Lacustrine Carbonate Research Articles

Lacustrine carbonate towers of Lake Abhe, Djibouti: Interplay of hydrologic and microbial processes

Lake Abhe, located at the triple junction between the Red Sea, Gulf of Aden, and Main Ethiopian rift trends, is a hypersaline and alkaline closed lake that is known for its exposures of massive carbonate chimneys on the flat-lying sediments of the lake's eastern margin. This study describes the morphological, textural, and petrographic characteristics of these chimneys at the basin- to microscopic-scale in order to constrain the carbonate depositional system in the context of basin hydroclimate history. Chimneys occur in three main fields and are assessed according to 1) large-scale (>5 m) morphological variations, 2) meso-scale (cm to <5 m) textures, and 3) micro-scale (<1 cm) fabrics. The dominant chimney fabric is a porous crystalline framework of trigonal prismatic and dendritic calcite crystals that locally contain spherulites, sickle-cell calcite fabrics, and entombed microbial cocci. In addition to the crystalline chimneys, other carbonate sediments include stromatolitic crusts composed of microdigitate laminated columns dominated by crystalline fan microfabrics, as well as carbonate-rich mudstones and relatively rare, localized, carbonate-rich diatomites. Chimneys are interpreted to form primarily as products of mixing between hydrothermal sublacustrine springs and lake waters during lake highstand intervals, while stromatolitic crusts are interpreted to form during lowstand lake levels. Our interpretation of mixing processes is supported by the δ18O composition of chimney calcite, which is representative of lake water and area hot spring endmembers. The observation of stromatolitic crusts with more positive values of δ13C and δ18O than crystalline chimneys indicates that crusts formed during periods of high evaporation and low lake level. Crusts also contain Mg-silicate minerals, which are not present in crystalline chimneys, and further support the interpretation of lowstand depositional conditions. Although the age of chimney formation is not well constrained, evidence from seismic reflection data suggests a pattern of chimney formation during lake level rise and highstand times, followed by lake level fall, subaerial exposure and weathering that occurred at several times throughout the Late Pleistocene and Holocene.

The fluctuation of warm paleoclimatic controls on lacustrine carbonate deposition in the Late Cretaceous (late Santonian), Southern Songliao Basin, Northeast China

The fluctuation of warm paleoclimatic controls on lacustrine carbonate deposition in the Late Cretaceous (late Santonian), Southern Songliao Basin, Northeast China

Holocene Hydroclimatic Reorganizations in Northwest Canada Inferred From Lacustrine Carbonate Oxygen Isotopes

AbstractSub‐centennial oxygen (δ18O) isotopes of ostracod and authigenic calcite from Squanga Lake provides evidence of hydroclimatic extremes and a series of post‐glacial climate system reorganizations for the interior region of northwest Canada. Authigenic calcite δ18O values range from −16‰ to −21‰ and are presently similar to modern lake water and annual precipitation values. Ostracod δ18O record near identical trends with calcite, offset by +1.7 ± 0.6‰. At 11 ka BP (kaBP = thousands of years before 1950), higher δ18O values reflect decreased precipitation−evaporation (P−E) balance from residual ice sheet influences on moisture availability. A trend to lower δ18O values until ∼8 ka BP reflects a shift to wetter conditions, and reorganization of atmospheric circulation. The last millennium and modern era are relatively dry, though not as dry as the early Holocene extreme. North Pacific climate dynamics remained an important driver of P−E balance in northwest Canada throughout the Holocene.

Climate change during the deposition of the Aptian Santana Formation (Araripe Basin, Brazil): Preliminary data based on wood signatures

This paper presents preliminary results of paleoclimatic signatures of conifer woods during the deposition of the basal Crato and topmost Romualdo members of the Santana Formation within the Tropical Equatorial Hot Arid Belt (late Aptian, Araripe Basin, Brazil). Analysis was carried out using standard thin sections, and the anatomical details were studied in transmitted light. The wood growth pattern from the lowermost laminated lacustrine carbonate level of the Crato Member was characterized by the absence of true growth rings and the common presence of wood growth interruptions, and could be linked to a tropical, equable but erratically humid environment. In an interlayered fine-to-coarse sandstone level attributed to a fluvio-deltaic interval, the wood growth pattern was homogeneous, lacking true growth rings, with weakly delineated growth interruptions over long radial distances. In this level the growth pattern could be related with a transition to a more equable tropical climate during a relatively humid period. In contrast, the wood pattern from the carbonate succession of the uppermost Romualdo Member, interpreted as a lagoon area with marine influence, showed true growth rings with abrupt ring boundaries and rings of variable width, also including frequent growth interruptions. This pattern could be linked to a monsoonal-like climate, subjected to distinct cyclical conditions and periodical droughts during the growing season.

