Kirkwood-Cohansey Aquifer System Research Articles

Effects of streamflow reductions on aquatic macroinvertebrates: linking groundwater withdrawals and assemblage response in southern New Jersey streams, USA

A comprehensive hydro-ecological investigation was conducted to determine the ecological response of increased groundwater withdrawals from the Kirkwood-Cohansey aquifer system, an important source of water supply in southern New Jersey, USA. Collocated observations were made of aquatic-macroinvertebrate assemblages and stream hydrologic attributes to develop flow–ecology response relations. A sub-regional transient groundwater flow model (MODFLOW) was used to simulate three plausible high-stress groundwater-withdrawal scenarios which resulted in stream baseflow reductions of approximately 0.12, 0.20, and 0.26 m3 s-1. These reduction scenarios were used to construct flow-alteration ecological response models to evaluate aquatic-macroinvertebrate response to streamflow reduction. For example, flow-alteration ecological response models indicate that if groundwater withdrawals diminish mean annual streamflow from 1.1 to 0.6 m3 s-1, the abundance of intolerant taxa could be reduced by as much as 20%. These flow-alteration ecological response modelling results could be used by resource professionals to evaluate alternative water management strategies to determine maximum basin withdrawal rates that meet ongoing human water demand while protecting biological integrity.Editor D. Koutsoyiannis; Guest editor M. AcremanCitation Kennen, J.G., Riskin, M.L., and Charles, E.G., 2014. Effects of streamflow reductions on aquatic macroinvertebrates: linking groundwater withdrawals and assemblage response in southern New Jersey streams, USA. Hydrological Sciences Journal, 59 (3–4), 545–561.

Modeling the Hydrology and water quality using BASINS/HSPF for the upper Maurice River watershed, New Jersey

Results of developing a watershed model for the Upper Maurice River watershed are presented. The model was calibrated against observed stream-flow using local coastal plain meteorology as input, for the ultimate purpose of estimating future development impacts on local hydrology, stream-flow and water quality. Due to insufficient data, the model has not been validated yet. Typically, development impacts expected to include are more frequent peak flows, flooding, increased channel-bed erosion, loss of wetlands, loss of forested land and more surface runoff, while water quality impacts expected to occur are an increase in nuisance vegetation in lakes and streams, and stream/lake-water quality degradation due to increased loads of pollutants. This paper reveals that a significant decrease in recharge of the Kirkwood-Cohansey unconfined aquifer system, lying below the watershed, will occur with further development, because development will alter the land-use toward more urbanization resulting in less water infiltration, hence less recharge of the aquifers below. Hydrologic Simulation Program, Fortran (HSPF), within the USEPA's BASINS-3 software system, was the modeling program used.

Overview of investigations into mercury in ground water, soils, and septage, new jersey coastal plain

Since the early 1980s, investigations by health departments of eight counties in southern New Jersey, by the NJ Department of Environmental Protection (NJDEP), and subsequently by the US Geological Survey (USGS), have shown that Hg concentrations in water tapped by about 600 domestic wells exceed the maximum contaminant level (MCL) of 2 μg/L. The wells are finished in the areally extensive unconfined Kirkwood-Cohansey aquifer system of New Jersey's Coastal Plain; background concentrations of Hg in water from this system are < 0.01 μg/L. Evidence of contributions from point sources of Hg, such as landfills or commercial and industrial hazardous-waste sites, is lacking. During 1996–2003, the USGS collected water samples from 203 domestic, irrigation, observation, and production wells using ultraclean techniques; septage, leach-field effluent, soils, and aquifer sediments also were sampled. Elevated concentrations of NH4, B, Cl, NO3, and Na and presence of surfactants in domestic-well water indicate that septic-system effluent can affect water quality in unsewered residential areas, but neither septage nor effluent appears to be a major Hg source. Detections of hydrogen sulfide in ground water at a residential area indicate localized reducing conditions; undetectable SO4 concentrations in water from other residential areas indicate that reducing conditions, which could be conducive to Hg methylation, may be common locally. Volatile organic compounds (VOCs), mostly chlorinated solvents, also are found in ground water at the affected areas, but statistically significant associations between presence of Hg and VOCs were absent for most areas evaluated. Hg concentrations are lower in some filtered water samples than in paired unfiltered samples, likely indicating that some Hg is associated with particles or colloids. The source of colloids may be soils, which, when undisturbed, contain higher concentrations of Hg than do disturbed soils and aquifer sediments. Soil disturbance during residential development and inputs from septic systems are hypothesized to mobilize Hg from soils to ground water.

