Karst Springs Research Articles

Using continuous electrical conductivity measurements to derive major solute concentrations in karst systems

AbstractHydrochemical data of karst springs provide valuable insights into the internal hydrodynamical functioning of karst systems and support model structure identification. However, the collection of high‐frequency time series of major solute species is limited by analysis costs. In this study, we develop a method to retrieve the individual solute concentration time series and their uncertainty at high temporal resolution for karst springs by using continuous observations of electrical conductivity () and low‐frequency ionic measurements. Due to the large ion content and non‐negligible concentrations of aqueous complexes in karst systems, the concentration of each solute species occurring as free ion and as part of aqueous complexes are computed separately. The concentration of species occurring as free ions are computed considering their contributions to the total , whereas the concentration of the species as part of complexes are obtained from speciation calculations. The pivotal role of the complexation processes for the reconstruction of solute concentration time series starting from the signal is investigated in two karstic catchments with different geologies and temporal resolution of the available hydrochemical datasets, that is the Kerschbaum dolostone system in Austria and the Baget limestone system in France. The results show that complexation processes are significant and should be considered for the estimation of the total solute concentration in case of SO4, Ca, Mg and HCO3. The signal of a karst spring can be used to interpolate and quantify the dynamics of those solutes characterized by large contribution (approximately >6%) to the total and low relative variability, that is HCO3, Ca and Mg. Moreover, the presented method can be used to estimate concentrations of solutes when applied to karst systems with stationary and hydrogeochemical homogeneous contributing area. On the contrary, the method is affected by large uncertainty in case of dynamic systems characterized by varying contributions of water from different geological areas. This study aims to contribute to the problem of hydrogeochemical data availability and to support future works on karst systems conceptualization.

Assessing spatial and temporal changes in diversity of copepod crustaceans: a key step for biodiversity conservation in groundwater-fed springs

Despite the close attention springs have received from a hydrologic perspective and as biodiversity hotspots, the multiple dimensions of spring meiofaunal assemblage diversity are still poorly investigated. Knowledge of beta diversity patterns and drivers can inform and improve management decisions on biodiversity conservation. Here, we analyzed beta diversity of copepod assemblages in karst springs in Central Italy by focusing on: 1) relative contributions of turnover and nestedness components to taxonomic and phylogenetic beta diversity; 2) temporal variation of species richness and beta diversity within and between the target springs in conjunction with models of the influence of physical-chemical parameters on within-spring diversity changes; 3) expected risk of habitat loss due to variation in groundwater recharge under climate change. To this end, we gathered data from 168 samples collected in four karst springs from 2004 to 2016. Overall, we found 48 copepod species, 22 of which are obligate groundwater dwellers while the remaining 26 usually occur in surface freshwaters. All springs showed significant changes in taxonomic and phylogenetic beta diversity over time. Total beta diversity was high for both the taxonomic and phylogenetic dimensions, and turnover was the main component. Inter-site variability in dissolved oxygen explained a noticeable part of temporal variation in beta diversity, likely reflecting the role of microhabitat heterogeneity in shaping site-specific assemblages. However, most of the temporal variation in species richness and beta diversity remained unexplained, suggesting a major role of other factors, such as seasonal discharge variations. Modelling of recharge rates for all the four springs over 2001–2020 suggested a potential >40% recharge deficit under dry conditions. Moreover, Cellular Automata-based modelling of rainfall over the Gran Sasso-Sirente hydrogeologic unit (feeding three of the four springs) predicted an overall precipitation decrease in the 2081–2095 period. Such changes could produce severe effects on springs’ microhabitats and related communities. Our results indicate that partitioning beta diversity, monitoring its temporal changes and assessing its environmental drivers are critical to evidence-based conservation of springs. Particularly, the high species turnover we have observed suggests that conservation strategies should seek to preserve as many microhabitats as possible within and among karst springs.

