Kaapvaal Research Articles

Sulphur isotopes (δ34S and Δ33S) in sulphides from cratonic mantle eclogites: A glimpse of volatile cycling in ancient subduction zones

Multiple sulphur isotopic compositions of sulphides from Kaapvaal craton mantle eclogites allow to elucidate the recycling of sulphur into the deep Earth and to differentiate between recycled crust and mantle origins of eclogite-hosted sulphides, including the precious metals that they capture. We present multiple sulphur isotope ratio measurements by secondary ion mass spectrometry for sulphides from a collection of mantle-derived eclogite xenoliths from Proterozoic and Mesozoic kimberlite occurrences in South Africa (Premier, Roberts Victor, Jagersfontein). Previous work established that the host eclogites have elemental and oxygen isotopic compositions in support of seawater-altered oceanic lithosphere protoliths, and for many of these xenolith suites Archean ages have been suggested.The eclogite-hosted sulphides have δ34S values from −5.7 to +29‰, with the upper end of this wide range representing the highest-ever recorded δ34S composition of material derived from the Earth's mantle. The Δ33S values range from −0.29 to +0.18‰ and do not record significant mass-independent sulphur isotope fractionation, i.e., there is no compelling S-MIF signature. Most of the sulphide grains have δ34S values that fall within a range between −6 and +4‰, and they probably retain an isotopic record of sulphides that formed originally within altered oceanic crust. In contrast, the highly positive δ34S values from +13 to +29‰ detected in sulphide grains from a single eclogite xenolith are similar to those of marine sulphates, which were probably a minor sulphur component of the oceanic crustal protolith. The lack of a significant S-MIF signature in the eclogitic sulphides that show δ34S evidence for a recycled crust origin implies that this sulphur component stems from a <2.4Ga post-Archean surficial reservoir. This finding suggests that the cratonic mantle eclogites may have formed from post-Archean oceanic crust (e.g., Paleoproterozoic eclogite protoliths), or – as is preferred here – the ‘surficial’ sulphur was introduced into the cratonic root during relatively young metasomatic events and is thus unrelated to eclogite petrogenesis and Archean continent formation.

Evolution of ultrapotassic volcanism on the Kaapvaal craton: deepening the orangeite versus lamproite debate

Abstract Orangeites are a significant source of diamonds, yet ambiguity surrounds their status among groups of mantle-derived potassic rocks. This study reports mineralogical and geochemical data for a c. 140 Ma orangeite dyke swarm that intersects the Bushveld Complex on the Kaapvaal craton in South Africa. The dykes comprise distinctive petrographic varieties that are linked principally by olivine fractionation, with the most evolved members containing minor amounts of primary carbonate, sanidine and andradite garnet in the groundmass. Although abundant groundmass phlogopite and clinopyroxene have compositions that are similar to those of cratonic lamproites, these phases show notable Ti-depletion, which we consider a hallmark feature of type orangeites from the Kaapvaal craton. Ti-depletion is also characteristic of bulk rock compositions and is associated with strongly depleted Th–U–Nb–Ta contents at high Cs–Rb–Ba–K concentrations. The resultant high large ion lithophile element/high field strength element ratios of orangeites suggest that mantle source enrichment occurred by metasomatic processes in the proximity of ancient subduction zones. The Bushveld-intersecting orangeite dykes have strongly enriched Sr–Nd–Hf isotopic compositions (initial 87 Sr/ 86 Sr = 0.70701–0.70741; ε Nd = −10.6 to −5.8; ε Hf = −14.4 to −2.5), similar to those of other orangeites from across South Africa. Combined with the strong Ti–Nb–Ta depletion, this ubiquitous isotopic feature points to the involvement of ancient metasomatized mantle lithosphere in the origin of Kaapvaal craton orangeites, where K-rich metasomes imparted a ‘fossil’ subduction geochemical signature. Previous geochronology studies identified ancient K-enrichment events within the Kaapvaal cratonic mantle lithosphere, possibly associated with collisional tectonics during the 1.2–1.1 Ga Namaqua–Natal orogeny of the Rodinia supercontinent cycle. It therefore seems permissible that the cratonic mantle root was preconditioned for ultrapotassic magma production by tectonomagmatic events that occurred along convergent plate margins during the Proterozoic. However, reactivation of the K-rich metasomes had to await establishment of an extensional tectonic regime, such as that during the Mesozoic breakup of Gondwana, which was accompanied by widespread (1000 × 750 km) small-volume orangeite volcanism between 200 and 110 Ma. Although similarities exist between orangeites and lamproites, these and other potassic rocks are sufficiently distinct in their compositions such that different magma formation processes must be considered. In addition to new investigations of the geodynamic triggers of K-rich ultramafic magmatism, future research should more stringently evaluate the relative roles of redox effects and volatile components such as H 2 O–CO 2 –F in the petrogeneses of these potentially diamondiferous alkaline rocks.

The onset of deep recycling of supracrustal materials at the Paleo-Mesoarchean boundary.

The recycling of supracrustal materials, and in particular hydrated rocks, has a profound impact on mantle composition and thus on the formation of continental crust, because water modifies the physical properties of lithological systems and the mechanisms of partial melting and fractional fractionation. On the modern Earth, plate tectonics offers an efficient mechanism for mass transport from the Earth's surface to its interior, but how far this mechanism dates back in the Earth's history is still uncertain. Here, we use zircon oxygen (O) isotopes to track recycling of supracrustal materials into the magma sources of early Archean igneous suites from the Kaapvaal Craton, southern Africa. The mean δ18O values of zircon from TTG (tonalite–trondhjemite–granodiorite) rocks abruptly increase at the Paleo-Mesoarchean boundary (ca. 3230 million years ago; Ma), from mantle zircon values of 5‰–6‰ to approaching 7.1‰, and this increase occurs in ≤3230 Ma rocks with elevated Dy/Yb ratios. The 18O enrichment is a unique signature of low-temperature water–rock interaction on the Earth's surface. Because the later phase was emplaced into the same crustal level as the older one and TTG magmas would derive from melting processes in the garnet stability field (>40 km depth), we suggest that this evident shift in TTG zircon O isotopic compositions records the onset of recycling of the mafic oceanic crust that underwent seawater hydrothermal alteration at low temperature. The onset of the enhanced recycling of supracrustal materials may also have developed elsewhere in other Archean cratons and reflects a significant change in the tectonic realm during craton formation and stabilization, which may be important processes for the operation of plate tectonics on early Earth.

