Enrichment In Large Ion Lithophile Elements Research Articles

Discovery of antiskarn-hosted strategic metal mineralization in the Upper Cretaceous Twihinate carbonatite intrusion (West African Craton Margin, Moroccan Sahara)

The Upper Cretaceous Twihinate carbonatite in Moroccan Sahara, which is the focus of ongoing exploration for Nb-P-Fe ± LREE ± U-Th resources, consists of a crescent-like intrusion made of a central sövite body encircled by an annular ring of vuggy siliceous breccia. Drill core logging coupled with petrographic observation, whole-rock and mineral chemistry reveal that the metasomatic interaction between the carbonatite melt and the silicate wall-rocks led to development of calc-silicate paragenesis within the sövite itself at depths ranging from ∼60 to >200 m from the surface for which the term antiskarn is attributed. We provide the first petrographic and textural descriptions, and report the whole-rock major- and trace-element geochemistry and chemical compositions of the main antiskarn-forming minerals and related strategic metal-bearing ore. Geochemically, the antiskarn lithotypes are characterized by a compositional range of 7–17 wt% SiO2, 25–72 wt% CaO, 1–2 wt% Al2O3, and 12–26 wt% loss on ignition, and enrichment in large-ion lithophile elements (LILE), particularly Sr (3125–7018 ppm ppm), Ba (393–1300 ppm), U (10–787 ppm) and light REEs (LREEs) (1058–1569 ppm), but not in the heavy REE (HREEs) and high-field strength elements (HFSE) such as Ti, Zr, Ta and Hf. Nb and V show, however, much higher concentrations ranging from 140 ppm to >1000 ppm, and 603 to 1008 ppm, respectively. Mineralogically, the antiskarn lithotypes consist predominantly of diopsidic (Di66-82 Hd18-34) to aegirine-augite clinopyroxene (Di38-55 Ae21-35) and andradite (And86-94 Gro1-9) with subordinate amounts of micas (biotite/phlogopite) and titanite. The paragenetically later mineral assemblages involve amphibole, chlorite, epidotes, baryte, fluorite, kaolinite, carbonates and quartz. The main Nb-P-Fe ± LREE ± U-Th ore minerals consist of Fe oxides (titanomagnetite principally), pyrochlore group minerals, phosphates (apatite, monazite-(Ce)), and REE-fluorcarbonates (bastnäsite-(Ce)) with subordinate sulfides (chalcopyrite, sphalerite, and galena), fluorite and baryte. Development of the antiskarn calc-silicate paragenesis and related strategic metal-bearing mineralization is consistent with derivation from a carbonatite melt through assimilation of silicate country rocks including the Silurian-Devonian gneissic granitoid of the Laknouk suite. From an economic perspective, the widespread occurrence of high-Ti (0.7–16. 9 wt% Ti) and V- (0.2–0.7 wt% V) magnetite opens new opportunities in regard of exploration for V; an emerging strategic commodity whose presence has to be reassessed in the Twihinate prospect. The currently described antiskarn paragenesis may be therefore used as reliable exploration metallotect to target prospective occurrences in the search for critical metals including V as by product.

Late Permian-Triassic ridge subduction beneath the northeastern margin of the North China Craton: Evidence from the Kaiyuan appinitic to high-Mg intermediate intrusions in northern Liaoning, North China

Recognizing terminal ridge subduction is of first-order importance in chronicling the tectonic timeline of any accretionary orogens, but remains elusive in the final suturing zone of the Paleo-Asian Ocean along the Solonker−Xar Moron−Changchun−Yanji swath. Here we report two generations of ultramafic-mafic to intermediate intrusions from northern Liaoning, North China, linking eastern Central Asian Orogenic Belt and northern North China Craton. The ca. 259 Ma appinites show variable enrichment in large-ion lithophile elements (LILEs) but depletion in high-field strength elements (HFSEs), and variably enriched isotopic compositions with εNd(t) of −11.8 to −2.4 and zircon εHf(t) of −15.7 to +5.0. These petro-geochemical traits argue for their derivation from partial melting of subduction-modified lithospheric mantle. By contrast, the high-Mg diorites of 226−223 Ma display decoupling features between LILEs and HFSEs and juvenile isotopic signatures with εNd(t) of −0.3 to +2.6 and zircon εHf(t) of +5.4 to +11.4. These characters are consistent with a magmatic origin from partial fusion of sediment-fertilized asthenospheric mantle. Synthesizing the two mantle-melting events with regional coeval igneous activities leads to the identification of Late Permian (265−250 Ma) and Middle-Late Triassic (241−218 Ma) magmatic flare-ups with a 10−15 m.y. lull along the northern North China Craton. This magmatic tempo tends to record a salient mantle replacement from hydrous metasomatized lithosphere to anhydrous asthenosphere. In combination with ensuing progressive crustal growth, simultaneous metamorphism, and structural activities, these diverse manifestations make a compelling case of ridge subduction and concomitant slab window formation during the eventual closure of the Paleo-Asian Ocean along the Solonker−Xar Moron−Changchun−Yanji swath.

