Large Enhancement Factor Research Articles

Exploring Excited State Landscapes with Surface Enhanced Hyper-Raman Spectroscopy.

In this Perspective, we provide a historical overview of the surface-enhanced hyper-Raman scattering (SEHRS) effect, describe its essential components, highlight the close connection between theory and experiment in several vignettes, and discuss recent analytical applications. SEHRS, the two-photon analog of surface-enhanced Raman scattering (SERS), is a spontaneous nonlinear scattering exhibited by molecules in a plasmonic field. Hyper Raman provides distinctive information on the molecular vibrations and electronic excited states of analytes. A 40-year old mystery surrounding the SEHRS spectra of R6G is used to illustrate the power of SEHRS to explore excited electronic states, revealing how non-Condon effects can influence the two-photon molecular properties. The exceptionally large enhancement factors (>1013) obtained from SEHRS enable the analysis of single molecules and molecules at very low concentrations. This high sensitivity is further augmented by an increased sensitivity to chemical effects, allowing SEHRS to probe changes in the local environment and the orientation of surface ligands. As most SEHRS experiments employ near-infrared (NIR) and short-wave infrared (SWIR) light, it also holds promise for bioimaging studies. Before concluding, we discuss future directions and challenges for the field as it moves forward.

Broadband and high-enhancement-factor integrated long-wave infrared sensor using the photonic crystal assisted subwavelength grating waveguide

In this paper, a broadband and high-enhancement-factor integrated long-wave infrared sensor using the photonic crystal assisted subwavelength grating waveguide is presented, optimized, and analyzed in detail. By reasonably designing the structure and optimizing the corresponding parameters, the dispersion relationship can be adjusted to realize a relatively flat band and the slow-light effect can be introduced to improve the interaction between light and matter so that large and stable slow-light enhancement factors are obtained in a wide wavelength range, achieving high-performance detection of multiple types of matter. For the optimized sensor, the operating bandwidth from 7.65142 to 7.71125 µm is realized. When C2H2, HNO3, CH4, H2O2, or N2O is treated as the target matter, the corresponding slow-light enhancement factor at 7.677 µm, 7.661 µm, 7.670 µm, 7.7 µm, or 7.705 µm is, respectively, 4.3405, 4.3432, 4.3194, 5.1584, or 5.9745; the relevant sensitivity is 0.2394Wmol−1L, 0.3466Wmol−1L, 0.3639Wmol−1L, 0.2058Wmol−1L, or 0.4791Wmol−1L; and the minimum detectable concentration is 0.6032 ppb, 0.4164 ppb, 0.3966 ppb, 0.7019 ppb, or 0.3010 ppb.

Fabrication of amino- and hydroxyl dual-functionalized magnetic microporous organic network for extraction of zearalenone from traditional Chinese medicine prior to the HPLC determination

Efficient enrichment of trace zearalenone (ZEN) from the complex traditional Chinese medicine (TCM) samples is quite difficult, but of great significance for TCM quality control. Herein, we reported a novel magnetic solid phase extraction (MSPE) strategy for ZEN enrichment using the amino- and hydroxyl dual-functionalized magnetic microporous organic network (Fe3O4@MON-NH2-OH) as an advanced adsorbent combined with the high-performance liquid chromatography (HPLC) determination. Efficient extraction of ZEN was achieved via the possible hydrogen bonding, hydrophobic, and π-π interactions between Fe3O4@MON-NH2-OH and ZEN. The adsorption capacity of Fe3O4@MON-NH2-OH for ZEN was 215.0 mg g−1 at the room temperature, which was much higher than most of the reported adsorbents. Under the optimal condition, the developed Fe3O4@MON-NH2-OH-MSPE-HPLC method exhibited wide linear range (5–2500 μg L−1), low limits of detection (1.4–35 μg L−1), less adsorbent consumption (5 mg), and large enhancement factor (95) for ZEN. The proposed method was successfully applied to detect trace ZEN from 10 kinds of real TCM samples. Conclusively, this work demonstrates the Fe3O4@MON-NH2-OH can effectively extract trace ZEN from the complex TCM matrices, which may open up a new way for the application of MONs in the enrichment and extraction of trace contaminants or active constituents from the complex TCM samples.

