Lake Sediment Cores Research Articles

Geochronology and glass geochemistry of major Pleistocene eruptions in the Main Ethiopian Rift: Towards a regional tephrostratigraphy

The Main Ethiopian Rift (MER) is renowned as a focus of investigations into human origins. It is also the site of many large volcanic calderas, whose eruptions have spanned the timeframe of speciation, cultural innovation, and dispersal of our species. Yet, despite their significance for dating human fossils and cultural materials, the timing and geochemical signatures of some of the largest eruptions have remained poorly constrained at best. Here, through a programme of field surveys, geochemical analysis and 40Ar/39Ar dating, we report the ages of MER ignimbrites and link them to widespread tephra layers found in sequences of archaeological and paleoenvironmental significance. We date major eruptions of Fentale (76 ± 18 ka), Shala (ca. 145–155 ka), Kone (184 ± 42 ka and ca. 200 ± 12 ka) and Gedemsa (251 ± 47 ka) volcanoes, and correlate a suite of regionally important tephra horizons. Geochemical analysis highlights the predominantly peralkaline rhyolitic melt compositions (7.5–12 wt% Na2O + K2O, 70–76 wt% SiO2) across the central MER and remarkable similarity in incompatible trace element ratios, limiting the correlation of deposits via glass composition alone. However, by integrating stratigraphic and geochronological evidence from proximal deposits, lake sediment cores and distal outcrops at archaeological sites, we have traced ash layers associated with the ca. 177 ka Corbetti, ca. 145–155 ka Shala and ca. 108 ka Bora-Baricha-Tullu-Moye eruptions across southern Ethiopia. In addition to strengthening the tephrochronological framework that supports paleoenvironmental and archaeological work in the region, our findings have wider implications for evaluating the hypothesis of a middle Pleistocene ‘ignimbrite flare-up’ in the MER, and for evaluating the impacts of these great eruptions on landscapes, hydrology, and human ecology.

Assessment of asbestos fiber contamination in lake sediment cores of the Thetford Mines region, southern Quebec (Canada)

• Lake sediments of the Thetford Mines region contain high asbestos concentrations. • Stratigraphic asbestos concentrations vary in accordance with mining history. • Asbestos mining waste erosion still today releases high amounts of asbestos fibers. • Asbestos fibers are transported over at least 25 km by the Bécancour River. The Bécancour River in southern Quebec (Canada) has evolved under the influence of the long asbestos mining history of the Thetford Mines region (1877–2011 Common Era; CE). This river originates at the outflow of Lake Bécancour, flows through the old mining sites, and then widens to successively form Stater Pond, Trout Lake, Lake William, and Lake Joseph (25 km from the closest mine). Our objective was to assess asbestos fiber contamination in dated sediment cores retrieved at these sites by means of transmission electron microscopy. Chrysotile was the most abundant form of asbestos identified in the samples. Asbestiform actinolite and tremolite were also found. Our results revealed that precolonial sediments deposited at 4 out of the 5 study sites naturally contained asbestos fibers (up to 3.5 wt%), with mass accumulation rates historically reaching up to 1.0 mg cm −2 yr −1 . However, fiber concentrations were greatly enhanced in the anthropogenic horizon of all sediment cores. The highest concentrations (up to 6.9 wt%) were found in layers from Stater Pond and Trout Lake deposited during the maximum of regional mining activities (1945‒1980 CE). Likewise, reconstructed mass accumulation rates indicated that asbestos fiber influx peaked (up to 38.6 mg cm −2 yr −1 ) during this epoch in all water bodies located downstream from Thetford Mines at magnitudes consistent with their proximity to the mining sites. They decreased after 1980 EC (≤ 24.4 mg cm −2 yr −1 ) following the decline of regional mining activities and improvement of air quality. Modern sediments of all study sites (including upstream Lake Bécancour) were nevertheless still highly enriched in asbestos fibers (up to 4.4 wt%), which can be attributed to intensive mining waste erosion in the lake catchments. Our study highlights that asbestos fiber contamination is important and widespread in the Bécancour River basin, which raises human and ecosystem health concerns.