Petrogenesis of Jurassic granitic plutons in Liaodong Peninsula, NE China: Insights into the subduction of Paleo − Pacific plate

• Jurassic granites in Liaodong Peninsula formed at 184–179 and 162–151 Ma. • Granite geochemistry reveals the thinning of continental crust from Early to Late Jurassic . • The granites constrain the subduction history of the Paleo–Pacific plate. There is a debate about the subduction of Paleo − Pacific plate in the Jurassic tectonic evolution of the northeastern North China Craton. Here we present new geochronological and geochemical investigations for Early and Late Jurassic granites on Liaodong Peninsula. The Early Jurassic granites (184–179 Ma) show high SiO 2 and low MgO contents, and are classified as I − type granites, with enrichment in large − ion lithophile elements (LILEs) and light rare earth elements (LREEs) and depletion in high − field − strength elements (HFSEs) and heavy REEs (HREEs), and enriched Sr − Nd − Hf − O isotopic compositions. Combined with their typical adakitic properties as high Sr, low Y and Yb contents, and high Sr/Y ratios, we conclude that they originated from thickened lower crust. The spatio − temporal distribution of Early Jurassic intrusive and volcanic rocks and large scale of compressive deformation suggest the onset of flat subduction of Paleo − Pacific plate. In contrast, the Late Jurassic granites (162–151 Ma) are classified as I − type granites, with enrichment in LILEs and LREEs and depletion in HFSEs and HREEs and more enriched Sr − Nd − Hf − O isotopic compositions. Based on Sr and Y contents and Sr/Y ratios, we divided them into two groups. Group 1 show high SiO 2 and low MgO contents and typical adakitic properties, indicating an origin of thickened lower crust. In contrast, group 2 show relatively higher SiO 2 and lower MgO contents, with low Sr and high Y contents and high Nb/U ratios, suggesting an origin of lower crust in normal thickness. The spatio − temporal distribution of Late Jurassic bimodal igneous rocks and continuous volcanic and sedimentary deposition as well as the shifted accretionary complexes, indicate the oblique subduction of Paleo − Pacific plate.

Lithospheric dripping in a soft collision zone: Insights from late Paleozoic magmatism suites of the eastern Central Asian Orogenic Belt

The closure of Paleo-Asian Ocean is considered to have occurred along the Solonker Suture in the southernmost segment of the Central Asian Orogenic Belt (CAOB), the largest Phanerozoic accretionary orogen on the globe. The suture branches to the east to form the northern Hegenshan–Heihe Suture and the southern Solonker–Changchun Suture. The Hegenshan–Heihe Suture is an ideal natural laboratory for studying the post-collisional geodynamic processes operating in a soft collision zone driven by divergent double-sided subduction. Here we report results from an integrated study of the petrology, geochronology, geochemistry, and Sr–Nd–Hf isotopic compositions of the Early Carboniferous–Early Permian magmatic suite in the Hailar Basin of the Xing’an–Erguna Block. The Early Carboniferous igneous rocks are represented by 356–349 Ma andesitic tuffs, exhibiting typical subduction-related features, such as enrichment in large-ion lithophile elements and depletion in high-field-strength elements. These features, together with the relatively depleted Sr–Nd–Hf isotopic compositions, constant Nb/Y values, but highly variable Rb/Y and Ba values indicate that these rocks were generated by partial melting of a depleted mantle wedge metasomatized by slab-derived fluids. The Late Carboniferous–Early Permian magmatic suite (317–295 Ma) is characterized by high Sr contents (313–1080 ppm) and low Y contents (5–13 ppm), and these can be subdivided into calc-alkaline adakitic rocks and high-K calc-alkaline adakitic rocks. The calc-alkaline adakitic rocks have higher values of Sr/Y, (Sm/Yb)source normalized, and Mg#, and lower values of Y, Ybsource normalized, and K2O/Na2O than the high-K calc-alkaline adakitic rocks, which suggests that the former was generated by partial melting of foundered lower continental crust and the latter by partial melting of normal lower continental crust. Based on our new data, in conjunction with those in previous studies, we conclude that the tectonic evolution of the Hegenshan–Heihe Suture involved Early Carboniferous double-sided subduction of the Nenjiang Ocean, latest Early Carboniferous soft collision between the Xing’an–Erguna and Songliao blocks, and Late Carboniferous–Early Permian post-collisional extension. We also propose a new geodynamic scenario in which removal of the lithospheric root might have occurred in a soft collision zone during the post-collision period via repeated and localized lithospheric dripping, which results from combinedeffects of hydration weakening of the lithosphere caused by pre-collision subduction and asthenospheric stirring triggered by slab break-off.

40Ar/39Ar Geochronology, Geochemistry and Petrogenesis of the Volcanic Rocks in the Jiangling Basin, China

In this study, 40Ar/39Ar geochronology and major and trace element data were presented for Paleogene basaltic rocks from the Jiangling Basin, China. The volcanic rocks erupted at ca. 53.19–60.78 Ma and belonged to the sub alkaline series. These basaltic rocks are generally characterized by enrichment in large-ion lithophile elements (LILEs) and light rare earth elements (LREEs) ((La/Yb)cn = 6.14–11.72) and lack of Eu anomalies (Eu/Eu* = 0.98–1.09), similar to ocean island basalts. The geochemical signatures of these rocks are similar to hotspot-related Paleogene volcanic rocks in the North China Block and late Cenozoic volcanic rocks in Southeast China. The Cenozoic lithospheric mantle, as well as the Mesozoic basalts that are beneath the northern Yangtze Blocks, might be inherited from the Mesozoic lithospheric mantle. The basaltic rocks from the Jiangling Basin in the northern Yangtze Block were generated from the partial melting of EMII (enrichedmantleII)-like lithospheric mantle due to the intracontinental extension.

