Laizhou Bay Area Research Articles

Study on the Variation in Coastal Groundwater Levels under High-Intensity Brine Extraction Conditions

The excessive exploitation of groundwater is becoming a serious global issue. Different from other regions, groundwater extraction in coastal areas usually stops and moves inland after causing seawater intrusion. The abundant salt fields in the Laizhou Bay area of China provide a unique case of maintaining high-intensity underground brine mining even after seawater intrusion. The intensive exploitation of underground brine has led to significant changes in the groundwater flow field. However, there is still a lack of research on how different factors affect the groundwater level in this mining situation. In this paper, time series analysis methods were used to investigate the impact of brine water extraction, tidal fluctuations, and precipitation on the groundwater level in the Laizhou Bay area. The results indicate that brine extraction is the main factor controlling the changes in groundwater level, with the cessation and resumption of extraction resulting in a 93.4 cm increase and a 122.5 cm decrease, respectively. Different rainfall patterns can also lead to an increase in groundwater levels, especially when a heavy rainfall event can cause a 61.2 cm increase. Tidal fluctuations can cause periodic fluctuations in the groundwater level, with a variation amplitude of approximately 11% of the tide itself.

The Study on the Genesis of Underground Brine in Laizhou Bay Based on Hydrochemical Data

The Laizhou Bay area contains a large amount of Quaternary brine resources, which have been gradually depleted by long-term high-intensity mining. The local brine genesis is still controversial, and the dominant theory of the evaporation of brine formation limits the exploration of brine resources to the land area, while the confirmation of freezing brine formation would greatly expand the brine storage range. In this research paper, the genesis of underground brines was analyzed based on the major ion concentrations of 62 samples of underground brines at different depths at 24 stations along the south coast of Laizhou Bay. The results show that the underground brines originated from seawater; however, their chemical components were changed during the evolution process after formation. The hydrogeochemical modeling results show that the mixing of seawater and fresh groundwater also affects the chemical composition of brines. The large-scale exploitation of brine resources in recent decades has also led to significant changes in the chemical composition of the underground brine in Laizhou Bay compared with the earlier period. The special geographic environment and the development of the brine chemical industry have led to the evolution of underground brines in Laizhou Bay being affected by a variety of factors, which makes the traditional analysis of brine genesis in this region not applicable. Furthermore, although evaporation and concentration are the dominant factors in the formation of brine, there is still a lack of evidence to rule out the existence of the freezing pathway.

Spatiotemporal variations and the ecological risks of organophosphate esters in Laizhou Bay waters between 2019 and 2021: Implying the impacts of the COVID-19 pandemic

Organophosphate esters (OPEs) are a group of synthetic chemicals used in numerous consumer products such as plastics and furniture. The Coronavirus Disease 2019 (COVID-19) pandemic significantly slowed anthropogenic activities and reduced the emissions of pollutants. Meanwhile, the mismanagement of large quantities of disposable plastic facemasks intensified the problems of plastic pollution and leachable pollutants in coastal waters. In this study, the joint effects of the COVID-19 outbreak on the occurrence of 12 targeted OPEs in the waters of Laizhou Bay (LZB) were investigated. The results showed that the median total OPE concentrations were 725, 363, and 109 ng L−1 in the sewage treatment plant effluent, river water, and bay water in 2021, decreased significantly (p < 0.05) by 67%, 68%, and 70%, respectively, compared with those before the COVID-19 outbreak. The release potential of targeted OPEs from disposable surgical masks in the LZB area was ∼0.24 kg yr−1, which was insufficient to increase the OPE concentration in the LZB waters. The concentrations of most individual OPEs significantly decreased in LZB waters from 2019 to 2021, except for TBOEP and TNBP. Spatially, a lower concentration of OPEs was found in the Yellow River estuary area in 2021 compared with that before the COVID-19 pandemic due to the high content of suspended particulate matter in the YR. A higher total OPE concentration was observed along the northeastern coast of LZB, mainly owing to the construction of an artificial island since 2020. The ecological risks of the OPE mixture in LZB waters were lower than those before the COVID-19 outbreak. However, TCEP, TNBP, and BDP should receive continuous attention because of their potential ecological risks to aquatic organisms.

Machine learning-based seawater concentration pathway prediction

This paper constructs a prediction model based on Multilayer Perceptron (MLP) to explore the formation mechanism of brine (seawater evaporation or freezing). Four brine sets are extracted from the published, real-world data, and the simulation test with the same six chemical substance features. After integrated comparative experiments on six evaluation metrics, the results show that this model outperforms the other baseline prediction algorithms, achieving the highest precision 0.9625 and at least 8.45% improvement. Furthermore, for predicting the real-world test set, the results confirm the existence of freezing brine for the first time in Laizhou Bay area, China. This model is also used to analyze the mixed simulation results for brine and fresh groundwater. The experimental results indicate that only two out of twenty-nine samples of various concentrations change formation mechanisms after mixing. Overall, the model can effectively distinguish the evaporation and freezing brine, and discover the seawater concentration pathway.

