Lacustrine Sediments Research Articles

Late Holocene vegetation history and monsoonal climate change from the Core Monsoon Zone of India

To understand the vegetation response to climate change and the Indian Summer Monsoon rainfall (ISMR) variability during the Late Holocene (approx. 2.5 ka), pollen analysis was conducted on a 1.2-m-long lacustrine sediment profile from the Korba District of Chhattisgarh, central India, within the core monsoon zone (CMZ). The pollen evidence suggest that between approx. 2500 and 1950 cal yr BP, open tropical deciduous forest vegetation occupied the landscape under a warm and relatively less humid climate, coupled with decreased ISMR. Between approx. 1950 and 1035 cal yr BP, a warm and relatively more humid climate prevailed, along with moderate ISMR, leading to the transition of the existing vegetation to an open mixed tropical deciduous forest. Between approx.1035 and 220 cal yr BP (CE 915–1730), the mixed tropical deciduous forest became established under a warm and humid climate with increased ISMR, coinciding globally with the Medieval Climatic Anomaly (MCA). Mixed tropical deciduous forest expanded and transformed into a dense mixed tropical deciduous forest between approx. 220 cal yr BP to the present (CE 1730 onwards). This transformation occurred under a warm and relatively more humid climate, accompanied by intensified ISMR, aligning with the Current Warm Period (CWP). Gradual forest transformation from open vegetation to dense mixed tropical deciduous forests, as well as in the ISMR has been observed since the last approx. 2.5 ka in central India. Cereal-based agricultural practices and other anthropogenic activities have been documented in the study area since approx. 2.5 ka, with an accelerated pace observed from 1035 cal yr BP to the present.

Mineral composition of lake Sabakty sediments as an indicator of paleoclimate, Southern Urals, Russia

Relevance. Reconstruction of climatic changes based on the lacustrine sediments of lakes makes it possible to identify climatic trends and events in the late Quaternary. The Urals is considered as one of the climatic divisions, therefore, studies of the conditions of lake sedimentation, including climatic ones, are relevant in this area. Aim. To study mineral composition as an indicator of paleoclimate of Lake Sabakty sediments. Object. Core of Lake Sabakty sediments (length is 298 cm). The age of the core is ~25 thousand years old. Materials and methods. Sampling was carried out taking into account seismoacoustic data, lithological description, as well as measurements of magnetic susceptibility and radiometric dating data. The granulometric analysis was carried out by laser granulometry using a Bluewave particle size analyzer (Microtrac, USA) combined with a sample loading and circulation system with an integrated ultrasonic dispersant. Mineral composition of the sediments was determined using the D2 PHASER X-ray diffractometer and the Merlin auto-emission scanning electron microscope. Results. The predominance of the siltstone fraction was established. The mineral composition is characterized by the predominance of allotigenic minerals in sediments (quartz, microcline, albite, mica, chlorite, mixed-layer clay minerals, hornblende, kaolinite) according to X-ray diffraction and electron microscopy. Autigenic minerals include biogenic silica (cristobalite, tridymite), pyrite, carbonates (calcite, dolomite), sulfates (gypsum, barite). Conclusions. The ratio of allogenic and autogenic components reflects the changes in the accommodation of the reservoir and the supply of clastic material associated with changes in climate humidity. Changes in climate humidity are reflected in changes in the contents of carbonate and sulfate minerals. At the beginning of sedimentation, Lake Sabakty was shallow and mineralized due to climate aridization, which probably included the global Bond 8 event (~26000–11700 BP). The study of the mineral composition of the sediments of Lake Sabakty allowed us to establish the events of climate aridization: ~10000 BP, ~7600 BP, ~6900 BP ~1900 BP and ~1400 BP. In Sabakty Lake, there is a bright episode of a decrease in climate humidity in the range of ~7300-5200 BP, which is marked by an increase in carbonate content up to 70% and the detection of gypsum at ~6900 BP.