Lacustrine carbonate lithofacies characterization, paleontological content and depositional processes in the Mayrán Basin System

Lithofacies analyses were undertaken on a suite of well-exposed carbonate deposits from the (Pliocene) Mayrán Formation, in the Mayrán Basin system, northeast Mexico to investigate the controls on carbonate lithofacies variability in a series of linked lacustrine subbasins, with a common hydrology yet very different inputs. The lacustrine carbonates contain variable proportions of production-derived components, with subordinate proportions of detrital and early diagenetic components. The lithofacies contain, inorganic and organic calcite (average 91% CaCO3), and organic matter (10.5%–13.8% average 12.6% TOC), together with minor detrital minerals. Nine sub-facies were identified: ostracod mudstone-wackestone, clotted boundstones, gastropod wackestone-packstones, oncoid wackestone-packstones, charophyte wackestone-packstones, crystalline carbonate mudstone, stromatolites, crystalline carbonate, marlstone, and associated evaporite minerals. Isotopic composition of specific components such as micritic laminations in stromatolites (δ13Ccalcite −6.3‰ and δ18Ocalcite −8.0‰), and micrititic matrix from samples in all the subbasins (δ13Ccalcite −5.7‰ and δ18Ocalcite −7.8‰), indicate that overall calcite deposition occurred in freshwater lakes. Non luminescent (e.g. charophytes) to orange dull luminescencent micrite strongly suggest in situ carbonate production. Together these processes contributed to the local production of lime mud. Additionally, microtextural evidence of scour surfaces however, indicates that occasionally the sediment was reworked and transported laterally and basinward. Fossil content and diversity composed by Limnaeidae, Physidae, and Planorbidae types, together with phosphatised bone fragments, micro-oncoids, stromatolites, microbial morphotypes, charophytes, macrophyte phytoherms, and microcodium structres, are good references for lithofacies characterization and indicators of specific paleoenvironmental conditions. Intense to moderate bioturbation (BI 1 to 4), indicates that deposition took place under predominantly oxic conditions. Significant organic matter was preserved in these lacustrine rocks, likely controlled by moderate rates of carbonate mud production. The lacustrine lithofacies were deposited in proximal and distal lacustrine settings, making possible to recognize basin scale variability. Strata staking patterns are organized into shallowing upwards cycles (0.3–2.5 m thick), which are capped either by evaporites or beds with a pedogenic overprint. Their stacking patterns reflect lake level variations which can be recognized in all the subbasins. The lithofacies architecture within each subbasin forms parasequences that overall exhibit aggradational geometries. The lithofacies and their large scale geometries also indicate deposition occurred in a series of relatively shallow (<10 m), lake systems with ramp-like margins. The aggradational stacking patterns of the carbonates and the presence of subordinate evaporites suggest that basin hydrology (water supply and precipitation/evaporation ratios) had an important influence on facies architecture and cyclicity. The Mayrán Formation lacustrine lithofacies deposited under overfilled to balance-filled lake conditions; although balance-filled conditions with an open hydrology were more likely. Overall, facies variability in the lacustrine carbonate lithofacies was controlled by basin inherited geomorphology, accommodation, and basin hydrology, which ultimately controlled clastic trapping, solute inputs, water chemistry, primary production, and lake level changes. We interpret that all these controls were largely driven by climate.

Sr isotopes in the Tortonian-Messinian Lake Bira and Gesher marshes, Northern Valleys of Israel: Implications for hydroclimate changes in East Mediterranean–Levant margins

Abstract 87Sr/86Sr isotope and Sr/Ca ratios in lacustrine carbonates were used to reconstruct the hydroclimate conditions in the watershed of Lake Bira that filled during the Tortonian-Messinian the tectonic depressions of the Northern Valleys of Israel in the East Mediterranean-Levant region. 87Sr/86Sr ratios of the Tortonian (ca. 10–8 Ma) carbonates of ∼0.7075 and the great expansion of the lake indicate wet conditions and enhanced supply of freshwater from the regional Mesozoic aquifers. Upon the transition to the Messinian period (ca. 7–6 Ma), the 87Sr/86Sr ratios in the carbonates rose to ∼0.7080–0.7085, reflecting the contribution of Sr from Sahara Desert dusts that came to comprise the regional surface cover. This contribution is also reflected in the silicate fraction of the lacustrine formations that show “granitic-crustal” 87Sr/86Sr ratios of ∼0.711. During the Messinian salinity crisis (5.9–5.6 Ma), the region became arid and Lake Bira possibly dried. Later, during the Lago Mare stage (ca. 5.5–5.3 Ma), the rainfall increased and paludal waterbodies scattered the area of the larger Lake Bira.

