Large Contact Area Research Articles

Abatement of Volatile Organic Compounds (VOCs) and Fluorine gases by a Microwave Plasma Torch (MPT)

The use of microwave plasma torch (MPT) in the abatement of potent greenhouse and fluorinated (F-gases) gases is crucial due to their high global warming potential. The purpose of this study was the abatement of volatile organic compounds (VOCs) and carbon tetrafluoride (CF4) using specifically designed reverse vortex flow reactor (RVR) and pillar of fire reactor (POF). The RVR has properties that are crucial for their synergistic effects with the MPT, and the POF configurations showed high-efficiency combustion due to plasma radicals and a large contact area with the MPT. The study used Aspen Plus and COMSOL software to analyse the mass balance involved in the thermal decomposition of isopropyl alcohol (C₃H₈O) and CF4 and to design the RVR and POF reactors. Using MPT without hydrocarbon fuel, low-concentration C₃H₈O and CF4 were successfully destroyed in high-flow streams. The experiment on C₃H₈O showed that using a plasma power of 2kW and 1 cubic meter per minute (CMM) of bulk gas, a destruction removal efficiency (DRE) of 95% was achieved for a polluted C₃H₈O of 410 ppm. In a second experiment, a DRE of 94% was achieved for a polluted C₃H₈O of 370 ppm. The first CF4 experiment achieved a DRE of 93.3% with a 7kW plasma power and 1 CMM bulk gas polluted at 285 ppm. In the second experiment, the presence of highly reactive hydroxyl radicals (OH⁎) in steam plasma improved the DRE to 99.8% at 7kW plasma power and 100 LPM bulk polluted at 180 ppm.

Effect of electrically aligned polycrystalline diamond flakes on the through-plane thermal conductivity of heat conduction sheets

Heat conduction sheets, which are composed of a thermally conductive filler and a base elastomer matrix, are important for dissipating heat from devices to a heat sink. Alignment of the heat-conducting two-dimensional filler particles enhances the thermal conductivity of the heat conduction sheet. In this study, we prepared polycrystalline diamond (PCD) flakes and then electrically aligned the PCD flakes in the through-plane direction of heat conduction sheet samples. The PCD flakes were fabricated by pulverizing a synthesized PCD thin layer. The typical size of the PCD flakes was ∼1 μm in thickness and ∼35 μm in diameter. The PCD flakes were electrically aligned in a polydimethylsiloxane (PDMS) matrix by applying alternating high voltage with parallel-plate electrodes. The heat conduction sheet containing 20 wt% aligned PCD flakes in the matrix exhibited high through-plane thermal conductivity of 0.47 W m−1 K−1, while that of the heat conduction sheet with aligned granular diamond filler particles was 0.37 W m−1 K−1. The high thermal conductivity comes from the formation of a large contact area between the filler particles and flake network by electrical alignment in the heat conduction sheet.

Influence of cork-rubber gasket on the circular propagation of train-induced vibration waves in high-speed railway shield tunnels

Shield tunnels are constructed by assembling segment, and this construction method will produce a large number of joints. As the component with the largest contact area in the joints of the shield tunnel, the cork-rubber gasket has a significant effect on the transmission of train-induced vibration waves between the segments. In order to study the influence of cork-rubber gasket on the transmission of train-induced vibration waves in the circumferential direction, based on the hammering test of high-speed railway shield tunnel, a dynamic calculation model for high-speed railway shield tunnel was constructed, and the influence of elasticity modulus of cork-rubber gasket on the propagation of train-induced vibration waves was investigated. The results show that: (1) the longitudinal joints of high-speed railway shield tunnels can weaken high-frequency vibration waves more than low-frequency vibration waves; (2) the lower the modulus of elasticity of cork-rubber gasket is, the greater the attenuation of the peak of the temporal range of vibration acceleration of train-induced vibration waves after they pass through the longitudinal joints; (3) compared with the cork-rubber gasket of high elasticity, the cork-rubber gasket with low elasticity can improve the damping effect of the longitudinal joints on low-frequency bands (0–500 Hz) effectively. This research offers new methodologies for optimising vibration isolation in shield tunnels and contributes to the advancement of tunnel design for high-speed rail systems.