The Neogene of the Vienna Basin – a synthesis

We present a revision of geological and paleontological data of the Vienna Basin (VB). The deposits comprise Miocene terrestrial, lacustrine and marine sediments, corresponding the Ottnangian, Karpatian, Badenian, Sarmatian and Pannonian regional stages (= Burdigalian to Tortonian). New 3D seismics and the analyses of hundreds of core samples resulted in a wealth of information. Absolute ages were published for two tuffs and the lithostratigraphy was largely formalized. The evolution of the paleoenvironments in the VB strongly reflects the impact by global climatic events such as the Miocene Climatic Optimum, the Middle Miocene Climate Transition and the Tortonian Thermal Maximum. Global 3 rd order sea level cycles are reflected in the successions of marine depositional environments. Major drops of the relative sea level caused strong erosion along the basin margins, with up to 300 m paleorelief. The strongest phase of erosion was linked to tectonics. Around the Early/Middle Miocene boundary, Lower Miocene strata became tilted during the Styrian Tectonic Phase. Up to 600-m-deep subaerial canyons incised the VB at that time. A second phase of basin-wide erosion occurred during the Late Miocene when more than 200 m of upper Pannonian strata became removed from large parts of the VB after 9 Ma.

Stratigraphic overview of the Neogene Transylvanian Basin, Romania

Although the Transylvanian Basin is often referred as part of the Miocene Pannonian Basin System, we point out important tectonic and sedimentary differences reflected in the stratigraphy. The Neogene of the Transylvanian Basin can be split into two tectonic megasequences: Lower Miocene and Middle to Upper Miocene. The Early Miocene onset of the back arc extension in the Pannonian Basin was not observed in the Transylvanian Basin, where shallow to deep marine sediments were deposited in a flexural basin. Diverse types of facies developed in the continental (e.g., Sânmihai) and marine (e.g., Coruş, Chechiş, Hida) Lower Miocene formations. Although these are poorly constrained to the standard biostratigraphy, recent 87 Sr- 86 Sr data support their limited correlation with the Burdigalian. The Middle Miocene extension in the Transylvanian Basin is very weak compared to that the Pannonian Basin. As the high-resolution Middle Miocene regional biostratigraphy of the Badenian and Sarmatian was calibrated by magnetostratigraphy and radiometric dating of the volcanic tuffs up to the Serravallian/Tortonian boundary, the influence of the regional tectonics on the basin's evolution and stratigraphy can be better understood. The regional tectonics produced a progressive basin isolation starting with the late part of the Middle Miocene. The uplift of the Carpathians isolated the basin at the beginning of the Pannonian and initiated the fan delta, lacustrine, and fluvial sedimentation. The basin was rapidly uplifted and eroded, while post-extensional subsidence was still ongoing in the Pannonian Basin. Endemic fossil assemblages allow only regional-scale correlations for this interval. The uppermost part of the stratigraphic record is represented by the volcano-sedimentary formations generated by the late evolution of the Eastern Carpathians. The sedimentation and subsidence pattern of the Transylvanian Basin reflect the effect of retreating subduction zone in the Eastern Carpathians.

Late Pleistocene charcoal-rich sediments in the Puerto Rico Trench, possible remnants of gigantic wildfires in North-Eastern South America

An 18,000 km2 area of the Guyana Shield of South America, known as the Gran Sabana, is characterized by savannah vegetation that contrasts strongly with surrounding rain forests. Its origin has been linked to multiple episodes of forest fires. In this paper, we report a deposit encountered in two piston cores sampled during the CASEIS marine cruise, at 6000 m-depth at the southern entrance of the Puerto Rico Trench. The existence of this deposit call into question our understanding of the evolution of the Gran Sabana. We sampled its upper ∼60 cm, which comprises leaves and wood fragments, seeds, and charcoal, intermixed with siliciclastic sediment of igneous-metamorphic continental provenance. Radiocarbon dates of the vegetal fragments and charcoal range between 30 and 23 kyr BP. We propose that these deep ocean charcoal-rich sediments, located 2500 km offshore from the Orinoco Delta, may be remnants of gigantic forest fires of the Guyana Shield. We infer that this material was eroded during an extreme regional rainfall event, transported down rivers during one or more episodes to the Orinoco delta, and then travelled offshore via a deep turbiditic submarine system flowing on the Atlantic seafloor. It finally reached the Puerto Rico Trench, forming what we term, the Baracuda Trench Debrite. While published paleoclimatic analyses of lacustrine sediments have suggested that the Gran Sabana originated during episodes of wildfire ∼12.5 kyr BP ago, radiocarbon dating of Baracuda Trench Debrite suggests the occurrence of earlier fires in this region, leading us to re-evaluate the age of the Gran Sabana. These fires occurred during the low glacial maximum (LGM) and were likely promoted by climate change.