Algal responses to metal(loid) pollution, urbanization, and climatic changes in subarctic lakes around Yellowknife, Canada

The lakes around Yellowknife (Northwest Territories, Canada) have been impacted by multiple environmental stressors throughout the 20th and early 21st centuries. Here, we have synthesized diatom assemblage data from ten lake sediment cores from the Yellowknife area and used a landscape-scale paleolimnological approach to investigate the cumulative impacts of past gold mining activities, urbanization, and climate warming on aquatic biota. Our investigations indicated that diatom species turnover (measured using detrended canonical correspondence analysis) was highest at lakes closer to the city and mines, as these sites were more severely impacted by land-use changes (e.g., sewage disposal, run-off from waste disposal sites) and roaster stack emission from the gold mines. Diatom assemblage shifts indicative of climate-induced changes to lake thermal properties were also observed across the gradient of human activities. The inclusion of remote sites was useful to disentangle the effects of climate-mediated changes from impacts related to mining and urbanization. This investigation suggests that the diatom assemblages of the lakes around Yellowknife have changed markedly over the last ∼80 years and there are no signs of biological recovery since the cessation of mining activities around the turn of the 21st century. The biota of the subarctic lakes around Yellowknife are now strongly influenced by climate-mediated changes to lake thermal properties and the urban lakes are also influenced by the legacies of past land-use changes.

Characteristics of Dissolved Organic Matter in Sediments of Typical Lakes in Southeastern Hubei Province, China.

This study aimed to reveal the distribution characteristics and sources of dissolved organic matter (DOM) in sediments of typical lakes in the southeastern of the Hubei province and provide a reference for pollution control of eutrophic lakes. The sediments of four typical lakes (Liangzi, Baoan, Daye, and Qingshan) in the southeastern of the Hubei Province were investigated in May 2019. Ultraviolet-visible (UV-Vis) absorption spectroscopy and excitation-emission matrixes characteristics of DOM were obtained by UV-Vis spectrophotometry and three-dimensional fluorescence spectroscopy. Moreover, the DOM fluorescence components were resolved by parallel factor analysis (PARAFAC). The results showed that: (1) The absorption coefficient a350 in surface sediments followed the order: Baoan Lake (16.99 ± 3.82 m−1) > Qingshan Lake (15.37 ± 3.8 m−1) > Liangzi Lake (12.54 ± 5.58 m−1) > Daye Lake (12.43 ± 1.43 m−1). Specifically, with increasing depth in the sediment cores, a350 increased and then gradually decreased in Daye Lake and Baoan Lake, but fluctuated in Liangzi Lake and Qingshan Lake with a roughly decreasing trend. (2) Two humic-like components (C1, C2) and one protein-like component (C3) were identified via PARAFAC. This analysis also showed that the surface sediment fluorescent dissolved organic matter (FDOM) was dominated by protein-like, while the sediment core FDOM was dominated by humic-like in Liangzi Lake. The proportion of humic-like in FDOM was higher than protein-like in surface sediments and sediment cores of Baoan, Daye, and Qingshan Lakes. (3) The DOM of surface sediments in the Liangzi Lake comprised mostly autochthonous components, mainly produced by the vital activities of aquatic organisms. The DOM of surface sediments in Baoan Lake and Qingshan Lake showed weak humic and moderate autochthonous characteristics. The humification of DOM in sediment cores of Liangzi, Baoan, and Qingshan Lakes gradually decreased from depth to the surface. The DOM in surface sediments of Daye Lake had strong humic and moderate autochthonous characteristics. (4) In general, the DOM of lake sediments in southeastern Hubei Province has dual-contribution characteristics representing terrigenous and endogenous sources. In the restoration and treatment of lake ecology, both internal and terrestrial pollution should be considered. At the same time, it is noteworthy that cyanobacteria depletion and aquatic residues caused potential internal pollution.

