This study was conducted to infer the effects of volcanic ash accumulating on a leaf surface on its photosynthesis. Particle size distribution and shading ratio were measured on 2 kinds of ash from Mt. Sakurajima (white and black) and 4 kinds from Mt. Unzen-Fugendake. Reflected spectral radiant flux density, temperature and Stomatal conductance of cucumber leaves covered with those ashes were also measured.Particle size distribution of ashes were different each other, Particle (<3μm) contents of them were 6 to 13%. Shading ratios were 8 to 20% at 5gm-2 of ash load. The ash with smaller particle size had bigger shading ratio. Integrated radiant flux density (280-2500nm) of reflection from leaves covered with ashes from Mt. Sakurajima (black and white) and Mt. Unzen-Fugendake at 50gm-2 were 65, 53 and 106% to control leaves, respectively. Temperature of leaves covered with these ashes at 50gm-2 increased by 2.4, 2.6 and 1.2°C, respectively, at a solar radiation of 876 W m-2. The ash from Mt. Unzen-Fugendake, with the smallest particle size, decrease stomatal conductance significantly even after it was washed out from the leaf surface. These results suggest that the volcanic ash with dark color and small particle size reduces photosynthesis through shading, increasing temperature and plugging stomata.