Multiple metasomatic diamond-forming events in a cooling lithosphere beneath Voorspoed, South Africa

Thermal events and metasomatic processes have influenced the Kaapvaal craton in South Africa. High-density fluids (HDFs) trapped as microinclusions in diamond are main metasomatic agents which provide an insight to these processes in the Earth's mantle. Here we present data for 15 fibrous, HDF-bearing diamonds from the Voorspoed mine, South Africa, reflecting multiple diamond-forming events in a cooling lithosphere. Analyzed by FTIR and EPMA, the Voorspoed fibrous diamonds reveal three populations that differ in their nitrogen aggregation and HDF composition. A silicic‑carbonatitic group containing 11–30% B-centers, a saline group containing 5–16% B-centers, and a single high-Mg carbonatitic diamond with 0% B-centers. The distinct nitrogen aggregation of the fibrous diamond groups in Voorspoed and the lack of clear major element evolutionary trends for each HDF type or intermediate compositions between the different types suggest different time-temperature formation histories. Thermobarometry of mineral inclusions in non-fibrous monocrystalline Voorspoed diamonds (Viljoen et al., 2018) indicates that the Voorspoed lithosphere cooled by 100–200 °C since their host diamonds crystallized at high initial temperatures. High temperatures in Voorspoed lithosphere can be correlated with the eruption of the Ventersdorp flood basalts at the central Kaapvaal (ca. 2.7 Ga) or the Bushveld complex (ca. 2.06 Ga), and cooling rates of the lithosphere provide a time frame for a cooling process that originated ~2–3 Ga. Combining these data with the nitrogen aggregation systematics of fibrous and monocrystalline Voorspoed diamonds, we suggest that most Voorspoed diamonds formed during 4 metasomatic events: the oldest one recorded took place between 2 and 3 Gyr as a result of a major thermal perturbation, whereas the following three occurred between 200 and 600 Myr, 30–90 and < 30 Myr before kimberlite eruption in a cooling lithosphere. An even older (or deeper) event is hinted by a few diamonds where all nitrogen is in B-centers. The sequence of events implied by Voorspoed HDF compositional and nitrogen aggregation differences show affinities with other occurrences in South Africa (e.g. Kimberley, Finsch and Koffiefontein) and may reflect thermal and lithological variation between the central and southwest Kaapvaal lithosphere.

Sheared Peridotite and Megacryst Formation Beneath the Kaapvaal Craton: a Snapshot of Tectonomagmatic Processes across the Lithosphere–Asthenosphere Transition

AbstractThe cratonic lithosphere–asthenosphere boundary is commonly invoked as the site of sheared peridotite and megacryst formation, a well-recognized petrological assemblage whose genetic relationships—if any—remain poorly understood. We have undertaken a comprehensive petrology and Sr–Nd–Hf–Ca isotope study of sheared peridotite xenoliths and clinopyroxene megacrysts from the c. 1150 Ma Premier kimberlite pipe on the central Kaapvaal craton in South Africa. New textural and mineral trace element evidence suggests that strong tectonic and magmatic overprinting affected the lower cratonic mantle over a vertical distance of ≥50 km from the lithosphere–asthenosphere boundary located at ∼200–225 km depth. Although modification of the central Kaapvaal cratonic mantle is commonly linked to the c. 2056 Ma Bushveld large igneous event, our thermobarometry, mantle redox, and Sr–Nd–Hf–Ca isotope data support a model in which volatile-rich low-volume melts and associated high-density fluids refertilized the lithosphere base shortly before or during asthenosphere-derived kimberlite and carbonatite magmatism at around 1150 Ma. This episode of lithospheric mantle enrichment was facilitated by exceptionally strong shear movements, as are recorded in the plastically deformed peridotites. We argue that stress-driven segregation of percolating carbonated melts contributed to megacryst formation along, or in close proximity to, shear zones within the cratonic mantle lithosphere. Integration of our results from the Kaapvaal craton and modern petrological concepts allows for the identification of a lithosphere–asthenosphere transition zone between ∼150 and 225 km depth. This horizon is defined by intersections of the ∼40–42 mW m–2 Premier paleogeotherm with (1) CO2–H2O-present solidus curves for peridotite (upper bound), and (2) typical mantle adiabats with potential temperatures between 1315 and 1420 °C (lower bound). At Premier, the most strongly deformed sheared peridotites occur mainly between ∼160 and 185 km depth, firmly within the lithosphere–asthenosphere transition zone. Contrary to many previous models, we suggest that sheared peridotite formation occurs in localized deformation zones spaced out across the entire width of the lithosphere–asthenosphere transition zone, rather than being restricted to a single thin layer at the craton base where mantle flow causes viscous drag. Hence, plate-tectonic stresses acting on the lower cratonic lithosphere may be accommodated by extensive networks of shear zones, which provide transient pathways and sinks for percolating volatile-rich melts, linking the formation of megacrysts and sheared peridotites.