A combination of plume and subduction tectonics contributing to breakup of northern Rodinia: Constraints from the Neoproterozoic magmatism in the Dunhuang-Alxa Block, northwest China

Neoproterozoic igneous rocks are widely distributed in the Dunhuang-Alxa Block, northwest China, and record geodynamic processes caused by the assembly and break-up of Rodinia. In this study, we present new petrological, geochemical, and zircon U-Pb-Hf isotope data for the Langshan gabbros in the northeastern Alxa Block. Langshan gabbros (827−819 Ma) have depleted whole-rock Nd (+3.2 to +4.9) and zircon Hf (+4 to +21) isotopic compositions and weak enrichments in large-ion lithophile elements. These rocks were probably derived by partial melting of a depleted mantle wedge metasomatized by fluids released from a subducted slab in a back-arc basin environment. Geochemical and zircon Hf isotope data for early Neoproterozoic igneous rocks are consistent with the presence of a long-lived (ca. 930−810 Ma) retreating subduction zone along the northern margin of the Dunhuang-Alxa Block, indicating it was located at the northern margin of Rodinia. Some mantle plume-related magmatism, including A1-type silicic volcanic rocks in the Langshan Group and Jinchuan ultramafic-mafic intrusions, occurred in the interior of the Dunhuang-Alxa Block, which was similar to early Neoproterozoic plume-related magmatism (ca. 850−820 Ma) in the interior of northern Rodinia. The temporal link between subduction and extension suggests that this retreating subduction zone along the northern margin of Rodinia, in combination with a mantle plume beneath its interior, resulted in lithospheric extension and break-up of Rodinia during ca. 850−810 Ma.

Petrogenesis, tectonic setting, and metallogenic significance of the Middle Permian volcanic rock system of the Miaoling Formation, Yanbian area, NE China: Constraints from geochronology, geochemistry, and Sr–Nd–Hf isotopes

The volcanic rock system of the Miaoling Formation contains the main ore-bearing rocks of two volcanogenic massive sulfide (VMS)-type deposits in the Yanbian area of NE China. Investigation of the VRSMF is needed to better understand the formation of these VMS-type deposits and the tectonic evolution of the Yanbian area. To determine the petrogenesis, material sources, and formation age of the VRSMF, and elucidate its late Paleozoic tectonic evolution and metallogenic significance, this paper presents new petrological, geochronological, geochemical, whole-rock Sr–Nd and in situ zircon Hf isotopic data for the VRSMF. The VRSMF is composed of marine carbonate, intermediate–felsic volcanic rocks (andesite–trachyandesite–dacite) and pyroclastic rocks. Laser-ablation–inductively coupled plasma–mass spectrometry zircon U–Pb dating gives an eruption age of ca. 265 Ma for the pyroclastic rocks in the VRSMF. These rocks are classified as low- to medium-K calc-alkaline series. They are characterized by enrichments in large-ion lithophile elements (e.g., K, Rb, and Ba) and light rare earth elements, and depletions in high field-strength elements (e.g., Nb, Ta, and Ti) and heavy rare earth elements, showing affinity to igneous rocks formed in arc-related tectonic settings. These features, together with homogeneous zircon εHf(t) values of 10.9–15.7 and depleted Sr–Nd isotopic compositions [εNd(t) values of 2.4–5.0], suggest that the parental magma was derived from the partial melting of depleted mantle that had been metasomatized by subduction-related fluids. These results, along with findings of regional geological investigations, suggest that the formation of the VRSMF was related to subduction of the Paleo-Asian oceanic plate during the middle Permian. The VMS-type mineralization in the Hongtaiping and Dongfengnanshan deposits is interpreted to have formed in a bimodal–felsic setting in a back-arc extensional tectonic environment.

40Ar–39 Ar dating, whole-rock and Sr-Nd isotope geochemistry of the Middle Eocene calc-alkaline volcanic rocks in the Bayburt area, Eastern Pontides (NE Turkey): Implications for magma evolution in an extension-related setting

