Reaction Kinetics Research Articles

Interfacial Engineering‐Assisted Energy Level Modulation Enhances the Photoelectrochemical Water Oxidation Performance of Bismuth Vanadate Photoanodes

AbstractBiVO4 faces significant challenges for widespread application in photoelectrochemical (PEC) water oxidation due to its poor hole transport ability, high surface defect density, and sluggish water oxidation reaction kinetics. Employing interfacial engineering to assist in energy level modulation is an effective strategy to address these challenges. Herein, a CuCrO2 hole transport layer (HTL) is coupled and further grew NiCo‐MOF in situ to prepare a NiCo‐MOF‐CuCrO2‐BiVO4 composite photoanode. The novel composite photoanode not only achieves a photocurrent density of 5.75 mA cm−2 at 1.23 V versus a reversible hydrogen electrode (vs RHE) but also maintains stable operation for over 24 h. Comprehensive physicochemical characterization and density‐functional theory calculations confirm that the built‐in electric field generated by the p–n heterojunction formed between the CuCrO2 HTL and BiVO4 photoanode enhances the hole transport ability. Moreover, the NiCo‐MOF chelated on the photoanode surface not only passivates the surface defect states but also accelerates the kinetics of the water oxidation reaction. Under the synergistic effect of dual modification, the PEC water oxidation performance of the BiVO4 photoanode is dramatically improved. This pioneering work presents a MOF/HTL/BiVO4 configuration that provides a blueprint for the future development of integrated photoanodes for efficient solar energy conversion.

Minimum Normalized Cycling Cadence to Increase Post-Cycling Gait Velocity

Background: Previous research has shown that increasing cycling cadence can result in improved post-cycling gait velocity. However, the specific threshold of cycling cadence required to bring about clinically meaningful changes in gait velocity remains unknown. This study aimed to determine the minimum increment in cycling cadence that would lead to a significant improvement in post-cycling gait velocity. Methods: A total of 42 young adults participated in our study and were randomly assigned to one of three groups: TEN, TWENTY, and THIRTY. Each group was assigned to cycle at a cadence at the corresponding percentage higher than the participant’s self-selected gait cadence. Each participant engaged in a 15-min cycling session at their respective assigned cycling cadence. Before and after cycling, participants completed a 10-meter walk test while spatiotemporal parameters of gait, ground reaction forces, lower extremity kinematics, and kinetics were recorded. Results: One-way ANOVA revealed no statistically significant changes in spatiotemporal, ground reaction force, kinematics, and kinetics variables pre- and post-cycling. However, there were both statistically significant (F(2,41) = 3.794, p = 0.031, η2 = 0.604) and clinically meaningful changes (0.07 m/s) in post-cycling gait velocity in the THIRTY group only. Conclusions: This suggests that a cycling cadence of 30% or higher is the minimum requirement to produce a clinically significant improvement in gait velocity.

In Situ Synthesis of MoO3 by Surface Oxidation of Mo2C (MXene) for Stable Near‐Surface Reactions in Aqueous Aluminum‐Ion Battery

AbstractMolybdenum trioxide (MoO3) is a promising positive electrode material for aqueous aluminum‐ion batteries (AAIBs) due to its high theoretical capacity. However, MoO3 faces several challenges in an aqueous electrolyte, such as easy dissolution of reaction products, volume expansion, and low conductivity, which severely limit its application in aqueous batteries. In this work, we effectively increased the overall conductivity of the electrode by in situ growing MoO3 on the Mo2C MXene layer. MXene can effectively inhibit the dissolution and structural loss of MoO3 reaction products. Additionally, the coordination effect of Mo2C and MoO3 achieves a stable near‐surface reaction on the MXene laminates, resulting in the Mo2C/MoO3 composite exhibiting excellent aluminum storage properties (123.5 mAh/g after 200 cycles at 0.4 A/g). The energy storage mechanism of H+/Al3+ co‐insertion/extraction was elucidated through ex situ characterization, and the promotion effect of Mo2C on MoO3 reaction kinetics was verified by density functional theory (DFT) calculations. This work provides new insights into improving the stability of AAIBs cathodes and extends the application of Mo‐based MXene in aqueous batteries.

In Situ Synthesis of MoO3 by Surface Oxidation of Mo2C (MXene) for Stable Near-Surface Reactions in Aqueous Aluminum-Ion Battery.