A geochemical study of the Crown Formation and Bird Member lavas of the Mesoarchaean Witwatersrand Supergroup, South Africa

Abstract The ca. 2.97 to 2.80 Ga Witwatersrand Supergroup, South Africa, represents the oldest intracontinental sedimentary basin of the Kaapvaal craton. Two volcanic units occur in this supergroup: the widespread Crown Formation lavas in the marine shale-dominated West Rand Group and the more geographically restricted Bird Member lavas, intercalated with fluvial to fluvio-deltaic sandstone and conglomerate of the Central Rand Group. These units remain poorly studied as they are rarely exposed and generally deeply weathered when cropping out. We report whole-rock major and trace elements, Hf and Nd-isotope whole-rock analyses of the lavas from core samples drilled in the south of the Witwatersrand basin and underground samples from the Evander Goldfield in the northeast. In the studied areas, both the Crown Formation and Bird Member are composed of two units of lava separated by sandstone. Whereas all the Crown Formation samples show a similar geochemical composition, the upper and lower volcanic units of the Bird Member present clear differences. However, the primitive mantle-normalized incompatible trace element concentrations of all Crown Formation and Bird Member samples show variously enriched patterns and marked negative Nb and Ta anomalies relative to Th and La. Despite the convergent geodynamic setting of the Witwatersrand Supergroup suggested by the literature, the Crown Formation and Bird Member are probably not related to subduction-related magmatism but more to decompression melting. Overall, the combined trace element and Sm-Nd isotopic data indicate melts from slightly to moderately depleted sources that were variably contaminated with crustal material. Greater contamination, followed by differentiation in different magma chambers, can explain the difference between the two signatures of the Bird Member. Finally, despite previous proposals for stratigraphically correlating the Witwatersrand Supergroup to the Mozaan Group of the Pongola Supergroup, their volcanic units are overall geochemically distinct.

A reappraisal of legacy reflection seismic data from the western margin of the Kaapvaal craton, South Africa, with implications for Mesozoic-Cenozoic regional tectonics

The 150 km long, 6 s TWT, 2D seismic profile KBF03A, which was acquired in 1994 and lies near the western edge of the Kaapvaal craton in South Africa, has been reprocessed using standard reflection seismic processing methods. The results exhibit a significant improvement in the imaging quality of the subsurface features and an evident boost in the signal-to-noise ratio. The improved seismic data, combined with application of seismic attributes, integration with surficial geological and geophysical maps, and computation of velocity tomograms, has revealed previously undetected structural features within the supracrustal sequences underlying the profile. In particular, the Phanerozoic sediments found along the profile, comprising exclusively Kalahari Group and Dwyka Group deposits, are disrupted by multiple folds of varying wavelengths (~1–10 km) and variably oriented normal and thrust faults. Additionally, the effect of the Moshaweng fault, previously characterised as a listric fault extending to depths of >10 km, on the Phanerozoic sediments has been further constrained to suggest repeated extensional reactivations and a more recent (<1 Ma) inversion. Considerations of the eastern end of the profile have suggested links between some of the observed structural features and the nearby ~146 Ma Morokweng impact structure, the lateral expanse of which is poorly constrained in the literature. The collection of these newly imaged features is interpreted as evidence for multiple Late Mesozoic to Cenozoic tectonic events, including polyphasic reactivation of basement structures, under both extensional and compressional stress regimes. By analysing these newly detected features, our study not only provides new insight into the neotectonic evolution of the Phanerozoic sediments along the western margin of the Kaapvaal craton, but also demonstrates the utility in reprocessing legacy data and reveals its untapped potential.

Cr-poor and Cr-rich clinopyroxene and garnet megacrysts from southern African Group 1 and Group 2 kimberlites: Clues to megacryst origins and their relationship to kimberlites

Controversies surround the origin of kimberlite megacrysts, including whether and how they are genetically related to their host kimberlites, the relationship between the Cr-poor and Cr-rich suites and the dominant processes responsible for elemental and isotopic variations of megacrysts from a given kimberlite. We present new in-situ major and trace element and Sr isotopic results for clinoyroxene and garnet megacrysts from four southern African kimberlites: Colossus and Orapa (Group 1 kimberlites on the Zimbabwe craton), and Kalkput and Bellsbank (Group 2 kimberlites on the western Kaapvaal craton), that include both Cr-poor and Cr-rich megacryst varieties. Cr-poor megacrysts are present at Colossus, Orapa and Kalkput and the data exhibit tight, well-defined trends on major element diagrams as well as incompatible and rare earth element abundances similar to those previously reported for Cr-poor megacrysts. Cr-rich megacrysts, which are also present at Orapa and are the only variety present at Bellsbank, generally have higher Mg# values, lack well-defined major element trends and show stronger incompatible element enrichments as well as more radiogenic 87Sr/86Sri ratios than Cr-poor megacrysts from the same kimberlite group. Thermobarometry indicates that the Cr-poor megacrysts equilibrated at temperatures of ≈1200 to 1450 °C and pressures of 4.5 to 7.5 GPa. Cr-rich megacrysts, in contrast, extend to temperatures and pressures as low as 700 °C and 3 GPa, respectively. This indicates that, in the studied suites, Cr-poor megacrysts equilibrated at high temperatures in the lower lithosphere (>135 km), whereas Cr-rich megacrysts typically equilibrated at lower temperatures and pressures. Within the Cr-poor megacrysts from Group 1 and Group 2 kimberlites, there is a clear correspondence between kimberlite group, diagnostic incompatible element ratios (e.g., Nb/La) and Sr isotope ratios that parallel the differences noted between whole-rock Group 1 and Group 2 kimberlites. In the case of Cr-poor megacrysts, similar calculated melt compositions in equilibrium with garnet and clinopyroxene from the same kimberlite were obtained using recent high-pressure mineral‑carbonated melt partition coefficients. This suggests formation in conditions close to trace element equilibrium, and is consistent with crystallization from primitive melts with kimberlite-like trace element compositions. In the case of Cr-rich megacrysts, differences in the compositions of melts in equilibrium with clinopyroxene and garnet tend to be larger, and melts in equilibrium with Cr-rich clinopyroxene tend to show significantly greater incompatible element enrichments than those of estimated near-primary kimberlite melts. This could be due to the different behaviour of clinopyroxene and garnet during metasomatic melt-rock interaction, but the apparent disequilibrium between clinopyroxene and garnet could also be due to some of the Cr-rich megacrysts actually being peridotitic xenocrysts. We propose a model for the origin of southern African megacrysts in which carbonated protokimberlite melts formed stockwork-like bodies of variable size in the deep lithosphere (>130 km), which fed networks of melt-filled veins extending into the surrounding and overlying mantle. Crystallization of larger melt bodies resulted in megacryst assemblages dominated by Cr-poor megacrysts, and the incompatible element and isotopic characteristics of these dominantly reflect those of the protokimberlite melt. In contrast, crystallization of smaller melt bodies and their vein networks resulted in megacryst assemblages dominated by Cr-rich megacrysts, which formed as a result of extensive assimilation and metasomatic melt-rock interaction between protokimberlite and peridotite wallrock at low melt/rock ratios, particularly in the middle to shallow lithosphere where pre-existing potassic metasomatic heterogeneities are prevalent. The Cr-rich nature and enrichments in incompatible elements and radiogenic Sr in the Cr-rich megacrysts reflect extensive interaction of their parental magmas with this metasomatized peridotite.

