Characteristics Of Lamina Research Articles

Laminae Characteristics and Their Relationship with Mudstone Reservoir Quality in the Qingshankou Formation, Sanzhao Depression, Songliao Basin, Northeast China

Lamination is the predominant and widely developed sedimentary structure in mudstones. Similar to organic pores in shale gas reservoirs, the inorganic pores in the laminae of shale oil reservoirs are equivalently important high-quality reservoir spaces and flow channels. The laminae characteristics are strongly heterogeneous, being controlled by both deposition and diagenesis. However, the origin of this diversity is poorly understood. A detailed examination of cores, thin sections, and scanning electron microscopy analyses were conducted on the lacustrine mudstone of the Qingshankou Formation in the Songliao Basin to study the influence of deposition and diagenesis on laminae characteristics and their relationship to reservoir quality. Three types of laminae are mainly developed, namely thick siliceous laminae, thin siliceous laminae, and thin siliceous and argillaceous mixed laminae. Deposition controls the type and distribution of laminae. The thin siliceous and argillaceous mixed laminae are controlled by climate-driven seasonal flux variations. The thick siliceous laminae and thin siliceous laminae are controlled by bottom current or gravity-driven transport processes due to increased terrestrial input. The thin siliceous laminae have the optimum reservoir properties, followed by the thin siliceous and argillaceous mixed laminae, while the thick siliceous laminae have the worst properties. Diagenesis controls the pore evolution of the laminae. Different laminae have different paths of diagenesis. The thin siliceous laminae are mainly cemented by chlorite, preserving some primary porosity. The clay mineral content of the thin siliceous and argillaceous mixed laminae is high, and the primary pores are mainly destroyed by the strong deformation of the clay minerals during compaction. The thick siliceous laminae are intensely cemented by calcite, losing most of the porosity. The present study enhances the understanding of reservoir characteristics in laminae and provides a reference for shale oil exploration.

Structural characteristics of continental carbonate-rich shale and shale oil movability: A case study of the Paleogene Shahejie Formation shale in Jiyang Depression, Bohai Bay Basin, China

Based on rock mineral and geochemical analysis, microscopic observation, physical property measurement, and thin laminae separation test, etc., the characteristics of typical laminae of the Paleogene Shahejie Formation carbonate-rich shale in the Jiyang Depression were analyzed, and the organic matter abundance, reservoir properties, and oil-bearing properties of different laminae were compared. Typical shale storage-seepage structures were classified, and the mobility of oil in different types of shale storage-seepage structure was compared. The results show that the repeated superposition of mud laminae and calcite laminae are the main layer structure of carbonate-rich shales. The calcite laminae are divided into micritic calcite laminae, sparry calcite laminae and fibrous calcite vein. The mud-rich laminae are the main contributor to the organic matter abundance and porosity of shale, with the best hydrocarbon generation potential, reservoir capacity, and oil-bearing property. The micritic calcite laminae also have relatively good hydrocarbon generation potential, reservoir capacity and oil-bearing property. The sparry calcite laminae and fibrous calcite vein have good permeability and conductivity. Four types of shale storage-seepage structure are developed in the carbonate-rich shale, and the mobility of oil in each type of storage-seepage structure is in descending order: sparry calcite laminae enriched shale storage-seepage structure, mixed calcite laminae enriched shale storage-seepage structure, fibrous calcite vein enriched shale storage-seepage structure, and micritic calcite laminae enriched shale storage-seepage structure. The exploration targets of carbonate-rich shale in the Jiyang Depression Shahejie Formation are different in terms of storage-seepage structure at different thermal evolution stages.