Climate and human exploitation have regulated Atlantic salmon populations in the River Spey, Scotland, over the last 2000 years

Historical salmon catch records suggest that climatic variability, and more recently human exploitation, control patterns of abundance in Atlantic salmon populations. We present the first long-term (2000-year) reconstruction of Atlantic Salmon population variations based on a Marine Derived Nutrient (MDN) lake sediment record. Our record is constructed from nitrogen isotopes (δ15N) measured from a lake sediment core, which we compare with an escapement index (EI) derived from historic net catch data on major Scottish salmon rivers. We used an isotope mixing model to demonstrate that the N isotope values are likely enriched with MDN and demonstrate that Loch Insh sediments are enriched compared with a control site (Loch Vaa) that has never had exposure to salmon. We demonstrate that current adult spawner returns are around half that of historic values prior to major human exploitation. Before the onset of widespread human exploitation and habitat degradation, large fluctuations in salmon abundance are attributed to variations in North Atlantic sea surface temperature. While our data support published reconstructions of declining Atlantic salmon stocks in Northwest European rivers over the last 1000 years, rather than point to a solely human cause, the human impact appears to be overprinted on larger-scale changes in marine habitat occurring at the transition from the warmer Medieval Climatic Anomaly (MCA) to the cooler Little Ice Age (LIA).

Mercury Isotope Variations in Lake Sediment Cores in Response to Direct Mercury Emissions from Non-Ferrous Metal Smelters and Legacy Mercury Remobilization.

Nature archives record atmospheric mercury (Hg) depositions from directly emitted Hg and re-emitted legacy Hg. Tracing the legacy versus newly deposited Hg is still, however, challenging. Here, we measured Hg isotope compositions in three dated sediment cores at different distances from the Flin Flon smelter, the largest Canadian Hg sources to the atmosphere during the 1930s-2000s. During the smelter's operative period, Hg isotope compositions showed limited variations in the near-field lake (<10 km) sediments but were rather variable in middle- (20-75 km) and far-field lake (∼800 km) sediments. Only the post-2000 sediments in middle/far-field lakes showed significantly negative Hg isotope shifts, while sediments from the 1970s-1990s had Hg isotope values resembling those of near-field lake post-1930 sediments. We suggest that the smelter's peak Hg emissions during the 1970s-1990s, which coincided with the deployment of a super stack in the mid-1970s, largely increased the long-range dispersion of smelter plumes. For the top post-2000 sediments, the fugitive dust from ore tailings and terrestrial legacy Hg re-emissions dominated Hg deposition in near-field lakes and middle/far-field lakes, respectively. Our study demonstrates that legacy Hg remobilization now exports substantial amounts of Hg to ecosystems, highlighting the need for aggressive remediation measures of Hg-contaminated sites.

History of human disturbance to vegetation in the Southeast Hills of China over the last 2900 years: Evidence from a high resolution pollen record

The lower reaches of the Yangtze River have a long history of human occupation and rice cultivation, but our understanding of human activities in the mountainous region south of the lower Yangtze is still limited. In this study, we present a high-resolution vegetation record spanning the past 2900 years from the Southeast Hills of China by analyzing loss-on-ignition, pollen, charcoal, and non-pollen-palynomorphs from a lake sediment core. Combining our data with historical records, results suggest the study region was covered by dense broadleaved forests dominated by evergreen Cyclobalanopsis/Quercus from the start of the pollen record at 890 BCE until 850 CE. During this early period, colonization of the mountainous region was limited by rugged relief, closed forests, and lack of suitable land for farming. Later between 850 CE and 1180 CE, a slight decrease of evergreen trees, small rises in cereals and the ruderal herb Artemisia, and more frequent fire events point to the development of small-scale agricultural practices related to increased population. This change may reflect the shift of the economic center of China towards the lower Yangtze reaches, which happened during the Tang Dynasty (618–907 CE) and the influx of war refugees from the north especially during the Song Dynasty (960–1279 CE). From 1180 CE, a sharp decline of evergreen broadleaved trees and a peak in fire frequency was closely linked to a wave of deforestation resulting from the abrupt expansion of cereal cultivation. These changes were accompanied by the remarkable spread of pioneer secondary plants such as Pinus, Artemisia, and Dicranopteris-type ferns, which are typical indicators of human-induced deforestation in the region. It is probable that the population boom spread to the mountains and intensive agricultural activities took place involving terraced fields. Additionally, the coeval mining, smelting, and porcelain production in the mountains enlarged the scale of deforestation. Our study provides valuable information for landscape management and biodiversity conservation in the mountainous hinterland of subtropical southeast China.