Depositional system and lake-stage control on microbialite morphology, Green River Formation, eastern Uinta Basin, Colorado and Utah, U.S.A.

ABSTRACT Lake-margin lacustrine carbonates of the Green River Formation, in the eastern Uinta basin of Colorado and Utah, occur interbedded with fluvial and shoreline-parallel sandstone and shale. Microbial bindstones were deposited in a saline-alkaline lake during and after the Early Eocene Climate Optimum (EECO) (52–50 million years ago) that is characterized by global hot-house conditions, elevated atmospheric CO2, and highly fluctuating climate conditions. The stratigraphic architecture, chemostratigraphy, and morphology of the microbialites and other associated carbonate beds can be related to these climatic conditions. Three facies associations are recognized in the carbonate units across the lake margin from upper littoral to lower sublittoral environments: facies association 1, delta proximal non-microbial carbonates, characterized by quartzose bioclastic, peloidal, intraclastic packstones and grainstones–rudstones, quartose peloid wackestones and sandy oil shale; facies association 2, microbialite associated non-microbial carbonates, composed of ostracod, ooilitic, peloidal packstones–grainstones and intraclastic packstones, grainstones and rudstones; and facies association 3, microbial carbonates, consisting of diverse forms of stromatolitic and thrombolitic lithofacies. Multiple scales of carbonate cyclicity are suggested by shifts of δ18O and δ13C stable isotopes and deepening-upward microbialite facies. High-frequency cycles, on the order of 1 to 5 m thickness, are characterized by positive shifts in stable isotopes and interpreted deepening trends from littoral to lower sublittoral conditions. Large-scale trends, on the order of tens to hundreds of meters thickness record long-term lake changes, including: 1) sparse microbialite deposition during initial fresh conditions in lake stage 1, with low macro-structure diversity and light δ18O and δ13C isotope values; 2) transitional lake stage 2 corresponding to moderate macro-structural diversity, large meter-scale biostromal and biohermal buildups, and a positive shift in δ18O and δ13C isotope values that suggest increasing saline and alkaline conditions; 3) a highly fluctuating lake stage 3 that contains the highest microbialite macro-structural diversity and marks the interval of heaviest δ18O and δ13C isotope values, suggesting the greatest lake restriction, and the highest salinity and alkalinity conditions; and 4) a rising lake stage 4 that marks the lowest microbialite macro-structure diversity and a reversal in trend of δ18O and δ13C isotope values, that indicate deepening and freshening conditions.

Rise of the Colorado Plateau: A Synthesis of Paleoelevation Constraints From the Region and a Path Forward Using Temperature-Based Elevation Proxies

The Colorado Plateau’s complex landscape has motivated over a century of debate, key to which is understanding the timing and processes of surface uplift of the greater Colorado Plateau region, and its interactions with erosion, drainage reorganization, and landscape evolution. Here, we evaluate what is known about the surface uplift history from prior paleoelevation estimates from the region by synthesizing and evaluating estimates 1) in context inferred from geologic, geomorphic, and thermochronologic constraints, and 2) in light of recent isotopic and paleobotanical proxy method advancements. Altogether, existing data and estimates suggest that half-modern surface elevations were attained by the end of the Laramide orogeny (∼40 Ma), and near-modern surface elevations by the mid-Miocene (∼16 Ma). However, our analysis of paleoelevation proxy methods highlights the need to improve proxy estimates from carbonate and floral archives including the ∼6–16 Ma Bidahochi and ∼34 Ma Florissant Formations and explore understudied (with respect to paleoelevation) Laramide basin deposits to fill knowledge gaps. We argue that there are opportunities to leverage recent advancements in temperature-based paleoaltimetry to refine the surface uplift history; for instance, via systematic comparison of clumped isotope and paleobotanical thermometry methods applied to lacustrine carbonates that span the region in both space and time, and by use of paleoclimate model mediated lapse rates in paleoelevation reconstruction.

