In the present work, an original method is used to determine a number of spectroscopic constants for ethanolic solutions of Rhodamine 3B, cresol violet, and oxazine-!7. Possible mechanisms of excitation-energy degradation in these dyes are discussed. The kinetics of the formation and extinction of induced absorption in the given solutions was investigated using an improved method of flash photolysis. A dye laser with lamp pumping was used as the excitation source. A high excitation energy, adequate monochromaticity, and also a comparatively large duration of the laser radiation (comparable with the inverse of the probability of intercombinational transition S~-$TI ) ensured effective population of the metastable T, level of the dyes even with a small quantum yield of particles in the triplet state. At the same time, because the exciting flux is directed and monochromatic, suppression of the scattered radiation in the recording system could readily be eliminated. In addition, selective excitation in the basic absorption band of the dye led to a minimum of undesirable photochemical conversions in the solution. To obtain information on the probabilities of triplet-level deactivation, it is necessary to measure the extinction kinetics of TI§ absorption with fast switching-off of the pumping. Thus, effective population of the TI state requires excitation of the given solution by light pulses of sufficiently long duration (microseconds), while investigation of the deactivation kinetics of the metastable level requires a sharp cutoff of the pumping pulse, i.e., a much shorter trailing edge. The trailing edge was abbreviated using a fastacting electrooptical valve based on a Pockels cell, positioned outside the laser resonator. As a result, for a total excitation-pulse length of (1-4)'10 -6 sec, the duration of the trailing edge was no more than 5'10 -8 sec. The spectral width of the pumping radiation was ~15 nm; variation of the wavelength in the range 460-700 nm was possible; in this spectral range, the output energy of the laser varied from 0.4 to 1.5 Ja Change in transmission of the dye solution after the cessation of the excitation pulse
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