Characteristics and geological significance of carbon and oxygen isotopes of the Permian Lucaogou Formation dolomite in the southern Junggar Basin, northwestern China

Anomalously positive δ13C values in ancient dolomites are very rare. Dark gray argillaceous rocks of the lacustrine sediments of the Permian Lucaogou Formation are important source rocks in the Junggar Basin, and dolomites of varying thicknesses from 10 cm to 150 cm are often interspersed in argillaceous rocks. Based on the study of petrographic sections, this paper systematically analyzes the carbon and oxygen isotopes of dolomite and discusses the causes of abnormally high carbon isotope values and their significance in reconstructing paleoenvironment and paleoclimate. The results show that carbon isotope values are abnormally high in the dolomite of Lucaogou Formation, and the δ13C value is between +3.2 ‰ PDB and +19.6‰ PDB, with an average of +9.7‰ PDB. The δ18O values range from -17.4‰ PDB to -1.7‰ PDB, with an average of -8.1‰ PDB. From the lower part to the upper part of the Lucaogou Formation, the carbon isotope value gradually increases and becomes increasingly positive, and the carbon isotope of the dolomite deposited near the shore is more positive than that of the dolomite deposited far from the shore. The anomalously positive δ13C of the dolomite is mainly caused by microbial methanogenesis, with some contribution from evaporation. Microorganisms are mainly distributed at the redox interface. Evaporation controls the salinity and fluctuation of the redox interface in sedimentary water. The positive deviation difference in carbon isotopes between nearshore and offshore sedimentary dolomites may be related to the location of the redox interface during deposition. Together, the petrographic features and carbon and oxygen isotope signatures of the sections reflect the gradual evolution of the paleolake from a hydrologically open environment to a hydrologically closed one and the possible transition of the paleoclimate from a relatively warm to an arid condition, which is possibly a geochemical response to global climate change in the Permian period.

Facies architecture, pedogenesis and palynology of the Olenekian dryland setting – A sedimentary record of Early Triassic climate oscillations in the SE Germanic Basin

The Early Triassic period was characterised by significant climatic perturbations driven by generally high global temperatures. Several significant shifts in the stable carbon and oxygen isotopes were recognised in the marine settings in the Olenekian age deposits that were linked to short-lasting but relatively high-amplitude climatic events. The record of these events in the continental strata is far less understood due to the stratigraphic incompleteness of such deposits. However, in the Holy Cross Mountains (Poland), the Olenekian continental deposits are well preserved, and sedimentation was relatively continuous, making them an ideal candidate for studying the effects of climate changes and their preservation in continental settings. As such, sedimentological analysis of five wells and one outcrop (over 530 m logged in total), integrated with new and legacy palynological data, allowed the reconstruction and dating of major steps in the palaeoenvironmental evolution of the SE part of the Central European (Germanic Basin), and its comparison with the marine-based climatic models for the Early Triassic. The lower and middle Olenekian stage is represented by fine-grained deposits of dry floodplain interbedded with sandstones deposited within fluvial distributary channels and terminal splays. The palaeosols are mainly represented by aridisols (calcisols), indicating a relatively dry, though not extreme, climate as some water was necessary to support relict plant cover. Towards the mid-Spathian times, the climate became more humid - lacustrine deposits appeared, and palaeosols displayed features of an elevated water table (gleyed vertisols and inceptisols). Frequent storms and floods also affected the lacustrine sedimentation, reflecting volatile climatic conditions. In the late Spathian time, continental sedimentation continued, and the dominance of vertisols and more stacked fluvial channels in the sequence is linked with an increased seasonality, with more pronounced humid seasons. The continental setting lasted until the latest Spathian time, when a marine transgression occurred, marking a new phase in the basin development.