In-situ U-Pb dating of Ries Crater lacustrine carbonates (Miocene, South-West Germany): Implications for continental carbonate chronostratigraphy

The Nördlinger Ries Crater lacustrine basin (South-West Germany), formed by a meteorite impact in the Miocene (Langhian; ∼14.9 Ma), offers a well-established geological framework to understand the strengths and limitations of U-Pb LA-ICPMS (in situ Laser Ablation-Inductively Coupled Plasma Mass Spectrometry) geochronology as chronostratigraphic tool for lacustrine (and more broadly continental) carbonates. The post-impact deposits include siliciclastic basinal facies at the lake centre and carbonate facies at the lake margins, coevally deposited in a time window of >1.2 and <2 Ma. Depositional and diagenetic carbonate phases (micrites and calcite cements) were investigated from three marginal carbonate facies (Hainsfarth bioherm, Adlersberg bioherm and Wallerstein mound). Petrography combined with C and O stable isotope analyses indicate that most depositional and early diagenetic carbonates preserved pristine geochemical compositions and thus the U-Pb system should reflect the timing of original precipitation. In total, 22 U-Pb ages were obtained on 10 different carbonate phases from five samples. The reproducibility and accuracy of the U-Pb (LA-ICPMS) method were estimated to be down to 1.5% based on repeated analyses of a secondary standard (speleothem calcite ASH-15d) and propagated to the obtained ages. Micrites from the Hainsfarth, Adlersberg and Wallerstein facies yielded ages of 13.90 ± 0.25, 14.14 ± 0.20 and 14.33 ± 0.27 Ma, respectively, which overlap within uncertainties, and are consistent with the weighted average age of 14.30 ± 0.20 Ma obtained from all the preserved depositional and early diagenetic phases. Data indicate that sedimentation started shortly after the impact and persisted for >1.2 and <2 Ma, in agreement with previous constraints from literature, therefore validating the accuracy of the applied method. Later calcite cements were dated at 13.2 ± 1.1 (nw=2), 10.2 ± 2.7 and 9.51 ± 0.77 Ma, implying multiple post-depositional fluid events. This study demonstrates the great potential of the U-Pb method for chronostratigraphy in continental systems, where correlations between time-equivalent lateral facies are often out of reach. In Miocene deposits the method yields a time resolution within the 3rd order depositional sequences (0.5–5 Ma).

Triple oxygen and clumped isotopes in modern soil carbonate along an aridity gradient in the Serengeti, Tanzania

The isotopic composition of paleosol carbonates is used extensively to reconstruct past vegetation, climate, and altimetry, but poor constraints on soil evaporation and temperature have limited the utility of oxygen isotopes in the studies. Recent advances in carbonate clumped isotope thermometry (TΔ47) allow for independent controls on temperature, but the influence of evaporation remains unresolved. However, the sensitivity of 18O-17O-16O distributions to kinetic fractionation makes it possible to use triple oxygen isotopes (Δ′17O) to track evaporation in water. Recent work shows the sensitivity of Δ′17O to evaporation in lakes and lacustrine carbonates, but little is known about variation of Δ′17O in soil carbonates and their potential to track evaporation. For this study, we sampled soils across an aridity gradient in the Serengeti, Tanzania to evaluate how soil carbonate Δ′17O tracks soil water evaporation. Modern soil carbonates were collected from 11 sites across a transect of the Serengeti Ecosystem where mean annual precipitation and aridity index range from 499 to 846 mm yr−1 and 0.33 to 0.55, respectively. δ13C values range from −2.7 to 1.8‰ and reflect C4 dominated grasslands, whereas δ18O values of soil carbonates vary by ∼8‰ along a gradient in aridity. TΔ47 from these soil carbonates average 23°C (1σ± 4°C), which does not vary significantly across sites or with depth, likely due to minimal annual variation in temperature at the equator. Using these temperatures for each carbonate, reconstructed δ18O values of soil water are up to 6‰ higher than δ18O values of local precipitation and springs, indicating considerable soil water evaporation. The Δ′17O values of these soil carbonates range from −162 to −106 per meg and decrease as both aridity and δ18O values increase. Our results support the hypothesis that soil water evaporation drives the variance in δ18O and Δ′17O of soil carbonate in arid climates, demonstrating the potential for soil carbonate Δ′17O to track paleoaridity and constrain interpretations of paleosol carbonate δ18O records.

A multi‐scale approach to laminated microbial deposits in non‐marine carbonate environments through examples of the Cenozoic, north‐east Iberian Peninsula, Spain

