Aviation turbine fuel and diesel fuel were blended with synthetic paraffins produced via two pathways and the combustion properties measured. Both aviation and diesel fuel containing synthetics produced from the fermentation of sugars, had a linear response to blending with decreasing ignition delay times from 5.05 - 3.52 ms for F-34 and 3.84 - 3.52 ms for F-76. For the same fuels blended with synthetics produced from the fermentation of alcohols, ignition delay times were increased out to 18.66 ms. The derived cetane number of the blends followed an inversely similar trend. Additionally, simulated distillation using ASTM D2887 at high synthetic paraffinic kerosene blend ratios resulted in the recovery temperatures being incorrectly reported. In this case, higher recovery volumes were at lower temperatures than earlier recovery points i.e. T90< T50, for SIP-SPK.