Fungal diversity in a sediment core from climate change impacted Boeckella Lake, Hope Bay, north-eastern Antarctic Peninsula assessed using metabarcoding.

We studied the fungal DNA present in a lake sediment core obtained from Trinity Peninsula, Hope Bay, north-eastern Antarctic Peninsula, using metabarcoding through high-throughput sequencing (HTS). Sequences obtained were assigned to 146 amplicon sequence variants (ASVs) primarily representing unknown fungi, followed by the phyla Ascomycota, Rozellomycota, Basidiomycota, Chytridiomycota and Mortierellomycota. The most abundant taxa were assigned to Fungal sp., Pseudeurotium hygrophilum, Rozellomycota sp. 1, Pseudeurotiaceae sp. 1 and Chytridiomycota sp. 1. The majority of the DNA reads, representing 40 ASVs, could only be assigned at higher taxonomic levels and may represent taxa not currently included in the sequence databases consulted and/or be previously undescribed fungi. Different sections of the core were characterized by high sequence diversity, richness and moderate ecological dominance indices. The assigned diversity was dominated by cosmopolitan cold-adapted fungi, including known saprotrophic, plant and animal pathogenic and symbiotic taxa. Despite the overall dominance of Ascomycota and Basidiomycota and psychrophilic Mortierellomycota, members of the cryptic phyla Rozellomycota and Chytridiomycota were also detected in abundance. As Boeckella Lake may cease to exist in approaching decades due the effects of local climatic changes, it also an important location for the study of the impacts of these changes on Antarctic microbial diversity.

Phosphate addition enhances alkaline extraction of glyphosate from highly sorptive soils and aquatic sediments.

Analytical constraints complicate environmental monitoring campaigns of the herbicide glyphosate and its major degradation product aminomethylphosphonic acid (AMPA): their strong sorption to soil minerals requires harsh extraction conditions. Coextracted matrix compounds impair downstream analysis and must be removed before analysis. A new extraction method combined with subsequent capillary electrophoresis-mass spectrometry for derivatization-free analysis of glyphosate and AMPA in soil and sediment was developed and applied to a suite of environmental samples. It was compared to three extraction methods from literature. We show that no extraction medium reaches 100% recovery. The new phosphate-supported alkaline extraction method revealed (1) high recoveries of 70-90% for soils and aquatic sediments, (2) limits of detections below 20 μg kg-1 , and (3) a high robustness, because impairing matrix components (trivalent cations and humic acids) were precipitated prior to the analysis. Soil and sediment samples collected around Tübingen, Germany, revealed maximum glyphosate and AMPA residues of 80 and 2100 μg kg-1 , respectively, with residues observed along a core of lake sediments. Glyphosate and/or AMPA were found in 40% of arable soils and 57% of aquatic sediment samples. In this work, we discuss soil parameters that influence (de)sorption and thus extraction. From our results we conclude that residues of glyphosate in environmental samples are easily underestimated. With its possible high throughput, the method presented here can resolve current limitations in monitoring campaigns of glyphosate by addressing soil and aquatic sediment samples with critical sorption characteristics.

A computational method for rapid orthographic photography of lake sediment cores

Photographs of sediment cores are an important dataset, often containing visual evidence for environmental change via sediment composition and structure. These photographs may be used to stratigraphically correlate adjacent cores or for automated image analysis, and can facilitate collaboration amongst researchers through sharing and annotation of the image files. Here we describe the use of computational photogrammetry (also known as Structure from Motion–Multi-View Stereo) to generate orthographic imagery of sediment cores. Computational photogrammetry is a rapid and economical technique, typically requiring only a few minutes for each metre of core, using consumer-grade digital camera equipment. The photogrammetric methodology corrects for topographic distortion caused by sediment surfaces that are not perfectly flat, and can also record features of the scene surrounding the core, such as notes, colour reference cards and measurement tapes or rulers. As the photogrammetric process also generates a three-dimensional reconstruction of the sediment core, spatial-based analysis can be used to identify damaged or non-representative sections of the core that are to be avoided during image analysis. Using an intermittently laminated sediment core from Lake Surprise, Australia, we tested 22 scenarios using control points in a variety of configurations, as well as calibrated and uncalibrated cameras, to identify techniques that can reconstruct the core accurately and generate orthophotos. Multiple techniques were able to achieve suitable accuracy. In particular, targets placed on the table alongside the core, combined with a calibrated camera, achieved high accuracy and enabled a simple, rapid, and repeatable method for generating high-quality sediment core images.