Metasomatized eclogite xenoliths from the central Kaapvaal craton as probes of a seismic mid-lithospheric discontinuity

The central region of the Kaapvaal craton is relatively understudied in terms of its lithospheric mantle architecture, but is commonly believed to be significantly impacted by post-Archean magmatism such as the ca. 2056 Ma Bushveld large igneous event. We investigate a collection of 17 eclogite xenoliths from the Cretaceous Palmietfontein kimberlite at the Western Limb of the Bushveld Complex for their mineralogical compositions (major and trace elements, plus Fe3+ contents), as well as stable oxygen and radiogenic Pb isotopic compositions to gain further insights into the nature and evolution of the central Kaapvaal cratonic mantle lithosphere. New U/Pb age determinations on mantle-derived zircon yield a magma emplacement age of ca. 75 Ma for the Palmietfontein Group-1 kimberlite, which means that the entrained eclogite xenoliths may record a protracted metasomatic history from the Proterozoic through to most of the Phanerozoic eon.Garnet δ18O values of up to 6.9‰ and positive Eu anomalies for the bulk rocks suggest seawater-altered oceanic crustal protoliths for the Palmietfontein eclogite xenolith suite, which is typical for the eclogitic components of the Kaapvaal root and other cratonic mantle sections worldwide. However, several features of the Palmietfontein eclogites are commonly not observed in other mantle-derived eclogite xenolith suites. Firstly, the samples studied yield relatively low equilibration pressures and temperatures between 2.7 and 4.5 GPa and 740–1064 °C, indicating a relatively shallow residence between 90 and 150 km depths. Secondly, euhedral coarse amphibole is present in several eclogite nodules where it is in equilibrium with ‘touching’ garnet, supporting eclogite residence within the amphibole stability field at uppermost lithospheric mantle conditions. Thirdly, primary omphacitic clinopyroxene is often overgrown by diopside, and is significantly enriched in incompatible trace elements. The clinopyroxene is also characterized by elevated 206Pb/204Pb of 17.28–19.20 and 207Pb/204 Pb of 15.51–16.27, and these Pb isotopic compositions overlap with those of Mesozoic Group-2 kimberlites from the Kaapvaal craton.Our results show that eclogites reside at ~85 km depth beneath the central Kaapvaal craton as part of a layer that corresponds to an approximately 50 km thick seismically-detected mid-lithospheric discontinuity. Mid-lithospheric discontinuities have been interpreted as metasomatic fronts formed by focussed crystallization of hydrous mineral phases from enriched volatile-bearing melts, and as such the strongly overprinted amphibole-bearing eclogite xenoliths from Palmietfontein may represent a physical expression of such seismically anomalous metasomatic layer at mid-lithospheric depth. Our Pb isotope data suggest that the focussed metasomatism can be attributed to volatile-rich melts reminiscent of potassic Group-2 kimberlites, which have been invoked in MARID-style metasomatic overprinting of the lower lithospheric mantle beneath the western Kaapvaal craton. However, the relatively low fO2 recorded by the Palmietfontein eclogites (minimum FMQ-4.5) suggests that the metasomatism at mid-lithospheric depth was less protracted compared to the more intensive and oxidizing metasomatism typically observed near the base of cratonic mantle roots. While it is possible that Proterozoic magmatic events were responsible for the focussed mid-lithospheric metasomatism of the Kaapvaal mantle, on the basis of the Pb isotope constraints the Palmietfontein eclogites were most likely overprinted during ca. 120 Ma Group-2 kimberlite magmatism.

Comment on "Correlation of the stratigraphic cover of the Pilbara and Kaapvaal cratons recording the lead up to Paleoproterozoic Icehouse and the GOE" by Andrey Bekker, Bryan Krapež, and Juha A. Karhu, 2020, Earth Science Reviews, https://doi.org/10.1016/j.earscirev.2020.103389

Triple oxygen isotope (∆17O with δ18O) signals of H2O and O2 found in sulfate of oxidative weathering origin offer promising constraints on modern and ancient weathering, hydrology, atmospheric gas concentrations, and bioproductivity. However, interpretations of the sulfate-water-O2 system rely on assuming fixed oxygen-isotope fractionations between sulfate and water, which, contrastingly, are shown to vary widely in sign and amplitude. Instead, here we anchor sulfate-water-O2 triple oxygen isotope systematics on the homogeneous composition of atmospheric O2 with empirical constraints and modeling. Our resulting framework does not require a priori assumptions of the O2- versus H2O‑oxygen ratio in sulfate and accounts for the signals of mass-dependent and mass-independent fractionation in the ∆17O and δ18O of sulfate's O2‑oxygen source. Within this framework, new ∆17O measurements of sulfate constrain ~2.3 Ga Paleoproterozoic gross primary productivity to between 6 and 160 times present-day levels, with important implications for the biological carbon cycle response to high CO2 concentrations prevalent on the early Earth.