Molybdenum trioxide (MoO3) is a promising positive electrode material for aqueous aluminum-ion batteries (AAIBs) due to its high theoretical capacity. However, MoO3 faces several challenges in an aqueous electrolyte, such as easy dissolution of reaction products, volume expansion, and low conductivity, which severely limit its application in aqueous batteries. In this work, we effectively increased the overall conductivity of the electrode by in situ growing MoO3 on the Mo2C MXene layer. MXene can effectively inhibit the dissolution and structural loss of MoO3 reaction products. Additionally, the coordination effect of Mo2C and MoO3 achieves a stable near-surface reaction on the MXene laminates, resulting in the Mo2C/MoO3 composite exhibiting excellent aluminum storage properties (123.5 mAh/g after 200 cycles at 0.4 A/g). The energy storage mechanism of H+/Al3+ co-insertion/extraction was elucidated through ex situ characterization, and the promotion effect of Mo2C on MoO3 reaction kinetics was verified by density functional theory (DFT) calculations. This work provides new insights into improving the stability of AAIBs cathodes and extends the application of Mo-based MXene in aqueous batteries.

Designable Electrochemiluminescence Patterning for Renewable and Enhanced Bioimaging.

Electrochemical imaging enables an in-depth analysis of the interface heterogeneity and reaction kinetics of single entities. However, electrode passivation during electrochemical reactions decreases the active sites and harms the long-term stability. Here, we introduce a method using laser-induced photothermal effects to restore the electrochemical activity, which is particularly displayed as enhanced micrometric patterns in electrochemiluminescence (ECL) microscopy. By co-localization characterization and X-ray photoelectron spectroscopy, the mechanism of active site regeneration is validated as the removal of the oxide film for restoring the local surface ECL reactivity under laser irradiation. The surface-confined and voltage-dependent features of ECL allows for easy pattern erasure and rewriting, and it shows good reversibility and anti-counterfeiting potential. This approach overcomes the passivation processes, evidently improves the image quality of single biological entities including Shewanella bacteria and cells, and makes the subtle contour structures more distinct. The renewable electrode interface also enhances the ECL signal of model bead-based bioassays. This approach not only showcases precise control in fabricating micron patterns but also holds promise for enhancing the sensitivity in electrochemical immunoassays and bioimaging.

Designable Electrochemiluminescence Patterning for Renewable and Enhanced Bioimaging

Electrochemical imaging enables an in‐depth analysis of the interface heterogeneity and reaction kinetics of single entities. However, electrode passivation during electrochemical reactions decreases the active sites and harms the long‐term stability. Here, we introduce a method using laser‐induced photothermal effects to restore the electrochemical activity, which is particularly displayed as enhanced micrometric patterns in electrochemiluminescence (ECL) microscopy. By co‐localization characterization and X‐ray photoelectron spectroscopy, the mechanism of active site regeneration is validated as the removal of the oxide film for restoring the local surface ECL reactivity under laser irradiation. The surface‐confined and voltage‐dependent features of ECL allows for easy pattern erasure and rewriting, and it shows good reversibility and anti‐counterfeiting potential. This approach overcomes the passivation processes, evidently improves the image quality of single biological entities including Shewanella bacteria and cells, and makes the subtle contour structures more distinct. The renewable electrode interface also enhances the ECL signal of model bead‐based bioassays. This approach not only showcases precise control in fabricating micron patterns but also holds promise for enhancing the sensitivity in electrochemical immunoassays and bioimaging.

Electrospun Micro/Nanofiber-Based Electrocatalysts for Hydrogen Evolution Reaction: A Review

Hydrogen is regarded as an ideal energy carrier to cope with the energy crisis and environmental problems due to its high energy density, cleanliness, and renewability. Although there are several primary methods of industrial hydrogen production, hydrogen evolution reaction (HER) is an efficient, eco-friendly, and sustainably green method for the preparation of hydrogen which has attracted considerable attention. However, this technique is characterized by slow reaction kinetics and high energy potential owing to lack of electrocatalysts with cost-effective and high performance which impedes its scale-up. To address this issue, various studies have focused on electrospun micro/nanofiber-based electrocatalysts for HER due to their excellent electron and mass transport, high specific surface area, as well as high porosity and flexibility. To further advance their development, recent progress of highly efficient HER electrospun electrocatalysts is reviewed. Initially, the characteristics of potential high-performance electrocatalysts for HER are elucidated. Subsequently, the advantages of utilizing electrospinning technology for the preparation of electrocatalysts are summarized. Then, the classification of electrospun micro/nanofiber-based electrocatalysts for HER are analyzed, including metal-based electrospun electrocatalyst (noble metals and alloys, transition metals, and alloys), metal–non-metal electrocatalysts (metal sulfide-based electrocatalysts, metal oxide-based electrocatalysts, metal phosphide-based electrocatalysts, metal nitride-based electrocatalysts, and metal carbide-based electrocatalysts), metal-free electrospun micro/nanofiber-based electrocatalysts, and hybrid electrospun micro/nanofiber-based electrocatalysts. Following this, enhancement strategies for electrospun micro/nanofiber-based electrocatalysts are discussed. Finally, current challenges and the future research directions of electrospun micro/nanofiber-based electrocatalysts for HER are concluded.