The Effects of Climate Variation and Anthropogenic Activity on Karst Spring Discharge Based on the Wavelet Coherence Analysis and the Multivariate Statistical

This study focused on the impact of anthropogenic activity on magnitude, frequency, and minima of spring discharge. Niangziguan Springs (NS), China, was selected as an example, as its discharge is decreasing due to the combined effects of climate variation and human activity. For exploring the impact of human activity on the spring discharge from climate change, the spring discharges from 1959 to 2015 were divided into two periods: pre-development period (i.e., 1959–1980) and post-development period (i.e., 1981–2015). A polynomial regression model of the spring discharge was developed for the pre-development period. We deduced the model in the post-development period, compared the results with the observed spring discharge, and concluded that the climate variation and human activity caused 6.93% and 32.38% spring discharge decline, respectively. The relationships of spring discharge with Indian Summer Monsoon (ISM), East Asian Summer Monsoon (EASM), E1 Niño Southern Oscillation (ENSO), and Pacific Decadal Oscillation (PDO) were analyzed by wavelet analysis during the two periods. The results illustrated that the monsoons (i.e., ISM and EASM) were dominated by climate factors that affect the NS discharge versus climate teleconnections (i.e., ENSO and PDO). According to different time scales, human activities have had an impact on the periodicity of NS discharge, which altered the periodicities of the spring discharge at inter-annual time scales, but the periodicities at intra-annual and annual time scales have remained the same between the two periods. Under the effects of human activity, the local parameter of non-stationary general extreme value (NSGEV) distribution varied with time. The predicted spring discharge minimum value is supposed to be 4.53 m3/s with a 95% confidential interval with an upper boundary of 6.06 m3/s and a lower boundary of 2.80 m3/s in 2020. The results of this study would benefit the management of spring discharge and water resources.

Hydrological Functioning and Water Availability in a Himalayan Karst Basin under Climate Change

Karst springs are important water sources for both human needs and environmental flows. The responses of karst springs to hydrometeorological factors vary depending on local conditions. In this study, we investigated Martandnag spring in the Liddar catchment in the Kashmir valley of northern India. We used statistical time series (autocorrelation and cross-correlation) and machine-learning (ML) techniques (random forest regression (RFR) and support vector regression (SVR)) to characterize how rainfall, temperature, and snow cover affect the karst spring flow and predict the future responses of the spring stage based on climate scenarios, in the Intergovernmental Panel on Climate Change Assessment Report 6. The statistical time series showed that the memory effect of Martandnag spring varies from 43 to 61 days, indicating moderate karstification and a relatively high storage capacity of the karst aquifer in the Liddar catchment. The delay between recharge and discharge varies from 13 to 44 days, and it is more strongly correlated to snow/ice melt than to rainfall. The ML analysis shows that SVR outperformed RFR in predicting spring flow. Under all climate scenarios, a trained SVR model showed that spring flow increased during the late winter to early spring, and decreased during the summer (except in August) and in autumn. Scenarios with increased greenhouse gas emissions further reduced flow in the summer and autumn. These predictions can be helpful for water-resource planning in similar watersheds in the Western Himalayas.

Comparison of artificial neural networks and reservoir models for simulating karst spring discharge on five test sites in the Alpine and Mediterranean regions

Abstract. Hydrological models are widely used to characterize, understand and manage hydrosystems. Lumped parameter models are of particular interest in karst environments given the complexity and heterogeneity of these systems. There is a multitude of lumped parameter modelling approaches, which can make it difficult for a manager or researcher to choose. We therefore conducted a comparison of two lumped parameter modelling approaches: artificial neural networks (ANNs) and reservoir models. We investigate five karst systems in the Mediterranean and Alpine regions with different characteristics in terms of climatic conditions, hydrogeological properties and data availability. We compare the results of ANN and reservoir modelling approaches using several performance criteria over different hydrological periods. The results show that both ANNs and reservoir models can accurately simulate karst spring discharge but also that they have different advantages and drawbacks: (i) ANN models are very flexible regarding the format and amount of input data, (ii) reservoir models can provide good results even with a few years of relevant discharge in the calibration period and (iii) ANN models seem robust for reproducing high-flow conditions, while reservoir models are superior in reproducing low-flow conditions. However, both modelling approaches struggle to reproduce extreme events (droughts, floods), which is a known problem in hydrological modelling. For research purposes, ANN models have been shown to be useful for identifying recharge areas and delineating catchments, based on insights into the input data. Reservoir models are adapted to understand the hydrological functioning of a system by studying model structure and parameters.