Discussions continue about whether Middle Eocene magmatism in the Eastern Pontides is associated with collision or subduction. This paper presents new whole-rock geochemistry, Sr-Nd isotopic and 40Ar-39Ar age data for Middle Eocene volcanic rocks from the Bayburt area of the Eastern Pontides (NE Turkey) to investigate their sources and evolutionary history. The new 40Ar–39Ar ages reveal that these volcanic rocks erupted between 44.6 ± 0.1 Ma and 43.5 ± 0.1 Ma, within the Lutetian (Middle Eocene). The studied volcanic rocks are composed of basalt, andesite, basaltic andesite and minor dacite lava and pyroclastic rocks. These rocks consist of plagioclase, amphibole, pyroxene, olivine, biotite, sanidine and minor quartz phenocrysts with Fe-Ti oxides. They have microlithic, hyalo-microlithic, porphyritic and rarely glomeroporphyritic textures. The volcanic rocks have low to high-K calc-alkaline affinities. They display enrichment in large-ion lithophile elements and depletion in high-field strength elements with high Th/Yb ratios, which indicate that the magmas forming the volcanic rocks were derived from lithospheric mantle sources enriched by mostly slab-derived fluids in the spinel stability field. 87Sr/86Sr(i) values vary between 0.70485 and 0.70551 and 143Nd/144Nd(i) values vary between 0.51255 and 0.51267. These data correspond to the mantle array on the isotope ratio diagram. The main solidification processes consist of fractional crystallization with minor assimilation. In light of the data obtained in this study together with data from previous studies, petrogenetic character of the Middle Eocene magmas from the southern parts of the Eastern Pontides may be explained by melting of an enriched lithospheric mantle source initially metasomatized by subduction fluids in a post-collisional extensional-related tectonic setting.

Geochemical and zircon U-Pb geochronological constraints on late mesozoic Paleo-Pacific subduction-related volcanism in southern Vietnam

Late Mesozoic volcanic rocks comprising mainly basalt and basaltic-andesite to dacite occur in south-central Vietnam (Dalat zone) and to a lesser extent in southwestern Vietnam (Bay Nui area). Mineral and whole-rock chemistry indicate a calc-alkaline affinity for samples in the Dalat zone and a high-K calc-alkaline to shoshonitic affinity for rocks in the Bay Nui area. Mineral characteristics and variation diagrams of selected elements suggest that fractional crystallization dominated during magma differentiation. The Bay Nui volcanic rocks generally are more enriched in potassium and LILEs (large-ion lithophile elements) than volcanic rocks from the Dalat zone, which may indicate a more evolved nature or crustal assimilation. The similar chemical characteristics and eruption/emplacement age range of volcanic and plutonic rocks (ca. 90–110 Ma) of equal silica concentration indicate that the magma feeding the volcanic eruptions had the same source as that of the plutonic rocks. The observed mineral and whole-rock compositions with enrichment in LILEs, depletion in HFSEs (high field strength elements), and noticeably negative Nb, Ta, and Ti anomalies are characteristic for arc signatures. Zircon U-Pb geochronological data for the volcanic rocks indicate an age range of 95–105 Ma for the eruption. These geochemical and geochronological data link this Late Mesozoic volcanism with continental arc magmatism driven by the subduction of the Paleo-Pacific beneath eastern Indochina. Zircon xenocrysts with a likely magmatic origin cluster around 350 Ma and 250 Ma, indicating two earlier magmatic events most likely related to the subduction of the Paleo-Tethys beneath western Indochina and the subsequent Indosinian orogeny.

Geochronology and Tectonic Implications of the Nianzigou Granites and Associated Mo Deposit, Inner Mongolia

Multiple stages of igneous rocks occur in the recently discovered Nianzigou Mo deposit in Chifeng, Inner Mongolia, which can provide insights into the late Mesozoic geodynamic evolution of the southern Da Hinggan Range. The mineralization age is similar to the age of local granites, but there are few detailed studies of the tectonic setting during Cu-Mo mineralization in this area. The Nianzigou Mo deposit is located close to the northern margin of the North China Craton and in the eastern Central Asian Orogenic Belt and is a typical quartz-vein-type Mo deposit in the Xilamulun Mo ore belt. The granite in this deposit has high SiO2, Al2O3, K2O, and Na2O contents, and low MgO, CaO, and Fe2O3t contents. The granite is characterized by enrichments in large-ion lithophile elements and depletions in high-field-strength elements and, in particular, Sr, Ti, and P. The granite has high contents of rare-earth elements, is enriched in light rare-earth elements, and has marked negative Eu anomalies. The granite is an alkaline and calc-alkaline and metaluminous A-type granite. The zircon U-Pb ages of the monzogranite and granite porphyry are 157.2 ± 0.3 and 154.4 ± 0.4 Ma. The model age obtained by Re-Os isotopic dating is 154.3 ± 1.7 Ma, indicating that molybdenite mineralization also occurred during the Late Jurassic period. Given that the molybdenite Re contents are 7.8–24.9 ppm (average = 16.8 ppm), the ore-forming materials of the Nianzigou Mo deposit had a mixed crust–mantle source, but were mainly derived from the lower crust. Based on the geology and geochemistry, we propose that the Nianzigou Mo deposit formed in a postorogenic extensional tectonic setting associated with the southward subduction of the Mongol–Okhotsk oceanic plate.