Microencapsulation of Caucasian blueberries (Vaccinium arctostaphylos L.) anthocyanins: Colour stability in varying storage conditions

AbstractThe aim of this study was to investigate the extraction of anthocyanins from the fruits of Caucasian blueberry (Vaccinium arctostaphylos L.) and examine the colour stability of anthocyanins encapsulated through spray drying in model systems. The trials were conducted to determine the optimal conditions for anthocyanin extraction using an ultrasonic water bath at temperatures of 25, 50 and 75°C. The ideal anthocyanin extraction occurred at 25°C using 100% acetone in an ultrasonic bath for 15 min at 35 kHz. Anthocyanin concentrations were evaluated using the pH differential method. The extracted anthocyanins were encapsulated through spray drying with maltodextrin as the encapsulating material. The encapsulation efficiency was 80.4 ± 0.20%, and the anthocyanin retention rate was 83.0 ± 0.76%. The coloured capsules were added to model systems with pH values of 4.50, 5.00, 5.50 and 6.00. The colour values (L* 50.16 ± 0.05, a* 4.08 ± 0.04, b* −9.35 ± 0.01, H° 293.57 ± 0.15, C* 10.20 ± 0.03) were measured during varying storage conditions. The results showed, that colour loss began on the fifth day and this was accelerated with higher temperatures and pH values. It was found that encapsulation significantly preserved the stability of the blue colour and the loss of the blue colour followed first‐order reaction kinetics. The study showed that the blue colour of microcapsules was best preserved at pH 5.00 at 25°C. In this case, the measured total colour change (∆E) was 5.86, the activation energy (Ea) was 37.64 kJ/mol, and the half‐life (t1/2) was determined to be 19.08 days.

Effect of Synthesis Temperature on Performance of Phenazine-Based Cathode for Sodium Dual-Ion Batteries.

Organic materials have attracted much attention in the field of electrochemical energy storage due to their ecological sustainability, abundant resources and structural designability. However, low electrical conductivity and severe agglomeration of organic materials lead to poor discharge capacity and reaction kinetics in batteries. Herein, the morphology of the phenazine-based organic polymer poly(5,10-diphenylphenazine) (PDPPZ) was modified by varying the synthesis temperature. PDPPZ-165 °C with an exceptional porous structure provides abundant reaction channels for rapid charge transfer and diffusion that improves the reaction kinetics in sodium dual-ion batteries. Therefore, PDPPZ-165 °C cathode possesses excellent rapid charge-discharge capability delivering a specific capacity of 119.2 mAh g-1 at 40 C. Furthermore, a high specific capacity of 124.7 mAh g-1 can be provided even at a high loading of 16 mg cm-2 at 0.5 C with a capacity retention of 86.4 % after 500 cycles. This work could afford new insights for optimizing the performance of organic cathode materials in sodium dual-ion batteries.

Demystifying Synergistic Multifunctional Electrocatalysis of N-Doped Graphene/WS2 Heterostructure with Single-Atom Catalysts for Water Splitting and Fuel Cells.