Post-glacial stratigraphy and late Holocene record of great Cascadia earthquakes in Ozette Lake, Washington, USA

Ozette Lake is an ~100-m-deep coastal lake located along the outer coast of the Olympic Peninsula (Washington, USA); it is situated above the locked portion of the northern Cascadia megathrust but also relatively isolated from active crustal faults and intraslab earthquakes. Here we present a suite of geophysical and geological evidence for earthquake-triggered mass transport deposits (MTDs) and related turbidite deposition in Ozette Lake since ca. 14 ka. Comprehensive high-resolution bathymetry data, seismic reflection profiles, and sediment cores are used to characterize the post-glacial stratigraphic framework and examine paleoseismic evidence in the lacustrine sediments. Stacked sequences of MTDs along the steep eastern flanks of the lake appear to grade basin-ward from thick, chaotic, blocky masses to thin, parallel-bedded turbidite beds. The discrete turbidite event layers are separated by fine-grained (silt and clay) lake sedimentation. The event layers are observed throughout the lake, but the physical characteristics of the deposits vary considerably depending on proximity to primary depocenters, steep slopes, and subaqueous deltas. A total of 30–34 event deposits are observed in the post-glacial record. Radiometric dating was used to reconstruct a detailed sedimentation history over the last ~5.5 k.y., develop an age model, and estimate the recurrence (365–405 yr) for the most recent 12 event layers. Based on sedimentological characteristics, temporal overlap with other regional paleoseismic chronologies, and recurrence estimates, at least 10 of the dated event layers appear to be sourced from slope failures triggered by intense shaking during megathrust ruptures; the recurrence interval for these 10 events is 440–560 yr. Thus, Ozette Lake contains one of the longest and most robust geological records of repeated shaking along the northern Cascadia subduction zone.

Redox conditions influence the chemical composition of iron-associated organic carbon in boreal lake sediments: A synchrotron-based NEXAFS study

The global carbon and iron cycles are intimately linked as redox-sensitive iron oxides readily bind organic carbon in a variety of environmental settings, including marine and lacustrine sediments. While these iron-organic carbon complexes sequester vast quantities of organic carbon, the composition of the organic matter within them remains unknown for lacustrine environments. Here we present C K1s and Fe L3,2 edge Near Edge X-ray Absorption Fine Structure (NEXAFS) spectra of surface sediments and authigenic iron complexes from adjacent basins of a pristine boreal lake located in Québec, Canada, with contrasting oxygen exposure regimes. We demonstrate differences in organic carbon speciation in sediments from both basins, as well as co-localization of organic carbon and iron on a sub-micron scale in 100 nm thick samples. Differences in redox cycling across these two basins allow for a direct comparison of the effect of oscillating redox conditions on the composition of organic carbon sequestered by iron. Our results suggest that reactive organic molecules, which may be polysaccharides, were found preferentially associated with iron in the perennially oxic sediments compared to more phenol rich organics in the seasonally anoxic sediments, highlighting the importance of iron oxides in the protection and preservation of labile organic compounds. Traces of aliphatic carbon were observed in sediments from the anoxic basin, alongside carboxyl and aromatic functionalities. This carboxyl-rich aliphatic material could possibly interact with the sediment mineral matrix either through a ligand exchange mechanism between the mineral phases and the carboxyl functionalities, or via non-specific hydrophobic interactions involving the aliphatic moieties. Finally, our work also shows that OC:Fe ratios should be used with caution when inferring a binding mechanism between OC and iron oxides.

Temperature changes of the Mid-Late Holocene transition in North China and their implications for regional cultural succession

Evaluating the influence of temperature on cultural successions in North China during the Mid-Late Holocene transition (MLHT) is a significant research problem. We used a lacustrine sedimentary profile (BG-2019) from Lake Baiyangdian, in the hinterland of the North China Plain, to quantitatively reconstruct temperature changes during the MLHT, using branched glycerol dialkyl glycerol tetraethers (brGDGTs). We then integrated this record with selected quantitative paleotemperature records from North China to explore the effects of temperature change on the evolution of Neolithic cultures in this region. The results show that the mean annual temperature (MAT) in the hinterland of the North China Plain during the MLHT averaged ∼15.7 °C (∼3.6 °C higher than today); and that three significant cooling events occurred (the 5.3 ka event, 4.8 ka event, and 4.2 ka event), at ∼5300-5100 cal yr BP, 4800 cal yr BP, and ∼4500-4300 cal yr BP, respectively, with cooling between −2.1 °C and −3.4 °C. Integration of our results with other regional quantitative paleotemperature records shows that these three cooling events are well documented in North China, with spatial consistency in their magnitude and onset of cooling. These cooling events are temporally correlated to two cultural transitions in North China: the cooling event at ∼5300-4800 cal yr BP corresponds to the decline of the Yangshao culture in the Central Plains region, and the decline of the Hongshan culture in the Yanliao region, which evolved into the Xiaoheyan culture. Additionally, we suggest that the cooling event at ∼5300-4800 cal yr BP, combined with the weakening of the summer monsoon, contributed to the end of the Yangshao culture and the rise of the Longshan culture in the Central Plains region, and that it accelerated the end of the Xiaoheyan culture and the rise of the Xiajiadian Lower Culture in the Yanliao region.