Two episodes of Eocene mafic magmatism in the southern Lhasa terrane imply an eastward propagation of slab breakoff

Past geodynamic events can be reconstructed using the spatial and temporal patterns of geochemical variability in igneous rocks. Here we apply this principle to define the timing and geometry of breakoff of the Neo-Tethyan slab after the India-Asia collision. Two episodes of mafic magmatism (∼53 Ma and ∼ 48 Ma) are preserved in the Quxu area of the southern Lhasa terrane (SL). We present their whole-rock geochemistry, zircon U-Pb ages, and in situ zircon Hf isotope ratios. The early gabbro (∼53 Ma) exhibits typical arc basalt characteristics, including enrichment of large-ion lithophile elements (LILEs), depletion of high-field strength elements (HFSEs), and radiogenic Nd and zircon Hf isotopes, implying that they were formed by partial melting of metasomatized lithospheric mantle. In comparison tothe early gabbro, the late hornblende gabbro (∼48 Ma) contains higher contents of HFSEs (e.g., Nb, Zr) and relatively less radiogenic Nd and zircon Hf isotopes, suggesting interaction between the enriched sub-continental lithospheric mantle and asthenospheric mantle. It is likely that upwelling asthenosphere reached the central SL around 50 Ma and that the Neo-Tethyan slab tore off under this area at this time. The spatial and temporal distribution of mafic rocks across the whole southern Lhasa terrane show that this geochemical transition and hence, presumably, the tearing off of the Neo-Tethyan slab, propagated eastward along the collision zone throughout Paleocene-Eocene time.

Petrogenesis and tectonic implications of 1.86–1.80 Ga A-type granites in the Daqingshan Complex, Khondalite Belt, North China Craton

The Khondalite Belt is regarded as a Paleoproterozoic continent–continent collisional belt along which the Yinshan Block and the Ordos Block amalgamated to form the Western Block in the North China Craton. Associated with the collision of the Yinshan and Ordos Blocks was granitic magmatism represented by quartz monzogranites in the Khondalite Belt, whose petrology, geochemistry and petrogenesis will provide important insights into understanding of the crustal evolution of the Khondalite Belt in the late Paleoproterozoic. In this paper, we carried out a detailed study on the petrography, geochronology, whole-rock geochemistry, and zircon Lu-Hf isotope of quartz monzogranites exposed in the Daqingshan Complex of the Khondalite Belt. Zircon LA-ICP-MS U-Pb dating results show that the Daqingshan quartz monzogranites were formed at 1.86–1.80 Ga, at some time posterior to the ∼ 1.95 Ga collision of the Yinshan and Ordos Blocks. Geochemically, the Daqingshan quartz monzogranites belong to ferroan, metaluminous to peraluminous, calc-alkalic to alkalic-calc series, exhibiting high SiO2, Na2O, K2O and FeOT / (FeOT + MgO), low Al2O3, MgO and CaO, and high Zr, Nb, Ce and Y, low Cr and Ni contents, with an affinity of A-type granites. In terms of REE and trace elements, the Daqingshan quartz monzogranites have right dipping patterns and negative Eu anomalies, enriched large ion lithophile elements (LILEs) (e.g. Rb, Zr and Hf), and depleted high field strength elements (HFSEs) (e.g. Ta, P and Ti). Zircon Lu-Hf isotopic characteristics (εHf(t) = -9.63 – −4.31, TDMC = 2744–3050 Ma) indicate that the Daqingshan quartz monzogranites were most likely originated from the partial melting of a Neoarchean ancient crust. Combining new results presented in this paper with previous data, we propose that the quartz monzogranites in the Daqingshan Complex were derived from the partial melting of Neoarchean TTG rocks under high temperatures caused by the upwelling of mantle magmas under a post-collision extensional setting. Meanwhile, it indicates that the Khondalite Belt completed collision at 1.86–1.80 Ga to form the Western Block.

Zinc isotope constraints on carbonated mantle sources for rejuvenated-stage lavas from Kauaʻi, Hawaiʻi

Sedimentary carbonates could be transported into Earth's mantle by plate subduction, but the ultimate fate of these carbonates remains unclear. Zinc isotopes can allow the tracing of recycled isotopically heavy Zn-rich sedimentary carbonates (δ66Zn up to 0.91‰) within the mantle. This study presents new whole-rock major- and trace-element geochemical and Sr–Nd–Pb–Hf–Zn isotopic data for a complete series of rejuvenated-stage alkaline samples from Kauaʻi, Hawaiʻi. These samples have high MgO contents (MgO >8.6 wt%) and show a wide range of whole-rock geochemical compositions, with lower SiO2 contents, higher alkali element contents, higher CaO/Al2O3 values at a given MgO content, more depleted Sr–Nd–Hf isotopic compositions, and more radiogenic Pb isotopic compositions relative to shield tholeiites. The trace-element compositions of these samples have some similarities to carbonatites, including large ion lithophile element enrichments and K, Pb, and ZrHf depletions. These samples also have systematically higher δ66Zn values (0.34–0.43‰) than shield tholeiites from the Kauaʻi (0.27 ± 0.04‰) and Kīlauea Iki lava lake (0.26–0.30‰) and normal mantle (0.18 ± 0.05‰). Modeling the elemental and isotopic behavior of Zn indicates that the heavy Zn isotopic compositions of these samples reflect the nature of their mantle source rather than any processes associated with mantle melting and fractional crystallization. The low 87Sr/86Sr and heavy Zn isotopic compositions of these alkaline samples can be replicated by mixing depleted mantle with minor amounts of sedimentary Mg‑carbonates (<5%). A decrease in whole-rock SiO2 contents from the alkaline basalts to the melilitites in this region correlates with increases in the geochemical signature of sedimentary carbonate-bearing enriched components (e.g., high δ66Zn and low εNd and εHf values). The correlation between the δ66Zn and 206Pb/204Pb values of the samples is in concert with the role of recycled carbonates that could elevate the U/Pb ratio of mantle component caused by the carbonated melt. This implies that the studied samples formed from magmas derived from a mixed mantle source at least containing depleted peridotite and sedimentary carbonate-bearing components. The addition of recycled sedimentary carbonates may be a key factor for the high δ66Zn and 206Pb/204Pb values of the Kauaʻi rejuvenated-stage lavas. These findings suggest that the subducted sedimentary carbonates could accompany the whole circle of recycling of oceanic slab and experience a recycle deep-to-lower mantle in the Hawaiian mantle plume.