Tracking contaminants in groundwater flowing across a river bottom within a complex karst system: Clues from hydrochemistry, stable isotopes, and tracer tests

Tracking contaminants in karst aquifers is challenging because of the high heterogeneity encountered in carbonate rocks. Multi-tracer tests, combined with chemical and isotopic analyses, were conducted to solve a groundwater contamination incident within a complex karst aquifer in Southwest China. Results showed that: (1) the wastewater from a paper mill, public sewers, and septic tanks were the three main potential contaminant sources identified by chemical and isotopic methods; (2) a direct effect of the paper mill wastewater with high Na+ (up to 2230.5 mg/L) and chemical oxygen demand (COD) concentrations on spring water quality was confirmed by multi-tracer tests, which changed the water type from Ca–HCO3 in the 1970s to Ca–Na–HCO3 in the present study and resulted in a depleted carbon isotope value (−16.5‰); and (3) the studied aquifer is a highly complex karst system, due to two conduits crossed each other without mixing, contaminants traveled a long distance (up to 14 km) within the lower conduit, paper mill-contaminated groundwater flowed across a river bottom and discharged to the opposite bank, and an active subsurface divide occurred. After several months of operation, the groundwater restoration measure based on karst hydrogeologic conditions proved that cutting off contaminant sources for karst aquifer self-restore was effective in practice, which contributed to the decline in NH4+ (from 7.81 mg/L to 0.04 mg/L), Na+ (from 50.12 mg/L to 4.78 mg/L), and COD (from 16.42 mg/L to 0.9 mg/L) concentrations coupled with an increase in δ13C-DIC value (from −16.5‰ to −8.4‰) in the earlier contaminated karst spring. This study's integrated method is expected to screen and confirm contaminant sources within complex karst systems rapidly and effectively, thereby contributing to karst groundwater environmental management.

Regional Analysis of Tracer Tests in the Karstic Basin of the Gacka River (Croatian Dinaric Karst)

Tracer testing is the only method in karst hydrogeology that can definitively determine whether a particular site belongs to a watershed of a particular karst spring. Therefore, it is an essential technique for delineating groundwater basins in karst areas. The availability of tracer test results is often limited due to the complicated and relatively expensive application of this approach, especially for large regional watersheds. The Croatian part of the Dinaric karst region extends for several hundred kilometers along the Adriatic coast and consists almost entirely of highly karstified carbonate rocks. The groundwater basins in these areas almost never match the surface morphology of the terrain. In practice, all available results of previous surveys are often used to define watersheds, regardless of the methodology and age of their implementation. This is also true for the earlier delineations of the Gacka River watershed, a regional karst basin in the Croatian Dinaric karst. However, tracer testing methods, especially the accuracy of tracer determination and monitoring, have improved significantly during this time. In order to assess the reliability of past tracing results in this significant karst basin, we reviewed reports of previous tracer tests. More recent tests, in particular the most recent multitracer injection test with continuous tracer detection on the major springs, produced high-quality data that allowed us to assess the reliability of the findings from prior research. A number of large karst springs with partially overlapping subcatchments feed the Gacka River. After discarding unreliable tracing data, we reevaluated the subcatchments of the main springs as well as the characteristics of the regional groundwater flow patterns throughout the basin, which is particularly important for water quality protection measures of the springs. The Gacka River basin is used as a case study to emphasize the importance of thoroughly assessing the reliability of previous tracing data before using them in regional analyses.

Subterranean transport of microplastics as evidenced in karst springs and their characterization using Raman spectroscopy

The increasing use of plastic materials has led to accumulation of large amounts of plastic waste in environment and a global challenge to be tackled with. The natural process of macro-plastics aging generates a multitude of secondary microplastic fragments accumulating in all areas of the planet. The pollution with microplastics of large water bodies, such as rivers, seas and oceans was already proven, but the presence of microplastics even in karst spring water was not reported yet. In this study, Raman micro-spectroscopy was used to confirm the presence of microplastics in the spring water samples collected from two rural karst springs in the Apuseni Mountains (Țarina and Josani), North-Western Romania. Two sets of water samples of 1000 L collected in spring time 2021 and one in autumn 2021 were filtered and analyzed. Using the Python programming language and combining two separate Raman databases, one for plastics and the other for pigments, we established a customized database to unambiguously identify the type of plastic and pigment present in the discovered micro-fragments. The generated reference pigment-plastic spectra were compared to those of potential microplastics found on filters and Pearson's coefficient was used to measure the level of similarity. The presence of microplastics in karst spring waters was confirmed and a quantitative estimation expressed as number of fragments or fibers per liter was 0.034 in Josani and 0.06 in Țarina karst spring. Five months later sampling (autumn 2021) revealed 0.05 microplastics per liter. The spectral results revealed that most microplastics found were dominated by polyethylene terephthalate (PET), followed by polypropylene and interestingly, abundant blue micro-fragments were identified according to their copper phthalocyanine pigments (pigment Blue 15) or indigo carmine (pigment Blue 63) characteristic spectral fingerprints, which surpassed the inherent spectral background level characteristic for the Raman spectra of naturally contaminated waste micro-samples. Their origin in mountain karst spring waters and potential decrease in time is discussed.