AbstractThis contribution focusses on stromatolites and oncolites as tools to seek diverse environmental and climate information at different temporal scales. The scales are: (a) Low frequency, dealing with macroscopic and megascopic scales, and (b) high frequency, involving calendar and solar frequency bands. Two depositional environments are used for this purpose: (a) Fluvial and fluvial–lacustrine, which can develop under high to moderate gradients, and in low‐gradient conditions, and (b) lacustrine, subject to low‐gradient, hydrologically closed lake conditions. Several current and ancient examples in the Iberian Peninsula allow high‐frequency and low‐frequency analyses. Within the wedge‐shaped depositional units that fill the high‐ to moderate‐gradient, stepped fluvial systems, stromatolites form half domes and lenticular bodies, commonly at the wedge front. Oncolites are uncommon. These stromatolites developed in moderate to fast‐flowing water in stepped cascades and rapids. Their geometry and extent reflect the topography of the bedrock and later ongoing growth. In low‐gradient fluvial and fluvial‐(open) lacustrine systems the depositional units are tabular, low‐angle wedge‐shaped and lenticular and have great spatial facies variability. The dominant oncoid and coated‐stem limestones form gently lenticular stacked bodies, developed in wide, low to high‐sinuosity channels within wide tufaceous palustrine areas and small lakes. In the Ebro Basin saline carbonate lacustrine systems, stromatolites form thin planar to domed and stratiform bodies and are associated with muddy‐grainy laminated carbonates and very rare oncolites, together forming ramp‐shaped units that represent the inner fringes of high lake‐level deposits. This geometry reflects low‐gradient lake surface and shallow water conditions. Textural and structural features allow different ranks of laminae and types of lamination to be distinguished. Texture, together with the δ13C and δ18O values of consecutive laminae, are useful in distinguishing environmental and climate changes operating over different time spans. Periodicity analysis of lamination can help to discern any temporal significance in the lamination.

Sedimentology and Miocene-Pliocene depositional evolution of the stream-dominated alluvial fan deposits at circum-Sultandağları region

Yalvaç and Ilgın basins surrounding the Sultandağları opened due to orogenic collapse in the early Miocene. The NW-SE trending Çakırçal and Akşehir Faults, forming boundaries with these basins, caused both opening of the basins and uplifting of the Sultandağları. During the Miocene-Pliocene period, alluvial fans fed from the Sultandağları developed on the basin margins, while lacustrine carbonate and clastic depositions occurred in the basin's interior. Alluvial fan sediments are laterally and vertically transitional with lacustrine sediments and alternate several times in the sequence. Alluvial fans, widespread in the region, consisting of "debris flow", "high density stream flood", "braided river" and "meandering river" deposits. Fan deposits that pass from the high-energy fluvial facies at the basin margin to the low-energy fluvial facies towards the basin interior have been interpreted as "stream-dominated alluvial fan deposits". Age data obtained from the fan deposits of the Yalvaç and the Ilgın basins show that the Sultandağları concurrently feeds the alluvial fans on both flanks. Alluvial fan deposition around the Sultandağları occurred under the control of tectonic and climatic processes. Tectonism led to the formation of basins and the creation of source areas. Simultaneously, the climate maintained the streams to be perennial by precipitation, thus proving a continuous sediment supply to the basins. Tectonism and climate-controlled base-level changes determined the quantity of sediments carried to the basin from the source area, causing regressive or transgressive developments.

Coeval primary and diagenetic carbonates in lacustrine sediments challenge palaeoclimate interpretations

Lakes are sensitive to climate change and their sediments play a pivotal role as environmental recorders. The oxygen and carbon isotope composition (δ18O and δ13C) of carbonates from alkaline lakes is featured in numerous studies attempting a quantitative reconstruction of rainfall, temperature and precipitation-evaporation changes. An often-overlooked challenge consists in the mineralogically mixed nature of carbonates themselves. We document a large variability of carbonate components and their respective distinct δ18O and δ13C values from sediments of Lake Van (Turkey) covering the last 150 kyr. The carbonate inventory consists of primary (1) inorganic calcite and aragonite precipitating in the surface-water, (2) biogenic calcite ostracod valves; and post-depositional phases: (3) dolomite forming in the sediment, and previously overlooked, (4) aragonite encrustations formed rapidly around decaying organic matter. We find a systematic relation between the lithology and the dominant deep-water carbonate phase formed recurrently under specific hydrological conditions. The presence of the different carbonates is never mutually exclusive, and the isotopic composition of each phase forms a distinctive cluster characteristic for the depth and timing of their formation. Our findings stretch the envelope of mechanisms forming lacustrine carbonates and highlight the urge to identify and separate carbonate components prior to geochemical analyses.