As the demand for sustainable energy continues to rise, electrocatalysis has become increasingly prominent in the advancement of clean energy technologies. By scrutinizing the material to function as a multifunctional catalyst, the effectiveness of energy conversion processes is significantly enhanced. This study focuses on harnessing graphene/WS2 van der Waals heterostructures for overall water splitting and fuel cell applications, using transition metals (TMs) from Sc-Zn as single-atom catalysts (SACs). Additionally, the research explores the synergistic effect of nitrogen doping combined with SACs to modify the material into multifunctional catalysts. The stability of all TMs as SACs in the vdW heterostructure (TM@GW) and nitrogen-doped TM@GW (TM@NGW) is validated with negative cohesive and formation energies, and thermodynamic stability is also corroborated with ab initio molecular dynamics (AIMD) analysis at both 300 and 500 K for 5 ps. The observed electrocatalytic performance of TM@GW and TM@NGW depicts that the Ni@NGW system exhibits trifunctional property with the lowest overpotentials {ηHER; ηOER; ηORR = 0.21; 0.42; 0.27 V}. Additionally, the Cr@NGW material displays bifunctional catalytic activity for the OER and ORR, with overpotentials of 0.53 and 0.37 V, respectively. The synergistic effect between N doping and SACs is further studied with the d, p band centers and density of states calculations. Furthermore, the scaling relation between the adsorption of intermediates and reaction kinetics is studied, which validates the coaction of N and SACs in the TM@NGW heterostructure. This study demonstrates that the inclusion of SACs and nitrogen atoms in the GW heterostructure significantly enhances the catalytic performance by approximately 26%, effectively transforming the system into a multifunctional catalyst. These findings emphasize the role of SACs in vdW heterostructures and N doping effects, providing valuable insights to guide the design of advanced catalysts for water splitting and fuel cell applications.

Dual Modulation of Hydroxyl Action on Ruthenium Surface by Single‐Atom Supports for Alkaline H2 Evolution

AbstractRuthenium (Ru)‐based catalysts are known to accelerate the slow kinetics of the alkaline hydrogen evolution reaction (HER). However, enhancing the transfer kinetics of adsorbed hydroxyl (OHad) remains challenging. Herein, a dual‐regulation strategy is presented to alleviate OH blockage on the catalyst surface, using a cluster‐level Ru electrocatalyst supported by single‐atom CoN4 generated in situ on carbon nanotubes (CNTs). Experimental and theoretical studies demonstrate that introducing oxophilic single‐atom CoN4 can mitigate the strong interaction between Ru and OHad by directly competing for OHad on the Ru surface, thereby preventing Ru site poisoning. Meanwhile, single‐atom CoN4 effectively modifies the electronic structure of Ru atomic clusters (ACs), indirectly optimizing the energy barriers for OH desorption at the Ru interface and promoting OHad release. The electronic interaction between Ru ACs and CoN4 also inhibits Ru atom migration, significantly enhancing catalytic stability. The resulting catalyst shows excellent HER activity at 10 mA cm−2 with a low overpotential of 15 mV in alkaline solution and remains stable at 200 mA cm−2 for over 1000 h. An alkaline anion‐exchange membrane water electrolyzer (AEMWE) using this catalyst can exhibit an ultralow potential (1.785 V at 1 A·cm−2) and high stability at 500 mA·cm−2.

Unraveling the Factors of Host Materials Affecting the Kinetics of Electrochemical Anion Intercalation Reaction

Unraveling the Factors of Host Materials Affecting the Kinetics of Electrochemical Anion Intercalation Reaction

Kinetics of the Dissolution Reaction of the U3O8 Powder in Nitric Acid after Oxidation Volatilization at 850 °C

Kinetics of the Dissolution Reaction of the U₃O₈ Powder in Nitric Acid after Oxidation Volatilization at 850 °C

Revisiting the Enhanced Chemical Reactivity in Water Microdroplets: The Case of a Diels-Alder Reaction.

Often, chemical reactions are markedly accelerated in microdroplets compared with the corresponding bulk phase. While identifying the precise causative factors remains challenging, the interfacial electric field (IEF) and partial solvation are the two widely proposed factors, accounting for the acceleration or turning on of many reactions in microdroplets. In sharp contrast, this combined computational and experimental study demonstrates that these two critical factors have a negligible effect on promoting a model Diels-Alder (DA) reaction between cyclopentadiene and acrylonitrile in water microdroplets. Instead, the acceleration of the DA reaction appears to be driven by the effect of confinement and the concentration increase caused by evaporation. Quantum chemical calculations and ab initio molecular dynamics simulations coupled with enhanced sampling techniques predict that the air-water interface exhibits a higher free-energy barrier of this reaction than the bulk, while external electric fields marginally reduce the barrier. Remarkably, the catalytic capability of the IEF at the water microdroplet surface is largely hampered by its fluctuating character. Mass spectrometric assessment of the microdroplet reaction corroborates these findings, suggesting that the DA reaction is not facilitated by the IEF as increasing the spray potential suppresses the DA products by promoting substrate oxidation. While the DA reaction exhibits a surface preference in water microdroplets, the same reaction tends to occur mainly within the core of the acetonitrile microdroplet, suggesting that the partial solvation is not necessarily a critical factor for accelerating this reaction in microdroplets. Moreover, experiments indicate that the rapid evaporation of microdroplets and subsequent reagent enrichment within the accessible confined volume of microdroplets caused the observed acceleration of the DA reaction in water microdroplets.