Cross-shaped nanoaperture nanoantennas inside plasmonic nanorings for large SERS enhancement and multiple hotspots

We have designed a novel nanostructure consisting of a cross-shaped nanoaperture nanoantenna inside plasmonic nanorings for achieving very large values of electric field enhancement, as well as large theoretical surface-enhanced Raman scattering (SERS) enhancement factor, towards the center of the nanostructure. In this work, we employed Finite-difference-time-domain (FDTD) numerical modeling to simulate the plasmonic (gold) nanostructures present on silica substrates. We found that the nanostructures being proposed by us show very high localized electric field enhancements as well as multiple hotspots in which the electric field is enhanced and localized. We observed that these hotspots have large electric field enhancements (and therefore large theoretical SERS enhancement factors) at more than one wavelength. Thus, the proposed nanostructure can be used to achieve a multiple wavelength SERS response. The electric field enhancements and the resonance wavelengths of nanostructures can be tuned in the visible and the NIR region by modifying the nanostructure dimensions like the gap between the tips in the central nanoaperture structure, height of nanostructure, and tip angle variation. It is observed that as the number of gold nanorings increase, the electric field enhancement (as well as the theoretical SERS enhancement factor) also increase due to the focusing of light towards the center of nanostructure, and after the addition of a few rings, the electric field enhancement becomes almost constant. We also studied the polarization dependence of the nanostructure by varying the angle of polarization of the incident light to check the variation of the electric field of the nanostructure, and observed that the proposed nanostructures did not have much polarization dependence. Moreover, due to the symmetric nature of the plasmonic nanostructure, the position of the hotspot region shifts to the adjacent corner on rotating the incident field polarization. We optimized all the dimensional parameters to get the best possible theoretical SERS enhancement factor of ∼ 1010. Moreover, we simulated a periodic array of these plasmonic nanostructures on the silica substrates, having equal periodicity in X and Y directions, and achieved a theoretical SERS enhancement factor of ∼ 1011.

Ultrahighly Sensitive Surface-Enhanced Raman Spectroscopy Film of Silver Nanoparticles Dispersed in Three Dimensions on a Thin Alumina Nanowire Framework.

To develop highly sensitive surface-enhanced Raman spectroscopy (SERS) films, various types of aggregated Ag nanowire (NW) and nanoparticle (NP) complex structures were fabricated using anodic aluminum oxide (AAO) templates and thermal evaporation. Aggregated AgNW structures with numerous tapered nanogaps were fabricated via Ag deposition on aggregated thin alumina nanowires of different lengths. AgNP complex structures were obtained by collapsing vertically aligned thin alumina nanowires 1 μm in length and depositing AgNPs on their tops and sides using surface tension during ethanol drying after functionalization. The Raman signal enhancement factors (EFs) of the samples were evaluated by comparing the SERS signal of the thiophenol (TP) self-assembled monolayer (SAM) on the nanostructures with the Raman signal of neat TP. EFs as high as ~2.3 × 107 were obtained for the optimized aggregated AgNW structure (NW length of 1 μm) and ~3.5 × 107 for the optimized AgNP complex structure. The large EF of the AgNP complex film is attributed mainly to the AgNPs dispersed in three dimensions on the sides of the thin alumina nanowires, strongly implying some important, relevant physics yet to be discovered and also a very promising nanostructure scheme for developing ultrahighly sensitive SERS films with EF > 108.

Contractible Plasmonic Nanospheres Array with Dynamically Tailorable Gap Size for Molecule Trapping and Sensitive SERS Detection

AbstractSurface‐enhanced Raman spectroscopy (SERS) is a powerful analysis technique, and the SERS sensitivity is strongly dependent on metallic nanogaps with a greatly enhanced local electromagnetic field (i.e., hot spots). Once the analytes are located in the hot spot region, their Raman signals are enormously amplified. However, delivering analytes into such tiny hot spots remains a great challenge, particularly for molecules with small Raman scattering cross‐sections and no metal affinity. Here, by employing the isotropic contraction characteristics of polyvinyl chloride (PVC) when heated, a molecule trapping and SERS sensing strategy is demonstrated based on a large‐area ordered gold‐coated polystyrene nanospheres (PS@Au NSs) array with well‐controlled gap size assembled on PVC sheet. Compared with the traditional contraction‐adsorption mode, the developed adsorption‐contraction mode enables efficient delivery of analytes with or without metal affinity into the hot spots between the PS@Au NSs, leading to a significantly improved SERS performance with a large SERS enhancement factor of ≈3.57 × 107. The contractible SERS substrate exhibits a high sensitivity of 10−12 m for rhodamine 6G (R6G), 10−10 m for thiram, and 5 × 10−6 m for 2,3,4‐trichlorobiphenyl, as well as good signal reproducibility with relative standard deviations of 2.81% and 4.25% for R6G and thiram, respectively.