Constructing house-of-cards-like networks with BNNS confined in interlocking Al2O3 platelet skeletons for thermally conductive epoxy composites

The construction of 3D filler networks is an effective strategy to improve the thermal conductivity of epoxy resins, yet it is still severely limited by the disconnection of conduction channels. In this contribution, an original interlocking hybrid skeleton with continuous conduction channels was developed by assembling BNNS into an in situ-formed interlocking Al2O3 platelet skeleton using commercial polyurethane as a template, where large intergranular contact areas of Al2O3 platelets were established by sintering to greatly decrease the contact thermal resistance. Besides, the interlocking Al2O3 skeleton coupled with BNNS under hydrogen bonding endowed further improvement of its thermal conductivity. The optimized Al2O3/BNNS/EP composite displayed an excellent thermal conductivity of 5.01 W/mK at 15.3 vol% of Al2O3 and 11.4 vol% of BNNS loading, far higher than that of neat epoxy resin by 1904.0 %. Meanwhile, the interlocking hybrid skeleton provided the epoxy resin with low dielectric loss, satisfactory thermal stability and flame retardancy.

Co-MOF-derived N-doped carbon nanosheet arrays on biomass carbon fiber membrane for highly sensitive detection of luteolin

Rapid and accurate determination of luteolin (LU) content is important for drug dosage control, treatment and prevention of disease. Traditional chromatographic and spectroscopic methods are gradually replaced by more sensitive and rapid electrochemical detection. 3D carbonized eggshell fiber membrane (3D CEFM) with good electrical conductivity and mechanical stability is prepared at high temperatures. To enhance the sensing performance of LU, nitrogen-doped carbon nanosheet arrays/3D CEFM (Co-NC NSAs/3D CEFM) derived from ZIF-67 nanosheet arrays (ZIF-67 NSAs) are prepared on the surface of 3D CEFM. Due to the synergistic effect, the Co-NC NSAs (thickness ∼ 1 μm, height ∼ 3 μm) provides a shorter electron transport path, while the 3D CEFM (pore size ∼5 μm) offers good electrical conductivity and a large solution contact area. Co-NC NSAs/3D CEFM electrode has a sensitivity of 1.31 μA·μM−1·cm−2 in the 0–60 μM LU and a limit of detection (LOD) of 0.04 μM (S/N = 3). Meanwhile, the electrode demonstrated recoveries of 98.0 % to 103.5 % in real samples, with a relative standard deviation (RSD) of 1.2 to 2.3 %. These results indicate that the electrode has significant potential for practical applications.

Hydrogen Bonds and In situ Photoinduced Metallic Bi0/Ni0 Accelerating Z-Scheme Charge Transfer of BiOBr@NiFe-LDH for Highly Efficient Photocatalysis.

For heterojunction system, the lack of stable interfacial driving force and definite charge transfer channel makes the charge separation and transfer efficiency unsatisfactory. The photoreaction mechanism occurring at the interface also receives less attention. Herein, a 2D/2D Z-scheme junction BiOBr@NiFe-LDH with large-area contact featured by short interface hydrogen bonds and strong interfacial electric field (IEF) is synthesized, and in situ photoinduced metallic species assisting charge transfer mechanism is demonstrated. The hydrogen bonds between O atoms from BiOBr and H atoms from NiFe-LDH induce a significant interfacial charge redistribution, establishing a robust IEF. Notably, during photocatalytic reaction, Bi0 and Ni0 are in situ performed in heterojunction, which separately act as electron transport mediator and electron trap to further accelerate charge transfer efficiency up to 71.2 %. Theoretical calculations further demonstrate that the existence of Bi0 strengthens the IEF. Therefore, high-speed spatial charge separation is realized in Bi0/BiOBr@Ni0/NiFe-LDH, leading to a prominent photocatalytic activity with a tetracycline removal ratio of 88.3 % within 7 min under visible-light irradiation and the presence of persulfate, far exceeding majority of photocatalysts reported previously. This study provides valid insights for designing hydrogen bonding heterojunction systems, and advances mechanistic understanding on in situ photoreaction at interfaces.