Age disequilibrium between zircon and their granitoid hosts caused by intracrustal reworking: Nd-Hf-Ar isotope evidence of Archaean Granitoids from Barberton Mountain Land (Kaapvaal craton, South Africa)

The degree of early Archaean terrestrial differentiation into mantle and crust is long debated. A number of studies rely on bulk rock Hf and Nd isotope data to gain further insight. Here we present Hf-Nd data from two igneous basements suites of Barberton Mountain Land, namely a tonalite-trondhjemite-granodiorite (TTG) and granodiorite-granite-monzogranite (GGM) suite to further decipher crust formation and its timing in the Archaean. TTG show high initial ε(Hf) and ε(Nd) if corrected using their respective U/Pb zircon ages that can be interpreted in two ways: (i) early differentiation of bulk silicate Earth or (ii) overcorrection of these data caused by decoupling of zircon from the ‘zircon-free’ bulk rock due to metamorphic overprint. Indeed, regional metamorphism affected the early TTG ca. 250 Ma after their emplacement and disturbed their bulk rock Hf and Nd systematics. Correction of bulk rock Hf and Nd data to the age of metamorphism yields values between +0.9 and − 6.2 and from −1.3 to −4.3, respectively, thus indicating open-system behaviour. Lu-Hf and Sm-Nd mineral isochron ages of two TTG plutons are significantly younger than their corresponding U/Pb zircon age, but agree within uncertainty perfectly with external age constraints for the age of the metamorphic overprint. The same accounts for the 40Ar-39Ar systematics of the investigated plutons. Amphibole samples consist of a mixture of heterochemical generations that yield ages that are both older and younger than the metamorphic overprint at 3.2 Ga. The metamorphic minerals in each plutons provide a highly divergent age information from the coexisting zircon. Hence, the positive ε(Nd) and ε(Hf)-values that resulted from age-correction to the respective U/Pb zircon age are most probably over-corrected. Finally, if all data is age-corrected to the metamorphic overprint all samples agree with models for the Nd-Hf isotopic evolution in the mantle that do not require a large-scale early differentiation of Earth into enriched and depleted reservoirs. Mantle extraction ages (TDM) of TTG are interpreted as minimum ages for the generation of felsic Archaean crust whereas TDM of GGM are interpreted as maximum ages for the last major crust growth episode in the Barberton Mountain Land.

A Thermodynamic Model for the Subsolidus Evolution and Melting of Peridotite

Abstract We present a structural update to the thermodynamic model for calculating peridotite phase relations and melt compositions at 0·01 to 60 kbar and from 600 °C to the peridotite liquidus in the system K2O–Na2O–CaO–FeO–MgO–Al2O3–SiO2–TiO2–Fe2O3–Cr2O3 (KNCFMASTOCr), based on the model of Holland et al., 2018 [Melting of Peridotites through to Granites: A Simple Thermodynamic Model in the System KNCFMASHTOCr. Journal of Petrology 59, 881–900]. The new model is better able to predict the phase relations and melting of ultramafic rocks, in particular the abundance of orthopyroxene in the residue and the concentration of silica in the melt. In addition, improvements in modelling Cr-spinels mean that the model is now able to reproduce Cr-content of garnet and spinel above and below the solidus without modification to the knorringite free energy. Model calculations indicate that, for peridotite composition KR4003, the spinel to garnet transition intersects the solidus at 22·1–24·8 kbar and orthopyroxene disappears from the solidus at 29·1 kbar. Below the solidus, the model is able to reproduce the abundances and compositions of phases in experimental studies and natural samples spanning a range of compositions, allowing it to be used for investigating subsolidus equilibration during mantle cooling and pressurisation/decompression. The liquid model provides a good fit to experimental data and is able to replicate the position of the solidus and the composition of both melt and residue at and above the solidus for a range of peridotite compositions. The model may, therefore, be used to investigate fractional mantle melting and basalt generation in modern geodynamic regimes, and also to explore equilibrium mantle melting in the early Earth. The model can also be used to explore liquid and residue compositions for melting of non-pyrolitic mantle, for which there is a paucity of experimental data. We demonstrate the scope of the model using two case studies investigating the subsolidus evolution and melting of a silica-rich cratonic peridotite from the Kaapvaal craton.

Dating the Bushveld Complex: Timing of Crystallization, Duration of Magmatism, and Cooling of the World’s Largest Layered Intrusion and Related Rocks

Abstract The Paleoproterozoic Bushveld Complex, including the world’s largest layered intrusion and host to world-class stratiform chromium, platinum group element, and vanadium deposits, is a remarkable natural laboratory for investigating the timescales of magmatic processes in the Earth’s crust. A framework for the emplacement, crystallization, and cooling of the Bushveld Complex based on integrated U–Pb zircon–baddeleyite–titanite–rutile geochronology is presented for samples of different rock types from the Bushveld Complex, including ultramafic and mafic cumulates, mineralized horizons, granitic rocks from the roof, and a carbonatite from the nearby alkaline Phalaborwa Complex. The results indicate that (1) the Bushveld Complex was built incrementally over an ∼5 Myr interval from 2060 to 2055 Ma with a peak in magma flux at c. 2055–2056 Ma, (2) U–Pb zircon crystallization ages do not decrease in an uninterrupted systematic manner from the base to the top of the intrusion, indicating that the Bushveld Complex does not represent the crystallized products of a single progressively filled and cooled magma chamber, and (3) U–Pb rutile dates constrain cooling of the intrusion at the level of the Critical Zone through ∼500 °C by 2053 Ma. The c. 2060 Ma Phalaborwa Complex (pyroxenite, syenite, carbonatite + Cu–Fe-phosphate–vermiculite deposits) represents one of the earliest manifestations of widespread Bushveld-related magmatism in the northern Kaapvaal craton. The extended range and out-of-sequence U–Pb zircon dates determined for a harzburgite from the Lower Zone (c. 2056 Ma), an orthopyroxenite from the Lower Critical Zone (c. 2057 Ma), and orthopyroxenites from the Upper Critical Zone (c. 2057–2060 Ma) are interpreted to indicate that the lower part of the Bushveld Complex developed through successive intrusions and accretion of sheet-like intrusions (sills), some intruded at different stratigraphic levels. Crystallization of the main volume of the Bushveld Complex, as represented by the thick gabbroic sequences of the Main Zone and Upper Zone, is constrained to a relatively narrow interval of time (∼1 Myr) at c. 2055–2056 Ma. Granites and granophyres in the roof, and a diorite in the uppermost Upper Zone, constitute the youngest igneous activity in the Bushveld Complex at c. 2055 Ma. Collectively, these results contribute to an emerging paradigm shift for the assembly of some ultramafic–mafic magmatic systems from the conventional ‘big tank’ model to an ‘amalgamated sill’ model. The volume–duration relationship determined for magmatism in the Bushveld Complex, when compared with timescales established for the assembly of other layered intrusions and more silica-rich plutonic–volcanic systems worldwide, is distinct and equivalent to those determined for Phanerozoic continental and oceanic flood basalts that constitute large igneous provinces. Emplacement of the 2055–2060 Ma Bushveld Complex corresponds to the end of the Lomagundi–Jatuli Event, the largest magnitude positive carbon isotope excursion in Earth history, and this temporal correlation suggests that there may have been a contribution from voluminous Bushveld ultramafic–mafic–silicic magmatism to disruptions in the global paleoenvironment.