Identification of Shale Lithofacies from FMI Images and ECS Logs Using Machine Learning with GLCM Features

The identification of sedimentary structures in lithofacies is of great significance to the exploration and development of Paleogene shale in the Boxing Sag. However, due to the scale mismatch between the thickness of laminae and the vertical resolution of conventional wireline logs, the conventional lithofacies division method fails to realize the accurate classification of sedimentary structures and cannot meet the needs of reservoir research. Therefore, it is necessary to establish a lithofacies identification method with higher precision from advanced logs. In this paper, a method integrating the gray level co-occurrence matrix (GLCM) and random forest (RF) algorithms is proposed to classify shale lithofacies with different sedimentary structures based on formation micro-imager (FMI) imaging logging and elemental capture spectroscopy (ECS) logging. According to the characteristics of shale laminae on FMI images, GLCM, an image texture extraction tool, is utilized to obtain texture features reflecting sedimentary structures from FMI images. It is proven that GLCM can depict shale sedimentary structures efficiently and accurately, and four texture features (contrast, entropy, energy, and homogeneity) are sensitive to shale sedimentary structures. To accommodate the correlation between the four texture features, the random forest algorithm, which has been proven not to be affected by correlated input features, is selected for supervised lithofacies classification. To enhance the model’s ability to differentiate between argillaceous limestone and calcareous mudstone, the carbonate content and clay content calculated from the ECS logs are involved in the input features. Moreover, grid search cross-validation (CV) is implemented to optimize the hyperparameters of the model. The optimized model achieves favorable performance on training data, validation data, and test data, with average accuracies of 0.84, 0.79, and 0.76, respectively. This study also discusses the application of the classification model in lithofacies and production prediction.

Characteristics and Effects of Laminae on a Cretaceous Reservoir in the Bozi–Dabei Area of the Tarim Basin, China

Reservoir heterogeneity is an important factor in oil and gas exploration and development. It has guiding significance for favourable target optimization because it helps clarify the formation and development characteristics of laminae: thin, alternating layers of sediment deposited in a repeating pattern in Cretaceous sandstone reservoirs. Reservoir heterogeneity is higher when laminae are densely distributed. For example, laminae have a significant influence on reservoir properties in the Kelasu structural belt in the Bozi–Dabei area, Tarim Basin, China, where oil and gas wells have very low productivity. Hence, this study attempts to develop a classification scheme based on laminae to identify how they influence reservoir properties. Based on an analysis of cores, thin section and logging imaging data, laminae in this area can be classified into three types: magnetite-enriched, iron-stained argillaceous-enriched, and grain-size change. Results show that magnetite-enriched and iron-stained argillaceous-enriched laminae are well-developed in the BZ1 and DB10 well areas in northern Bozi. They have much lower porosity compared to a non-laminae reservoir and their lateral permeability is greater than vertical permeability. Grain-size change laminae are well-developed in the southern Bozi region. For the laminated reservoirs, increasing the length of the perforation interval and the perforation density using sand or acid fracturing is an effective method for communicating with the vertical reservoir layers, improving permeability, and increasing single-well production.

Mechanism study of tobacco pyrolysis based on the analysis of characteristic products and in-situ identification of functional groups evolution on pyrolytic char

To master the fundamental knowledge of the tobacco thermal degradation process is of great significance for the utilization of tobacco waste. Thermogravimetric analysis coupled with Fourier transform infrared spectrometer was used to analyze the thermal degradation of tobacco lamina and the release behavior of small molecular gas products. Based on the composition and component characteristics of tobacco lamina, the process was divided into four stages to elucidate its thermal degradation mechanism. Tobacco lamina pyrolysis at 200–800 °C was carried out on a microreactor with the products analyzed by gas chromatography-mass spectrometry. On the basis of obtaining variation rule of products belonging to different families of organic compounds with temperature, the evolution properties of products within the same family were summarized. Thereinto, the compositions of nitrogen-containing heterocyclic compounds and hydrocarbons were most affected by temperature. The in-situ infrared of the solid residue during tobacco lamina pyrolysis and the corresponding two-dimensional perturbation correlation infrared spectroscopy were performed to reveal the evolution of functional groups on the surface of the pyrolytic char. The results showed that the dehydration and ring-opening reaction of polysaccharides were earlier than the decomposition of carbonyl containing compounds.

Laminae characteristics of lacustrine shales from the Paleogene Kongdian Formation in the Cangdong Sag, Bohai Bay Basin, China: Why do laminated shales have better reservoir physical properties?