Multifunctional Ultrathin Ti3C2Tx MXene@CuCo2O4 /PE Separator for Ultra-High-Energy-Density and Large-Capacity Lithium-Sulfur Pouch Cells.

The shuttling of lithium polysulfides (LiPSs), sluggish reaction kinetics, and uncontrolled lithium deposition/stripping remain the main challenges in lithium-sulfur batteries (LSBs), which are aggravated under practical working conditions, i.e., high sulfur loading and lean electrolyte in large-capacity pouch cells. This study introduces a Ti3C2Tx MXene@CuCo2O4 (MCC) composite on a polyethylene (PE) separator to construct an ultrathin MXene@CuCo2O4/PE (MCCP) film. The MCCP functional separator can deliver superior LiPSs adsorption/catalysis capabilities via the MCC composite and regulate the Li+ deposition through a conductive Ti3C2Tx MXene framework, enhancing redox kinetics and cycling lifetime. When paired with sulfur/carbon (S/C) cathode and lithium metal anode, the resultant 10 Ah-level pouch cell with the ultrathin MCCP separator achieves an energy density of 417Wh kg-1 based on the whole cell and a stable running of 100 cycles under practical operation conditions (cathode loading = 10.0 mg cm-2, negative/positive areal capacity ratio (N/P ratio) = 2, and electrolyte/sulfur weight ratio (E/S ratio) = 2.6 µL mg-1). Furthermore, through a systematic evaluation of the as-prepared Li-S pouch cell, the study unveils the operational and failure mechanisms of LSBs under practical conditions. The achievement of ultrahigh energy density in such a large-capacity lithium-sulfur pouch cell will accelerate the commercialization of LSBs.

Giant Charge Separation-Driving Force Together with Ultrafluent Charge Transfer in TiO2/ZnFe-LDH Photoelectrode via Ferroelectric Interface Engineering.

Hydrogen fuel production using photoelectrochemical (PEC) water-splitting technology is incredibly noteworthy as it provides a sustainable and clean method to alleviate the energy environmental crisis. A highly rapid electron shuttle at the semiconductor/WOC (water oxidation cocatalyst) interface is vital to improve the bulk charge transfer and surface reaction kinetics of the photoelectrode in the PEC water-splitting system. Yet, the inevitably inferior interface transition tends to plague the performance enhancement on account of the collision of hole-electron transport across the semi/cat interface. Herein, we address these critical challenges via inserting ferroelectric layer BTO (BaTiO3) into the semi/cat interface. The embedded polarization electric field induced by ferroelectric BTO remarkably pumped hole transfer at the semiconductor/WOC (TiO2/ZnFe-LDH) interface and selectively tailored the electronic structure of LDH surface-active sites, leading to overwhelmingly improved surface hole transfer kinetics at LDH/electrolyte interface, which minish the electron-hole recombination in bulk and on the surface of TiO2. The TiO2 nanorods encapsulated by ferroelectric-assisted ZnFe-LDH achieve 105% charge separation efficiency improvement and 53.8% charge injection efficiency enhancement compared with pure TiO2. This finding offers a strategic design for electrocatalytic-assisted photoelectrode systems by ferroelectric-pumped charge extraction and transfer at the semiconductor/WOC interface.

An Ultrafast and Ultralow‐Temperature 3D‐Printed All‐Organic Proton Pseudocapacitor

AbstractA critical challenge for pseudocapacitors applications is the rapid capacitance fading under extreme environments, which originates from sluggish diffusion kinetics of inorganic materials and tortuous ionic channels in conventional bulk electrodes. Herein, a novel 3D‐printed all‐organic proton pseudocapacitor (composed of 2,6‐diaminoanthraquinone (DQ)‐based anode and polyaniline‐based cathode) with chemical and structural stability is developed, which exhibits an extraordinary rate performance and cycle stability under ultralow temperature. The DQ molecules are anchored on reduced graphene oxide, which enhances the electronic conductivity and structural stability. Theoretical calculation and spectroscopic characterization reveal that the two‐electron transfer process involves quinone/hydroquinone transition. Exploiting the synergy of fast reaction kinetics of organic and the efficient ion diffusion paths of the 3D architecture, the 3D‐printed anode achieves an impressive areal capacitance of 10.14 F cm−2 at high mass loading (28.73 mg cm−2). The 3D‐printed all‐organic proton pseudocapacitor shows stable cycling performance at −80 °C and releases a high energy density of 0.76 mWh cm−2 at −60 °C. This work is instructive for the development of competitive ultra‐low temperature energy storage devices via integrating organic materials and 3D architectural electrode designs.