Effect of CeO2 on the preparation of functional ceramsite and the adsorption effect of ammonia-nitrogen wastewater treatment

This study investigates the effect of rare earth oxide CeO2 on the physical properties of ceramsite and its efficiency in treating ammonia-nitrogen wastewater. Ceramsite was prepared from solid waste with 10 % coal gangue added as a pore-forming agent. Ceramsite sample I with CeO2 and sample II without CeO2 were prepared using pure reagents. The process parameters for both samples were optimized using an orthogonal test. Additionally, the effects of CeO2 on ceramsite performance and the treatment of ammonia-nitrogen wastewater were studied, and the adsorption mechanism of CeO2 on ammonia-nitrogen wastewater was clarified. The process parameters for preparing ceramsite sample Ⅰ were: preheating for 30 min at 600 °C, followed by roasting for 20 min at 1090 °C. The parameters for preparing ceramsite sample Ⅱ were: preheating for 30 min at 600 °C, followed by roasting time for 15 min at 1090 °C. The presence of CeO2 increased the porosity of the ceramsite by 0.89 % and the specific surface area by 0.66 m2/g. Under neutral environmental conditions of water samples, CeO2 increased the removal rate of ammonia nitrogen by 1.85 %. Ceramsite has a high porosity and specific surface area, indicating that it has abundant internal pores, a large contact area with ammonia-nitrogen, a strong ability to remove ammonia nitrogen, and resistance to erosion and water flow shear, which are conducive to the treatment of ammonia-nitrogen wastewater.

Electrosurgery: heating, sparking and electrical arcs.

The translation of impedance (R), current (I), and voltage (V) into tissue effects and the understanding of the settings of electrosurgical units is not obvious if judged by the many questions during live surgery. Below 200 V, the current heats the tissue until the steam of boiling stops the current. Thus, slower heating, because of less energy or a larger contact area, results in deeper coagulation. Above 200 V and a duty cycle (per cent of time electricity is delivered) of >50% (yellow pedal), sparks become electric arcs, and the heat causes the explosion of superficial cells, i.e. cutting. With higher voltages, cutting is associated with coagulation, i.e. blended current. With even higher voltages and a duty cycle <10% preventing arching, only coagulation occurs (blue pedal; forced coagulation). Voltage being crucially important for tissue effects, newer electrosurgical units deliver a constant voltage and limit the energy output (Maximal Watts: W=I*V= joules/sec). Unfortunately, the electrosurgical units indicate the combination of voltage and duty cycles as a force of cutting (pure cutting or blended) or coagulation (soft, forced or spray) current. It is important that the surgeon understands whether electrosurgical units control voltages or output, as well as the electrical basics of the different settings and programs used.

Effects of prefabricated arch-support insole hardness on foot pressure and muscle activity in mountaineer porters during load-bearing tasks in mountainous terrain

BackgroundThe study aimed to compare the effects of medium hardness and high hardness arch-support insoles, with the latter modified by a soft forefoot pad, on foot pressure distribution and muscle activation during high-load carrying tasks in authentic mountainous trail environments. MethodsSixteen male mountaineer porters with experience in high-load carrying tasks participated in the experiments. They wore commercially available prefabricated arch-support insoles, specifically referred to as medium hardness arch-support material (MH) and high hardness arch-support material attached a 1-mm soft sponge pad to the forefoot area (HHSF) during uphill and downhill walking tasks with a 25-kg load. Foot pressure and muscle activation were measured using wireless pressure distribution insoles and a wireless surface electromyography system, respectively. ResultsThe HHSF showed significantly higher perceived comfort scores and reduced foot pressure in specific regions during downhill walking (p < 0.05). It exhibited increased peak foot pressure in the forefoot during uphill walking (p < 0.05). The MH showed greater foot pressure in the second metatarsal during downhill walking and a larger contact area in the midfoot during uphill walking (p < 0.05). Muscle activation did not differ significantly between the two insoles (p > 0.05). ConclusionThe study indicates that combining a high hardness arch-support insole with a soft forefoot pad may enhance comfort and potentially reduce foot injury risks, and improves foot propulsion and pressure distribution.