Parity-violating trispectrum from Chern-Simons gravity

A potential source for parity violation in the Universe is inflation. The simplest inflationary models have two fields: the inflaton and graviton, and the lowest-order parity-violating coupling between them is dynamical Chern-Simons (dCS) gravity with a decay constant f. Here, we show that dCS imprints a parity-violating signal in primordial scalar perturbations. Specifically, we find that, after dCS amplifies one graviton helicity due to a tachyonic instability, the graviton-mediated correlation between two pairs of scalars develops a parity-odd component. This correlation, the primordial scalar trispectrum, is then transferred to the corresponding curvature correlator and thus is imprinted in both large-scale structure (LSS) and the cosmic microwave background (CMB). We find that the parity-odd piece has roughly the same amplitude as its parity-even counterpart, scaled linearly by the degree of gravitational circular polarization Πcirc ∼ √ε[h 2/(M Pl f)] ≤ 1, with ε the slow-roll parameter, H the inflationary Hubble scale, and the upper bound saturated for purely circularly-polarized gravitons. We also find that, in the collapsed limit, the ratio of the two trispectra contains direct information about the graviton's spin. In models beyond standard inflationary dCS, e.g. those with multiple scalar fields or superluminal scalar sound speed, there can be a large enhancement factor F ≳ 106 to the trispectrum. We find that an LSS survey that contains N modes linear modes would place an nσ constraint on Πcirc r of ∼ 0.04 (n/3)(106/F)(106/N modes)1/2 from the parity-odd galaxy trispectrum, for tensor-to-scalar ratio r. We also forecast for several spectroscopic and 21-cm surveys. This constraint implies that, for high-scale single-field inflation parameters, LSS can probe very large dCS decay constants f ≲ 4 × 109 GeV(3/n)(F/106)(N modes/106)1/2. Our result is the first example of a massless particle yielding a parity-odd scalar trispectrum through spin-exchange.

On the evaluation of field emission parameters of V2O5 and TiO2 nanostructure cathodes

The self-assembled V2O5 and TiO2 nanowires are prepared hydrothermally from vanadium (V) hydroxylamido complex and titanium oxide powder, respectively, and studied for their crystalline phase, morphology, and electron emission characteristics. V2O5 is shown to exhibit an orthorhombic phase with preferential growth of the (010) face along the [010] direction; wire size being diameter 100–400 nm, and length several micrometers. TiO2 nanowires depict a monoclinic β-phase with a typical diameter of ∼ 30 nm. Their bundles serve as potential cathodes giving electron emission following the Fowler–Nordheim (F-N) mechanism but from infinitely small areas with large field enhancement factors. In comparison, β-TiO2 provides better emission characteristics at similar operating parameters (e.g., low threshold voltage 250–400 V and current density 109−1013 A m−2). The unique properties (viz., tip geometry, roughness, and local field enhancement) of one-dimension (1D) nanowires make them prospective candidates for high-brightness electron sources and development of the display devices [1–7]. A simple procedure developed by the authors is applied successfully in actual evaluation of the field emission parameters from the current–voltage data. This involves F-N formulation with physical considerations like variation of work function, effective emission area, and field enhancement factor [31].

Branched Aluminum Nanocrystals with Internal Hot Spots: Synthesis and Single-Particle Surface-Enhanced Raman Scattering.

Owing to their unique and sustainable surface plasmonic properties, Al nanocrystals have attracted increasing attention for plasmonic-enhanced applications, including single-particle surface-enhanced Raman scattering (SERS). However, whether Al nanocrystals can achieve single-particle SERS is still unknown, mainly due to the synthetic difficulty of Al nanocrystals with internal gaps. Herein, we report a regrowth method for the synthesis of Al nanohexapods with tunable and uniform internal gaps for single-particle SERS with an enhancement factor of up to 1.79 × 108. The uniform branches of the Al nanohexapods can be systematically tuned regarding their dimensions, terminated facets, and internal gaps. The Al nanohexapods generate hot spots concentrated in the internal gaps due to the strong plasmonic coupling between the branches. A single-particle SERS measurement of Al nanohexapods shows strong Raman signals with maximum enhancement factors comparable to that of Au counterparts. The large enhancement factor indicates that Al nanohexapods are good candidates for single-particle SERS.