Electrodeposition Decoration of Pd0 on F‐Co(OH)2 Nanoarrays with Intentionally Introduced Pd2+ Species for Efficient Electrocatalytic Hydrodechlorination of 2,4‐Dichlorophenol

AbstractDeveloping a Pd‐based catalyst possessing high efficiency and low mass loading remains a big obstacle for the large‐scale application of electrocatalytic hydrodechlorination (EHDC) of chlorophenols (CPs). Herein, high dispersion Pd nanoparticles imbedded in Pd2+ hydroxide species are decorated on the surface of F−Co(OH)2 nanowire arrays with a newly developed electrodeposition and hydrolysis coupled process. EHDC of 2,4‐dichlorophenol (2,4‐DCP) with the as‐obtained Pd/F−Co(OH)2/NF‐a exhibits superior performance than other control samples in this work and literature reports. A 100 % removal of 2,4‐DCP is accomplished within 120 min, featuring fast reaction kinetics (kobs=5.0×10−2 min−1) and mass activity (MA=22.2 min−1 g−1Pd). Mechanism investigation shows that the intentionally introduced Pd2+ sites play a pivotal role in the adsorption of 2,4‐DCP, while high dispersion of Pd facilitates the generation of active H*, thus promoting the catalytic performance. This work presents a valuable example for designing high‐performance Pd‐based EHDC catalysts by composition tuning.

Coordination-Driven in Situ Grown Copper Peroxide in Mesoporous Dopamine with Self-Supplied H2O2 for Synergistic Enhanced PTT/CDT Antibacterial Treatment and Wound Healing.

As antibiotic resistance increases, alternative antimicrobial methods become essential. Chemical dynamics therapy (CDT) utilizing copper peroxide (CuO2) nanodots shows significant potential in antibacterial applications due to its ability to self-supply hydrogen peroxide (H2O2) on its own. This characteristic effectively addresses the challenges of low H2O2 levels and high glutathione (GSH) expression in the bacterial infection microenvironment. However, its tendency to aggregate and instability greatly affect its effectiveness. Therefore, this study developed a coordination-driven strategy to prepare copper peroxide-loaded mesoporous polydopamine nanomaterials (CuO2@MPDA) through in situ growth of CuO2 in mesoporous polydopamine utilizing the chelating interaction between amino and catechol structures of MPDA with copper ions. This strategy not only ensures that copper peroxide is evenly distributed within the pores of mesoporous polydopamine but also protects it through the shielding effect of pores, greatly enhancing its dispersibility and stability. More notably, the loading of CuO2 enhances the photothermal performance of MPDA by broadening its light absorption range, and MPDA-mediated photothermal therapy (PTT) can accelerate CuO2 to produce more hydroxyl radicals by speeding up chemical reactions, resulting in a combined boost in PTT and CDT. The developed CuO2@MPDA nanomaterials at very low concentrations exhibit improved antibacterial efficiency both in vitro and in vivo. Overall, this study provides an innovative strategy to construct an antibacterial nanoplatform for synergistically enhanced PTT/CDT dual-mode antibacterial treatment, exhibiting great potential for future biomedical applications.

Kinetic study of mineral oil removal from wastewater by the sono-electrochemical process

ABSTRACT Chemical kinetics can be a useful tool for determining the optimal operating time of electrochemical processes. The main objective of the study was to determine the mineral oil removal rate by sono-electrochemical treatment. In this study, zero-, first-, and second-order kinetic models were used to determine the reaction rate of mineral oil removal with the sono-electrochemical process. The reaction rate experiments were conducted under the following optimal conditions: 8 min of treatment time, a current density of 53.1 A/m2, and a flow rate of 0.23 L/s. It was found that the changes in mineral oil concentrations follow second-order kinetics with a coefficient of determination of 0.9732. The mineral oil removal efficiency was 94.4%. This study concludes that sono-electrochemical process could be a promising technology for the removal of mineral oil from wastewater, and that the mineral oil removal rate can be determined by chemical kinetics. The results obtained may be useful for the optimization of the sono-EC process and reactor design.