Experiment constraints on orthopyroxene enrichment in the Kaapvaal craton lithospheric mantle

Peridotite xenoliths from the Kaapvaal cratonic lithosphere are characterized by high modal orthopyroxene (Opx), which is inconsistent with the mineralogy of residues of partial melting of primitive mantle. The high orthopyroxene content has been explained by the reaction between Opx-poor peridotite and silica-rich melts. To assess and further constrain this model, we conducted a series of experiments on the interaction of Si-rich melt with Opx-poor harzburgite at 1.5 GPa and 1100 to 1250 °C. Orthopyroxene is enriched in all experiments. In the low temperature run at 1100 °C, melt is consumed and phlogopite is precipitated with the generation of orthopyroxene. Mg# (atomic 100*Mg/(Mg+Fe)) values in olivines also exhibit a decrease compared with the starting olivines. At temperatures of ≥1200 °C, phlogopite is absent as the temperatures are higher than its upper stability field. The residues are composed of high modal orthopyroxene and high Mg# olivine. Only the residues in the high temperature runs are consistent with Kaapvaal cratonic mantle xenoliths. Combined our experiments with the distribution, geochronological and geochemical data of the xenoliths, we propose a two-stage ‘metasomatism-depletion’ model to explain the generation of Opx-rich xenoliths in Kaapvaal craton. In the early Archean, high-degree melting of primitive mantle produced a highly depleted lithospheric mantle, which was Opx-poor. Subsequently, Si-rich melts/fluids were released from the subducting oceanic slabs to interact with the Opx-poor mantle, generating an Opx-rich, but hydrous and fertile mantle. The metasomatic mantle is similar to the result of the run at 1100 °C. In the late Archean, the metasomatic mantle was re-melted in post-collisional extensional environments, which produced voluminous lavas with residues of highly depleted, Opx-rich peridotites. The Opx-rich residual peridotites are consistent with the runs at ≥1200 °C. Thus, Opx enrichment in the Kaapvaal craton lithospheric mantle can be well explained by the two-stage ‘metasomatism-depletion’ model.

Constraints on Archean crust recycling and the origin of mantle redox variability from the δ44/40Ca – δ18O – fO2 signatures of cratonic eclogites

The nature of the deep calcium geochemical cycle through time is unresolved, in part due to the dearth of information about the calcium isotope composition of Archean recycled oceanic crust. Remnants of such ancient oceanic crust are preserved in the form of cratonic mantle eclogites, brought to surface as xenoliths in kimberlite magma eruptions. The δ44/40Ca of fresh mantle-derived eclogite xenoliths (i.e., garnet and omphacite mineral separates) from the Bellsbank kimberlite on the Kaapvaal craton in South Africa are presented here in combination with their trace element compositions, garnet Fe3+ contents and δ18O values.The studied Bellsbank eclogite xenoliths have geochemical compositions that indicate oceanic crustal protoliths, with bulk Al2O3 from 15 to 27 wt.%, Eu anomalies from 0.8 to 2.6 and, significantly, garnet δ18O values from +2.7 to +6.2‰. Garnet Fe3+/ΣFe contents yield logfO2(ΔFMQ) values between −4.0 and −1.2 for a depth range of 110–180 km, recording strong redox heterogeneity of the eclogite component within the Archean Kaapvaal mantle lithosphere. Reconstructed bulk eclogite MgO contents correlate negatively with fO2, suggesting that the redox compositions are related to magmatic differentiation during oceanic crust formation, excluding secondary metasomatic overprints. These data may thus emphasize that Archean basaltic oceanic crust had a similarly variable redox composition to modern MORB-type crust.Reconstructed bulk δ44/40Ca values for the Bellsbank eclogites range from +0.28 to +1.56‰. Although some of the xenoliths have δ44/40Ca values that overlap with the average mantle composition and modern MORB (+0.94 ± 0.1 and +0.83 ± 0.05‰), half of our dataset shows excursions to more extreme Ca isotopic compositions. Both higher and lower δ44/40Ca relative to mantle compositions are recorded by the eclogites, with a general negative correlation with δ18O suggestive of seawater-alteration of oceanic crust. The combined low δ44/40Ca (+0.28‰) and δ18O (+3.4‰) measured for one eclogite xenolith may record a subtle imprint by carbonate-rich mantle melts, which are known to contain isotopically light calcium contributed by recycled sediments. In contrast, the high δ44/40Ca of up to +1.56‰ for some eclogite xenoliths, coupled with strong LREE depletion, can be explained by calcium isotope fractionation during partial melting.The protracted history of recycled oceanic crust as probed by cratonic mantle eclogites is recorded by their highly variable δ44/40Ca–δ18O–fO2 signatures. Whereas some of this heterogeneity can be linked to processes that operated on the Archean ocean floor such as seawater-alteration of basaltic crust, other sources of compositional variability are introduced by loss and addition of melts during subduction recycling and mantle residence. The observed δ44/40Ca complexity of ancient recycled oceanic crust components at the scale of a single mantle-derived eclogite xenolith suite implies that mantle plume sourced intraplate magmas should reveal similarly strong calcium isotope variations contributed by apparently essential recycled crust components – as observed in the global oceanic island basalt record.

