre–Gaussian laser pulse with l = 2. The peak brightness of the helical γ beam reaches 1.22 × 1024 photons s−1 mm−2 mrad−2 per 0.1% BW (at 10 MeV), and the laser-to-γ-ray angular momentum conversion rate is approximately 2.1%.

Optical echo memory based on photonic crystal cavities

Like internet, connecting quantum computers together to build a full quantum network will enhance the ability to process quantum information. On-chip quantum memories can possess the essential functionalities in building a quantum network, including synchronizing a large number of quantum computers and implementing long-distance quantum communication. However, owning mainly to the constraints imposed by the micro-photonic structures themselves, on-chip quantum memories cannot satisfy the requirement for constructing the full quantum network for the incompatibility of their memory property and integration property. We here propose to build an on-chip quantum memory by using spatial-phase-mismatching effect in photonic crystal cavities. In this scenario, not only is the large orbital angular momentum of photonic crystal cavities utilized to realize photon-echo type memory, but also the light-matter enhancement of a photonic cavity is used to achieve a high-efficiency quantum storage.

Optical echo memory based on photonic crystal cavities

Like internet, connecting quantum computers together to build a full quantum network will enhance the ability to process quantum information. On-chip quantum memories can possess the essential functionalities in building a quantum network, including synchronizing a large number of quantum computers and implementing long-distance quantum communication. However, owning mainly to the constraints imposed by the micro-photonic structures themselves, on-chip quantum memories cannot satisfy the requirement for constructing the full quantum network for the incompatibility of their memory property and integration property. We here propose to build an on-chip quantum memory by using spatial-phase-mismatching effect in photonic crystal cavities. In this scenario, not only is the large orbital angular momentum of photonic crystal cavities utilized to realize photon-echo type memory, but also the light-matter enhancement of a photonic cavity is used to achieve a high-efficiency quantum storage.

Multipolar Fermi-surface deformation in a Rydberg-dressed Fermi gas with long-range anisotropic interactions

We study theoretically the deformation of the Fermi surface (FS) of a three-dimensional gas of Rydberg-dressed $^6$Li atoms. The laser dressing to high-lying Rydberg $D$ states results in angle-dependent soft-core-shaped interactions whose anisotropy is described by multiple spherical harmonics. We show that this can drastically modify the shape of the FS and that its deformation depends on the interplay between the Fermi momentum $k_F$ and the reciprocal momentum $\bar{k}$ corresponding to the characteristic soft-core radius of the dressing-induced potential. When $k_F< \bar{k}$, the dressed interaction stretches a spherical FS into an ellipsoid. When $k_F\gtrsim \bar{k}$, complex deformations are encountered which exhibit multipolar characteristics. We analyze the formation of Cooper pairs around the deformed FS and show that they occupy large orbital angular momentum states ($p$, $f$, and $h$ wave) coherently. Our study demonstrates that Rydberg dressing to high angular momentum states may pave a route toward the investigation of unconventional Fermi gases and multiwave superconductivity.

Phase gradient protection of stored spatially multimode perfect optical vortex beams in a diffused rubidium vapor.

We experimentally investigate the optical storage of perfect optical vortex (POV) and spatially multimode perfect optical vortex (MPOV) beams via electromagnetically induced transparency (EIT) in a hot vapor cell. In particular, we study the role that phase gradients and phase singularities play in reducing the blurring of the retrieved images due to atomic diffusion. Three kinds of manifestations are enumerated to demonstrate such effect. Firstly, the suppression of the ring width broadening is more prominent for POVs with larger orbital angular momentum (OAM). Secondly, the retrieved double-ring MPOV beams' profiles present regular dark singularity distributions that are related to their vortex charge difference. Thirdly, the storage fidelities of the triple-ring MPOVs are substantially improved by designing line phase singularities between multi-ring MPOVs with the same OAM number but π offset phases between adjacent rings. Our experimental demonstration of MPOV storage opens new opportunities for increasing data capacity in quantum memories by spatial multiplexing, as well as the generation and manipulation of complex optical vortex arrays.

High Magnetic Anisotropy of a Square-Planar Iron-Carbene Complex.

Among Earth-abundant catalyst systems, iron-carbene intermediates that perform C-C bond forming reactions such as cyclopropanation of olefins and C-H functionalization via carbene insertion are rare. Detailed descriptions of the possible electronic structures for iron-carbene bonds are imperative to obtain better mechanistic insights and enable rational catalyst design. Here, we report the first square-planar iron-carbene complex (MesPDPPh)Fe(CPh2), where [MesPDPPh]2- is the doubly deprotonated form of [2,6-bis(5-(2,4,6-trimethylphenyl)-3-phenyl-1H-pyrrol-2-yl)pyridine]. The compound was prepared via reaction of the disubstituted diazoalkane N2CPh2 with (MesPDPPh)Fe(thf) and represents a rare example of a structurally characterized, paramagnetic iron-carbene complex. Temperature-dependent magnetic susceptibility measurements and applied-field Mössbauer spectroscopic studies revealed an orbitally near-degenerate S = 1 ground state with large unquenched orbital angular momentum resulting in high magnetic anisotropy. Spin-Hamiltonian analysis indicated that this S = 1 spin system has uniaxial magnetic properties arising from a ground MS = ±1 non-Kramers doublet that is well-separated from the MS = 0 sublevel due to very large axial zero-field splitting (D = -195 cm-1, E/D = 0.02 estimated from magnetic susceptibility data). This remarkable electronic structure gives rise to a very large, positive magnetic hyperfine field of more than +60 T for the 57Fe nucleus along the easy magnetization axis observed by Mössbauer spectroscopy. Computational analysis with complete active space self-consistent field (CASSCF) calculations provides a detailed electronic structure analysis and confirms that (MesPDPPh)Fe(CPh2) exhibits a multiconfigurational ground state. The majority contribution originates from a configuration best described as a singlet carbene coordinated to an intermediate-spin FeII center with a (dxy)2{(dxz),(dz2)}3(dyz)1(dx2-y2)0 configuration featuring near-degenerate dxz and dz2 orbitals.

