Preferential c-axis orientation of LiTaO3 was observed in surface crystallized 35Li2O·30Ta2O5·35SiO2 glass. Second harmonic generation (SHG) was observed in surface crystallized glass poled at room temperature for 24 h under a 0.7 kV dc voltage, whereas it was not observed in an unpoled sample. The SHG observed in this study was attributed to residual polarization in LiTaO3. The d33 value of the poled sample was estimated as 0.13 pm/V which was 0.5% of the d33 value for LiTaO3 single crystal.