Diversity and distribution of sediment bacteria across an ecological and trophic gradient.

The microbial communities of lake sediments have the potential to serve as valuable bioindicators and integrators of watershed land-use and water quality; however, the relative sensitivity of these communities to physio-chemical and geographical parameters must be demonstrated at taxonomic resolutions that are feasible by current sequencing and bioinformatic approaches. The geologically diverse and lake-rich state of Minnesota (USA) is uniquely situated to address this potential because of its variability in ecological region, lake type, and watershed land-use. In this study, we selected twenty lakes with varying physio-chemical properties across four ecological regions of Minnesota. Our objectives were to (i) evaluate the diversity and composition of the bacterial community at the sediment-water interface and (ii) determine how lake location and watershed land-use impact aqueous chemistry and influence bacterial community structure. Our 16S rRNA amplicon data from lake sediment cores, at two depth intervals, data indicate that sediment communities are more likely to cluster by ecological region rather than any individual lake properties (e.g., trophic status, total phosphorous concentration, lake depth). However, composition is tied to a given lake, wherein samples from the same core were more alike than samples collected at similar depths across lakes. Our results illustrate the diversity within lake sediment microbial communities and provide insight into relationships between taxonomy, physicochemical, and geographic properties of north temperate lakes.

Seabird-mediated transport of organohalogen compounds to remote sites (North West Greenland polynya)

The role of sea birds as carriers of pollutants over long distances was evaluated by analyzing organochlorine and organobromine compounds in lake sediment cores from three remote sites around the North Water polynya (North West Greenland). One lake, NOW5, was in the vicinity of a little auk (Alle alle L.) bird colony, whereas the other two lakes, NOW14 and Q5, were undisturbed by seabirds. The former was strongly acidic (pH = 3.4) but the latter had a pH close to 8. Due to the guano loading, NOW5 exhibited higher chlorophyll concentrations (74 μg/L) than the other two lakes (1.6–3.4 μg/L), higher content of total phosphorous (0.34 mg/L vs. 0.007–0.01 mg/L) and total nitrogen (3.75 mg/L vs. 0.21–0.75 mg/L).The concentrations of all organohalogen compounds were substantially greater in NOW5 than in the other lakes, indicating the strong influence of these seabirds in the transport and deposition of these compounds to remote sites. However, not all compounds showed the same increases. Hexachlorocyclohexanes and endosulfans were more than 18 times higher in NOW5, the drin pesticides and hexachlorobenzene (HCB), between 9.5 and 18 times and DDTs, polybromodiphenyl ethers (PBDEs), polychlorobiphenyls (PCBs) and chlordanes about 2.7–6 times. These differences demonstrated that the bird-mediated deposition has preservation effects of the less stable and more volatile compounds, e.g. those with log Kaw < −2.4, log Koa < 9 and/or log Kow < 6.8.The sedimentary fluxes of PCBs, HCHs, drins, chlordanes, PBDEs, HCB and endosulfans were highest in the upper sediment layer of the polynya lake (year 2014). In contrast, the highest DDT fluxes were found in 1980. These trends indicate that despite restrictions and regulations, bird transport continues to introduce considerable amounts of organohalogen pollutants to the Arctic regions with the exception of DDTs, which show successful decline, even when mediated by bird metabolism.

Scanning Hyperspectral Imaging for In Situ Biogeochemical Analysis of Lake Sediment Cores: Review of Recent Developments.

Hyperspectral imaging (HSI) in situ core scanning has emerged as a valuable and novel tool for rapid and non-destructive biogeochemical analysis of lake sediment cores. Variations in sediment composition can be assessed directly from fresh sediment surfaces at ultra-high-resolution (40–300 μm measurement resolution) based on spectral profiles of light reflected from sediments in visible, near infrared, and short-wave infrared wavelengths (400–2500 nm). Here, we review recent methodological developments in this new and growing field of research, as well as applications of this technique for paleoclimate and paleoenvironmental studies. Hyperspectral imaging of sediment cores has been demonstrated to effectively track variations in sedimentary pigments, organic matter, grain size, minerogenic components, and other sedimentary features. These biogeochemical variables record information about past climatic conditions, paleoproductivity, past hypolimnetic anoxia, aeolian input, volcanic eruptions, earthquake and flood frequencies, and other variables of environmental relevance. HSI has been applied to study seasonal and inter-annual environmental variability as recorded in individual varves (annually laminated sediments) or to study sedimentary records covering long glacial–interglacial time-scales (>10,000 years).