Cyanobacteria decay alters CH4 and CO2 produced hotspots along vertical sediment profiles in eutrophic lakes

Cyanobacteria-derived organic carbon has been reported to intensify greenhouse gas emissions from lacustrine sediments. However, the specific processes of CH4 and CO2 production and release from sediments into the atmosphere remain unclear, especially in eutrophic lakes. To investigate the influence of severe cyanobacteria accumulation on the production and migration of sedimentary CH4 and CO2, this study examined the different trophic level lakes along the middle and lower reaches of the Yangtze River. The results demonstrated that eutrophication amplified CH4 and CO2 emissions, notably in Lake Taihu, where fluxes peaked at 929.9 and 7222.5 μmol/m2·h, mirroring dissolved gas levels in overlying waters. Increased sedimentary organic carbon raised dissolved CH4 and CO2 concentrations in pore-water, with isotopic tracking showing cyanobacteria-derived carbon specifically elevated CH4 and CO2 in surface sediment pore-water more than in deeper layers. Cyanobacteria-derived carbon deposition on surface sediment boosted organic carbon and moisture levels, fostering an anaerobic microenvironment conducive to enhanced biogenic CH4 and CO2 production in surface sediments. In the microcosm systems with the most severe cyanobacteria accumulation, average CH4 and CO2 concentrations in surface sediments reached 6.9 and 2.3 mol/L, respectively, surpassing the 4.7 and 1.4 mol/L observed in bottom sediments, indicating upward migration of CH4 and CO2 hotspots from deeper to surface layers. These findings enhance our understanding of the mechanisms underlying lake sediment carbon emissions induced by eutrophication and provide a more accurate assessment of lake carbon emissions.

A historical Llewellyn Ivor Price fossil fish collection from the Middle to Late Miocene of the Brazilian Amazon

Brazilian Miocene fluvial and lacustrine deposits are mainly found in the southwestern Amazon basin in the state of Acre, where fossiliferous sections from the Middle to Late Miocene of the Solimões Formation (Fm.) emerge in riverbanks during the dry season and low river-water level periods. The Solimões Fm. is notable for its high fossil vertebrate diversity (Myliobatiformes, Siluriformes, Ceratodontiformes, Osteoglossiformes, Characiformes, Acregoliathidae, Squamata, Crocodilia, Testudines, Suliformes, Rodentia, Notoungulata, Litopterna, Astrapotheria, Proboscidea, Didelphimorphia, Pilosa, Sirenia, Cetacea, Primates, Chiroptera, and Artiodactyla) deposited in the paleo-Amazon context. This fossiliferous faunal assemblage reflects the major geological and paleoclimatic Miocene/Pliocene transition events that triggered the greatest extinction of megafauna and other groups of animals in the Paleo-Amazon and, alongside the establishment of the largest Amazon transcontinental river in South America, led to species turnover and the diversity explosion to current levels. Paleontological expeditions carried out between 1950s and 1970s at Solimões Fm. outcrops along the Acre and Upper Juruá rivers allowed the recovery of an extraordinary vertebrate paleontological collection, albeit published in fragmentary contributions. Despite supporting the largest continental fish fauna, comprising ca. 2400 valid extant species, the Amazon hydrographic system harbors a still poorly known fossil ichthyofauna. This study describes a fossil fish assemblage from the Solimões Fm. for the first time based on high accuracy data acquired by improved microCT techniques, computerized systems, and examinations of the best recent and fossil fish collections. This fish assemblage is employed to elucidate ancestral Amazonian fauna paleodiversity and paleoenvironmental context interpretations and explore the elements that led to coeval paleo-ichthyofauna from the northwestern paleo-Amazon region. Miocene species Phractocephalus (†P. acreornatus and †P. nassi) are proposed as fossil guides.