Oriented growth of NiCo metal–organic framework nanosheets on electrode materials for ternary mixed metal oxide supercapacitors

Metal–organic frameworks (MOFs) are porous structures that possess high specific surface areas, making them promising cathode materials for energy storage devices. However, solving the problems of random growth and easy aggregation of MOF nanosheets remains a challenge. In this study, hydrothermal and calcination methods were used to successfully create nickel cobalt molybdenum metal oxide (NCMO) nanoflowers, followed by the directional growth of NiCo–MOF on its surface. The oriented growth of NiCo–MOF nanosheets on NCMO nanospheres effectively prevented agglomeration, forming NCMO@NiCo–MOF with enhanced electrochemical sensitivity and a large quantity of active sites. When used as an electrode, NCMO@NiCo–MOF forms a large contact area with the electrolyte, demonstrating a high specific capacitance of 1724 F g−1 at a current density of 1 A g−1. Furthermore, at a power density of 824.8 W kg−1, an asymmetric supercapacitor constructed from NCMO@NiCo–MOF and activated carbon exhibited a high energy density of 44.5 Wh kg−1. This study presents a facile method for the assembly of MOF nanosheets for three-dimensional supercapacitors.

Simulating droplet distribution characteristics in sprinkler irrigation using a modified ballistic model under multifactor coupling

External factors affecting the processes of sprinkler irrigation water flow generation, flight, and landing have not been thoroughly considered in existing ballistic models. This result indicates that ballistic models with better prediction effects under specific conditions are not sufficient for extension to multi-factor coupled scenarios in large-scale farmlands. Therefore, wind, evaporation, surface slope, and tilted sprinkler riser factors were comprehensively considered in this study. Differential equations for jet and droplet motion under the influence of wind, differential equations of droplet evaporation, sprinkler riser deflection angle matrix, and surface slope angle matrix were constructed to establish a droplet distribution model for sprinkler irrigation considering multifactor coupling using MATLAB 2018a software. The results showed that, under different working conditions, the data points of the droplet landing diameter, velocity, and angle were distributed near the 1:1 line. The Nash efficiency coefficients (NSE) for the droplet landing diameter, velocity, and angle varied from 0.821 to 0.932, 0.616 to 0.931, and 0.770 to 0.911, respectively. The increase in slope resulted in droplets with diameters larger than 4.63 mm concentrating on the land in the reverse slope direction. When the ambient temperature increases from 10 to 45 °C and the total evaporation rate increases from 0.45 to 4.37 %, the larger droplets have a larger area of contact with the air, and the higher the temperature, the greater the energy loss to the larger droplet diameters. The higher the wind speed, the more droplets in the downwind direction fall to the ground at a smaller landing angle, which can easily increase the risk of soil shear damage. If the sprinkler riser was tilted east, the droplets on both the east and west sides tended to be distributed centrally; the maximum droplet landing velocity occurred on the east side (tilted side), and the maximum droplet landing angle occurred on the west side. This study considers various factors that may affect the motion of sprinkler irrigation water flow, extends the application scenarios of the theoretical model, and improves the applicability of the theoretical model for sprinkler irrigation droplet motion in more complex and practical agricultural environments.

Numerical Study of Tangential Traction Mechanism between Pattern Blocks of Agricultural Radial Tires and Soft Soil.

