Due to the growing dependencies of information network technology, networked control systems are undergoing a severe blow of cyberattacks, and simply modeling cyberattacks is inadequate and impractical for the detection requirements, because of various vulnerabilities in these systems and the diversities of cyberattacks. Actually, a feasible viewpoint is to identify misbehaviors by constructing a normal model of industrial communication behaviors. However, one of the chief difficulties is how to completely and appropriately summarize industrial communication behaviors according to the specific communication characteristics. In view of process control and data acquisition, this paper associates industrial communication characteristics with the time sequence, and further extracts two distinct behaviors: function control behavior and process data behavior. Based on these double behavior characteristics, we introduce one-class classification to detect the corresponding anomalies, respectively. Besides, we also present the weighted mixed Kernel function and parameter optimization method to improve classification performance. Experimental results clearly demonstrate that the proposed approach has significant advantages of classification accuracy and detection efficiency.