Mercury concentrations in water from an unconfined aquifer system, New Jersey coastal plain

Concentrations of total mercury (Hg) from 2 μg/L (the USEPA maximum contaminant level) to 72 μg/L in water from about 600 domestic wells in residential parts of eight counties in southern New Jersey have been reported by State and county agencies. The wells draw water from the areally extensive (7770 km 2) unconfined Kirkwood–Cohansey aquifer system, in which background concentrations of Hg are about 0.01 μg/L or less. Hg is present in most aquifer materials at concentrations <50 μg/kg, but is at 100–150 μg/kg in undisturbed surficial soils. No point sources of contamination to the affected areas have been conclusively identified. To determine whether high levels of Hg in ground water are related to a particular land use and (or) water chemistry, water samples from 105 wells that tap the aquifer system were collected by the United States Geological Survey. These included randomly selected domestic wells, domestic and observation wells in selected land uses, and sets of clustered observation wells—including two sets that are downgradient from residential areas with Hg-contaminated ground water. Hg concentrations in filtered samples (Hg f) were at or near background levels in water from most wells, but ranged from 0.1 to 3.8 μg/L in water from nearly 20% of wells. Hg f concentrations from 0.0001 to 0.1 μg/L correlated significantly and positively with concentrations of other constituents associated with anthropogenic inputs (Ca, Cl, Na, and NO 3) and with dissolved organic carbon. Hg f concentrations >0.1 μg/L did not correlate significantly with concentrations of the inorganic constituents. Hg f concentrations near or exceeding 2 μg/L were found only in water from wells in areas with residential land use, but concentrations were at background levels in most water samples from undeveloped land. The spatial distribution of Hg-contaminated ground water appears to be locally and regionally heterogeneous; no extensive plumes of Hg contamination have yet been identified.

Changes in sample collection and analytical techniques and effects on retrospective comparability of low-level concentrations of trace elements in ground water

Ground-water sampling techniques were modified to reduce random low-level contamination during collection of filtered water samples for determination of trace-element concentrations. The modified sampling techniques were first used in New Jersey by the US Geological Survey in 1994 along with inductively coupled plasma-mass spectrometry (ICP-MS) analysis to determine the concentrations of 18 trace elements at the one microgram-per-liter (μg/L) level in the oxic water of the unconfined sand and gravel Kirkwood–Cohansey aquifer system. The revised technique tested included a combination of the following: collection of samples (1) with flow rates of about 2 L per minute, (2) through acid-washed single-use disposable tubing and (3) a single-use disposable 0.45-μm pore size capsule filter, (4) contained within portable glove boxes, (5) in a dedicated clean sampling van, (6) only after turbidity stabilized at values less than 2 nephelometric turbidity units (NTU), when possible. Quality-assurance data, obtained from equipment blanks and split samples, indicated that trace element concentrations, with the exception of iron, chromium, aluminum, and zinc, measured in the samples collected in 1994 were not subject to random contamination at 1 μg/L. Results from samples collected in 1994 were compared to those from samples collected in 1991 from the same 12 PVC-cased observation wells using the available sampling and analytical techniques at that time. Concentrations of copper, lead, manganese and zinc were statistically significantly lower in samples collected in 1994 than in 1991. Sampling techniques used in 1994 likely provided trace-element data that represented concentrations in the aquifer with less bias than data from 1991 when samples were collected without the same degree of attention to sample handling.

Effect of Infiltrating Solutions on the Desorption of Mercury from Aquifer Sediments

Mercury mobilization off of aquifer sediments by acid rain, road salt runoff and fertilizer solutions is investigated using column and batch equilibria experiments. Sediments from the Kirkwood Cohansey aquifer System, New Jersey are used to determine the mobilization potential of mercury due to changing infiltration water chemistry. In a series of batch equilibria and column experiments mercury contaminated sediments were treated with a dilute nitric acid solutions, 20-20-20 fertilizer, super phosphate fertilizer and dilute sodium chloride solutions. Mercury mobilization is enhanced by solutions containing sodium chloride and 20-20-20 fertilizer. These solutions can remove up to 90% of the mercury sorbed to the sediments. Mercury mobilization by phosphate fertilizer and acid rain proceeds at a slower rate and only 30% of the mercury is removed. It was found that irrigation of the sediments following treatment with 20-20-20 fertilizer or sodium chloride increased mercury mobilization associated with the destabilization of iron and aluminum oxides.