Emerging organic contaminants in springs of the highly karstified Dinaric region

Emerging organic contaminants (EOCs) have become of increasing interest due to concerns about their impact on humans and the wider environment. Karst aquifers are globally widespread, providing critical water supplies and sustaining rivers and ecosystems, and are particularly susceptible to pollution. However, EOC distributions in karst remain quite poorly understood. This study looks at the occurrence of EOCs in the Croatian karst, which is an example of the “classical” karst, a highly developed type of karst that occurs throughout the Dinaric region of Europe. Samples were collected from 17 karst springs and one karst lake used for water supply in Croatia during two sampling campaigns. From a screen of 740 compounds, a total of 65 compounds were detected. EOC compounds from the pharmaceutical (n = 26) and agrochemical groups (n = 26) were the most frequently detected, while industrials and artificial sweeteners had the highest concentrations (range 8–440 ng/L). The number of detected compounds and the frequency of detection demonstrate the vulnerability of karst to EOC pollution. Concentrations of 5 compounds (acesulfame, sucralose, perfluorobutane sulfonate, emamectin B1b, and triphenyl phosphate) exceeded EU standards and occurred at concentrations that are likely to be harmful to ecosystems. Overall, most detections were at low concentrations (50 % <1 ng/L). This may be due to high dilution within the exceptionally large springs of the Classical karst, or due to relatively few pollution sources within the catchments. Nevertheless, EOC fluxes are considerable (10 to 106 ng/s) due to the high discharge of the springs. Temporal differences were observed, but without a clear pattern, reflecting the highly variable nature of karst springs that occurs over both seasonal and short-term timescales. This research is one of a handful of regional EOC investigations in karst groundwater, and the first regional study in the Dinaric karst. It demonstrates the need for more frequent and extensive sampling of EOCs in karst to protect human health and the environment.

Assessing the Effect of Conduit Pattern and Type of Recharge on the Karst Spring Hydrograph: A Synthetic Modeling Approach

It is widely accepted that spring hydrographs are an effective tool for evaluating the internal structure of karst aquifers because they depict the response of the whole aquifer to recharge events. The spring hydrograph is affected by various factors such as flow regime, geometry, type of recharge, and hydraulic properties of conduit. However, the effect of conduit network geometry received less attention and required more comprehensive research studies. The present study attempted to highlight the impact of the two most frequent patterns of karst conduits (i.e., branchwork and network maze) on the characteristic of the spring hydrograph. Therefore, two conduit patterns, branchwork and network maze, were randomly generated with MATLAB codes. Then, MODFLOW-CFP was used to quantify the effect of conduit pattern, conduit density, and diffuse or concentrated recharge on the spring hydrograph. Results reveal that peak discharge, fast-flow recession coefficient, and the return time to baseflow are mainly affected by conduit network pattern, conduit network density, and recharge, respectively. In contrast, the time to reach peak flow only reacts to recharge conditions. Large variations in conduit density produce tangible changes in the baseflow recession coefficient.

Circadian (re)colonisation dynamics of macroinvertebrates in an isolated karst spring.

Freshwater ecosystems, especially springs, are highly sensitive to environmental changes. They are also excellent natural laboratories because of their stable conditions, reducing the number of variables to be considered in field studies. We examined the composition, dynamics and colonisation patterns of macroinvertebrates with respect to canopy coverage and time of day in which available areas are actively colonised. We used artificial substrates that mimicked the natural habitat structure at an isolated karst spring and recovered exposed substrates every 12 h. Physico-chemical parameters of water did not differ significantly regardless of canopy cover. The most numerous representatives and the pioneering champions were larvae of Baetidae (Ephemeroptera) and Chironomidae (Diptera). Simuliidae were also among the most successful pioneering species. Most observed groups more actively colonised substrates in the closed canopy area. Oligochaeta and Gammarus fossarum were more numerous on substrates in the open canopy area. Individuals of all analysed groups showed day-night migration patterns and were more active at night. Coleoptera (Elmis sp.) were the poorest (re)colonisers among the analysed taxa.