Large‐Area Gold‐Coated Polyamide Nanopillar Arrays Consisting of Secondary Lamellar Structures and Sub‐10‐nm Gaps for Ultrasensitive SERS Detection

AbstractLarge‐area gold‐coated polyamide 66 (PA66) nanopillar (PA66NP@Au) arrays consisting of secondary lamellar structures and sub‐10–nm gaps are fabricated for surface‐enhanced Raman spectroscopy (SERS) using ultrathin anodized aluminum oxide (AAO) template, solution‐phase growth of PA66 lamellae, and Au sputtering. Such closely packed PA66NP@Au arrays with high density of electromagnetic field enhancement (“hot spots”) on large area exhibit high SERS sensitivity for detection of rhodamine 6g (R6G) molecules with concentration down to 10−14 m and a large Raman analytical enhancement factor (AEF) of ≈1010. Furthermore, the as‐fabricated PA66NP@Au arrays provide highly sensitive Raman signals in detection of a commonly pesticide residue, carbendazim with a limit of detection (LOD) of 0.05 mg L−1 (0.05 ppm), which is lower than that of maximum residue limit of 0.2 ppm allowed in Europe Union. The as‐fabricated PA66NP@Au arrays are promising for highly sensitive and uniform SERS detection.

A tip-enhanced quantum emitter with integrated TiO2 slot waveguides in the optical regime

We study the coupling between a nanoscopic dielectric slot waveguide and a metallic-tip-enhanced dipole quantum emitter and search for optimal emission and guiding of photons along a titanium dioxide photonic waveguide. Finite element calculations are used to characterize the mode properties of the waveguide over a range of parameters and predict the efficiency of emission guidance along the waveguide. We show how the effective quantum yield is dependent on the waveguide parameters as well as the dipole position and orientation and show that the integrated system can reach a maximum quantum yield of more than 30% along each direction of the waveguide. By placing the dipole emitter near the apex of a silver nanotip situated above or inside the slot waveguide to increase the overall emission rate, we also enable the capability of controlling the emitter–waveguide​ coupling in situ. We numerically compute the excitation and radiation fields and find that despite a reduction in the quantum yield, a 35-fold increase in the overall emission rate can be obtained due to very large field enhancement factors of up to 4000 at the location of the dipole. By using alternative materials for the tip, this tip-enhanced-waveguide approach has the potential of further increasing the guided photon emission rate. With the possibility of controlling emitter–waveguide coupling in situ, this tip-enhanced emitter configuration provides an alternative approach for the realization of an efficient single-photon source.

Comparative Optical Analysis of Imprinted Nano‐, Micro‐ and Biotextures on Solar Glasses for Increased Energy Yield

In modern photovoltaic (PV) systems such as bifacial and building‐integrated PV, a big share of sunlight impinges at large incident angles on the air‐to‐glass module interface. These designs exceedingly call for effective omnidirectional antireflective (AR) measures. Texturing of PV cover glasses can effectively mitigate reflection losses in a broad spectral and angular range. Numerous individual textures have been presented in the literature; however, the lack of consistent material stacks hinders a comparative evaluation. Herein, UV‐nanoimprint lithography is used to fabricate and analyze 12 different artificial and bioreplicated textures from nano‐ to mesoscale on glass. The angle‐resolved reflectance is examined for incident angles from 5° to 80° and analyzed the scattering properties. For example, the effect of the investigated textures on the annual energy yield is calculated for a tilted bifacial PV module located in Berlin, Germany. While well‐known moth‐eye nanostructures exhibit excellent AR behavior near‐normal incidence, their shallow angle performance is often not reported. The best‐performing textures exhibit features on microscale and a large surface enhancement factor, increasing the annual energy yield up to 5% when compared to nontextured devices. The results give clear design guidelines for textured glasses of future PV applications.

Giant Out-of-Plane Exciton Emission Enhancement in Two-Dimensional Indium Selenide via a Plasmonic Nanocavity

Out-of-plane (OP) exciton-based emitters in two-dimensional semiconductor materials are attractive candidates for novel photonic applications, such as radially polarized sources, integrated photonic chips, and quantum communications. However, their low quantum efficiency resulting from forbidden transitions limits their practicality. In this work, we achieve a giant enhancement of up to 34000 for OP exciton emission in indium selenide (InSe) via a designed Ag nanocube-over-Au film plasmonic nanocavity. The large photoluminescence enhancement factor (PLEF) is attributed to the induced OP local electric field (Ez) within the nanocavity, which facilitates effective OP exciton-plasmon interaction and subsequent tremendous enhancement. Moreover, the nanoantenna effect resulting from the effective interaction improves the directivity of spontaneous radiation. Our results not only reveal an effective photoluminescence enhancement approach for OP excitons but also present an avenue for designing on-chip photonic devices with an OP dipole orientation.

