Accurately characterizing the spatial variability of tension water storage capacity (TWC) within a catchment is challenging due to limited in-situ hydrologic data availability. Conventional conceptual rainfall-runoff models typically rely on an empirically specified TWC distribution. However, this empirical distribution lacks a physical foundation and fails to effectively redistribute critical hydrologic components, such as local capacity and contributing area, to real-world contexts. To overcome this limitation, the topographic wetness index (TWI) and its generalized form (GTWI) are introduced to bridge local topographic information with hydrologic components. Four TWC distribution curves are contrived based on the empirical parabolic distribution, empirical linear distribution, TWI, and GTWI, respectively. The effects of these alternate TWC distributions on streamflow are investigated within the framework of the HYdrologic MODel (HYMOD) across 460 Australian catchments. The results illustrate that the GTWI-based HYMOD (GTHYMOD) outperforms other models in terms of daily streamflow, with high Kling-Gupta Efficiency (KGE) attained in 74.8% of the study catchments during the validation period. The eastern coast of Australian catchments presents a superior streamflow performance compared to that in the western coast. GTHYMOD demonstrates its superiority in characterizing spatial variability, an aspect HYMOD lacked. This study has the potential to refine the empirical TWC distribution from a physical perspective and advance our comprehension of underlying hydrologic behaviors.