Arthur Marble Aquifer and Te Waikoropupu Springs, New Zealand: flow contributions and nitrate sources

This paper investigates sources of early signs of nitrate pollution in a karst aquifer and major karst spring. Te Waikoropupu Springs are the largest springs in New Zealand and amongst the largest in the Southern Hemisphere with a mean outflow of 13.4 m3/s. They discharge the clearest water ever recorded from a karst spring, but early warning of water quality deterioration is signalled by increasing nitrate concentrations. The springs discharge water from a partly artesian aquifer of 2.85 km3 volume in karstified Ordovician marble with a transmission time averaging 7.9 years. Reservoir porosity is unusually high for a crystalline carbonate rock, estimated as 6%. Water emerging at Main Spring (9.89 m3/s) and adjacent Fish Creek Springs (3.48 m3/s) is a mix of recharge from four main sources. The paper investigates by means of mass balance modelling the proportions of water coming from each source, the origins of nitrate contamination and the contribution of nitrification. Water losses into the bed of the upper Takaka River, about 17 km from the Springs, provide 13% of the mean flow at Main Spring, 34% of the flow at Fish Creek Springs, and 83% of the volume discharged at submarine springs. Infiltration from rain falling over farmed land in the middle valley is estimated to supply 10% of total outflow at Main Spring and Fish Creek Springs but to contribute 82% of the NO3-N output discharged at the springs. Nitrification accounts for 16% of the nitrate discharged. A 34% reduction of leachate concentration in the middle valley would be required to bring NO3-N values at Main Spring back to levels recorded in the 1970s.

Development of SLO KARST Near Fault Observatory site in SW Slovenia

The project RI-SI-EPOS (Research Infrastructure-Slovenia-European Plate Observing System) provided new scientific equipment for solid Earth science related to geology, seismology, geodesy and karstology. Karst research infrastructure is primarily used at the SLO KARST NFO (Near Fault Observatory) developing site. The area covers ~ 2600 km2 and is one of the most seismically active areas in SW Slovenia. It consists mostly of karstified Mesozoic carbonate rocks and partly of non-karstified Eocene flysch. The landscape has numerous karst features including caves, poljes, dolines, uvalas, karst springs, ponors and periodic karst lakes, with typical karst underground water drainage. Site development commenced with the installation of seven temporary seismic stations in the area, along with other geoscience equipment (gravimeter, 3D laser terrestrial scanner, GNSS antenna, TM72 extensometers, spectrometer for methane and drone), deployed in 2020. With the new dense seismic network, locations and other seismic parameters are already determined more reliably than in the past, contributing to a better understanding of active tectonic deformations at the junction between the seismically active Friuli region (Italy) and the Zagreb–Petrinja area (Croatia). The new solid Earth Geoscience research infrastructure is already collecting a big amount of data following the FAIR principles (making data Findable, Accessible, Interoperable and Reusable) aiming to be included in the national and international research databases. Here, the first results from the newly operating SLO KARST NFO temporary seismic network (May 2020–June 2021) are discussed.

Geochemical signature of the bed sediments at the outlet of the Ibrahim River (Lebanon): temporal variation

Bed sediments were collected monthly at the outlet of the Ibrahim River between May 2016 and July 2017. Their physical and chemical characteristics were studied to highlight the impact of seasonal variations and discharge on the sediments' geochemical signatures. Granulometric analysis showed that samples collected after rain events contained abundant sand fractions (> 80%), while the clay fraction was more present at the beginning of the dry season, at low monthly average flows (1 m3/s). Ten major elements, 14 rare earth elements (REE), and 30 trace elements (TE) were analyzed. An excess of CaO reflected the contribution of the carbonate rocks of the Ibrahim karstic springs (30.35 ± 3.91%) but CaO concentration decreased during periods of high water. On another hand, no REE enrichment was detected, both in high and low flows. Most sediments collected at low flow had a pronounced REE depletion that occurred particularly for LREE composition (Nd, Pr, Ce, and La). A negative Ce anomaly (0.992) and a positive Eu anomaly (1.313) were revealed with an average La/Yb ratio of 0.570, reflecting a slight enrichment in HREE. Most studied TE were less concentrated than the averages mentioned in PAAS, UCC, and WSA references. However, a Ze enrichment was mainly due to the regional geochemical background, an As enrichment was associated with anthropogenic contribution, and a Zr enrichment was linked to discharges from pharmaceutical industries located at the river outlet. This study still needs to be complemented binding both spatial and temporal criteria for further fluvial sediments' monitoring of the entire catchment area.