A 12,000 kyr paleohydroclimate record in the southeastern, U.S.A based on deuterium from bat guano

The southeastern United States endures environmental change from human population increase, climate change, and land-use alterations creating the need to understand baseline conditions and environmental patterns prior to human impacts. While paleoenvironmental data can be reconstructed from a variety of archives (e.g., lake sediments, tree rings, speleothems), some geographic areas contain fewer such records. One archive capable of recording moisture regimes and other paleoenvironmental changes over millennia but has received little attention relative to other climate proxies is bat guano deposits in cave systems. Bat guano deposits are found in many cave environments in the southeastern United States and can be used as an archive of paleoenvironmental data including precipitation, vegetation, and aspects associated with the ecology of bats. Here, we present a 12,000-year record of paleoenvironmental change based on δ2H stable isotopes in a guano core collected from Cave Springs Cave in Alabama, USA. Results suggest distinct shifts in moisture with dryer conditions during the early Holocene/late Pleistocene (12,200–9500 cal year BP) (δ2H values − 86.82 to −-77.70), wetter conditions during the middle Holocene (9300–3900 cal year BP) (δ2H values − 125.74 to − 80.63), roughly coinciding with the Holocene Climatic Optimum event time interval (9000–5000 cal year BP). During the last 4000 years, conditions in the region shifted in the southeastern United States region becoming dryer once again. Climate inferences based on guano δ2H are consistent with the role of atmospheric moisture on regional vegetation changes suggested by previous pollen records obtained from lake sediment cores. This study suggests bat guano δ2H may be a reliable method to provide a long-term paleoclimate record.

Black carbon and organic carbon dataset over the Third Pole

Abstract. The Tibetan Plateau and its surroundings, also known as the Third Pole, play an important role in the global and regional climate and hydrological cycle. Carbonaceous aerosols (CAs), including black carbon (BC) and organic carbon (OC), can directly or indirectly absorb and scatter solar radiation and change the energy balance on the Earth. CAs, along with the other atmospheric pollutants (e.g., mercury), can be frequently transported over long distances into the inland Tibetan Plateau. During the last decades, a coordinated monitoring network and research program named “Atmospheric Pollution and Cryospheric Changes” (APCC) has been gradually set up and continuously operated within the Third Pole regions to investigate the linkage between atmospheric pollutants and cryospheric changes. This paper presents a systematic dataset of BC, OC, water-soluble organic carbon (WSOC), and water-insoluble organic carbon (WIOC) from aerosols (20 stations), glaciers (17 glaciers, including samples from surface snow and ice, snow pits, and 2 ice cores), snow cover (2 stations continuously observed and 138 locations surveyed once), precipitation (6 stations), and lake sediment cores (7 lakes) collected across the Third Pole, based on the APCC program. These data were created based on online (in situ) and laboratory measurements. High-resolution (daily scale) atmospheric-equivalent BC concentrations were obtained by using an Aethalometer (AE-33) in the Mt. Everest (Qomolangma) region, which can provide new insight into the mechanism of BC transportation over the Himalayas. Spatial distributions of BC, OC, WSOC, and WIOC from aerosols, glaciers, snow cover, and precipitation indicated different features among the different regions of the Third Pole, which were mostly influenced by emission sources, transport pathways, and deposition processes. Historical records of BC from ice cores and lake sediment cores revealed the strength of the impacts of human activity since the Industrial Revolution. BC isotopes from glaciers and aerosols identified the relative contributions of biomass and fossil fuel combustion to BC deposition on the Third Pole. Mass absorption cross sections of BC and WSOC from aerosol, glaciers, snow cover, and precipitation samples were also provided. This updated dataset is released to the scientific communities focusing on atmospheric science, cryospheric science, hydrology, climatology, and environmental science. The related datasets are presented in the form of excel files. BC and OC datasets over the Third Pole are available to download from the National Cryosphere Desert Data Center (https://doi.org/10.12072/ncdc.NIEER.db0114.2021; Kang and Zhang, 2021).