Spring origin of Eocene carbonate mounds in the Green River Formation, Northern Bridger Basin, Wyoming, USA

AbstractModern and ancient lacustrine carbonate build‐ups provide uniquely sensitive sedimentary and geochemical records for understanding the interaction between tectonics, past climates, and local and regional scale basin hydrology. Large (metre to decametre), well‐developed carbonate mounds in the Green River Formation have long been recognized along the margins of an Eocene lake, known as Lake Gosiute. However, their mode of origin and significance with respect to palaeohydrology remain controversial. Here, new sedimentological, Sr isotope data and structural evidence show that significant spring discharge led to the formation of a decametre size complex of shoreline carbonate mounds in the upper Wilkins Peak Member of the Green River Formation at Little Mesa and adjacent areas in the Bridger Basin, Wyoming, USA. Sedimentological evidence indicates that spring discharge was predominantly subaqueous but was, at times, also subaerial, which produced tufa cascades and micro‐rimstone dam structures. The 87Sr/86Sr ratios measured from these subaerial spring deposits are less radiogenic (87Sr/86Sr = 0.71040 to 0.71101) than contemporaneous palaeolake carbonates (87Sr/86Sr = 0.71195 to 0.71561) because their parent groundwaters likely interacted with less‐radiogenic Palaeozoic carbonate. Calcite‐cemented sandstone cones and spires (87Sr/86Sr = 0.71037 to 0.71057) in the Wasatch Formation directly below the spring deposits suggest that groundwaters derived from Palaeozoic carbonates preferentially flowed along thrust faults. These results imply that high spring discharge coincided with lake high stands of the upper Wilkins Peak Member, suggesting that recharge at the north‐west margin of the Bridger Basin contributed to Lake Gosiute’s water budget and lowered the salinity of an underfilled, evaporative lake basin. The findings of this study provide criteria for the recognition of groundwater discharge in palaeolake systems which may lead to the discovery of palaeospring systems in other ancient lake deposits.

Early Permian during the Variscan orogen collapse in the equatorial realm: insights from the Cantabrian Mountains (N Iberia) into climatic and environmental changes

We report the results of a multidisciplinary study of the early Permian (Artinskian–Kungurian) Sotres Formation of northern Spain integrating sedimentology, palaeosols, mineralogy, stable isotopes, palynology, ichnology and tectonics. This continental unit was deposited in the near-equatorial Peri-Tethyan Cantabrian Basin. Having developed in the middle of the Variscan fold belt, it is preserved within the present-day Cantabrian Mountains. Three subunits are recognised in the Sotres Formation based on tectono-stratigraphic and sedimentological data: a lower alluvial subunit, a middle carbonate lacustrine subunit, and an upper palustrine subunit. Multidisciplinary results reveal an upward change in climate from humid-subhumid conditions at the base of the formation (Artinskian) to semi-arid and arid conditions at the top of the formation (Kungurian), which may reflect global deglaciation near the end of the Late Paleozoic Ice Age and a probable northward migration of the Intertropical Convergence Zone. This general upward warming/drying climate trend was interrupted by a short-lived interval of monsoon conditions in mid-Kungurian times, which may have coincided with a pulse of global cooling. Our findings are in agreement with the climate trends reported for other central Pangaean basins. Rising CO2 levels may have been a driving factor for climate transition during this time interval. However, in our study area, which lies within the active central Variscan orogenic belt, tectonic conditions must have also played a role in driving climate change.

Tectonically conditioned record of continental interior paleoclimate during the Carnian Pluvial Episode: The Upper Triassic Los Rastros Formation, Argentina

Abstract Discerning paleoclimate parameters in depositional systems of the continental interior is challenging because the system response and stratigraphic record of climate are controlled by tectonic processes and are mediated through landscape and hydrological evolution of fluvial lacustrine systems. Climate and tectonic signals cannot be deconvolved from stratigraphic patterns alone but require additional information or data sets that directly record climate or tectonic influence. The Carnian Los Rastros Formation in northwest Argentina provides an excellent case study that integrates an appropriate range of information in a system with strong climate and tectonic signals, being deposited in part during the Carnian Pluvial Episode and spanning the active rift phase of the Ischigualasto–Villa Unión Basin. We examined the stratigraphic and spatial patterns of carbon (C) and oxygen (O) stable isotopes in lacustrine carbonates from the Los Rastros Formation in multiple parts of the basin to constrain paleohydrological conditions and paleotemperatures. Practically all C and O isotope values are characterized by negative values: δ18Ocarb –11.6&amp;#x89; and –15.7&amp;#x89; (χ average –13.1&amp;#x89;; 1σ = 1.6) and δ13Ccarb –2.6&amp;#x89; to –8.0&amp;#x89; (χ average –5.1&amp;#x89;; 1σ = 2.1), reflecting the latitude, altitude, and continentality of the lake system and its vegetated and humid catchment area. Stratigraphic patterns of stable isotope data from two different localities (Cerro Bola North and Cerro Bola South) show a change from short water-residence time to long residence time and back to short residence time. This contrasts with sedimentologic, organic geochemical, and small-scale stratigraphic patterns that indicate an overfilled lake basin, which is expected to contain a completely open-hydrology isotopic signature. Paleotemperatures calculated from marginal lacustrine carbonates show a warm and quite variable paleothermal range consonant with their continental interior position and with Global Climate Models estimates for high paleolatitudes. Warmer paleotemperatures (linked to aridity, probably smaller lake size, and less thermal mass) precede the Carnian Pluvial Episode, whereas relatively cooler paleotemperatures coincide with the Carnian Pluvial Episode (linked to humidity, probably larger lake size, and more thermal mass). Carbon and oxygen stable isotope signatures integrated with sedimentologic and physiographic information allow us to propose that tectonics, specifically, half-graben tilting during the active synrift phase, dominated over climate effects as the cause of hydrological fluctuations of this system, even during the Carnian Pluvial Episode. Without appropriate stratigraphic-tectonic context, single-proxy reconstructions of continental-interior paleoclimate can be misleading. A robust interpretation of climate effects requires characterization of tectonic effects, geomorphology, paleohydrology, and sedimentary system responses.