The Neoarchean Conglomerate-Hosted Gold of the West Pilbara Craton, Western Australia

Abstract Recently discovered Au in boulder conglomerate between the Mesoarchean West Pilbara superterrane basement and the overlying volcano-sedimentary stratigraphy of the Neoarchean Fortescue Group in Western Australia has renewed comparisons with the Witwatersrand conglomerate Au deposits in South Africa. As such, this has reignited the question of the Pilbara and Kaapvaal cratons being linked as part of the postulated Vaalbara continent during the Archean. However, little is known about the origin of the Pilbara conglomerate Au and its host conglomerates, as they are hitherto unstudied, and their formation and/or source is uncertain. Here we present a detailed study on the textures, composition, and sedimentology of one newly discovered Pilbara conglomerate Au deposit at the base of the Neoarchean Fortescue Group in the northwestern Pilbara craton. The Pilbara conglomerate Au occurrences are characteristically Ag-bearing but Hg-poor polycrystalline discoid masses that are overgrown by Au-poor chloritic halos, which are further enveloped by a hydrothermal alteration halo of disseminated Au within chlorite. Both the discoids and the auriferous chlorite halo are Ag bearing, with up to ~9 wt % Ag, consistent with a hydrothermal (orogenic) origin. The discoids do not display any physical or chemical evidence for sedimentary transport; thus, their formation (placer versus hydrothermal) remains unclear. However, the position of the Au in the conglomerate, limited to the basal section of the conglomerate, is difficult to account for in a purely hydrothermal deposit model. We argue the Pilbara conglomerate Au represents a modified placer deposit from a primary orogenic Au source, with surface evidence for sedimentation removed by partial dissolution during later hydrothermal alteration in the host conglomerate and the crystalline basement. While the basal Fortescue Group conglomerate Au shares commonalities with the time equivalent (&amp;gt;~2.7 Ga) Venterspost Conglomerate Formation, which overlies the Witwatersrand Supergroup, inconsistencies remain, with different Au chemistries and tectonic, magmatic, sedimentary, and metamorphic-metallogenic histories of the Pilbara and Kaapvaal cratons prior to deposition of the &amp;gt;2.7 Ga conglomerate sequences. This collectively indicates the drivers of Au metallogenesis and ultimate Au deposition in conglomerate facies were fundamentally different in the Pilbara and Kaapvaal cratons.

Diamondiferous lamproites of the Luangwa Rift in central Africa and links to remobilized cratonic lithosphere

Mesozoic diamondiferous lamproite pipes occur along the Kapamba River within the Luangwa Valley of eastern Zambia, which is a ca. 300–200 Ma old Karoo-age precursor branch to the East African Rift System. The Luangwa Rift developed above a reactivated mega-shear zone that cuts through the Proterozoic Irumide Belt between the Congo-Tanzania-Kalahari cratons and thus it provides a rare snapshot of early-stage cratonic rift evolution.The primary mineralogy of the fresh volcanic rocks suggests that they represent a continuum between primitive olivine lamproites and slightly more evolved olivine-leucite lamproites. Mineral compositions and evolutionary trends, such as the strong Al-depletion at Ti-F enrichment in groundmass phlogopite and potassic richterite, resemble those of classic lamproite provinces in circum-cratonic settings (e.g., the Leucite Hills of Wyoming and the West Kimberley field in Australia). However, there are some similarities to orangeites from the Kaapvaal craton (formerly Group-2 kimberlites), type kamafugites from the East African Rift, and ultramafic lamprophyres from a key region of the rifted North Atlantic craton, which implies a complex interplay between source-forming and tectonic processes during Karoo-age lamproite magma formation beneath south-central Africa.The bulk compositions of the Kapamba volcanic rocks fall within the range of ‘cratonic’ low-silica lamproites, but there is overlap with orangeites, in particular with the more evolved leucite- and sanidine-bearing orangeite varieties. Modelling of the process by which most of the original leucite was transformed into analcime suggests that the primitive alkaline magmas at Kapamba contained ~6–9 wt% K2O and had high K2O/Na2O ratios between ~1.6–6.2 at >10 wt% MgO – confirming the ultrapotassic nature of the mantle-derived magmatism beneath the Luangwa Rift. The virtually CO2-free, H2O-F-rich Kapamba lamproites present an extension of the geochemical continuum displayed by the members of the CO2-H2O-rich kamafugite/ultramafic lamprophyre group. Hence, we suggest that the Kapamba lamproites and the type kamafugites, located within separate branches of the East African Rift System, represent melting products of similar K-metasomatized cratonic mantle domains, but their formation occurred under contrasting volatile conditions at different stages during rift development (i.e., incipient versus slightly more advanced rifting).Temperature estimates for peridotite-derived olivine xenocrysts from the Kapamba lamproites suggest that the Luangwa Valley is an aborted cratonic rift that retained a relatively cold (≤42 mW/m2) lithospheric mantle root down to ~180–200 km depth during the Mesozoic. Olivine major and trace element compositions support the presence of an Archean mantle root (up to 92.4 mol% forsterite contents) that is progressively metasomatized toward its base (e.g., increasing Ti-Cu contents with depth). For south-central Africa, it appears that significant volumes of Archean cratonic mantle domains ‘survived’ beneath strongly deformed and granite-intruded Proterozoic terranes, which suggests that the continental crust is more strongly impacted during collisional or rift tectonics than the ‘stabilizing’ mantle lithosphere.

Deformation characteristics, kinematic analysis, and formation ages of gneissose Palala granite in the Palala Shear Zone, southern boundary of the Central Zone, Limpopo Belt, South Africa