Simulating the Detection of Dioxin-like Pollutants with 2D Surface-Enhanced Raman Spectroscopy Using h-BNC Substrates

The ability of 2D hybrid structures formed by boron, nitrogen and carbon atoms (h-BNCs) to act as potential substrates for the surface-enhanced Raman spectroscopy (SERS) detection of dioxin-like pollutants is theoretically analyzed. The strong confinement and high tunability of the electromagnetic response of the carbon nanostructures embedded within the h-BNC sheets point out that these hybrid structures could be promising for applications in optical spectroscopies, such as SERS. In this work, two model dioxin-like pollutants, TCDD and TCDF, and a model h-BNC surface composed of a carbon nanodisk of ninety-six atoms surrounded by a string of borazine rings, BNC96, are used to simulate the adsorption complexes and the static and pre-resonance Raman spectra of the adsorbed molecules. A high affinity of BNC96 for these pollutants is reflected by the large interaction energies obtained for the most stable stacking complexes, with dispersion being the most important contribution to their stability. The strong vibrational coupling of some active modes of TCDF and, specially, of TCDD causes the static Raman spectra to show a ”pure” chemical enhancement of one order of magnitude. On the other hand, due to the strong electromagnetic response of BNC96, confined within the carbon nanodisk, the pre-resonance Raman spectra obtained for TCDD and TCDF display large enhancement factors of 108 and 107, respectively. Promisingly, laser excitation wavelengths commonly used in SERS experiments also induce significant Raman enhancements of around 104 for the TCDD and TCDF signals. Both the strong confinement of the electromagnetic response within the carbon domains and the high modulation of the resonance wavelengths in the visible and/or UV region in h-BNCs should lead to a higher sensitivity than that of graphene and white graphene parent structures, thus overcoming one of the main disadvantages of using 2D substrates for SERS applications.

Experimental evidence of large collective enhancement of nuclear level density and its significance in radiative neutron capture

The collective enhancement of nuclear level density and its fade out with excitation in the deformed 171Yb nucleus has been inferred through an exclusive measurement of neutron spectra. The statistical model analysis of neutron spectra demonstrated a large collective enhancement factor of 40±3, a value consistent with recent microscopic model predictions but is an anomalous result compared with the measurements in the nearby deformed nuclei. The complete picture of the energy dependent collective enhancement has been obtained by combining the present results with those obtained with the Oslo method below neutron binding energy. The signature of a large collective enhancement in radiative neutron capture cross section of astrophysical interest is highlighted.

Band Alignment Enabling Effective Charge Transfer for the Highly Enhanced Raman Scattering and Fluorescence of Metal-Nanoparticle-Decorated Conjugated Polymer Nanowires.

The charge transfer (CT) process has attracted much attention due to its contribution to the improvement of spectroscopic phenomena such as Raman scattering and fluorescence. A current challenge is understanding what factors can influence CT. Here, it is demonstrated that the enhancement factor (EF) of CT (∼2000) can reach the level of electromagnetic enhancement (∼1680) when resonant CT is carried out by (Fermi level energy) band alignment between a metal nanoparticle (NP) and conjugated polymer (polypyrrole (PPy)) nanowire (NW). This band alignment results in an on- or off-resonant CT. As a proof of concept for CT based surface enhanced Raman scattering (SERS) template, the Ag NPs-decorated PPy NW is utilized to effectively enhance the Raman signal of rhodamine 6G (EF of 5.7 × 105). Hence, by means of our demonstration, it is proposed that controlling the band alignment should be considered an important parameter for obtaining a large EF of spectroscopic phenomena.

Study on explosive emission characteristics of the silicon carbide modified graphite cathodes with varied morphologies

Explosive emission cathodes are extensively used in high power microwave sources. Growing requirements are highlighted in the performance of the explosive emission cathode with the development of the high power microwave technology. In order to improve the emission properties of the graphite cathode, modifications using SiC particles or whiskers are carried out by the in situ chemical vapor reaction method. The experiments demonstrate that SiC whiskers accelerate the explosive emission turn-on speed of the graphite cathode for large field enhancement factors and improve the emission uniformity due to the surface flashover plasma generation mechanism. SiC particles increase the emission capability of the graphite cathode, possibly corresponding to the dielectric properties of SiC particles. These results suggest that the SiC whiskers modified graphite cathode is suitable for applications under low magnetic field and large emission area conditions, while the SiC particles modified graphite cathode has a brighter application prospect in the long-time stable operation.