With the increasing requirements of agricultural machinery, the study of the contact relationship between the tire-soil interface and the improvement of traction efficiency has gradually become a main concern. In this study, the pattern on the agricultural tire was simplified into single-pitch pattern blocks. The pattern blocks were made of rubber material that was highly resistant to abrasion and bending. The experiment was carried out by pressing the three types of patterned block construction into the soil and the pure sliding under the soil. The simulation used the Coupled Eulerian-Lagrangian Method (CEL) to verify the experimental results. We found that the herringbone pattern block was subjected to the highest stress for the same depth of downward pressure. The horizontal force generated by the pure sliding was also the highest. The results showed that the numerically simulated and experimentally measured data exhibited similar trends and average values. In addition, the increase in the contact area between the tire and the soil reduced the compaction and sinking of the soil. The herringbone pattern structure not only had a large contact area but also produced the most significant shear force on the soil. Thus, it may generate greater traction in actual operations.

Carbon‐Based Textile‐Structured Triboelectric Nanogenerators for Smart Wearables

Recent advances in wearable electronics have been propelled by the rapid growth of microelectronics and Internet of Things. The proliferation of electronic devices and sensors relies heavily on power sources, predominantly batteries, with significant implications for the environment. To address this concern and to reduce carbon emissions, there is a growing emphasis on renewable energy harvesting technologies, among which textile‐based triboelectric nanogenerators (T‐TENGs) stand out as an innovative and sustainable solution due to having the interesting characteristics like large contact area, lightweight design, flexibility, comfort, scalability, and breathability. T‐TENGs can harness mechanical energy from human movement and convert it into electric energy. However, one of the challenges is low electric power output, which can be addressed by meticulous selection of material pairs with significant differences in work function and optimizing contact areas. The incorporation of carbon‐based nanomaterials, such as carbon nanotubes and graphene, emerges as a key strategy to enhance output. This review delineates recent progress in T‐TENGs incorporating carbonaceous nanofillers, comprehensively addressing fundamental classification, operational mode, structural design, working performance, and potential challenges that are hindering commercialization. By doing this, this review aims to stimulate future investigations into sustainable, high‐performance smart wearables integrated with T‐TENGs.

Performance analysis and optimization of an annular thermoelectric generator integrated with vapor chambers

To overcome the structural barriers of conventional annular thermoelectric generators (ATEGs), a new ATEG integrated with vapor chambers (VCs) is proposed in this paper, where the use of VCs enables a large hot-end contact area and a high temperature uniformity for traditional planar thermoelectric modules. Besides, a numerical model for the ATEG is built to conduct performance analysis and optimization under different parameters. Results suggest that the heat absorption of the ATEG increases with the increase of the number of VCs, thereby boosting the output power of the system. When the flow rate is lower than 35 g/s, the optimal number of VCs for the ATEG is 12, with the highest output power, conversion efficiency, net power, and net efficiency of 287.3 W, 5.36 %, 214.1 W, and 3.99 %, respectively, at the exhaust temperature of 800 K. Besides, the exhaust temperature does not affect the optimal result, while the ATEG should be designed with fewer VCs when applied to the waste heat recovery with a larger flow rate. The increase in the VC thermal conductivity is not related to heat absorption but can improve temperature uniformity, and the thermal conductivity of 4000 W m−1 K−1 already meets performance requirements. This study provides new perspectives on the structure design of ATEGs.

Boosted antibiotic elimination over 2D/2D mesoporous CeO2/BiOCl S-scheme photocatalyst

Exploring efficient photocatalysts holds significant importance for the prevention and treatment of antibiotic pollution. This research reports a 2D/2D CeO2/BiOCl S-scheme photocatalyst constructed by mesoporous CeO2 and BiOCl nanosheets (NSs). Efficient charge separation and transfer was achieved by the synergistic effect of large-area contact and S-scheme charge transfer mechanism, which significantly enhanced the photocatalytic performance of CeO2/BiOCl. Experimental results demonstrated that the CeO2/BiOCl photocatalyst displayed superior photocatalytic activity to the individual components, which could efficiently eliminate four types of antibiotics, namely tetracycline (TC), chlortetracycline (CTC), doxycycline (DOC), and oxytetracycline (OTC) under UV light irradiation. Particularly, the sample of 0.4CeO2/BiOCl exhibited the highest catalytic efficiency, with a TC degradation rate constant of 0.01524 min−1, which was 1.85 and 22.74 times higher than that of single CeO2 and BiOCl, respectively. Moreover, liquid chromatograph-mass spectrometer (LC-MS) analysis is employed to reveal the degradation pathways of TC. This work offers an insightful idea for the fabrication of novel S-scheme photocatalysts applied in environmental purification.