Laminae are the most typical and representive sedimentary feature in organic-rich shales, and revealing their influences on the reservoir physical properties is vital to understand the oil enrichment mechanisms of lacustrine shale. This study investigated the laminae characteristics and their effects on the physical properties of the shales from the Second Member of the Kongdian Formation (Ek2). The research presented in this study is based on core and thin section observations, XRD analysis, low-pressure nitrogen physisorption (LNP), high-pressure mercury intrusion porosimetry (MIP), nuclear magnetic resonance (NMR), and scanning electron microscopy (SEM). The results show that the Ek2 shales developed massive and laminated sedimentary structures. The laminae can be categorized as siliceous laminae, dolomite laminae, clay-rich siliceous laminae, organic matter laminae, and calcite laminae. Analysis of SEM, LNP, MIP, and NMR show that macropores and micro-fractures contribute significantly to the total pore volume of laminated samples, while micropores and mesopores are the dominant pore types in massive samples. The pore structure and connectivity of the laminated samples are better than that of the massive samples. Comparison of laminar and massive mudstones in the Ek2 showed that the development of laminae physical properties that are more conducive for reservoir formation as a result of interlaminated fractures, optimized arrangement of minerals, and improved organic-inorganic interactions.

The Impact of Lamina Characteristics and Types on Organic Matter Enrichment of Chang 73 Submember in Ordos Basin, NW China

The Chang 7 member in Ordos Basin is an important shale oil exploration layer, with new shale-oil discoveries in recent years. The Chang 73 submember is rich in organic shale, which is the main source rock of shale oil in the Yanchang Formation. In order to clarify the lamina structure, composition, types, and distribution characteristics in Chang 73 submember and its influence on organic matter enrichment, a full coring well in Chang 73 submember located in deep-lacustrine facies is selected to obtain intensive systematic core samples. Core observation, thin section identification, X-ray fluorescence element analysis, X-diffraction analysis, scanning electron microscope, electron probe, rock pyrolysis, and other techniques are performed to systematically analyze the morphology, structure, thickness, mineral compositions, and organic matter content of the shale lamina in the Chang 73 submember. Five types of lamina are identified: silty felsic lamina (SF), tuffaceous lamina (TF), organic-rich clay lamina (ORC), organic-bearing clay lamina (OBC), and homogeneous clay lamina (HC), which are further subdivided into eight subtypes. The lamina types change greatly vertically in the Chang 73 submember, in which the lower part is mainly silty felsic lamina, organic-rich clay, and tuffaceous lamina, the middle part is mainly organic rich and organic clay lamina and organic-bearing clay lamina, and the upper part is mainly homogeneous clay lamina and a small amount of silty felsic organic-bearing clay lamina and organic-bearing clay lamina. Different laminae show various organic matter types, organic matter content (TOC), and organic matter occurrence states which can be divided into four occurrence types. The TOC in organic-rich clay lamina and part of homogeneous clay lamina is high, while that of silty felsic lamina is lower. The relationship between shale lamina and organic matter enrichment is established according to the correlation analysis of laminar characteristics, mineral content, and organic matter content. Among them, the organic-rich lamina is richest of TOC and is a favorable “sweet point” for shale oil exploration.

Characteristics of Lithofacies Combinations and Reservoir Property of Carbonate-Rich Shale in Dongying Depression, Eastern China

Drilling has demonstrated that oil can be produced from the lacustrine shale in the upper part of the fourth member of the Shahejie Formation (Es4s) in Dongying Depression. These wells are often drilled in multiple lithofacies combinations, rather than a single lithofacies. Thus, it is necessary to classify the shale lithofacies combinations to optimize favorable exploration targets. The basic characteristics of carbonate mineral-rich shales in the Es4s were determined by core description, optical microscopy of thin sections, mineral analysis by X-ray diffraction, and scanning electron microscope analysis of argon ion-polished samples, combined with organic geochemical analysis and reservoir property analysis. The depositional setting was determined, and the lithofacies combinations of the shale were divided based on the depositional setting and vertical changes in lithofacies combination. Lithofacies combinations include 1) laminated argillaceous limestone interbedded with the calcareous mudstone (LLM); 2) laminated argillaceous limestone interbedded with dolomite (LLD); and 3) calcareous mudstone intercalated with argillaceous limestone (BML). LLM formed in a semi-humid climate, with limited detrital provenance, while LLD was mainly the product of an arid climate, little detrital input, semi-deep water, and a strongly reducing saltwater environment. In addition to the basal strata in the center of the depression, the LLD lithofacies combination was also widely developed on the gentle slope and the slope area transitional to deep depression in the south of the basin. BML was mainly formed in a semi-humid climate, brackish, deep water, and a reducing environment with many detrital provenances. The porosity in LLM and LLD consists of various types. Intercrystalline pores in clay minerals, intercrystalline pores and dissolution pores in carbonate minerals, interbedded fractures, and ultra-pressure fractures are well developed. The pore width distribution range of both LLM and LLD is large. The porosity of LLM is slightly higher than that of LLD. Interlayers with higher dolomite content have higher permeability. The types of pores in BML with no significant laminae characteristics are less abundant, and it is difficult to form an effective reservoir porosity network from the pores and microfractures, and hence, the reservoir physical properties are relatively poor. Oil saturation index indicates that both LLD and LLM of medium–low degree of evolution have good oil content.