Microbial and hydrothermal dolomite formation in Early Cretaceous lacustrine sediments in Yin'e Basin: Insights from petrology and geochemistry

Dolomite is widely present in geological history, but its origin has always been a prominent problem that troubles sedimentologists. For lacustrine dolomite, current research has not yet provided a reliable explanation for its complex genesis mechanism. The Early Cretaceous lakes in Northwest China host various morphological dolomites, providing valuable materials for exploring the origin of dolomites. According to their petrological and mineralogical characteristics, it can be divided into thick laminated dolomite, thin laminated dolomite, dolomitic mudstone, and vein dolomite. The ratios of trace elements and rare earth elements show that these dolomites precipitated in a brackish–suboxic environment. The high δ13C values (>8 ‰VPDB) of thick laminated dolomite and some thin laminated dolomite suggest the involvement of methane-producing microorganisms in the precipitation of dolomite, and the appearance of microscale/nanoscale spherical dolomite aggregates and the dispersed organic matter around dolomite particles jointly confirm that microbial-mediated biological activity promotes dolomite precipitation. The dolomite stoichiometry (mole % MgCO3) confirms that thick laminated dolomite was deposited in a restricted shallow water environment, while dolomitic mudstone is mainly deposited in relatively open water areas. The thin laminated dolomite in the shale laminae represents short-term or seasonal climatic and environmental fluctuations. In addition, some carbonate minerals of dolomitic mudstone in shallow water environment recrystallized by post-depositional hydrothermal effect, resulting in δ18O value decreased (<−10 ‰VPDB). The vein dolomite is characterized by high rare earth content and low δ13C and δ18O values, and its Sr isotope (0.712894 ± 0.000374) values reflect that the hydrothermal fluid may have been formed by the mixing of infiltrating lake water and crustal magmatic water. According to the characteristics of fluid inclusions, it is inferred that the hydrothermal fluid has the characteristics of low temperature (108.3 °C–159.8 °C), medium salinity (3.5 wt%–14.3 wt% NaCl) and high density (0.95–1.00 g/cm3). The microbial mediation and tectonic hydrothermal fluids play an important role in the formation of the Early Cretaceous lacustrine dolomite.

The northernmost Polish Eemian palaeolake near Łęczyce − Stratigraphic and palaeoecological implications for a MIS 6a − MIS 5d sediment record

We report the results of high-resolution multi-proxy studies of a 10 m thick sedimentary profile from Łęczyce, Poland. It reveals a continuous lacustrine succession from the Eemian Interglacial. On this basis, we have distinguished seven sedimentary units (U7a-U7f) and ten local palynological zones (LPAZ Lec 1 − Lec 10), revealing the evolution of the lake from the moment of dead-ice melting, through the continuous filling of the lake basin with organic mud, to the final stage of shallowing and transformation into a peat bog. This northernmost known Eemian site was investigated for the first time, therefore, the reconstructed changes in local conditions were correlated with global changes from the final phase of the penultimate glaciation through the Eemian Interglacial to the beginning of the last glaciation. The results show that the melting of dead ice blocks at this site was delayed compared to central Poland, with lacustrine processes starting as glaciolimnic sedimentation. Furthermore, the delayed start of vegetation development around the lake resulted in the absence of a Pinus-Betula-Ulmus E2 level. During the Eemian, local conditions were generally stable, and sedimentation took place in a relatively deep basin with well-defined epilimnion and hypolimnion zones. Climatic instability at the end of the Eemian resulted in reduced vegetation cover. During the first climatic deterioration in the Weichselian (presumably the Herning Stadial), lacustrine sedimentation was reduced and the deposition of fine-grained mineral material predominated. This was followed by the complete drying out of the lake and the development of soil formation. The subsequent climatic warming (Brørup Interstadial?) recorded in the uppermost part of the profile (U7f) was characterised by the plant community Lec 10 (Carpinus-Corylus-Picea) and was presumably warmer than commonly assumed. Multi-proxy studies show that the development of the lake was more similar to that of southern Scandinavia than to that of Poland.