The Palala Shear Zone (PSZ) is a c. 13 km wide part of a vertical, crustal-scale lineament that forms the southern boundary of the polymetamorphic high grade Central Zone of the Limpopo Belt in Southern Africa. We have studied a set of strongly sheared samples of Palala granite, taken at the southern edge of the shear zone at the Palala River transect, in order to determine the deformation patterns and evolution history of the PSZ as well as the age and petrogenesis of the granite. We studied the characteristics of macro- and microscopic deformations, analyzed the finite strain and quartz electron backscatter diffraction (EBSD) fabrics, and estimated the rheological parameters of these mylonitic gneisses. We also carried out zircon U–Pb dating and geochemical analysis. The former yielded a weighted mean 207Pb/206Pb age of 2053.5 ± 9.9 Ma which is within error identical to the age of the Bushveld Igneous Complex (BIC). The Palala granite is an alkaline A-type ferroan granite very similar in major- and trace element chemistry to the voluminous and well-studied Nebo Granite, considered to be a final differentiation product of the BIC magma. The deformed samples have uniform subhorizontal lineation and exhibit steady-state microstructures. The quartz CPO's in a non-coaxial deformation regime are promoted by pervasive dynamic recrystallization with a dominant prismatic <a> slip and rhomb <a> slip system. The main high-grade dextral shearing along the PSZ in the study area is associated with this high-medium temperature deformation at 500–600 °C. The strain measurement indicates that the strain types of all these SL-type and L = S-type tectonites were a flattening strain within a steady-state simple shear-dominant ductile deformation. Rheological parameter estimations suggest differential stress within the range of 15.67–17.50 MPa with the paleo-strain rate in a relatively high range of 3.97 × 10−12 to 1.06 × 10−13 S−1. Together with published research, these data impose a constraint on the initiating of the transpression stage of a Paleoproterozoic intracontinental orogenic event of the Limpopo Belt. The main ductile deformation was the product of an NNW-SSE directed shortening that produced flattening strain and horizontal lineations along dextral sense shear zones, and resulted from NNW-SSE compression of the area between the Zimbabwe and Kaapvaal cratons. This high-level ductile deformation and mylonitization occurred after the emplacement of the Palala Granite at 2.05 Ga, and is thought to have taken place at medium crustal levels under upper greenschist to low amphibolite facies conditions. A late low-temperature deformation phase might be related to low-temperature basal <a> slip which is identified by our EBSD analysis.

Siderophile and chalcophile elements in spinels, sulphides and native Ni in strongly metasomatised xenoliths from the Bultfontein kimberlite (South Africa)

The metasomatised continental mantle may play a key role in the generation of some ore deposits, in particular mineral systems enriched in platinum-group elements (PGE) and Au. The cratonic lithosphere is the longest-lived potential source for these elements, but the processes that facilitate their pre-concentration in the mantle and their later remobilisation to the crust are not yet well-established. Here, we report new results on the petrography, major-element, and siderophile- and chalcophile-element composition of native Ni, base metal sulphides (BMS), and spinels in a suite of well-characterised, highly metasomatised and weakly serpentinised peridotite xenoliths from the Bultfontein kimberlite in the Kaapvaal Craton, and integrate these data with published analyses. Pentlandite in polymict breccias (failed kimberlite intrusions at mantle depth) has lower trace-element contents (e.g., median total PGE 0.72 ppm) than pentlandite in phlogopite peridotites and Mica-Amphibole-Rutile-Ilmenite-Diopside (MARID) rocks (median 1.6 ppm). Spinel is an insignificant host for all elements except Zn, and BMS and native Ni account for typically <25% of the bulk-rock PGE and Au. High bulk-rock Te/S suggest a role for PGE-bearing tellurides, which, along with other compounds of metasomatic origin, may host the missing As, Ag, Cd, Sb, Te and, in part, Bi that are unaccounted for by the main assemblage.The close spatial relationship between BMS and metasomatic minerals (e.g., phlogopite, ilmenite) indicates that the lithospheric mantle beneath Bultfontein was resulphidised by metasomatism after initial melt depletion during stabilisation of the cratonic lithosphere. Newly-formed BMS are markedly PGE-poor, as total PGE contents are <4.2 ppm in pentlandite from seven samples, compared to >26 ppm in BMS in other peridotite xenoliths from the Kaapvaal craton. This represents a strong dilution of the original PGE abundances at the mineral scale, perhaps starting from precursor PGE alloy and small volumes of residual BMS. The latter may have been the precursor to native Ni, which occurs in an unusual Ni-enriched zone in a harzburgite and displays strongly variable, but overall high PGE abundances (up to 81 ppm). In strongly metasomatised peridotites, Au is enriched relative to Pd, and was probably added along with S. A combination of net introduction of S, Au +/− PGE from the asthenosphere and intra-lithospheric redistribution, in part sourced from subducted materials, during metasomatic events may have led to sulphide precipitation at ~80–120 km beneath Bultfontein. This process locally enhanced the metallogenic fertility of this lithospheric reservoir. Further mobilisation of the metal budget stored in these S-rich domains and upwards transport into the crust may require interaction with sulphide-undersaturated melts that can dissolve sulphides along with the metals they store.

Alluvial fan to shallow marine sedimentation record in the ~3.0 Ga Keonjhar Quartzite, Singhbhum Craton, India: An example of Phanerozoic style passive margin sedimentation from the Mesoarchean

The arenite-dominant Mesoarchean Keonjhar Quartzite (>700 m) succession unconformably overlies the granitoid-greenstone core of the Singhbhum craton in the north and west of the Keonjhar town in eastern India. The Keonjhar Quartzite is characterized by eleven lithofacies. The lower part of the succession represents proximal subaerial fan association dominated by cohesive and cohesionless mass-flow conglomerates deposited in a falling stage to lowstand systems tracts (FSST-LST). The channelized conglomerates are likely to be incised valley fills (IVF) from the FSST. The differentiated mass-flow deposits interbedded with tractional deposits such as trough cross-stratified sandstone with ubiquitous evidence of wave-reworking represent subaqueous delta front setting. The upper 3/4th of the succession is dominated by mature wavy bedded arenites and is arranged in aggradational stacking pattern representing TST to early stage of HST of a tectonically driven sea level rise cycle. The Keonjhar Quartzite is a rare example of well preserved record of stable siliclastic shelf development during the Mesoarchean time. The arenite-dominated Keonjhar Quartzite is comparable to only a few well studied examples of such Mesoarchean stable siliciclastic shelf sedimentation, for example, the arenite-dominated units of the Mozaan Group of the Pongola Supergroup and its correlatable Westrand and Centralrand Groups of the Witwatersrand Supergroup in the Kaapvaal craton. The presence of thick mature arenite and wave-tide reworking implies existence of Mesoarchean stable shelf depositional setting similar to the modern day passive continental margins at least in the Singhbhum and in the Kaapvaal cratons.