Sources, concentrations, distributions, fluxes and fate of microplastics in a hypersaline lake: Maharloo, south-west Iran

Hypersaline lakes support unique ecosystems and biogeochemistries but are often subject to anthropogenic pressures from pollution, water abstraction-diversion and climate change. Less understood, however, are the inputs, distributions and impacts of microplastics (MPs) in hypersaline environments. In this study, MPs are determined in water and sediment cores of Maharloo Lake, south-west Iran, and in the anthropogenically-impacted rivers that recharge the lake. MP concentrations in river water ranged from 0.05 MP L−1 in the headwaters to about 2 MP L−1 downstream of industrial effluents, with intermediate (but elevated) concentrations observed in the lake. The maximum surface concentration in lake sediment cores was about 860 MP kg−1, and concentrations displayed a progressive reduction with increasing depth down to 50 cm that are qualitatively consistent with temporal changes in plastic production. The size distribution of MPs was skewed towards the finest fraction (< 100 μm) and the most abundant polymer types were polyethylene terephthalate, polyethylene and nylon. Flux calculations using river water data and published atmospheric deposition data for the region reveal that the atmosphere is, by at least an order of magnitude, the more important source. MPs added to the lake appear to be maintained in suspension by high density water but are subsequently deposited to sediments by encapsulation and nucleation as salts precipitate. In addition, it is proposed that direct atmospheric deposition to sediment takes place on areas that seasonally dry out and are subsequently inundated. The impacts of MPs on hypersaline ecosystems and biomass resources are unknown but warrant investigation.

Evidence that modern fires may be unprecedented during the last 3400 years in permafrost zone of Central Siberia, Russia

Recent climate change in Siberia is increasing the probability of dangerous forest fires. The development of effective measures to mitigate and prevent fires is impossible without an understanding of long-term fire dynamics. This paper presents the first multi-site palaeo-fire reconstruction based on macroscopic charcoal data from peat and lake sediment cores located in different landscapes across the permafrost area of central Siberia. The obtained results show similar temporal patterns of charcoal accumulation rates in the cores under study, and near synchronous changes in fire regimes. The paleo-fire record revealed moderate biomass burning between 3.4 and 2.6 ka BP, followed by the period of lower burning occurring from 2.6 to 1.7 ka BP that coincided with regional climate cooling and moistening. Minimal fire activity was also observed during the Little Ice Age (0.7–0.25 ka BP). Fire frequencies increased during the interval from 1.7 to 0.7 ka BP and appears to be partly synchronous with climate warming during the Medieval Climate Anomaly. Regional reconstructions of long-term fire history show that recent fires are unprecedented during the late Holocene, with modern high biomass burning lying outside millennial and centennial variability of the last 3400 years.

Evolution of Glacial Lake Cochrane During the Last Glacial Termination, Central Chilean Patagonia (∼47°S)