Carboniferous–Permian interglacial warming and volcanism temporally linked to the world's oldest alkaline lake deposit of the Fengcheng Formation, NW China

In addition to being an important lacustrine hydrocarbon source rock, the Fengcheng Formation possesses well-preserved sodium‑carbonate evaporite units and tuff beds. Known ancient alkaline salt-lake deposits bearing sodium‑carbonate evaporite minerals like the Late Paleozoic Fengcheng Formation are limited beyond the modern day. However, hitherto the absolute age of the alkaline lacustrine Fengcheng Formation of the Junggar Basin (China) is debated (Late Carboniferous and/or Early Permian), and therefore its temporal link to a specific stage of the Late Paleozoic Ice Age (LPIA) remains unclear. Here, new ReOs geochronology demonstrates that the Fengcheng Formation is predominately of Late Carboniferous-age (304.4 to 297.3 Ma), and therefore its deposition coincides with the interglacial climate warming interval between glaciation C4 and P1 of the LPIA and not the younger interglacial stages as previously proposed. The ReOs isotope systematics indicate that the lake water column during the deposition of the Fengcheng Formation had a relatively unradiogenic Os (187Os/188Os, Osi) isotope composition (0.32 to 0.36), which is in contrast to the typical radiogenic Osi recorded for lacustrine deposits throughout geological time. The unradiogenic Osi for the Fengcheng Formation ties the source of the Os in the lake to the weathering of adjacent mafic volcanic rocks and/or hydrothermal input (∼0.13). As a result, the penecontemporaneous relationship to the Late Paleozoic interglacial climate warming (causing enhanced evaporation) coupled with weathering of volcanic rocks and/or hydrothermal fluid input into the lake is considered to have been mechanistic in the formation of an alkaline salt lake dominated by sodium and carbonate.

Paleoclimate, paleoenvironment, and human impact over the last 400 years based on lipid biomarkers from Lake Höglwörth, Germany

Lipid biomarkers are valuable proxies for reconstructing paleoclimate and paleoenvironmental changes as well as human impact. However, little attention has been paid on evaluating how the combination of biomarkers can be used to reconstruct various aspects of local paleoenvironmental conditions. This study presents a suite of lipid biomarker records from a sediment core from Lake Höglwörth, southern Germany, covering the past 400 years. Compound-specific hydrogen isotopic compositions (δD) of terrestrial n-alkanes (n-C29-alkane) and n-alkanoic acids (n-C30-acid) indicate minor changes in isotopic composition of precipitation. The δD of n-C22-acid is interpreted to record the isotopic composition of the lake water and evaporative enrichment, which drops after 1700 CE, coinciding with the construction of a mill and the related rerouting of a creek into Lake Höglwörth. The δD of n-C25-alkane is also enriched but decoupled from the reconstructed isotopic composition of precipitation and lake water. Therefore, we suggest that δD of n-C25-alkane reflects the leaf water isotopic composition of Sphagnum, which is present in the catchment and undergoes transpirative enrichment. Both short-chain compounds have become more enriched over the last century, maybe related to increasing temperature associated with anthropogenic climate warming. The faecal biomarkers record the changes in human population, partly related to the history of the local Monastery, the World Wars I and II as well as the intensive farming after the mid-20th century. Polycyclic aromatic hydrocarbons (PAHs) reveal a significant change in combustion activities associated with human activities such as the industrial revolution, biomass burning, and environmental cleanup as well as the implementation of emission standards. Our study demonstrates that the combination of plant wax compounds, faecal biomarkers, and PAHs from lacustrine sediment serves as a valuable tool to reconstruct and distinguish various aspects of paleoclimate and paleoenvironmental changes including human impacts.

Stability of sedimentary organic matter: Insights from molecular and redox analyses

Sedimentary organic matter (SOM) affects the stability of the aquatic carbon pool. The degradation process of SOM is complex for its multifaceted composition. The concentration and properties of SOM affect its steady state, yet the transformation processes of SOM in lakes remain unclear. Here we show the molecular and redox perspectives of SOM stability in polluted sediments with high organic matter content and diverse vegetation. We find significant differences in carbon fractions across various sites. The origin of the organic matter, determined using excitation-emission matrix spectra, influences the consistency of organic matter composition and biochemical degradation in lacustrine sediment. We also observe that sulfur-containing substances decrease carbon chain length and reduce organic matter stability. Fourier-transform ion cyclotron resonance mass spectrometry shows that sulfur-containing substances decrease the degree of saturation and cause reduction. In contrast, nitrogen-containing compounds increase the modified aromaticity index and humin content, enhancing organic carbon complexity and stability (p < 0.05). These results complement the characteristics and transformations of SOM. In a broader perspective, this study contributes to laying the foundation for understanding SOM stability in the carbon cycle and its future effects.