The Influence of Lamina Density and Occurrence on the Permeability of Lamellar Shale after Hydration

The characteristics of laminae in lamellar shale oil reservoirs have important influences on reservoir parameters, especially permeability. In order to explore the influence of lamina density and occurrence on the permeability of lamellar shale after hydration, we studied the lamellar shale in the Chang 7 member of the Yanchang Formation of Triassic in Ordos Basin. By comparing the permeability of bedding shale and lamellar shale with different densities of laminae, it was found that the permeability anisotropy of lamellar shale was stronger. In the direction parallel to the lamina, the permeability increased approximately linearly with an increase in lamina density. The effect of hydration on rock micropore structure and permeability was studied by soaking shale in different fluids. Most of the microfracture in the lamellar shale was parallel to the lamina direction, and hydration led to a widening of the microfracture, which led to the most obvious increase in permeability parallel to the lamina. Collectively, the research results proved that lamina density, occurrence, and hydration have a significant influence on the permeability anisotropy of lamellar shale.

Lamination Texture and Its Effects on Reservoir and Geochemical Properties of the Palaeogene Kongdian Formation in the Cangdong Sag, Bohai Bay Basin, China

The characteristics of laminae are critical to lacustrine shale strata. They are the keys to the quality of source rocks and reservoirs, as well as engineering operations in shale plays. This study uses organic geochemistry, thin section identification, X-ray diffraction, field emission scanning electron microscopy, and other analytical methods, to reveal the detailed lamination texture and vertical distribution of laminae in the second Member of the Kongdian Formation in Cangdong Sag. The principal results are as follows: (1) A classification of laminae is proposed to characterize reservoir and geochemical properties. The five types of laminae are as follows: feldspar-quartz laminae (FQL), clay laminae (CLL), carbonate laminae (CAL), organic matter laminae (OML), and bioclastic laminae (BCL). There are also four significant lamina combinations (with the increasing TOC values): FQL-CLL combination, FQL-CLL-BCL combination, FQL-CLL-OML combination, and FQL-CAL-CLL-OML combination; (2) differences between laminae occur because of the variability in pore types and structures. There appears to be a greater abundance of intercrystalline pores of clay minerals in the FQL, CAL, BCL, and OML, and well-developed organic pores in the CAL and CLL, and the counterparts of intragranular pores of bioclastic material in the BCL. This detailed characterization provides the following comparative quantification of the thin section porosity of laminae in the second Member of the Kongdian Formation can be differentiated: CAL > FQL > OML > BCL > CLL; (3) differentiation between vertical distributions of laminae is carried out in a single well. The FQL and CLL are widely distributed in all the samples, while the BCL is concentrated in the upper part of the second Member of the Kongdian Formation, and CAL is concentrated in the lower part. This detailed classification method, using geochemical analysis and vertical distribution descriptions, offers a detailed understanding of lamination texture and its effects on reservoir and geochemical properties, which will provide a scientific guidance and technical support to better estimate reservoir quality and to identify new sweet spots in the second Member of the Kongdian Formation in the Cangdong Sag.