Short- and medium-chain chlorinated paraffins in sediments from the Laizhou Bay area, North China: Implications for transportation from rivers to marine environment

The concentrations of short- and medium-chain chlorinated paraffins (SCCPs and MCCPs) were measured for riverine and marine sediments from the Laizhou Bay area in order to investigate their spatial distributions, possible sources and transport behaviors. Concentrations of SCCPs and MCCPs in riverine sediments varied from 8.4 to 2000 ng g−1 dw and from 1.8 to 3200 ng g−1 dw, respectively. Higher concentrations were found exclusively at industrial sites. Emissions from local factories were the main source of CPs in river sediments of this region. It was 5–22 ng g-1 dw and 6–63 ng g−1 dw with an average value of 11 ng g−1 dw and 9 ng g−1 dw for SCCPs and MCCPs in marine sediments of Laizhou Bay, respectively. In addition to riverine input, ship related emissions are suggested to be another important source of CPs in the Laizhou Bay. MCCPs/SCCPs values and compositional profiles of SCCPs were found to vary along with CP concentrations. A distinct shift to congener groups with shorter carbon chains and lower chlorination from emission sources to remote areas was noticed. The role of log octanol-water partition coefficient (LogKow) values indicated decisive in their transportation from emission sources to remote areas in the Laizhou Bay area.

From headwaters to estuary: Distribution and fate of halogenated flame retardants (HFRs) in a river basin near the largest HFR manufacturing base in China

With the gradual phasing out of polybrominated diphenyl ethers (PBDEs), market demands for alternative halogenated flame retardants (HFRs) are increasing. The Laizhou Bay area is the biggest manufacturing base for brominated flame retardants (BFRs) in China, and the Xiaoqing River is the largest and most heavily contaminated river in this region. Water and sediment samples were collected from the headwaters to the estuary of the Xiaoqing River to investigate the distribution and fate of HFRs [i.e., PBDEs, alternative brominated flame retardants (aBFRs) and dechlorane plus (DPs). In the water samples, DPs was the most abundant flame retardant (median: 11.7ng/L), followed by decabromodiphenylethane (DBDPE) (5.92ng/L). In the sediment samples, DBDPE was the predominant flame retardant (39.5ng/g dw), followed by decabromodiphenyl ether (BDE 209) (2.81ng/g dw). The levels of DBDPE exceeded those of BDE 209 in most samples, indicating the overwhelming replacement of BDE 209 by DBDPE in this area. In the river section of this study, point source and atmospheric deposition followed by land runoff were the major factors influencing the distribution of HFRs, whereas in the estuary, riverine discharge, the estuarine maximum turbidity zone (MTZ), and hydrodynamic parameters played more important roles. Manufacturing is a significant source of contamination of the Xiaoqing River basin through atmospheric deposition and wastewater discharge.

Habitat Suitability Analysis of Suaeda heteroptera in Wetlands of Laizhou West Bank Based on GIS

Along with the development of marine economy, west bank of Laizhou Bay, efficient and economical core area, suffered some degree of damage, and local habitats of &lt;em&gt;Suaeda heteroptera &lt;/em&gt;were correspondingly affected. Using geographic information systerms (GIS) technology and HIS model, analysis on habitat suitability of&lt;em&gt; S. heteroptera&lt;/em&gt; in tital wetlands of Lanzhou west bank. The results show that: Although high soil salinity in the study area, and serious petroleum and heavy metal pollution, the regional environmental conditions meet the basic survival and growth requirement of &lt;em&gt;S. heteroptera&lt;/em&gt;, because its strong salt tolerance, as well as petroleum and heavy metal absorption and accumulation ability, consequently, &lt;em&gt;S. heteroptera&lt;/em&gt; can be relatively normally grow in this habitat. Generally, Laizhou Bay is a highly or moderate suitable area for &lt;em&gt;S. heteroptera&lt;/em&gt; growth.

