It can be said that the start of the successful start up business road is usually not after graduation. To obtain the successful start up business, the most important is to have the very rich social practical experience and the solid and stable professional knowledge. At the initial stage of college students’ entrepreneurship, financial management always throughout the enterprise production management and entrepreneurship in many aspects. Individual proprietorship enterprises, partnership enterprises and limited liability companies belong to the most common three kinds of enterprises. These three kinds of enterprises all need in accordance with the relevant provisions of the financial management of the Chinese enterprises, establishing the effective accounting books, to carry out the financial accounting work. Study on the existed problems of the financial management in the initial stage of starting up business by the college students, mainly is want to make the financing and financial management of the college students’ pioneering enterprises more smoothly carry on, reasonably control the risks may appear, fully play the essential benefits of venture capital, in the aspects of policy and theory, bring the effective basis for constructing the perfect financial management model of the enterprises in the initial stage of start up business by the college students.