Abstract CO2 injection is a prominent measurement to enhance the recovery of shale reservoirs. The imbibition of fracturing fluid + CO2 additive is considered important for promoting the enhancement and stabilization of shale oil production to ensure energy supply. The imbibition experiments of fracturing fluid + CO2 additive were carried out in shale reservoirs with a nuclear magnetic resonance (NMR) test. The imbibition displacement characteristics at different pore scales of shale were quantitatively evaluated. The variability of the imbibition effects in shale reservoirs was clarified in terms of shale type, fracturing fluid type, and CO2 additive (pressure). This finding indicates that the effectiveness of the fracturing fluid + CO2 additive imbibition on shale reservoirs is stronger, and the imbibition displacement efficiency ranges from 33.38 % to 41.56 %. The imbibition contribution rate is considerably higher for small pores than for large pores, and the difference between them is more than 10%. Therefore, the imbibition of fracturing fluid + CO2 additive mainly extracted crude oil from the small pores of shale reservoirs. CNI nano variable-viscous slippery water is more effective for imbibition displacement in laminar type shale. For laminated type shale, EM30+ + guanidine gum mixed water has a better imbibition effect than CNI nano variable-viscous slippery water. Under 16 MPa CO2 + fracturing fluid (miscible states), the imbibition displacement efficiency of the shale is significantly enhanced. The imbibition displacement degree at different pore scales is also increased. For different types of shale reservoirs, the imbibition displacement degree at different pore scales would be improved by methods, including the optimization of the fracturing fluid or the change of imbibition conditions. This study presents a theoretical underpinning for the high-efficiency exploitation in shale reservoirs.
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