The Korean Peninsula, characterized by low-to-moderate seismicity, faces a shortage of strong ground motion records, posing challenges for the seismic safety assessment of critical infrastructures. Given the rarity of large-magnitude earthquakes, generating a variety of earthquakes with rational values of Peak Ground Acceleration (PGA) is essential for robust seismic fragility and risk analysis. To address this, a new stochastic approach is proposed to simulate artificial earthquakes at multiple source-to-site distances and derive the probability distribution of PGA based on recorded data from a single seismic event. Two key source parameters, seismic moment and corner frequency, are treated as random variables with a negative correlation, reflecting their uncertainties and dependence on source-to-site distance. The Monte Carlo simulation with copula sampling of the key source parameters generates Fourier spectra for artificial earthquakes, which are transformed into the time domain to yield PGA distributions at various distances. A comparison with recorded data shows that the proposed method effectively simulates ground motion intensities, with no statistically significant differences between the simulated results and recorded data (p > 0.05). The present method of determining PGA distributions provides a robust framework to enhance seismic risk analysis for the safety assessment of structures.