Last Glacial Maximum cryogenic calcite deposits in an alluvial fan at Villetoureix, southwest France

AbstractThe origin of white calcite silts forming 0.5 to 3‐cm‐thick lenses in alluvial fan deposits 14C‐dated to the Last Glacial Maximum in the Dronne Valley (Dordogne, southwest France) is investigated using microscopic imagery, chemistry, and O and C stable isotopes. The calcite silts, composed mainly of aggregates of 3–5‐μm euhedral crystals, do not resemble secondary precipitations of pedological origin because of the strata‐like pattern and the lack of clearly identifiable biological structures. Their association with evidence of ice formation in the soil (platy structure, involutions) suggests that they were deposited in a deep seasonal frost context. Their isotopic composition differs significantly from those of detrital carbonates and of Holocene bioprecipitation and seems to be best explained by precipitation under closed‐system conditions. Calculation of the isotopic composition of calcite that would have formed in equilibrium with groundwater of regional LGM aquifers provides values that are in the range of the composition of the calcite silts for a precipitation temperature close to 0°C. Therefore, these deposits are interpreted as cryogenic calcite precipitated from waters close to saturation with respect to calcite freezing at the base of/within icings or within the ground, possibly from frost blisters. Similar calcite precipitation at the outlet of karstic springs may have been abundant in the calcareous terrains of southwest France during the LGM, although still unrecognized in the geological record.

Study on turbidity sources for a karst spring downgradient of a marble quarry

Study on turbidity sources for a karst spring downgradient of a marble quarry

Accumulation, conversion and storage of solute from sinkholes to karst spring under concentrated recharge conditions

Concentrated recharge processes can define water quantity and quality in karst aquifer systems. Hydrological and hydrochemical dynamics at Qinglongkou (QLK) spring and two sinkholes were synchronously monitored to elucidate solute migration processes under concentrated recharge conditions. The results show that the hydrological and hydrochemical processes of the sinkholes and karst spring have corresponding impulse responses after rainfall events. The components of the leachate including Ca2+, Mg2+, Sr2+ and HCO3− in QLK spring decrease due to dilution during the periods of concentrated recharge, but their fluxes increase by 4% to 271% compared to the sinkholes input owing to the continuous water–rock interactions. Most chemical indicators are diluted along the hydrograph peaks, but the pollutants including nitrogen and phosphorus are aggregated to higher values after rainstorms, both at sinkholes and spring outlet, with total inorganic nitrogen and PO43− concentrations up to 11.34 mg/L and 1.16 mg/L. During heavy rainfall events, the nutrients from agricultural activities are easily dissolved into overland flow, and nitrification mainly controls the nitrogen conversion in karst aquifer system. Pollutant fluxes of karst spring are lower than that of sinkholes due to solute storage, and pollutant concentrations are 2∼3 times higher than their natural background values in spring outlet after rainstorms. Accumulation and storage of pollutants are problems that cannot be underestimated for the clean utilization of karst water resources and the prevention, control, and repair of karst groundwater pollution, which pose severe threats to the karst water quality.

Characteristic of regional groundwater flow system: case modeling study in Longzici karst spring area, North China

Characteristic of regional groundwater flow system: case modeling study in Longzici karst spring area, North China

KarstID: an R Shiny application for the analysis of karst spring discharge time series and the classification of karst system hydrological functioning

KarstID: an R Shiny application for the analysis of karst spring discharge time series and the classification of karst system hydrological functioning

Morphological Typology and Petrography of Plio-Quaternary Continental Carbonates of Aït Chaïb, Skoura Basin, Middle Atlas, Morocco

The Plio-Quaternary Ait Chaib basin occupies the northwestern part of the Skoura Syncline, which is part of the northern Middle Atlas Folded Zone. This intracontinental basin was formed probably in the Pliocene after the Tortono-Messinian regression sea. The Plio-Quaternary deposits are bound by fluvial conglomerates and continental carbonates. They consist of barrage travertines; travertine limestones and oncholitic travertine silts and sands of the upstream and downstream deposits. These travertines laterally pass to lacustrine limestones at the bottom of the basin. The genesis of these continental carbonates, correlative to phases of karstification, has affected the Meso-Cenozoic carbonate deposits of the folded Middle Atlas, and is linked to favorable paleo-environmental conditions of geological, geomorphological, hydrogeological, hydrological and bioclimatic order. The petrographic study of these lacustrine limestones shows laminar structure allowing to assimilate into continental stromatolites. They were formed by cyanobacterial mats in a shallow lacustrine environment in which water were was non-turbid and supersaturated in limestone solution, coming from karstic springs staking out the Middle Atlasic North Accident. The important diagenesis evolution is linked to the surface water table contain, which has as a floor gypsiferous lagoonal marl of the Upper Miocene age.