Hallux valgus treatment by percutaneous scarf-like screwless osteotomy: surgical technique and medium-term outcomes

BackgroundHallux valgus is a common condition. There is a consensus that distal metatarsal osteotomies have positive outcomes for the correction of mild-to-moderate deformities, and that proximal osteotomies are preferable for more severe ones. The well-known scarf osteotomy technique is considered powerful enough for both types of deformation and is described without internal fixation. We aimed to describe a new surgical technique for hallux valgus percutaneous scarf like osteotomy (PSLO) without internal fixation, and to report the medium-term radiological and clinical outcomes. HypothesisA combination of a PSLO without internal fixation will lead to optimal results. Patients and methodsThis retrospective case series reports on 126 cases involving 106 patients who underwent hallux valgus surgery with the PSLO technique +/− Akin, +/− lateral release. The osteotomy was stabilized by a bandage, and immediate weight bearing was allowed. The surgeries took place in 3 clinics in France from March 2016 to July 2017. ResultsAll radiological parameters: hallux valgus angle (HVA), the 1–2 intermetatarsal angle (IMA) and the distal metatarsal articular angle (DMAA) showed statistically significant improvement. The mean preoperative HVA, IMA and DMAA were 27.7 °, 14.2 ° and 12.7 ° respectively. The mean postoperative HVA, IMA and DMAA were 8.23 °, 8.1 ° and 3.8 °, respectively. Clinically, 97% were satisfied or very satisfied with the results, 92% could wear “normal” shoes (45 days - 6 months), 99% returned to the same athletic activities after surgery (3–5 months), and the average time to return to work was 4 weeks (1 day - 51 days). DiscussionThe combination of scarf -like osteotomy and the percutaneous technique provide sufficient initial stabilization through the large horizontal area of contact between the fragments and the preservation of the attachment of the soft tissue. The lack of internal fixation significantly shortens the surgery time, cost, and reduces x-ray exposure without compromising the results. Level of evidenceIII, retrospective comparative study

Effect of ferrotitanium slag particle size on properties of Al2O3–SiC–C castables

Ferrotitanium slag can be used to replace bauxite to fabricate refractories owing to its high refractoriness (>1790 °C) and Al2O3 content (≥70 wt%). However, impurities in the ferrotitanium slag is harmful to the materials. In this paper, the mechanical properties and molten slag resistance of Al2O3–SiC–C castables were improved by replacing part of bauxite with large size ferrotitanium slag (8-5 mm). The large size ferrotitanium slag contained a small amount of impurities, which reacted with SiO2 at high temperature to form CaO–Al2O3–SiO2–TiO2 liquid layer on the surface of particles. Under the action of the liquid phase, the ferrotitanium slag particles and the matrix were combined more closely. With the decrease of the particle size of ferrotitanium slag, the slag resistance of the castables began to decrease. This was because the specific surface area of the particles with smaller particle size was relatively larger, large contact area with molten slag resulted in worse slag resistance. Meanwhile, decreasing ferrotitanium slag particle size brought the increase of apparent porosity of Al2O3–SiC–C castables, resulting in weak mechanical properties.

Biomechanical evaluation of different plunger size and plunger position on removing soft contact lenses and rigid gas permeable contact lenses.