PRIMER REGISTRO DE DENNSTAEDTIA DISSECTA (DENNSTAEDTIACEAE) PARA LA FLORA ARGENTINA

Dennstaedtia dissecta is recorded for the first time for the Argentinean flora in the Misiones Province. This new record was discovered during the study of herbarium specimens from BA and LP, and then corroborated with field collections from Cruce Caballero Provincial Park and Urugua-i Provincial Park. In addition to the characteristics of rhizome and lamina, the spores were an important information source for the identification of this species. The diagnostic characters are described and illustrated, including a key to identify the species of Dennstaedtia from Misiones.

Variability of morphometric characteristics of Betula pendula lamina under technogenic conditions of Dnipro city

The response of a plant organism to the effects of negative environmental factors, including the effects of multicomponent pollution, can be determined using a morphometric approach, setting the range of variability of biometric indicators of assimilation organs. The obtained data allow us to identify the directions of evolution of leaf shape and parameters under conditions of anthropogenic environment. The purpose of this work is to evaluate the variability of morphometric characteristics of lamina of Вetula pendula Roth. under technogenic conditions of the city of Dnipro. Leaf samples were collected in September – October 2018 at five test areas in the city of Dnipro (100 sheets each), which differed in the level of environmental pollution. For each leaf according to the method, five dimensions were measured on the left and right sides: width of the left and right halves of the leaf; the length of the vein of the second order, the second from the base of the leaf; the distance between the bases of the first and second veins of the second order; the distance between the ends of the first and second veins of the second order; the angle between the main vein and the second vein from the base of the leaf of the second order. It is shown that by the degree of increase of variation in the conditions of influence on the plants of B. pendula under conditions of multicomponent contamination of the environment the investigated signs of the lamina can be arranged as follows: 5 < 2 < 1 < 4 < 3. It is established that the most stable feature of the B. pendula lamina in the conditions of technogenesis is the angle between the main vein and the second vein from the base of the leaf of the second order, and the most variable one is the distance between the bases of the first and second veins of the second order. A tendency was found for the differences in the reactions of plants from the relatively clean area and contaminated territories: the control trees had a coefficient of variation higher for the right half of the leaf (right-sided asymmetry), whereas plants of the technogenic zones had left-sided asymmetry.

Laminae characteristics and influence on shale gas reservoir quality of lower Silurian Longmaxi Formation in the Jiaoshiba area of the Sichuan Basin, China

Abstract Widely developed in shale strata, laminae are the most typical shale sedimentary structure. To investigate their influence on shale gas reservoir quality, we conducted complementary studies by integrating microscopic observations, geochemical analyses, field-emission scanning electron microscopy (FE-SEM) imaging, and mercury intrusion capillary pressure (MICP) techniques. The microscopic observation of thin sections enabled us to detect the laminae characteristics, including the density and maximum thickness of individual lamina, and three types and stages of lamina development were identified. The total organic carbon (TOC) content, mineral composition, natural fracture, pore type, pore size distribution, porosity, permeability, and tortuosity were investigated in these different laminae types using FE-SEM, MICP and geochemical analysis. Combining the laminae characteristics and pore structure, we concluded that the organic pores and total pore area are mainly affected by the TOC content, whereas the development of the laminae controls the inorganic macropore scale and affects the pore size distribution. In addition, we found that the excessive development of shale laminae is not conducive to organic matter accumulation because of the change in redox condition, and because it has an adverse impact on the formation of complex artificial fractures during hydraulic fracturing.

Laboratory Investigation of the Effect of Injection Rate on Hydraulic Fracturing Performance in Artificial Transversely Laminated Rock Using 3D Laser Scanning

Among many factors that affect the hydraulic fracturing responses, the injection rate is identified as the first critical factor to be considered by many researchers. However, the internal mechanism of injection rate on the morphology of fracturing surface and gas productivity are still not well understood. In scaled laboratory experiments, artificial interlayered model blocks were produced, according to the development characteristics of silty laminae in continental shale, China, to investigate the effect of injection rate on hydraulic fracturing effectiveness. Macroscopic failure morphology descriptions combined with mesoscopic 3-D laser scanning techniques are both used to reveal the internal influence mechanism of injection rate. Results show that hydraulic fracturing effectiveness improves with the increase of injection rate, by enhancing the total contact area of fracture system, and increasing micro-fractures in the fracture surface. The experimental result first reveals the influential mechanism of injection rate on hydraulic fracturing performance.