Petrogenesis of Neoproterozoic magmatic rocks in the Songnen Massif (northeastern China): Implications for basement composition and crustal growth

This paper reports new zircon U–Pb geochronological, whole-rock geochemical, and zircon Hf isotopic data for Neoproterozoic intrusive rocks in the Songnen Massif in the eastern Central Asian Orogenic Belt (CAOB), with the aim of revealing the petrogenesis of the Neoproterozoic intrusive rocks, and constraining the basement composition and crustal growth process of the Songnen Massif. Dating results identify three episodes of Neoproterozoic magmatism at ca. 950, ca. 856, and ca. 790 Ma in the eastern Songnen Massif. The ca. 950 Ma magmatic rocks consist of syenogranites, the ca. 856 Ma magmatic rocks comprise mainly gneissic monzogranites, and the ca. 790 Ma magmatic rocks consist of gneissic monzonites and monzogranites. The Neoproterozoic granitoids have high contents of SiO2 and K2O, low contents of total Fe2O3 and MgO, and show characteristics of enrichment in large-ion lithophile elements (e.g., K and Rb), and depletion in high-field-strength elements, implying that their primary magmas could have been derived from partial melting of the lower crust. However, compared with the ca. 790 Ma monzogranites [εHf(t) = +7.3 to +9.5] in the south of the Songnen Massif, the ca. 950 and ca. 856 Ma granitoids in the north have much lower zircon εHf(t) values (−2.0 to −0.2 and −10.6 to −8.9, respectively), suggesting that the ca. 950 and ca. 856 Ma magmas were generated by the reworking of ancient mafic lower crust, whereas the ca. 790 Ma granitic magma was generated by the reworking of juvenile mafic lower crust. In contrast, the ca. 790 Ma gneissic monzonites were formed by mixing of the mantle-derived and crust-derived melts. Considering the Precambrian magmatism, detrital and captured zircons, and zircon Hf model ages together, the Precambrian basement of the Songnen Massif includes not only the Neoproterozoic crustal materials, but also the Neoarchean–Mesoproterozoic components. Zircon εHf(t) values of the Neoproterozoic granitoids in the Songnen Massif appear to progressively decrease from south to north, reflecting a lateral heterogeneity of basement composition of the eastern Songnen Massif, and indicating that crustal growth occurred mainly during the late Mesoproterozoic and Neoproterozoic in the south, while during the late Paleoproterozoic in the north.

Petrology, zircon U–Pb geochronology and tectonic implications of the A1-type intrusions: Keban region, eastern Turkey

The Southeast Anatolian Orogenic Belt (SAOB), the most extensive segment of the Alpine-Himalayan Orogenic Belt, resulted from the northward subduction of the southern branch of the Neotethys oceanic crust beneath the Anatolian micro-plate. We present new whole-rock geochemistry, zircon U–Pb ages, and Lu–Hf isotope data from the stocks and dykes with a length of up to tens of meters belonging to the Keban magmatic rocks, eastern Turkey. These rocks are represented by syenite and quartz monzonite intruded into the Keban metamorphic complex. The geochemistry data indicates that the samples bear mostly metaluminous, variably high alkalines (K2O + Na2O), Ga/Al ratios and zircon saturation temperature, and typically the A-type granite characters. According to the Y/Nb vs Yb/Ta diagram, the Keban magmatic rocks show A1-type geochemical signatures modified by crustal melts. Syenite and quartz monzonite samples from Keban magmatic rocks give zircon U–Pb ages of 77.4 ± 0.34 Ma, 76.3 ± 0.3 Ma and 76.36 ± 0.34 Ma, respectively. On the primitive mantle-normalised trace element patterns, the Keban magmatic rocks show enrichment in large-ion lithophile elements (LILEs) relative to high field strength elements (HFSEs). They are coupled with slightly negative Nb–Ta anomalies. Chondrite-normalised rare earth-element patterns show strong enrichment in LREEs relative to HREEs, a typical A-type granites feature. The zircons have negative εHf(t) values that vary from −2.68 to −0.41, and Hf model ages (TDM2) range from 1171.54 to 1329.26 Ma, indicating the enriched lithospheric mantle sources and crustal contribution. The sources and evolution of the alkaline magmas might be related to the post-collisional tectonic setting.