To avoid risks of mucosal infection from contact lenses removal, a contact lens plunger is often used. Given various types of contact lens plungers available on the market, no study has yet been done on mechanical effects of the contact lens plunger on contact lens removal. Here, this study used finite element analysis to investigate the effects of plunger size and plunger position on the removal of soft and rigid gas permeable (RGP) contact lenses. First, we established finite element analysis models for the plunger, contact lens, cornea, and aqueous humor. The plunger is made of mostly silicone rubber, and the contact lenses are mainly made of soft and hard material. The part of the plunger used for removal was located either at the central or the edged position, with pulling 1 mm distance. The main parameters observation indicators of in this study were the reaction force at the fixed end of the cornea, aqueous humor, the von Mises stress of the plunger, the contact lenses, and the cornea. Results of this study showed that when a plunger of a larger diameter was used, the reaction force of the plunger was also larger, especially when applied to RGP lenses, which required a slightly larger force (∼0.27 N). Also, when removing a RGP lens from the edge, there was a greater stress at the edge of the contact lens (2.5799 MPa), and this caused a higher stress on both the cornea (0.0165 MPa) and the aqueous humor (0.00114 MPa). When using a plunger with a larger diameter to remove a RGP lens, although a larger force required, the relatively larger contact area likely reduced the stress on the cornea and aqueous humor, thereby reducing the risk of eye injury. In addition, when removing a RGP lens, the results of this study recommended it to be removed from the plunger edge, as that facilitated the removal of contact lens.

Increased performance of A-DA’D-A type acceptor based organic solar cell using a thermally coevaporated cathode-modifying blend layer

The blend thin films of bathocuproine and fullerene (BCP:C60) have been thermally coevaporated to modify the active layer/cathode interfaces in organic solar cells. The BCP forms a much smaller-barrier contact with cathode than the C60. Because the surface zone of active layer is polymer donor-rich and small-molecular acceptor-deficient, C60 molecules make insufficiently large contact area with electron acceptor, leading to inefficient electron extraction. However, BCP molecules penetrate the surface of active layer, due to the smaller molecular size of BCP than that of C60, and likely form sufficiently large contact area with electron acceptor thereby to enable efficient electron extraction. Compared to conventional 10 nm BCP, 10 nm BCP:C60 (1:1 in mass ratio) enables higher efficiency based on the active layer using A-DA’D-A type acceptor, mostly because C60 constituent dissociates some excitons photogenerated in the polymer donor of surface zone and thereby increases short-circuit current density. The current research provides novel insights into the development of cathode-modifying layers for organic solar cells.

Anisotropy of Electrical and Thermal Conductivity in High-Density Graphite Foils.

Flexible graphite foils with varying thicknesses (S = 282 ± 5 μm, M = 494 ± 7 μm, L = 746 ± 8 μm) and an initial density of 0.70 g/cm3 were obtained using the nitrate method. The specific electrical and thermal conductivity of these foils were investigated. As the density increased from 0.70 g/cm3 to 1.75 g/cm3, the specific electrical conductivity increased from 69 to 192 kS/m and the thermal conductivity increased from 109 to 326 W/(m·K) due to the rolling of graphite foils. The study showed that conductivity and anisotropy depend on the shape, orientation, and contact area of thermally expanded graphite (TEG) mesoparticles (mesostructural factor), and the crystal structure of nanocrystallites (nanostructural factor). A proposed mesostructural model explained these increases, with denser foils showing elongated, narrowed TEG particles and larger contact areas, confirmed by electron microscopy results. For graphite foils 200 and 750 μm thick, increased density led to a larger coherent scattering region, likely due to the rotation of graphite mesoparticles under mechanical action, while thinner foils (<200 μm) with densities > 1.7 g/cm3 showed increased plastic deformation, indicated by a sharp reduction in the coherent scattering region size. This was also evident from the decrease in misorientation angles with increasing density. Rolling reduced nanocrystallite misorientation angles along the rolling direction compared to the transverse direction (TD) (for 1.75 g/cm3 density ΔMA = 1.2° (S), 2.6° (M), and 2.4° (L)), explaining the observed anisotropy in the electrical and mechanical properties of the rolled graphite foils. X-ray analysis confirmed the preferred nanocrystallite orientation and anisotropy coefficients (A) using Kearns parameters, which aligned well with experimental measurements (for L series foils calculated as: A0.70 = 1.05, A1.30 = 1.10, and A1.75 = 1.16). These calculated values corresponded well with the experimental measurements of specific electrical conductivity, where the anisotropy coefficient changed from 1.00 to 1.16 and mechanical properties varied from 0.98 to 1.13.