This work investigated the effects of heat treatment on the tensile behavior of 3D-printed high modules carbon fiber-reinforced composites. The manufacturing of samples with different material combinations using polylactic acid (PLA) reinforced with 9% carbon fiber (PLACF), acrylonitrile butadiene styrene (ABS) reinforced with 9% carbon fiber (ABSCF) were made. This paper addresses the tensile behavior of different structured arrangements at different% of densities between two kinds of filaments. The comparison of the tensile behavior between heat treated and untreated samples. The results showed that heat treatment improves the tensile properties of samples by enhancing the bonding of filament layers and by reducing the porosity content. At all structure specifications, the rectilinear pattern gives higher strength of up to 33% compared with the Archimedean chords pattern. Moreover, there is a limited improvement in the tensile strength and modulus of elasticity values for the samples treated at low heat-treatment temperature. The suggested methodology to evaluate the tensile behavior of the pairs of materials selected is innovative and could be used to examine sandwich designs as an alternative to producing multi-material components using inexpensive materials.