Abstract The influence of anode distance from hollow cathode on the blackening∗ of spectral lines excited by means of the modified Grimm's lamp was investigated for three representative cathodic materials, i.e. aluminium, copper and graphite using argon as the carrier gas. On the basis of the experimental results as well as voltage-current characteristic curves at distances of 7, 15, 20, 25 and 33 mm, it was possible to conclude that the optimal sets of discharge parameters for all the materials investigated are based on an electrode distance of 20-25 mm. In the case of copper a distance of 33 mm was also found to be highly suitable. An increase in the emission of copper lines at the largest anodic length with increasing pressure of the noble gas was also observed, in contrast with the behavior of the same element at shorter distances. A tentative interpretation of the phenomenon is given.