Lamina characteristics of gas-bearing shale fine-grained sediment of the Silurian Longmaxi Formation of Well Wuxi 2 in Sichuan Basin, SW China

Abstract Based on various test data, the composition, texture, structure and lamina types of gas-bearing shale were determined based on Well Wuxi 2 of the Silurian Longmaxi Formation in the Sichuan Basin. Four types of lamina, namely organic-rich lamina, organic-bearing lamina, clay lamina and silty lamina, are developed in the Longmaxi Formation of Well Wuxi 2, and they form 2 kinds of lamina set and 5 kinds of beds. Because of increasing supply of terrigenous clasts and enhancing hydrodynamics and associated oxygen levels, the contents of TOC and brittle mineral reduce and content of clay mineral increases gradually as the depth becomes shallow. Organic-rich lamina, organic-rich + organic-bearing lamina set and organic-rich bed dominate the small layers 1-3 of Member 1 of the Longmaxi Formation, suggesting anoxic and weak hydraulic depositional setting. Organic-rich lamina, along with organic-bearing lamina and silty lamina, appear in small layer 4, suggesting increased oxygenated and hydraulic level. Small layers 1-3 are the best interval and drilling target of shale gas exploration and development.

Functional Characterization of Lamina X Neurons in ex-Vivo Spinal Cord Preparation.

Functional properties of lamina X neurons in the spinal cord remain unknown despite the established role of this area for somatosensory integration, visceral nociception, autonomic regulation and motoneuron output modulation. Investigations of neuronal functioning in the lamina X have been hampered by technical challenges. Here we introduce an ex-vivo spinal cord preparation with both dorsal and ventral roots still attached for functional studies of the lamina X neurons and their connectivity using an oblique LED illumination for resolved visualization of lamina X neurons in a thick tissue. With the elaborated approach, we demonstrate electrophysiological characteristics of lamina X neurons by their membrane properties, firing pattern discharge and fiber innervation (either afferent or efferent). The tissue preparation has been also probed using Ca2+ imaging with fluorescent Ca2+ dyes (membrane-impermeable or -permeable) to demonstrate the depolarization-induced changes in intracellular calcium concentration in lamina X neurons. Finally, we performed visualization of subpopulations of lamina X neurons stained by retrograde labeling with aminostilbamidine dye to identify sympathetic preganglionic and projection neurons in the lamina X. Thus, the elaborated approach provides a reliable tool for investigation of functional properties and connectivity in specific neuronal subpopulations, boosting research of lamina X of the spinal cord.

Predicting Lamina Yield from Logs of Different Diameters for Cross Laminated Timber Production

The goal of this study was to predict lamina yield from logs of different diameter for production of cross laminated timber. Log characteristics of red pine (Pinus densiflora) and Japanese cedar (Pryptomeria japonica), including diameter, length, volume, and defects were used for statistical and geometrical analyses, along with the lamina characteristics, including width, thickness, and defects. Based on the data obtained, the strong factors influencing the yield and grade of lamina from the two species were statistically evaluated. A geometrical ap proach was used for analysis of the yield from logs of given diameters. Statistical analysis showed that lamina yield was dependent on target lamina size but the grade of lamina was not related to any of the log characteristics. The suggested yield equations from the geometrical approach indicated an accuracy of less than 20% difference.

Method to Estimate Mechanical Properties of Glulam on Flexure Testing Based on Its Laminae Characteristics and Position

Glulam strength is affected by its laminae characteristics and position. Modulus of Elasticity and Modulus of Rupture of layer system (including glulam) is usually estimated by Transformed cross section (TCS) method recently. But, TCS does not follow the principal due to its contrary assumption related with the reduction of material’s plane area for laminae with lower E value and the extension of its plane area for laminae with higher E value. In fact the material properties are independent from its shape and size. Therefore, new calculation method is required. As the relevance, this paper discusses the formulation of a new method to determine the E and SR for glulam based on its laminae properties and position. E and SR calculated by TCS and new method give identical values. The new method confirms the independence of E and SR which could not be fulfilled by TCS. According to this fact, TCS could be replaced by new method. The theoretical E value was higher than its coresponding empirical value, but it has high correlation (R2=68.53%). On the contrary, the theoretical SR value was not significantly different from its coresponding empirical values, but they have poor correlation (R2=27.93%). This condition happened because of finger joint effect on the compression and tension side of the sample. Incorporating the finger joint effect into regression analysis, the equation provides very good prediction. The coefficients of determination were 99.58% and 97.19%, for E and SR respectively.