Compositional signatures of ophiolitic rocks from the Dongco massif: Novel insights into the evolution of the central Tibetan Meso-Tethyan oceanic plateau

The role of the Meso-Tethyan oceanic plateau in the growth of the Tibetan Plateau is debated. In this paper, we report coexistence of large-scale mid-ocean ridge basalt (MORB)-like and enormous ocean island basalt (OIB)-type mafic rocks from the Dongco ophiolitic rocks of the Bangong–Nujiang Suture Zone. The MORB-like rocks host tholeiitic geochemical characterizes, and have supra-subduction zone affinity such as enrichments in large ion lithophile elements (LILEs), depletions in high field strength elements, high εNd(t) values (+6.5 to +9.5) and low initial 87Sr/86Sr ratios (0.7033–0.7050). The OIB-type rocks have an alkaline affinity and are characterized by enrichments in LILEs and light rare earth elements, strongly negative Sr anomalies, variable εNd(t) values of −3.7 to +7.3, and low initial 87Sr/86Sr ratios ranging from 0.7034 to 0.7050. Metamorphic zircons from amphibolites in the sole of the ophiolitic rocks yielded UPb ages of 104–100 Ma. Detrital zircons from the upper Cretaceous sandstone of the Abushan Formation (K2ab) yielded young UPb ages of 100–86 Ma. Considering the regional geology, we suggest that the Dongco MORB-like rocks were derived from a depleted mantle source and formed from an intra-oceanic subduction-related setting, representing remnants of normal oceanic crust, whereas the OIB-type rocks were derived from an enriched mantle source representing remnants of a Meso-Tethyan oceanic plateau. Our preferred hypothesis is that the Meso-Tethyan oceanic plateau experienced a phase of accretion at 104–100 Ma, which probably increased local subduction erosion of the upper plate and providing provenance for the deposition of the K2ab sandstone. The maximum depositional ages of K2ab sandstone constraint the minimum ages for closure of the Bangong–Nujiang Tethys Ocean most likely at 100–86 Ma.

Petrogenesis of the late Paleoproterozoic Gleibat Lafhouda dolomite carbonatite (West African Craton Margin, Moroccan Sahara) and its relevance to the onset of fragmentation of the Columbia supercontinent

The Gleibat Lafhouda dolomite carbonatites of the Moroccan Sahara occur as three separate cone-shaped plugs intruding an autochthonous succession of Archean supracrustal basement rocks. Geochemically, the Gleibat Lafhouda dolomite carbonatites are characterized by a compositional range of 11.3–27.1 wt% MgO, 3.1–29.7 wt% CaO, 3.5–38.0 wt% FeOtot and < 0.1–7.5 wt% SiO2, and enrichment in large-ion lithophile elements (LILE), particularly Sr (2173–11,310 ppm), Ba (174–4537 ppm), U (0.1–296 ppm) and light REEs (LREEs) (131–1295 ppm), but not in the heavy REE (HREEs) and high-field strength elements (HFSE) such as Ti, Zr, and Hf. Nb and Ta show, however, much higher concentrations ranging from 0.5 ppm to 1.0 wt%, and < 0.0 to 199 ppm, respectively, which set them apart from naturally occurring carbonatites and the experimentally derived carbonated melts. The combined stable (δ13CV-PDB = −2.5 to −6.6‰, δ18OV-SMOW = 6.0 to 20.7‰) and radiogenic 87Sr/86Srin (0.7032–0.7046), 143Nd/144Ndin (0.5105–0.5106) or εNd(t) (+ 3 to +6), and 206Pb/204Pb (19.06–49.05), 207Pb/204Pb (15.90–18.87), and 208Pb/204Pb (37.87–38.50) isotope compositions are consistent with low degree partial melting, at convecting upper mantle conditions, of a predominantly depleted mantle source in a rift-related environment. Based on these geochemical features, it is suggested that the Gleibat Lafhouda dolomite carbonatites represent the earliest manifestation of rifting processes related to the fragmentation of the Columbia supercontinent at 1.85 Ga. Accordingly, we propose that these carbonatitic rocks represent the initial Mg-rich melt in the mantle plume head that derived from decompressional adiabatic melting of a depleted mantle source.

The Karavansalija Mineralized Center at the Rogozna Mountains in SW Serbia: Magma Evolution and Time Relationship of Intrusive Events and Skarn Au ± Cu–Pb–Zn Mineralization

