Nuclear structure of Pt 196 has been investigated from the decay of the 6.2 d Au 196. New weak gamma rays of 312, 444, 522, 568, 644, 757, 762 and 1090 keV were found in the analysis of conversion electron spectra by the use of a sector-type double focusing beta ray spectrometer. These new gamma rays were all coincident with the 356 keV gamma transition between the first and ground state of Pt 196. From the ratio of electron capture to positon emission rate ϵ K.L.M./ β + = 2.0±0.4 × 10 6, the electron capture decay energy of the 6.2 d Au 196 is estimated as 1480 −12 +8 keV. Directional correlation measurements of 1090-356, 760-340, 530-340 and 333-356 keV gamma ray cascades were also performed. The level scheme of Pt 196 is proposed as folows: 1446 keV, 3 −: (1316 keV, 3 +, 2 +): 1117 keV, 2 +; 1002 keV, 3 +: 877 keV, 4 +; 689 keV 2 +; 356 keV, 2 +. The 1446 keV 3 − state is assigned as the lowest octupole vibrational state. Almost all these levels are compared with ones determined from the measurement of the Pt 195(d, p)Pt 196 reaction. The large excitation of the 3 − state by the stripping process seem to be difficult to understand on the basis of any of the usual theories. The extremely low value of the 689 keV cross over transition from the second excited 2 + state, 689 K/356 K = 1.0±1.0 × 10 −5 is discussed in terms of intrinsic nucleonic excitations.