Relativistic aspects of orbital and magnetic anisotropies in the chemical bonding and structure of lanthanide molecules

The electronic structure of magnetic lanthanide atoms is fascinating from a fundamental perspective. They have electrons in a submerged open 4f shell lying beneath a filled 6s shell with strong relativistic correlations leading to a large magnetic moment and large electronic orbital angular momentum. This large angular momentum leads to strong anisotropies, i. e. orientation dependencies, in their mutual interactions. The long-ranged molecular anisotropies are crucial for proposals to use ultracold lanthanide atoms in spin-based quantum computers, the realization of exotic states in correlated matter, and the simulation of orbitronics found in magnetic technologies. Short-ranged interactions and bond formation among these atomic species have thus far not been well characterized. Efficient relativistic computations are required. Here, for the first time we theoretically determine the electronic and ro-vibrational states of heavy homonuclear lanthanide Er2 and Tm2 molecules by applying state-of-the-art relativistic methods. In spite of the complexity of their internal structure, we were able to obtain reliable spin–orbit and correlation-induced splittings between the 91 Er2 and 36 Tm2 electronic potentials dissociating to two ground-state atoms. A tensor analysis allows us to expand the potentials between the atoms in terms of a sum of seven spin–spin tensor operators simplifying future research. The strengths of the tensor operators as functions of atom separation are presented and relationships among the strengths, derived from the dispersive long-range interactions, are explained. Finally, low-lying spectroscopically relevant ro-vibrational energy levels are computed with coupled-channels calculations and analyzed.

Slow Magnetic Relaxation in Mono- and Bimetallic Lanthanide Tetraimido-Sulfate S(NtBu)4 2- Complexes.

Lanthanide ions are particularly well‐suited for the design of single‐molecule magnets owing to their large unquenched orbital angular momentum and strong spin‐orbit coupling that gives rise to high magnetic anisotropy. Such nanoscopic bar magnets can potentially revolutionize high‐density information storage and processing technologies, if blocking temperatures can be increased substantially. Exploring non‐classical ligand scaffolds with the aim to boost the barriers to spin‐relaxation are prerequisite. Here, the synthesis, crystallographic and magnetic characterization of a series of each isomorphous mono‐ and dinuclear lanthanide (Ln=Gd, Tb, Dy, Ho, Er) complexes comprising tetraimido sulfate ligands are presented. The dinuclear Dy complex [{(thf)2Li(NtBu)2S(tBuN)2DyCl2}2 ⋅ ClLi(thf)2] (1c) shows true signatures of single‐molecule magnet behavior in the absence of a dc field. In addition, the mononuclear Dy and Tb complexes [{(thf)2Li(NtBu)2S(tBuN)2LnCl2(thf)2] (2b,c) show slow magnetic relaxation under applied dc fields.

Generation of a large orbital angular momentum beam via an optical fiber winding around a curved path and its application* *Project supported by the National Natural Science Foundation of China (Grant No. 11504074) and the State Key Laboratory of Quantum Optics and Quantum Optics Devices, Shanxi University (Grant No. KF202004).

Many papers have been published on the study of orbital angular momentum (OAM) of the laser modes based on the Laguerre–Gaussian (LG) beam and helical phase plate or rotating cylindrical lens, and the principal ray of the LG beam remains straight line. These ways are difficult to get a large OAM modes. In this paper, we propose a novel method to prepare a large OAM modes when the light propagates through a optical fiber winding around a curved path, and establish a theoretical framework based on the principal ray path changing. Firstly, we investigate three kinds of winding structure. Secondly, based on the analytical solutions and numerical calculations, we can find that the spiral body can achieve a large OAM temporal pulse. At the same time, based on the zero OAM diffraction diagram, we can obtain an improvement of resolving power beyond Rayleigh’s criterion. Finally, applying a large OAM diffraction pattern to realize 12-bitencodes, we can obtain a high-security optical information transfer system.

Isolated intense half-cycle attosecond pulse generation with orbital angular momentum

A relativistic linearly polarized Laguerre–Gaussian (LG) laser pulse interacting with a combination of gas plasma and an oblique foil target is proposed to generate an intense attosecond pulse carrying large orbital angular momentum (OAM). The LG laser pulse firstly produces an ultra-thin relativistic electron sheet (RES) in underdense plasma and transfers the OAM to the latter at the same time. When the RES passes through the oblique foil, it radiates an intense half-cycle attosecond pulse carrying large OAM. Three-dimensional particle-in-cell simulation confirms that an isolated ultra-intense half-cycle attosecond pulse with a duration of 542 as and a peak electric field of 5 × 1012 V m−1 is produced. The average OAM per photon of the attosecond pulse is about −1ћ. Such an intense, isolated attosecond pulse with the large OAM would provide new possibilities in attosecond scientific research.