Mixed siliciclastic–carbonate sedimentation in an evolving epicontinental sea: Aptian record of marginal marine settings in the interior basins of north‐eastern Brazil

AbstractThe Aptian evaporitic transitional sequence (sag phase) of the Brazilian marginal basins records the first connection between the Central and South Atlantic oceans in the equatorial area. During this phase, lacustrine carbonate reservoirs and giant salt deposits developed in the southern basins of Santos and Campos, forming world‐class petroleum reservoirs. The sag succession is also well‐preserved in the interior rift basins of north‐eastern Brazil, where upper Aptian strata are represented by a continuous section. This contribution presents an interpretation of the evolution of a third‐order depositional sequence comprising lacustrine limestones, marine siliciclastic facies and evaporite deposits of the intracontinental Araripe Basin. The Lowstand Systems Tract is characterized by fluvial deposits filling accommodation generated during the syn‐rift phase. The overlying deposits comprise marine facies with preservation of dinoflagellates and marine ichnotaxa, evidencing marine deposition in bayhead delta settings. The transgressive surface is represented by limestones, including the Konservat–Lagerstätte laminites, onlapping the basement rocks. Above, tide‐dominated bay deposits with distinct subtidal, intertidal and supratidal portions are recorded. The Maximum Flooding Surface is a dark shale below foreshore to shoreface facies, marking the beginning of the Highstand Systems Tract, culminating with deposition of evaporites (gypsum and anhydrite). The stratigraphic architecture and palaeocurrents measured in different facies associations suggest that marine waters reached the basin from the south. The data unequivocally records late Aptian marine ingressions of an incipient South Atlantic Ocean over the interior basins of north‐eastern Brazil, while lacustrine conditions were still prevailing in the Pre‐Salt sag units of the Santos and Campos basins.

Stable isotopic and geochemical analysis of lacustrine carbonates from the Al-Azraq basin, Jordan: implications for paleoenvironment and paleohydrology

This study tests the geochemical basis for the paleoenvironmental history of 31 m of cored lacustrine sediments in the Al-Azraq basin, in the eastern desert of Jordan. The analysis of carbon and oxygen isotopes of carbonates distinguishes patterns of aridity and increased moisture over greater than 250 ka. Initial analysis examined the isotope data identifying oxygen isotopes of carbonate that reflect precipitation and evaporation trends which are further supported by the paleoenvironmental proxies of ICP-AES, SEM, XRD, and magnetic susceptibility. The study identifies seven environmental zones that fluctuate between phases of aridity punctuated with periods of higher moisture and occasional aeolian deposition. The covariance of δ13Ccarb and δ18Ocarb indicates the paleolake was a closed-basin system throughout its history. Sediments from 31.69 m to the surface transition from lake to increasingly arid environments with multiple wet periods and the upper most sediments reflecting aeolian deposition determined by significant fluctuations in isotopes, grain size, and element ratios. Fe/Mn demonstrates a saw-toothed pattern for the first 10 m averaging below 100. The ratio then fluctuates substantially into the 200 and 300s in Zones F and G. The ratio of Sr/Ba averages 1.46 yet fluctuates strongly in arid zones of F and G, and to as much as 43.48 in Zone C. X-ray diffraction and SEM reveal the presence of carbonate minerals including authigenic calcite, dolomite, gypsum, and celestite in arid zones. Zones B and D signal higher moisture environments with negative δ18Ocarb values and increases in clay percent. IRSL determinations provide a sequence of three ages reaching saturation limits of greater than 250 ka at 10 m. The AZ1 lacustrine basin record has significantly older sediment ages than the fringing marsh and oasis sites. Correlation with speleothem records from local and northern Israel caves generally corresponds with MIS 9, MIS 8, and MIS 6. Correlation with the youngest age could be either MIS 5, a significant wet period recognized regionally and along the basin margins, or MIS 2, but neither are strong signals in the central basin.