Large ice-dammed lakes developed along the eastern margin of the Patagonian Ice Sheet (PIS) during the Last Glacial Termination (T1). Their spatial/temporal evolution, however, remains poorly constrained despite their importance for deciphering fluctuations of the shrinking PIS, isostatic adjustments, and climate forcing. Here we examine the distribution and age of shoreline features deposited or sculpted by Glacial Lake Cochrane (GLC) in the Lago Cochrane/Pueyrredón (LCP) basin, Central Patagonia, following recession of the LCP glacier lobe from its final Last Glacial Maximum (LGM) moraines. GLC drained initially toward the Atlantic Ocean and continuing ice shrinking opened new drainage routes allowing the discharge toward the Pacific Ocean. We identify five clusters of lake terraces, shorelines, and deltas between elevations ∼600–500 (N5), ∼470–400 (N4), ∼360–300 (N3), ∼230–220 (N2), and ∼180–170 masl (N1) throughout the LCP basin. The distribution of these clusters and associated glaciolacustrine deposits provide constraints for the evolving position of the damming glacier bodies. Elevation gradients within the landform clusters reveal glacio-isostatic adjustments that enable us to quantify the magnitude of deglacial rebound and construct isostatically corrected surfaces for the different phases in the evolution of GLC. Our chronology, based principally on radiocarbon dates from lake sediment cores and new OSL dating, suggests that these phases developed between ∼20.7–19.3 ka (N5), ∼19.3–14.8 ka (N4), ∼14.8–11.3 ka (N3), and shortly thereafter (N2 and N1). The N3 landforms are the most ubiquitous, well-preserved, and voluminous, attributes that resulted from a ∼3,500-year long period of glacial stability, enhanced sediment supply by peak precipitation regime, and profuse snow and ice melting during the most recent half of T1. This scenario differs from the cold and dry conditions that prevailed during the brief N5 phase and the moderate amount of precipitation during the N4 phase. We interpret the limited development of the N2 and N1 landforms as ephemeral stabilization events following the final and irreversible disappearance of GLC after N3. This event commenced shortly after the onset of an early Holocene westerly minimum at pan-Patagonian scale at ∼11.7 ka, contemporaneous with peak atmospheric and oceanic temperatures in the middle and high latitudes of the Southern Hemisphere.

Molecular and Pigment Analyses Provide Comparative Results When Reconstructing Historic Cyanobacterial Abundances from Lake Sediment Cores.

Understanding the historical onset of cyanobacterial blooms in freshwater bodies can help identify their potential drivers. Lake sediments are historical archives, containing information on what has occurred in and around lakes over time. Paleolimnology explores these records using a variety of techniques, but choosing the most appropriate method can be challenging. We compared results obtained from a droplet digital PCR assay targeting a cyanobacterial-specific region of the 16S rRNA gene in sedimentary DNA and cyanobacterial pigments (canthaxanthin, echinenone, myxoxanthophyll and zeaxanthin) analysed using high-performance liquid chromatography in four sediment cores. There were strong positive relationships between the 16S rRNA gene copy concentrations and individual pigment concentrations, but relationships differed among lakes and sediment core depths within lakes. The relationships were more consistent when all pigments were summed, which we attribute to different cyanobacteria species, in different lakes, at different times producing different suites of pigments. Each method had benefits and limitations, which should be taken into consideration during method selection and when interpreting paleolimnological data. We recommend this biphasic approach when making inferences about changes in the entire cyanobacterial community because they yielded complementary information. Our results support the view that molecular methods can yield results similar to traditional paleolimnological proxies when caveats are adequately addressed.

A Holocene Sedimentary Record and the Impact of Sea-Level Rise in the Karst Lake Velo Blato and the Wetlands on Pag Island (Croatia)

Lakes in coastal lowland areas represent a critically vulnerable environment as a transitional space between freshwater and seawater environments. The paleoenvironmental reconstruction and anthropogenic impact are assessed through the lake sediment cores from Velo, Malo, and Kolanjsko Blato using multi-proxy analyses (sedimentological, mineralogical, geochemical, 137Cs and ostracod analyses, and AMS 14C radiocarbon dating). The freshwater lake Velo Blato was formed at 8100 cal yr BP due to rising groundwater levels as a consequence of sea-level rise. The brackish conditions in Lake Velo Blato started at 7100 cal yr BP, giving the index point for the sea-level curve of 7-m lower than present. Lead concentrations showed slightly increased values in the last 1800 cal yr BP, while the spike in Malo Blato lake sediments probably derived from bird hunting with lead bullets. Kolanjsko Blato sediment core archives the sediment record of the last 2050 years, which represents a shallow brackish coastal wetland under marine influence. Enrichment factors showed the accumulation of Cu, Hg, P, Pb, S, and Zn in the sediments from Kolanjsko Blato in the last 650 cal yr BP, which coincides with the high organic carbon content, and in sediments from Malo Blato after the lake’s formation (from the depth of 20 cm upwards). Anthropogenic Cu introduced into the Kolanjsko Blato sediments is the highest in the surface sample. Surficial sediments from Velo Blato are characterized by the high organic carbon, S, P, and N content, indicating high productivity and eutrophication which led to occasional anoxic conditions on the lake bottom in the last 200 years.