The Karavansalija Mineralized Center (KMC) with its Au–Cu skarn mineralization associated with the Rogozna Mountains magmatic suite in southwestern Serbia belongs to the Oligocene Serbo-Macedonian magmatic and metallogenic belt (SMM-MB). Samples from intrusive and volcanic rocks at the KMC show typical arc signatures of subduction-derived magmas through enrichment in large-ion lithophile elements (LILE) and depletion of high–field strength elements (HFSE). The magmas developed a high-K (calc-alkaline) fractionation trend and evolved toward shoshonitic compositions. Whole-rock trace element data suggest plagioclase-absent, high-pressure amphibole ± garnet fractionation that generates adakite-like hydrous magmas during evolution in lower crustal magma chambers. Zircon LA–ICP–MS and high-precision CA–ID–TIMS dating together with zircon trace elements and Hf isotope measurements were carried out in order to couple the geochronologic and geochemical evolution of the KMC. The results suggest that magmatism starts around 29.34 Ma with granitic to rhyodacitic subvolcanic intrusions followed by a more evolved magmatic intrusion that was emplaced into Cretaceous limestone, generating a widespread skarn alteration at ca. 28.96 Ma. After a period of quiescence of about 1.2 My, either another magma body evolved or the same upper crustal magma chamber was recharged and also likely partly reactivated older plutonic rocks as indicated by xenocrysts. The REE ratios shift from apatite, titanite ± amphibole-dominated fractionation of the older magmatic event to crystallization of allanite, efficiently depleting the LREE and Th/U in the younger upper crustal magma. After a lamproite-like melt was injected, the increased heat and fluid pressure led to the expulsion of a quartz-monzonite porphyritic stock at ca. 27.72 Ma, strongly interacting with the skarns and established a fertile hydrothermal system. Soon after a non-mineralized second pulse of some porphyry dykes cut the previous phenocryst-rich “crowded” porphyries and skarns at ca. 27.60 Ma, thus bracketing the maximum timespan of ore mineralization to about 112 ± 45 Ka. Increased contribution of a lamproite-like melt is inferred from the presence of phlogopite micro-phenocrysts, phlogopitization of biotite, and diopside clusters in the latest porphyry dykes. There is a trend of increased crustal assimilation from the oldest volcanic phase to the emplacement of the youngest porphyry dykes recorded by ɛ-Hf of the zircons. Oligocene occurrences of significant base metal mineralization within Serbia, northern Macedonia, and Greece, e.g., Crnac, Rudnik, Veliki Majdan, Stratoniu, or the Cu–Au porphyry at Buchim (northern Macedonia), are all associated with trachy-andesitic (quartz latitic) porphyry dykes, which originated through post-collisional tectonic settings or upper plate extension involving reworking of crustal arc-derived rocks and partial melting of the mantle wedge. This study demonstrates that on the basis of field relationships and the application of high-precision CA-ID-TIMS zircon age data, pulses of porphyry dykes of a 10ka age range can be distinguished, and the timing of mineralization can be parenthized.

Petrogenesis of Dacites in a Triassic Volcanic Arc in the South China Sea: Constraints From Whole Rock and Mineral Geochemistry

Triassic volcanic rocks, including basalts and dacites, were drilled from Meiji Atoll in the South China Sea (SCS), which represents a rifted slice from the active continental margin along the Cathaysia Block. In this study, we present apatite and whole rock geochemistry of Meiji dacites to decipher their petrogenesis. Apatite geochronology yielded U-Pb ages of 204–221 Ma, which are identical to zircon U-Pb ages within uncertainty and thus corroborate the formation of the Meiji volcanic rocks during the Late Triassic. Whole rock major elements suggest that Meiji dacites mainly belong to the high-K calc-alkaline series. They display enriched patterns in light rare earth elements (LREE) and flat patterns in heavy rare earth elements (HREE). They show enrichment in large-ion lithophile elements (LILE) and negative anomalies in Eu, Sr, P, Nb, Ta, and Ti. The dacites have initial 87Sr/86Sr ratios of 0.7094–0.7113, εNd(t) values of -5.9–-5.4 and εHf(t) values of -2.9–-1.7, whereas the apatite has relatively higher initial 87Sr/86Sr ratios (0.71289–0.71968) and similar εNd(t) (-8.13–-4.56) values. The dacites have homogeneous Pb isotopes, with initial 206Pb/204Pb of 18.73–18.87, 207Pb/204Pb of 15.75–15.80, and 208Pb/204Pb of 38.97–39.17. Modeling results suggest that Meiji dacites can be generated by &amp;lt;40% partial melting of amphibolites containing ∼10% garnet. Therefore, we propose that the Meiji dacites were produced by partial melting of the lower continental crust beneath the South China block, triggered by the underplating of mafic magmas as a response to Paleo-Pacific (Panthalassa) subduction during the Triassic. Meiji Atoll, together with other microblocks in the SCS, were rifted from the South China block and drifted southward due to continental extension and the opening of the SCS.

Plio-Quaternary Volcanism in Northeastern Morocco: Petrography and Geochemistry of Outcrops with High Geothermal Potential

Cenozoic volcanic activity in Morocco started in the Miocene and proceeded, after a short break, during Pliocene and Quaternary. Calc-alkaline magmatic activity occurred first and was accompanied by the eruption of transitional lavas, followed by Plio-Quaternary alkali basaltic activity, which was emplaced within Neogene sedimentary basins of the Rif belt and its foreland. From calc-alkaline to alkaline magmatism, passing through a transitional term, volcanic activities in Morocco formed magnificent outcrops, very diversified in their affinities, their mineral compositions and their geochemistry. The petrographic study and geochemistry of Plio-quaternary volcanic rocks in the areas with high geothermal potential in northeast of Morocco show a dominance of Na-rich basaltic rocks (basanites, basalts, tephrites and basaltic trachy-andesites), followed by trachy-andesites. Most of the samples exhibit an enrichment of large-ion lithophile elements (LILEs) over high-field-strength elements (HFSEs). These results were used to test the global model of Circum-Mediterranean Anorogenic Cenozoic Igneous Province (CiMACI) and the regional model of [1].