Assessing the pollution risk of a groundwater source field at western Laizhou Bay under seawater intrusion

Coastal areas have great significance for human living, economy and society development in the world. With the rapid increase of pressures from human activities and climate change, the safety of groundwater resource is under the threat of seawater intrusion in coastal areas. The area of Laizhou Bay is one of the most serious seawater intruded areas in China, since seawater intrusion phenomenon was firstly recognized in the middle of 1970s. This study assessed the pollution risk of a groundwater source filed of western Laizhou Bay area by inferring the probability distribution of groundwater Cl− concentration.The numerical model of seawater intrusion process is built by using SEAWAT4. The parameter uncertainty of this model is evaluated by Markov Chain Monte Carlo (MCMC) simulation, and DREAM(ZS) is used as sampling algorithm. Then, the predictive distribution of Cl- concentration at groundwater source field is inferred by using the samples of model parameters obtained from MCMC. After that, the pollution risk of groundwater source filed is assessed by the predictive quantiles of Cl- concentration.The results of model calibration and verification demonstrate that the DREAM(ZS) based MCMC is efficient and reliable to estimate model parameters under current observation. Under the condition of 95% confidence level, the groundwater source point will not be polluted by seawater intrusion in future five years (2015–2019). In addition, the 2.5% and 97.5% predictive quantiles show that the Cl− concentration of groundwater source field always vary between 175mg/l and 200mg/l.

The distribution and variation of elements in sediments off the Huanghe (Yellow) River mouth

Surface sediment samples collected off the Huanghe (Yellow) River mouth during the period 2007–2009 were analyzed for major and trace element concentrations. Concentrations of 16 elements were measured using X-ray fluorescence spectrometry. Results demonstrate that sediment grain size is the dominant factor controlling the spatial variations of elemental concentrations. Correlation and cluster analyses allowed classification of the study area into four geochemical regions: Regions I and III are characterized by high concentrations of Al2O3, Fe2O3, MgO, Na2O, K2O, Cr, Cu, Mn, Ni, Pb, V, and Zn, and contain fine-grained sediments with mean grain size (M z)<22 μm; and; Regions II and IV contain mostly coarse-grained sediments, and are characterized by high concentrations of SiO2, Na2O, and Zr. The sediment entering the sea from the Huanghe River and its tributaries is enriched in Ca. Thus, the Ca/Al ratio was used as an indicator of the proportion of sediments in the study area that originated from the Huanghe River. Ca/Al ratios decrease from Regions I and II (located in the nearshore zone of the Huanghe River delta) to Regions III and IV (distributed in the offshore zone of the northern Huanghe River delta, southern and southeastern Laizhou Bay area).

Levels and distribution of hexabromocyclododecane (HBCD) in environmental samples near manufacturing facilities in Laizhou Bay area, East China

A total of 55 samples including soil, sediment, plants (cypress, reed and seepweed) and aquatic species were collected at locations around hexabromocyclododecane (HBCD) manufacturing facilities in Laizhou Bay area, East China. HBCD was determined at concentrations ranging between 0.88 and 6901 ng g(-1) dry weight (dw), 2.93-1029 ng g(-1) dw, 8.88-160241 ng g(-1) dw, and 7.09-815 ng g(-1) lipid weight (lw), respectively. Significant negative correlations (r(2) = 0.54, p = 0.006) were observed between HBCD concentrations in soils and the distance from the manufacturing facility, and the concentrations became constant when the distance was >4 km. The calculation results on the bioaccumulation factors (BAFs) suggested that HBCD may be accumulated in plants. Tissue-specific bioaccumulation of HBCD diastereoisomers was found in aquatic species. For example, in crabs the highest concentrations of HBCD (815 ng g(-1) lw for female and 446 ng g(-1) lw for male) were observed in the gill. Besides the gill, α-HBCD was more preferentially accumulated in the spermary and ovary, while β- and γ-HBCD were more accumulated in the muscle. A similar distribution was also observed in roe and muscle of goby fish.

Polychlorinated naphthalenes (PCNs) in riverine and marine sediments of the Laizhou Bay area, North China

PCN congeners were analyzed in marine and riverine sediments of the Laizhou Bay area, North China. Concentrations of PCNs ranged from 0.12 to 5.1 ng g − 1 dry weight (dw) with a mean value of 1.1 ng g − 1 dw. The levels of PCNs varied largely, with industrial group approximately ten folds higher than those of the rural in riverine sediment. A strong impact by direct discharge from local factories was suggested. Similar compositional profiles were found within groups. High resemblance of compositional profiles between industrial samples and Halowax 1014 was observed. It was indicated that PCNs in riverine sediments were mainly from release of industrial usage, with additional contributions from industrial thermal process at certain sites. In marine sediments, it was suggested that PCNs along the coast of Laizhou Bay were mainly controlled by riverine input. While in the central bay, PCN distributions were possibly impacted by combined multiple factors.