Size dependence of ozone lamina characteristics and their correlations

Ozone profiles contain narrow layers of substantially enhanced or reduced ozone, called positive and negative laminae, respectively. They reflect both evolutions of stratospheric ozone content and stratospheric dynamics. Here we deal only with positive laminae. The following lamina characteristics are investigated in dependence on lamina size: the number of laminae per profile, the overall ozone amount in laminae per profile and the ozone amount in one lamina at the European ozonosonde stations. An important role of the vertical resolution of ozonesonde measurements is specified. Lamina characteristics for Legionowo and Lindenberg, and small lamina (<2mPa) characteristics for all stations suffer with effects of vertical resolution of measurements. For this reason they are not used here for long-term trend investigations. The long-term evolution of the ozone amount in one lamina does not display a trend. The results for the three remaining stations, Hohenpeissenberg, Payerne and Uccle, are largely consistent with our previous results on lamina behaviour, which means that our previous results on trends in laminae (e.g., Križan and Laštovička, 2005; Laštovička et al., 2014) are basically correct. The number of laminae per profile and the overall ozone amount in laminae per profile show negative trends before (1979–1995) and rather positive trends after (1996–2011) the reversal of trends in total columnar ozone over Europe. Both parameters reach the highest values for small laminae and with increasing size they decrease. Correlations between characteristics of laminae of different size ranges at individual stations are better for neighbour lamina ranges than for distant lamina ranges. The number of statistically significant correlations of laminae of the same size between pairs of stations is much higher for large laminae above 4mPa, probably due to processes responsible for their formation and their expected larger horizontal size.

Characteristics of silty laminae in Zhangjiatan Shale of southeastern Ordos Basin, China: Implications for shale gas formation

Shale oil and gas have been discovered in the lacustrine organic-rich Zhangjiatan Shale of the Upper Triassic Yanchang Formation, Ordos Basin, China. Core observations indicate abundant silty laminae in the producing shales. This study documents the stratigraphic distribution of silty laminae and their relationship with interlaminated clay laminae. The type, structure, and characteristics of pores and mineral composition of silty laminae were observed and analyzed through thin section and scanning electron microscopy, X-ray diffraction, low-pressure ![Formula][1] and ![Formula][2] adsorption, mercury porosimetry, and helium pycnometry. Results from silty laminae are compared with those of clayey laminae. The frequency and thickness of silty laminae vary over a wide range. The thickness ranges from 0.2 to 4 mm and is 1.5 mm on average; the frequency ranges from 4 to 32 laminae/m and is 23 laminae/m on average. The thickness percentage of silty laminae in the measured segments ranges from 6% to 17%. Silty laminae consist of quartz, feldspar, mixed-layer montmorillonite, and chlorite. In comparison to clayey laminae, non-clay detrital grains are larger, quartz and feldspar are more common, and clay minerals are less abundant. Pores in silty laminae are primary interparticle, dissolutional, intercrystalline, and microfracture types. Mesopores (2–50 nm in diameter) and macropores (50 nm–1 μm) are common, whereas, micropores ![Formula][3] are rare; the distribution of pore diameters is multimodal. However, microscopic pores with a diameter commonly smaller than 100 nm are common in clayey laminae. Thus, pore volume and surface area of micropores in silty laminae are less than those in the adjacent clayey laminae, and vice versa for meso- and macropores. The porosity of shales increases with the proportion of silty laminae in the shales. The silty laminae provide the storage space and flow conduit for oil and gas, and they play a significant role in the migration, accumulation, occurrence, and amount of gas in the shales. [1]: /embed/mml-math-1.gif [2]: /embed/mml-math-2.gif [3]: /embed/mml-math-3.gif