Model for calcite spherulite formation in organic, clay-rich, lacustrine carbonate shales (Barbalha Formation, Aptian, Araripe Basin, NE Brazil)

The formation of carbonate spherulites, recognized as part of the South-Atlantic Pre-Salt reservoir rocks, remains enigmatic. Well-chosen analogues provide insights into depositional and diagenetic conditions and the biotic versus abiotic processes that might influence or even control spherulite growth. Radial fibrous calcite spherulites of the Batateira beds in the Barbalha Formation (Aptian, Araripe, NE Brazil) formed mainly in organic and clay-rich laminite layers as nodules that grew around different nuclei, now represented by, amongst others, micrite and apatite ostracods. They vertically alternate with clays, but also carbonate laminites, which locally also contain spherulites. Characterization of the organic matter content of spherulitites (petrography, total organic carbon, vitrinite reflectance, stable isotopes) reveals TOC's of up to 30% related to the presence of mainly oil-prone alginite next to huminite, inertinite, sporinites and zooclasts. The complex mixture of clays, dominantly autogenic mixed layered illite-montmorrilonite, which alternate with lacustrine carbonates and evaporites, is diagnostic for lakes in a semi-arid environment. The occurrence of gypsum, calcitic alveolar honeycomb spherulite textures, preferential concentration of pyrite at the spherulite-matrix contact and inward spherulite perforations suggest bacterial activity under shallow and evaporitic syn-depositional conditions. Although the Barbalha spherulites formed chemically-driven in a viscous matrix, the microbial influence, mainly as lamalginite in the clayey matrix, is undeniable. The mixed organic-silicate gel catalyzed calcite spherulite formation. The Barbalha spherulites consequently illustrate the complementary influence of clays, organic matter and evaporitic syn-sedimentary conditions.

The Upper Jurassic Garedu Red Bed Formation of the northern Tabas Block: elucidating Late Cimmerian tectonics in east-Central Iran

The Garedu Red Bed Formation (GRBF) of the northern Tabas Block (Central-East Iranian Microcontinent, CEIM) is a lithologically variable, up to 500-m-thick, predominantly continental unit. It rests gradually or unconformably on marine limestones of the Esfandiar Subgroup (Callovian–Oxfordian) and is assigned to the Kimmeridgian–Tithonian. In the lower part, it consists of pebble- to boulder-sized conglomerates/breccias composed of limestone clasts intercalated with calcareous sandstones, litho-/bioclastic rudstones and lacustrine carbonates. Up-section, sharp-based pebbly sandstones and red silt-/fine-grained sandstones of braided river origin predominate. Palaeocurrent data suggest a principal sediment transport from west to east and a lateral interfingering of the GRBF with marine greenish marls of the Korond Formation at the eastern margin of the Tabas Block. Westwards, the GRBF grades into the playa deposits of the Magu Gypsum Formation. Red colours and common calcretes suggest arid to semi-arid climatic conditions. The onset of Garedu Red Bed deposition indicates a major geodynamic change with the onset of compressive tectonics of the Late Cimmerian Tectonic Event (LCTE), being strongest at the eastern margin of the northern Tabas Block. When traced southwards, the same tectonic event is expressed by extension, indicating a shift in tectonic style along the boundary fault between the Tabas and Lut blocks. The complex Upper Jurassic facies distribution as well as the spatio-temporal changes in tectonic regime along the block-bounding faults are explained by the onset of counterclockwise vertical-axis rotation of the CEIM in the Kimmeridgian. The block boundaries accommodated the rotation by right-lateral strike slip, transpressional in today’s northern and transtensional in today’s southern segments of the block-bounding faults. Rotation occurred within bracketing transcurrent faults and continued into the Early Cretaceous, finally resulting in the opening of narrow oceanic basins encircling the CEIM. Palaeogeographically, the GRBF is part of a suite of red bed formations not only present on the CEIM, but also along the Sanandaj-Sirjan Zone (NW Iran), in northeastern Iran and beyond, indicating inter-regional tectonic instability, uplift and erosion under (semi-)arid climatic conditions across the Jurassic–Cretaceous boundary. Thus, even if our geodynamic model successfully explains Late Jurassic tectonic rotations, fault motions and facies distribution for the CEIM, the basic cause of the LCTE still remains enigmatic.