Polybrominated diphenyl ethers (PBDEs) in the riverine and marine sediments of the Laizhou Bay area, North China

62 riverine and marine sediments were collected from the Laizhou Bay area, where the largest manufacturing base of brominated flame retardants (BFRs) in Asia is located. Eight polybrominated diphenyl ethers (PBDEs) were analyzed to investigate the impact of rapidly-developed bromine industries on the regional aquatic system. PBDE concentrations varied largely in riverine sediments. Σ(7)PBDEs (including BDE 28, 47, 99, 100, 153, 154 and 183) and BDE 209 ranged from 0.01 to 53 ng g(-1) dw and from 0.74 to 285 ng g(-1) dw with a mean value of 4.5 ng g(-1) dw and 54 ng g(-1) dw, respectively, indicating a strong influence of direct pollution discharges from local factories. In marine sediments, Σ(7)PBDEs and BDE 209 ranged from not detected (nd) to 0.66 ng g(-1) dw and from 0.66 to 12 ng g(-1) dw with a mean value of 0.32 ng g(-1) dw and 5.1 ng g(-1) dw, respectively. PBDE concentrations were mostly <10 ng g(-1) dw for Σ(7)PBDEs and <50 ng g(-1) dw for BDE 209, which are at a relatively low level for monitored riverine and coastal sediments around the world. Even at the most contaminated sites in Laizhou Bay area, PBDE concentrations were not among the highest concentrations reported in the literature. Congener compositions were dominated by BDE 209 (57.2-99.9% of the sum of BDE congeners), with minor contributions from penta- and octa-BDE products. Tri- to octa-BDE congeners were well correlated among each other (r > 0.75) and thus sources from similar mixing of penta- and octa-BDE products were suggested in this area. Compared with riverine sediments, a much better correlation between PBDE concentrations with TOC was observed in marine environment. The congener pattern changed and their correlation coefficients among each other were remarkably reduced. Contributions of BDE 28, 47 and 99 to Σ(7)PBDEs were generally the same in almost all the marine sites, while it was distinctively higher for BDE 153. These are probably attributable to several reasons, such as contributions by atmospheric deposition and/or redistribution between particles of various sizes during and/or after fluvial transportation combined with the difference of physiochemical properties of BDE congeners.

The numerical simulation and analysis of three-dimensional seawater intrusion and protection projects in porous media

For the three-dimensional seawater intrusion and protection system, the model of dynamics of fluids in porous media and the modified upwind finite difference fractional steps schemes are put forward. Based on the numerical simulation of the practical situation in the Laizhou Bay Area of Shandong Province, predictive numerical simulation and analysis of the consequence of protection projects, underground dams, tidal barrage projects and the applied modular form of project adjustment have been finished. By using the theory and techniques of differential equation prior estimates, the convergence results have been got.

Study of shallow groundwater quality evolution under saline intrusion with environmental isotopes and geochemistry

Evolution of the shallow groundwater quality under saline intrusion in porous aquifer system has been studied with environmental isotopes and geochemistry in the Laizhou Bay area, China. Two campaigns of water sampling from various sources were carried out in spring and winter for environmental isotopic and chemical analyses. The origin of groundwater salinity from intrusion of both modern seawater and deep brine water was identified by analysing the correlations between 18O, D, T, Cl−, SO 4 2− and electrical conductivity. The results indicate that the brine is originated from evaporating and concentrating of intruded seawater and its δD and δ18O are different from modern seawater but similar to those of mixture of seawater with fresh groundwater. It is hard to distinguish the salinity origin in this area by the δD–δ18O relationship alone. The relations between δ18O and conductivity, Cl− and SO 4 2− have been used to identify the salinity origin due to the distinct difference in salinity between the brine and seawater, conjunctively with use of T. A threshold of T = 12 TU was adopted to identify the origin of saline groundwater.

Predicting the consequences of seawater intrusion and protection projects

The simulation of this process and the effects of protection projects lays the foundation of its effective control and defence. The mathematical model of the problem and upwind splitting alternating direction method were presented. Using this method, the numerical simulation of seawater intrusion in Laizhou Bay Area of Shandong Provivce was finished. The numerical results turned out to be identical with the real measurements, so the prediction of the consequences of protection projectects is reasonable.

Experimental studies of farmland ecological engineering for controlling saltwater intrusion in the Laizhou Bay area of China

In view of the grim situation of drought, water shortage, serious intrusion of saltwater and field yield declines facing the Laizhou Bay area of China, and in accordance with the principles of suiting local conditions and pursuing high efficiency, experimental studies of farmland ecological engineering have been carried out in Laizhou and Shouguang. Remarkable ecological and economic benefits have been achieved in these areas, serving as an exemplary model for preventing and dealing with the disaster of saltwater intrusion and realizing the sustainable development of agriculture.