Environmental magnetic records derived from lacustrine sediments in the Western Guangdong Province, China: Implications for Late-Holocene climatic/environmental changes

The western Guangdong Province (WGDP) in China, influenced by both the East Asian and the Indian summer monsoon, is a pivotal region for exploring the Asian summer monsoon (ASM) evolution. So far, there still lacks detail studies on late Holocene climatic/environmental changes here. In this study, multiple magnetic parameters were measured on the lake sediments of Hedong section in this area. Results indicated a dominance of pseudo-single-domain detrital (titano-)magnetite or maghemite mixed with paramagnetic and anti-ferromagnetic minerals in sediments, and the impacts of authigenic greigite, bacterial activity, post-depositional dissolution, and dilution effects were trivial. Changes in rainfall-induced surface erosion intensity were determined as a role in sediment magnetic properties. Intensified surface erosion deduced by increased rainfall favored enhanced concentrations and more coarse-grained magnetic minerals in sediments, and vice versa. Thus, the magnetic parameters can be used to reflect varying ASM strength in the past ~4300 years. They revealed four relatively humid (strengthened ASM) (i.e., 4300–4000 cal. yr BP, 3500–3130 cal. yr BP, 2640–1950 cal. yr BP, and 1250–850 cal. yr BP), and three dry periods (weakened ASM) (i.e., 4000–3500 cal. yr BP, 3130–2640 cal. yr BP, and 1950–1250 cal. yr BP) which coincided with the Bond events 3, 2, and 1 respectively. In combination with the three significant cycles (i.e., 1250-, 75-, and 65-year) revealed by spectral analysis on SIRM record, we inferred both the external forcing (e.g., solar activity) and internal hemispheric-scale atmospheric processes (e.g., ENSO, North Atlantic Oscillation) have played an integral role in late Holocene climate changes in the study region.

Presence and implications of petrogenic organic carbon in High Himalayan Crystalline lake sediment

AbstractTwelve lacustrine sediment samples from a relict lake in the Kalla Glacier valley were co-dated using AMS radiocarbon (14C) and infrared stimulated luminescence (IRSL) dating methods. In general, the radiocarbon ages of bulk organic matter were older by a minimum of 1500 years compared to (age depth) modeled luminescence ages after fading corrections. This is observed for the first time in the lake sediments of High Himalayan Crystalline zone. A combination of lipid n-alkane data, Raman spectra and geochemical proxies suggested that this was due to ancient organic carbon (OCancient) that is a mixture of pre-aged (OCpre-aged) and petrogenic (OCpetro) organic carbon within older glacial moraine debris that served as sediment source to the lake. Raman spectra suggest the presence of moderate to highly graphitized OCpetro in all the profile samples. The OCpetro contributed 0.064 ± 0.032% to the sediment and the lake stored 2.5 ± 0.7 Gg OCpetro at variable rates during the last 16 kyr, with the mean burial flux 160 kg OCpetro yr−1. This study implies (1) employing another independent dating method in addition to radiocarbon method using bulk sediment organic matter, if the carbon content is low, to observe any discrepancy, and (2) a need to investigate on the fate of OCpetro as many such small lakes become relict in this region.

To rush into the secret house of death: The fate of a Tournaisian plant

Tournaisian-age failure of marginal lacustrine sediments, and their bulk collapse into an inland rift-basin lake in the Moncton Subbasin, Canada, led to the entrainment of rare, almost complete, three-dimensionally preserved non-woody trees. Preservation of these unique fossils from the Albert Formation was a consequence of contemporaneous seismicity. Synsedimentary structures include an array of soft-sediment deformational features and a field of cross-cutting sand boils indicating multiple seismic shocks &amp;gt;4.6 Mw. This tectonically controlled event, entombing trees whose novel growth form is both evolutionarily and ecologically transitionary and unlike other Paleozoic plants, is a one-off in the paleobotanical record.