Boosting of the terahertz absorption spectrum based on one-dimensional plastic photonic crystals.

Although terahertz (THz) spectroscopy exhibits a broad application potential in the field of fingerprint sensing and detection, there remain some limitations with the conventional sensing methods for analyzing trace analytes. In this study, a terahertz absorption spectrum boosting method based on the defect one-dimensional (1D) plastic photonic crystal (PPC) structure is proposed to improve the interaction between the terahertz wave and the trace samples. Affected by the Fabry Perot resonance, the local electric field in thin film analytes will be improved. Furthermore, the resonant frequency will be varied by changing the defect width of the 1D PPC. The structure of the uniform planar film sample is easily built and measured. The boosted terahertz absorption spectrum can be obtained by linking the resonant absorption peaks. For the 0.2 μm α-lactose films, a large absorption enhancement factor of about 105 times can be achieved, which has great potential in identifying different analytes. The study performed here gives a novel investigation direction for boosting the broad terahertz absorption spectrum of trace amounts of analytes.

CNT/Cu composite cathode: A new approach to long lifetime for explosive emission cathode

Carbon nanotube (CNT) cathodes have attracted much attention in recent years due to the advantages of large field enhancement factor and low emission threshold. However, the severe ablation under intense emission makes the lifetime short and therefore limits the application in the field such as high power microwave generation. To resolve this problem, this paper proposes to mix CNTs with metals, and a novel CNT/Cu composite cathode is manufactured. The lifetime experiments under voltage of 940 kV and repetition frequency of 20 Hz demonstrate that the lifetime of the CNT/Cu composite cathode is over 3 × 105 pulses, which is much longer than that of the normal copper cathode by at least one order of magnitude. The microscopic morphology analysis reveals that the CNT micro-protrusions and whiskers should be vital for the good emission property of the new cathode.

Numerical investigation of plasmonic bowtie nanorings with embedded nanoantennas for achieving high SEIRA enhancement factors

This paper presents the numerical investigation of several complex plasmonic nanostructures — bowtie nanoring and crossed-bowtie nanoring nanoantennas with embedded bowtie nanoantennas and crossed-bowtie nanoantennas — for surface enhanced infrared absorption (SEIRA) spectroscopy-based substrates. The proposed nanostructures exhibit substantially large SEIRA enhancement factor (∼8.1 × 105) compared to previously reported enhancement factor values for bowtie nanoantennas or nanoring antennas. The plasmonic properties of the proposed nanostructures have been studied by the numerical evaluation of the near-field electromagnetic enhancement at resonant plasmon mode excitation wavelengths in the mid-IR spectral regime. The highest SEIRA enhancement of ∼8.1 × 105 occurs at a wavelength of ∼6800 nm (6.8 μm). A substantial electric field enhancement as large as ∼375, corresponding to SEIRA EF of ∼1.4 × 105 is noted even when the minimum gaps between the plasmonic nanostructures is as large as 10 nm, which can easily be fabricated using the conventional nanolithography techniques. The occurrence of several electric field hotspots due to the presence of plasmonic nanoantennas embedded inside the nanorings was observed, as the electric fields are enhanced in the vicinity of the plasmonic nanostructures being proposed. The multiple electric field hotspots in the proposed nanostructures can lead to larger average electric field enhancement as well as the average SEIRA enhancement for these substrates. Moreover, by embedding plasmonic nanoantenna structures inside the bowtie nanorings and crossed-bowtie nanorings, large spectral tunability of plasmon resonance wavelengths is achieved in the spectral regime from 4 μm to 8 μm. This is done by varying a larger number of spectral parameters that are present in these complex nanostructures. This paper also reports a novel configuration of crossed-bowtie nanoring plasmonic structure exhibiting less polarization dependence of the SEIRA enhancement factor. This structure also exhibits tunability of hotspot positions when the direction of the polarization of the incident light is rotated. The proposed structures in this paper can be fabricated by the state-of-the-art nanofabrication technologies. The proposed structures could find potential applications in chemical and biological sensing and biochemical detection of analyte molecules.